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Bi_(0.5)Sb_(1.5)Te_(3)块体热电材料的高气压烧结与热电性能研究
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作者 庞超 李武 +3 位作者 仲德晗 陈上峰 李美玲 孙乃坤 《沈阳理工大学学报》 CAS 2021年第5期57-60,78,共5页
利用自制高压炉烧结制备Bi_(0.5)Sb_(1.5)Te_(3)块料,采用光学显微镜研究不同制备条件对Bi_(0.5)Sb_(1.5)Te_(3)样品形貌的影响,并采用X射线衍射仪、扫描电子显微镜、能谱仪和Seebeck系数电导率测试仪分析Bi_(0.5)Sb_(1.5)Te_(3)块体材... 利用自制高压炉烧结制备Bi_(0.5)Sb_(1.5)Te_(3)块料,采用光学显微镜研究不同制备条件对Bi_(0.5)Sb_(1.5)Te_(3)样品形貌的影响,并采用X射线衍射仪、扫描电子显微镜、能谱仪和Seebeck系数电导率测试仪分析Bi_(0.5)Sb_(1.5)Te_(3)块体材料的成分、元素含量和热电参数。X射线衍射结果表明:少量的氢原子和氮原子被引入到Bi_(0.5)Sb_(1.5)Te_(3)晶格中;在550℃、40MPa、氮气条件下制备的Bi_(0.5)Sb_(1.5)Te_(3)块体较好(直径为12.6mm,厚度为1.5mm),氮化后的Bi_(0.5)Sb_(1.5)Te_(3)在25℃时的功率因子为2379.5μW·m^(-1)·K^(-2)。 展开更多
关键词 Bi_(0.5)Sb_(1.5)Te_(3)块体 热电性能 高温高压 块体烧结
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粉末冶金法制备高铌TiAl基合金的表征(英文)
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作者 孙宏飞 李学问 +1 位作者 冯杰 房文斌 《中国有色金属学会会刊:英文版》 CSCD 2012年第S2期491-495,共5页
利用机械球磨法制备了名义成分为Ti45Al10Nb(摩尔分数,%)的复合粉末,采用真空热压烧结工艺对粉末进行固结,利用OM、XRD、SEM、EDX对球磨12h的粉末及烧结块体材料进行表征。结果表明,所得Ti/Al/Nb复合粉末的成分均匀,晶粒细小。烧结后所... 利用机械球磨法制备了名义成分为Ti45Al10Nb(摩尔分数,%)的复合粉末,采用真空热压烧结工艺对粉末进行固结,利用OM、XRD、SEM、EDX对球磨12h的粉末及烧结块体材料进行表征。结果表明,所得Ti/Al/Nb复合粉末的成分均匀,晶粒细小。烧结后所得合金的显微组织由细小等轴晶和均匀分散其中的大的纯Nb颗粒组成。增加10%(摩尔分数)的Nb元素,TiAl基合金的室温强度及塑性有显著提高,屈服强度和断裂强度分别为842MPa和1314MPa,室温压缩率达到12.4%。 展开更多
关键词 TIAL基合金 粉末冶金 颗粒尺寸 复合材料 烧结块体
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The influence of agglomerates on the densification and microstructural evolution in sintering of a multi-particle system 被引量:2
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作者 WANG Chao CHEN ShaoHua 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2012年第6期1051-1058,共8页
Effects of agglomerates on the densification behavior and microstructural evolution during solid-state sintering of a cube of copper particles have been studied with discrete element method (DEM).It is found that the ... Effects of agglomerates on the densification behavior and microstructural evolution during solid-state sintering of a cube of copper particles have been studied with discrete element method (DEM).It is found that the densification of the sintering system decreases as the volume fraction of agglomerates increases.At a given volume fraction of agglomerates,the smaller the size of agglomerates,the poorer the densification and more inhomogeneous the compact is.The morphology and distribution of agglomerates have negligible effects on the densification,especially for the case with a low volume fraction of agglomerates.Agglomerates with a smaller average coordination number would have more restriction on the densification of sintering bodies.To our best knowledge,it is the first time to study the effect of agglomerates on sintering behavior using DEM.This study should be useful for further investigations of the effect of various inhomogeneities of microstructure on the complex sintering process by DEM. 展开更多
关键词 solid-state sintering discrete element method AGGLOMERATE microstructure evolution
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