Aim To develop a physical and mathematical model related to micropore para- meters of steady-state convective combustion of micropore propellants(MPP). Methods The micropore parameters were measured by WXT-88 mage ana...Aim To develop a physical and mathematical model related to micropore para- meters of steady-state convective combustion of micropore propellants(MPP). Methods The micropore parameters were measured by WXT-88 mage analysis apparatus and the convective combustion characteristic of MPP was measured by a large volume closed bomb, respectively. Rasults Statistical physical model of burning in the micropore and granular burning were developed. The burning rate equation of steady-state convective combustion of MPP was obtained. Conclusions This model correlates the convective burning rate with micropores para- meters for the first time,and the calculating values of convective burning rate are in agreement with test results.The model also can be used to estimate the effects of microporous parame- ters, basic mass burning rate, MPP density and pressure in combustion chamber on the convective combustion characteristics of MPP.展开更多
By substituting rock skeleton modulus expressions into Gassmann approximate fluid equation, we obtain a seismic porosity inversion equation. However, conventional rock skeleton models and their expressions are quite d...By substituting rock skeleton modulus expressions into Gassmann approximate fluid equation, we obtain a seismic porosity inversion equation. However, conventional rock skeleton models and their expressions are quite different from each other, resuling in different seismic porosity inversion equations, potentially leading to difficulties in correctly applying them and evaluating their results. In response to this, a uniform relation with two adjusting parameters suitable for all rock skeleton models is established from an analysis and comparison of various conventional rock skeleton models and their expressions including the Eshelby-Walsh, Pride, Geertsma, Nur, Keys-Xu, and Krief models. By giving the two adjusting parameters specific values, different rock skeleton models with specific physical characteristics can be generated. This allows us to select the most appropriate rock skeleton model based on geological and geophysical conditions, and to develop more wise seismic porosity inversion. As an example of using this method for hydrocarbon prediction and fluid identification, we apply this improved porosity inversion, associated with rock physical data and well log data, to the ZJ basin. Research shows that the existence of an abundant hydrocarbon reservoir is dependent on a moderate porosity range, which means we can use the results of seismic porosity inversion to identify oil reservoirs and dry or water-saturated reservoirs. The seismic inversion results are closely correspond to well log porosity curves in the ZJ area, indicating that the uniform relations and inversion methods proposed in this paper are reliable and effective.展开更多
A series of granular activated carbons (GACs) were prepared by briquetting method from Chinese coals of different ranks and their blends, with coal pitch as the binder. Pore structural parameters including BET speci...A series of granular activated carbons (GACs) were prepared by briquetting method from Chinese coals of different ranks and their blends, with coal pitch as the binder. Pore structural parameters including BET specific surface area (SBEr), total pore volume (Vr) and average pore diameter (da) were measured and cal- culated as well as process parameters such as yield of char (CY) and burn-off (B). The relationship between the pore structural parameters of the GAC from coal blend (BC-GAC) and the ones of the GACs from corresponding single coals (SC-GACs) was analyzed, in which an index, the relative error (δ), was presented to define the bias between fitted values and experimental values of these parameters of the BC-GACs. The results show that the BC-GAC keeps qualitatively the pore structural features of the SC-GACs; as concerned as the quantitative relationship, the pore structural parameters of the BC-GAC from coal blend consisting of non-caking coals can be obtained by adding proportionally the pore structural parameters of the SC-GACs with a less than 10%. Meanwhile, for the BC-GAC from coal blend containing weak caking bituminous coal, the δ increases up to 25% and the experimental pore size distribution differs greatly from the fitted one.展开更多
文摘Aim To develop a physical and mathematical model related to micropore para- meters of steady-state convective combustion of micropore propellants(MPP). Methods The micropore parameters were measured by WXT-88 mage analysis apparatus and the convective combustion characteristic of MPP was measured by a large volume closed bomb, respectively. Rasults Statistical physical model of burning in the micropore and granular burning were developed. The burning rate equation of steady-state convective combustion of MPP was obtained. Conclusions This model correlates the convective burning rate with micropores para- meters for the first time,and the calculating values of convective burning rate are in agreement with test results.The model also can be used to estimate the effects of microporous parame- ters, basic mass burning rate, MPP density and pressure in combustion chamber on the convective combustion characteristics of MPP.
基金supported by the National Nature Science Foundation of China(Grant No.41174114)Important National Science and Technology Specific Projects(Grant No.2011ZX05025-005-010)
文摘By substituting rock skeleton modulus expressions into Gassmann approximate fluid equation, we obtain a seismic porosity inversion equation. However, conventional rock skeleton models and their expressions are quite different from each other, resuling in different seismic porosity inversion equations, potentially leading to difficulties in correctly applying them and evaluating their results. In response to this, a uniform relation with two adjusting parameters suitable for all rock skeleton models is established from an analysis and comparison of various conventional rock skeleton models and their expressions including the Eshelby-Walsh, Pride, Geertsma, Nur, Keys-Xu, and Krief models. By giving the two adjusting parameters specific values, different rock skeleton models with specific physical characteristics can be generated. This allows us to select the most appropriate rock skeleton model based on geological and geophysical conditions, and to develop more wise seismic porosity inversion. As an example of using this method for hydrocarbon prediction and fluid identification, we apply this improved porosity inversion, associated with rock physical data and well log data, to the ZJ basin. Research shows that the existence of an abundant hydrocarbon reservoir is dependent on a moderate porosity range, which means we can use the results of seismic porosity inversion to identify oil reservoirs and dry or water-saturated reservoirs. The seismic inversion results are closely correspond to well log porosity curves in the ZJ area, indicating that the uniform relations and inversion methods proposed in this paper are reliable and effective.
基金financially supported by the National High-Tech Research and Development Program of China (No.2008AA05Z308)the National Natural Science Foundation of China (No.20776150)
文摘A series of granular activated carbons (GACs) were prepared by briquetting method from Chinese coals of different ranks and their blends, with coal pitch as the binder. Pore structural parameters including BET specific surface area (SBEr), total pore volume (Vr) and average pore diameter (da) were measured and cal- culated as well as process parameters such as yield of char (CY) and burn-off (B). The relationship between the pore structural parameters of the GAC from coal blend (BC-GAC) and the ones of the GACs from corresponding single coals (SC-GACs) was analyzed, in which an index, the relative error (δ), was presented to define the bias between fitted values and experimental values of these parameters of the BC-GACs. The results show that the BC-GAC keeps qualitatively the pore structural features of the SC-GACs; as concerned as the quantitative relationship, the pore structural parameters of the BC-GAC from coal blend consisting of non-caking coals can be obtained by adding proportionally the pore structural parameters of the SC-GACs with a less than 10%. Meanwhile, for the BC-GAC from coal blend containing weak caking bituminous coal, the δ increases up to 25% and the experimental pore size distribution differs greatly from the fitted one.