The uncertainty in assessing the numerous atmospheric pollutants transported via wind from arid and semi-arid regions is affecting the glacial ecosystem. In our study area due to the complexity of the system, a promin...The uncertainty in assessing the numerous atmospheric pollutants transported via wind from arid and semi-arid regions is affecting the glacial ecosystem. In our study area due to the complexity of the system, a prominent seasonal difference noticed among major ions(Ca^(2+), Mg^(2+), SO_4^(2-), and NO_3^-). There is a need for understanding the ions cycling as a whole and the directionality of the feedback loops in the system. Therefore, we provide an appraisal of our current hypothesis for seasonal difference in major ion concentration from snow samples for two corresponding years(2013 and 2015) at Dokriani Glacier. A systematic study of chemical compositionsin the shallow snow pit from Dokriani Glacier was undertaken for the pre-monsoon season to understand the cycling of major ions from atmosphere to solute acquisition process. The intimating connections of ions cycling in snow and its temporal behavior was observed and analyzed through various statistical tests. Among major ions, the SO_4^(2-)has the highest concentration among anions on an average considered as 14.21% in 2013 and 29.46% in 2015. On the other side Ca^(2+) is the dominant cation contributing 28.22% in 2013 and 15.3% in 2015 on average. The average ratio of Na+/Cl-was higher in 2013 whereas lower in 2015. The backward trajectory analysis suggests the possible sources of the ions transported from Central Asia through the Western Disturbance(WD) as a prominent source of winter precipitation mainly in the Central Himalaya. Ionicconcentration of Ca^(2+) in cations was highly dominated while in anion SO_4^(2-)played the major role. Factor analysis and correlation matrix suggested that, the precipitation chemistry is mostly influenced by anthropogenic, crustal, and sea salt sources over the studied region. The elemental cycling through ocean, atmosphere and biosphere opens up new ways to understand the geochemical processes operating at the glacierized catchments of the Himalaya. Moreover, increasing the field-based studies in the coming decades would also have the certain advantage in overcoming the conceptual and computational geochemical modelling difficulties.展开更多
A new analytical solution for ground surface settlement induced by deep excavation is proposed based on the elastic half space Melan’s solution,and the analytical model is related to the physical and mechanical prope...A new analytical solution for ground surface settlement induced by deep excavation is proposed based on the elastic half space Melan’s solution,and the analytical model is related to the physical and mechanical properties of soil with the loading and unloading action during excavation process.The change law of earth pressure of the normal consolidation soil after the foundation pit excavation was analyzed,and elastic displacement calculation methods of analytic solution were further established given the influence of excavation and unloading.According to the change of stress state in the excavation process of foundation pit,the planar mechanical analysis model of the foundation excavation problem was established.By combining this model with the physical equations and geometric equations of plane strain problem with consideration of the loading and unloading modulus of soil,constitutive equation of the plane strain problem was also established.The loading and unloading modulus formula was obtained by using the parameter calculation method in Duncan-Chang curve model.The constitutive equation obtained from the model was used to calculate the soil stress state of each point to determine its loading and unloading modulus.Finally,the foundation pit displacement change after excavation was calculated,and thus the soil pressure distribution after retaining structure deformation.The theoretical results calculated by making corresponding programs were applied to engineering practice.By comparing the conventional calculation results with monitoring results,the practicability and feasibility of the calculation model were verified,which should provide a theoretical basis for similar projects.展开更多
A high-frequency and precise ultrasonic sounder was used to monitor precipitated/deposited and drift snow events over a 3-year period(17 January 2005 to 4 January 2008) at the Eagle automatic weather station site,inla...A high-frequency and precise ultrasonic sounder was used to monitor precipitated/deposited and drift snow events over a 3-year period(17 January 2005 to 4 January 2008) at the Eagle automatic weather station site,inland Antarctica.Ion species and oxygen isotope ratios were also generated from a snow pit below the sensor.These accumulation and snowdrift events were used to examine the synchronism with seasonal variations of δ^(18)O and ion species,providing an opportunity to assess the snowdrift effect in typical Antarctic inland conditions.There were up to 1-year differences for this 3-year-long snow pit between the traditional dating method and ultrasonic records.This difference implies that in areas with low accumulation or high wind,the snowdrift effect can induce abnormal disturbances on snow deposition.The snowdrift effect should be seriously taken into account for high-resolution dating of ice cores and estimation of surface mass balance,especially when the morphology of most Antarctic inland areas is similar to that of the Eagle site.展开更多
