The influence of calcination temperature on TiO2 nanotubes' catalysis for TiO2/UV/03 was investigated. TiO2 nanotubes (TNTs) were prepared via the sol-gel method and calcined at 300--700 ℃, which were labeled as T...The influence of calcination temperature on TiO2 nanotubes' catalysis for TiO2/UV/03 was investigated. TiO2 nanotubes (TNTs) were prepared via the sol-gel method and calcined at 300--700 ℃, which were labeled as TNTs-300, TNTs-400, TNTs-500, TNTs-600 and TNTs-700, respectively. TNTs were characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). It is found that TNTs calcined at 400 ℃ showed the best thermal stability. When the calcination temperature increased from 400 ℃ to 700 ℃, the special structure of tubes was destroyed and gradually converted into nanorods and/or particles. The transformation from anatase to rutile occurred at 600 ℃, and the rutile phase was enhanced when the calcination temperature was increased to over 600 ℃. The calcina- tion temperature's influence on TNTs' adsorption activity for for TiO2/UV/O3 was investigated in landfill leachate solution chemical oxygen demand (COD) and catalytic activity In landfill leachate solution, the adsorption activity of COD decreased in the reduced order of TNTs-300, TNTs-400, TNTs-500, TNTs-600 and TNTs-700. In photocatalytic ozonation, TNTs-400 showed the best catalytic activity while TNTs-700 exhibited the worst. In other three processes, the COD removal of TNTs-300/UV/O3 was higher than those of TNTs-500/UV/O3 and TNTs-600/UV/O3 in the first 20 rain, and then became close to those of the latter two in the following 40 rain. Compared with TNTs-300 and TNTs- 400, TNTs-600 had the best anti-fouling activity, while TNTs-500 and TNTs-700 had lower anti-fouling activity than the former three. In photocatalytic ozonation, the calcination temperature of 400 ℃ was appropriate when TNTs were obtained at the synthesis temperature of 105 ℃.展开更多
This paper mainly discusses the protection of water resource environment in Three Gorge Water Reservoir, a systematic investigation and analysis of the landfill leachate's polluting components, hazardous and changing...This paper mainly discusses the protection of water resource environment in Three Gorge Water Reservoir, a systematic investigation and analysis of the landfill leachate's polluting components, hazardous and changing rule in landfill leachate from hinterland landfill located in the surrounding area have been carried out, and proposed the countermeasures for disposition the leachate furtherly.展开更多
One of the most important issues regarding the design of engineered landfill is landfill leachate that is produced when water passes through the waste. Landfill Leachate comprises a mass of different organic and inorg...One of the most important issues regarding the design of engineered landfill is landfill leachate that is produced when water passes through the waste. Landfill Leachate comprises a mass of different organic and inorganic components which can be dissolved or suspended. Regardless of the nature of the components, it poses a potential pollution on local land and surface waters. The present work was undertaken to assess, isolate, identify and characterize the hydrocarbon degrading bacteria associated with environmental samples collected from discharge of Ain Temouchent, Algeria. The samples (landfill leachate) were chemically and microbiologically analyzed using standard techniques. These organisms were further studied to determine the level of biodegrading activities on hydrocarbons as the single carbon source using enrichment medium under different physical and chemical parameters (pH, temperature, NaCI and tolerance of crude oil...), The identification of seven strains isolated named as Pseudomonas aeruginosa, Pseudomonas fluorescens, Pseudornonas sp., Staphylococcus aureus, Staphylococcus xylosus, Staphylococcus hominis and Staphylococcus warnerii. These strains growth on a neutral medium and temperature between 30 ℃ and 37 ℃, 5 at 6% of NaCI concentration, and can use a concentration of 5 at 10% of crude oil as sole source of carbon.展开更多
The objectives of this study are to determine the characteristics of leachates generated from landfill lysimeters of municipal solid waste. Two lysimeters with diameter and height of 0.70 and 2.40 m, respectively, wer...The objectives of this study are to determine the characteristics of leachates generated from landfill lysimeters of municipal solid waste. Two lysimeters with diameter and height of 0.70 and 2.40 m, respectively, were prepared. The lysimeters were operated with and without leachate recirculation. The leachate produced were quantified and characterised every day for the quantity, pH and ORP (oxidation reduction potential). Meanwhile, the BOD and COD parameters were characterised every once week. Based on the data of experimental results that the lysimeter with a recirculation gave positive effects on the degradation of waste in landfills, that is the degradation process becomes faster. This is indicated by the quantity and quality of leachate generated. The lyisimeter conducted with recirculation of leachate shew the quantity of leachate generated larger than the lysimeter without recirculation. While the quality of the leachate includes pH, ORP, made it shown that the degradation process is faster. These results operations, especially for young waste. BOD and COD indicate that leachate recirculation on lysismeter suggest that leachate recirculation can be performed on landfills展开更多
基金Supported by Tianjin Science and Technology Development Plan Project (No.06YFGZSH06700)
文摘The influence of calcination temperature on TiO2 nanotubes' catalysis for TiO2/UV/03 was investigated. TiO2 nanotubes (TNTs) were prepared via the sol-gel method and calcined at 300--700 ℃, which were labeled as TNTs-300, TNTs-400, TNTs-500, TNTs-600 and TNTs-700, respectively. TNTs were characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). It is found that TNTs calcined at 400 ℃ showed the best thermal stability. When the calcination temperature increased from 400 ℃ to 700 ℃, the special structure of tubes was destroyed and gradually converted into nanorods and/or particles. The transformation from anatase to rutile occurred at 600 ℃, and the rutile phase was enhanced when the calcination temperature was increased to over 600 ℃. The calcina- tion temperature's influence on TNTs' adsorption activity for for TiO2/UV/O3 was investigated in landfill leachate solution chemical oxygen demand (COD) and catalytic activity In landfill leachate solution, the adsorption activity of COD decreased in the reduced order of TNTs-300, TNTs-400, TNTs-500, TNTs-600 and TNTs-700. In photocatalytic ozonation, TNTs-400 showed the best catalytic activity while TNTs-700 exhibited the worst. In other three processes, the COD removal of TNTs-300/UV/O3 was higher than those of TNTs-500/UV/O3 and TNTs-600/UV/O3 in the first 20 rain, and then became close to those of the latter two in the following 40 rain. Compared with TNTs-300 and TNTs- 400, TNTs-600 had the best anti-fouling activity, while TNTs-500 and TNTs-700 had lower anti-fouling activity than the former three. In photocatalytic ozonation, the calcination temperature of 400 ℃ was appropriate when TNTs were obtained at the synthesis temperature of 105 ℃.
文摘This paper mainly discusses the protection of water resource environment in Three Gorge Water Reservoir, a systematic investigation and analysis of the landfill leachate's polluting components, hazardous and changing rule in landfill leachate from hinterland landfill located in the surrounding area have been carried out, and proposed the countermeasures for disposition the leachate furtherly.
文摘One of the most important issues regarding the design of engineered landfill is landfill leachate that is produced when water passes through the waste. Landfill Leachate comprises a mass of different organic and inorganic components which can be dissolved or suspended. Regardless of the nature of the components, it poses a potential pollution on local land and surface waters. The present work was undertaken to assess, isolate, identify and characterize the hydrocarbon degrading bacteria associated with environmental samples collected from discharge of Ain Temouchent, Algeria. The samples (landfill leachate) were chemically and microbiologically analyzed using standard techniques. These organisms were further studied to determine the level of biodegrading activities on hydrocarbons as the single carbon source using enrichment medium under different physical and chemical parameters (pH, temperature, NaCI and tolerance of crude oil...), The identification of seven strains isolated named as Pseudomonas aeruginosa, Pseudomonas fluorescens, Pseudornonas sp., Staphylococcus aureus, Staphylococcus xylosus, Staphylococcus hominis and Staphylococcus warnerii. These strains growth on a neutral medium and temperature between 30 ℃ and 37 ℃, 5 at 6% of NaCI concentration, and can use a concentration of 5 at 10% of crude oil as sole source of carbon.
文摘The objectives of this study are to determine the characteristics of leachates generated from landfill lysimeters of municipal solid waste. Two lysimeters with diameter and height of 0.70 and 2.40 m, respectively, were prepared. The lysimeters were operated with and without leachate recirculation. The leachate produced were quantified and characterised every day for the quantity, pH and ORP (oxidation reduction potential). Meanwhile, the BOD and COD parameters were characterised every once week. Based on the data of experimental results that the lysimeter with a recirculation gave positive effects on the degradation of waste in landfills, that is the degradation process becomes faster. This is indicated by the quantity and quality of leachate generated. The lyisimeter conducted with recirculation of leachate shew the quantity of leachate generated larger than the lysimeter without recirculation. While the quality of the leachate includes pH, ORP, made it shown that the degradation process is faster. These results operations, especially for young waste. BOD and COD indicate that leachate recirculation on lysismeter suggest that leachate recirculation can be performed on landfills