In this paper, we demonstrated a simple method to create either a hydrophilic or hydrophobic surface. With femtosecond laser irradiation at different laser parameters, the water contact angle (WCA) on polystyrene’s s...In this paper, we demonstrated a simple method to create either a hydrophilic or hydrophobic surface. With femtosecond laser irradiation at different laser parameters, the water contact angle (WCA) on polystyrene’s surface can be modified to either 12.7° or 156.2° from its original WCA of 88.2°. With properly spaced micro-pits created, the surface became hydrophilic probably due to the spread of the water droplets into the micro-pits. While with properly spaced micro-grooves created, the surface became rough and more hydrophobic. We investigated the effect of laser parameters on WCAs and analyzed the laser-treated surface roughness, profiles and chemical bonds by surface profilometer, scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS). For the laser-treated surface with low roughness, the polar (such as C—O, C=O, and O—C=O bonds) and non-polar (such as C—C or C—H bonds) groups were found to be responsible for the wettability changes. While for a rough surface, the surface roughness or the surface topography structure played a more significant role in the changes of the surface WCA. The mechanisms involved in the laser surface wettability modification process were discussed.展开更多
A correlation study between the observed surface morphology using high-resolution scanning electron microscopy(HRSEM) and the observed structural imperfections using transmission electron microscopy(TEM) has been cond...A correlation study between the observed surface morphology using high-resolution scanning electron microscopy(HRSEM) and the observed structural imperfections using transmission electron microscopy(TEM) has been conducted for a-plane Ga N. There are three different sized asymmetric surface pits: large pit of 500 nm–2 ?m in side length, medium pit of 50 nm in side length, and small pit with side lengths of less than 5 nm, which originate from incomplete island coalescence, screw dislocation, and partial dislocation(PD), respectively. Both screw dislocation and PD can produce pits on the free surface because they have a perpendicular line tension to the surface, which must remain in balance with the surface tension. The two types of dislocation lead to distinctive pit sizes because the PD has a smaller Burgers vector component along the dislocation line than the pure screw dislocation. A pit that is produced in the island-coalescing process is much larger than those caused by dislocations because island coalescence is a kinetic process that involves large-scale mass transportation, whereas the dislocation mediates the surface in the local area. These three types of surface pits sometimes interact with one another in space. The coalescence of the island determines the surface morphology at large scales, whereas the defects affect the details.展开更多
基金funded by the Department of Science and Technology,Government of India,New Delhi
文摘The uncertainty in assessing the numerous atmospheric pollutants transported via wind from arid and semi-arid regions is affecting the glacial ecosystem. In our study area due to the complexity of the system, a prominent seasonal difference noticed among major ions(Ca^(2+), Mg^(2+), SO_4^(2-), and NO_3^-). There is a need for understanding the ions cycling as a whole and the directionality of the feedback loops in the system. Therefore, we provide an appraisal of our current hypothesis for seasonal difference in major ion concentration from snow samples for two corresponding years(2013 and 2015) at Dokriani Glacier. A systematic study of chemical compositionsin the shallow snow pit from Dokriani Glacier was undertaken for the pre-monsoon season to understand the cycling of major ions from atmosphere to solute acquisition process. The intimating connections of ions cycling in snow and its temporal behavior was observed and analyzed through various statistical tests. Among major ions, the SO_4^(2-)has the highest concentration among anions on an average considered as 14.21% in 2013 and 29.46% in 2015. On the other side Ca^(2+) is the dominant cation contributing 28.22% in 2013 and 15.3% in 2015 on average. The average ratio of Na+/Cl-was higher in 2013 whereas lower in 2015. The backward trajectory analysis suggests the possible sources of the ions transported from Central Asia through the Western Disturbance(WD) as a prominent source of winter precipitation mainly in the Central Himalaya. Ionicconcentration of Ca^(2+) in cations was highly dominated while in anion SO_4^(2-)played the major role. Factor analysis and correlation matrix suggested that, the precipitation chemistry is mostly influenced by anthropogenic, crustal, and sea salt sources over the studied region. The elemental cycling through ocean, atmosphere and biosphere opens up new ways to understand the geochemical processes operating at the glacierized catchments of the Himalaya. Moreover, increasing the field-based studies in the coming decades would also have the certain advantage in overcoming the conceptual and computational geochemical modelling difficulties.
基金Project(41672290)supported by the National Natural Science Foundation of ChinaProject(2016J01189)supported by the Natural Science foundation of Fujian Province,China
文摘A new analytical solution for ground surface settlement induced by deep excavation is proposed based on the elastic half space Melan’s solution,and the analytical model is related to the physical and mechanical properties of soil with the loading and unloading action during excavation process.The change law of earth pressure of the normal consolidation soil after the foundation pit excavation was analyzed,and elastic displacement calculation methods of analytic solution were further established given the influence of excavation and unloading.According to the change of stress state in the excavation process of foundation pit,the planar mechanical analysis model of the foundation excavation problem was established.By combining this model with the physical equations and geometric equations of plane strain problem with consideration of the loading and unloading modulus of soil,constitutive equation of the plane strain problem was also established.The loading and unloading modulus formula was obtained by using the parameter calculation method in Duncan-Chang curve model.The constitutive equation obtained from the model was used to calculate the soil stress state of each point to determine its loading and unloading modulus.Finally,the foundation pit displacement change after excavation was calculated,and thus the soil pressure distribution after retaining structure deformation.The theoretical results calculated by making corresponding programs were applied to engineering practice.By comparing the conventional calculation results with monitoring results,the practicability and feasibility of the calculation model were verified,which should provide a theoretical basis for similar projects.
基金supported by the National Basic Research Program of China(Grant No. 2013CBA01804)the National Natural Science Foundation of China(Grant Nos.41425003 & 41601070)+1 种基金the State Oceanic Administration of the People s Republic of China Project on Climate in Polar Regions(Grant No. CHINARE2016-2020)Climate Change Estimation Program by China Meteorological Administration(Grant No.CCSF201332)
文摘A high-frequency and precise ultrasonic sounder was used to monitor precipitated/deposited and drift snow events over a 3-year period(17 January 2005 to 4 January 2008) at the Eagle automatic weather station site,inland Antarctica.Ion species and oxygen isotope ratios were also generated from a snow pit below the sensor.These accumulation and snowdrift events were used to examine the synchronism with seasonal variations of δ^(18)O and ion species,providing an opportunity to assess the snowdrift effect in typical Antarctic inland conditions.There were up to 1-year differences for this 3-year-long snow pit between the traditional dating method and ultrasonic records.This difference implies that in areas with low accumulation or high wind,the snowdrift effect can induce abnormal disturbances on snow deposition.The snowdrift effect should be seriously taken into account for high-resolution dating of ice cores and estimation of surface mass balance,especially when the morphology of most Antarctic inland areas is similar to that of the Eagle site.
文摘In this paper, we demonstrated a simple method to create either a hydrophilic or hydrophobic surface. With femtosecond laser irradiation at different laser parameters, the water contact angle (WCA) on polystyrene’s surface can be modified to either 12.7° or 156.2° from its original WCA of 88.2°. With properly spaced micro-pits created, the surface became hydrophilic probably due to the spread of the water droplets into the micro-pits. While with properly spaced micro-grooves created, the surface became rough and more hydrophobic. We investigated the effect of laser parameters on WCAs and analyzed the laser-treated surface roughness, profiles and chemical bonds by surface profilometer, scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS). For the laser-treated surface with low roughness, the polar (such as C—O, C=O, and O—C=O bonds) and non-polar (such as C—C or C—H bonds) groups were found to be responsible for the wettability changes. While for a rough surface, the surface roughness or the surface topography structure played a more significant role in the changes of the surface WCA. The mechanisms involved in the laser surface wettability modification process were discussed.
基金supported by the National Natural Science Foundation of China(Grant Nos.11204009&61204011)Beijing Municipal Natural Science Foundation(Grant No.4142005)
文摘A correlation study between the observed surface morphology using high-resolution scanning electron microscopy(HRSEM) and the observed structural imperfections using transmission electron microscopy(TEM) has been conducted for a-plane Ga N. There are three different sized asymmetric surface pits: large pit of 500 nm–2 ?m in side length, medium pit of 50 nm in side length, and small pit with side lengths of less than 5 nm, which originate from incomplete island coalescence, screw dislocation, and partial dislocation(PD), respectively. Both screw dislocation and PD can produce pits on the free surface because they have a perpendicular line tension to the surface, which must remain in balance with the surface tension. The two types of dislocation lead to distinctive pit sizes because the PD has a smaller Burgers vector component along the dislocation line than the pure screw dislocation. A pit that is produced in the island-coalescing process is much larger than those caused by dislocations because island coalescence is a kinetic process that involves large-scale mass transportation, whereas the dislocation mediates the surface in the local area. These three types of surface pits sometimes interact with one another in space. The coalescence of the island determines the surface morphology at large scales, whereas the defects affect the details.
