Local fluid flow（LFF） at the mesoscopic scale is the main dissipation mechanism of seismic waves in heterogeneous porous media within the seismic frequency band.LFF is easily influenced by the structure and boundary...Local fluid flow（LFF） at the mesoscopic scale is the main dissipation mechanism of seismic waves in heterogeneous porous media within the seismic frequency band.LFF is easily influenced by the structure and boundary conditions of the porous media,which leads to different behaviors of the peak frequency of attenuation.The associated transition frequency can provide detailed information about the trend of LFF;therefore,research on the transition frequency of LFF and its relationship with the peak frequency of the corresponding attenuation（i.e.,inverse of quality factor） facilitates the detailed understanding of the effect of inner structures and boundary conditions in porous media.In this study,we firstly obtain the transition frequency of fluid flux based on Biot＇s theory of poroelasticity and the fast Fourier transform algorithm in a sample containing one repeating unit cell（RUC）.We then analyze changes of these two frequencies in porous media with different porous properties.Finally,we extend our analysis to the influence of the undrained boundary condition on the transition frequency and peak frequency in porous media with multiple RUCs.This setup can facilitate the understanding of the effect from the undrained boundary condition.Results demonstrate that these two frequencies have the same trend at low water saturation,but amplitude variations differ between the frequencies as the amount of saturation increases.However,for cases of high water saturation,both the trend and the amplitude variation of these two frequencies fit well with each other.展开更多
Controlling the nucleation and growth of organic-inorganic hybrids perovskite is of key importance to improve the morphology and crystallinity of perovskite films. However, the growth mechanism of perovskite films bas...Controlling the nucleation and growth of organic-inorganic hybrids perovskite is of key importance to improve the morphology and crystallinity of perovskite films. However, the growth mechanism of perovskite films based on classical crystallization theory is not fully understood. Here, we develop a supersaturation controlled strategy(SCS) to balance the nucleation and crystal growth speeds. By this strategy, we are able to find an ideal supersaturation region to realize a balance of nucleation and crystal growth, which yields highly crystallized perovskite films with micrometer-scale grains. Besides, we provide a thoughtful analysis of nucleation and growth based on the fabrication of the perovskite films. As a result, the highest photovoltaic power conversion efficiencies(PCE) of 19.70% and 20.31% are obtained for the planar and the meso-superstructured devices, respectively. This strategy sheds some light for understanding the film growth mechanism of high quality perovskite film, and it provides a facile strategy to fabricate high efficiency perovskite solar cells.展开更多
基金supported by National Natural Science Foundation of China(Grant No.41374116)the Fundamental Research Funds for Central Universities(Grant No.2014B39014)
文摘Local fluid flow（LFF） at the mesoscopic scale is the main dissipation mechanism of seismic waves in heterogeneous porous media within the seismic frequency band.LFF is easily influenced by the structure and boundary conditions of the porous media,which leads to different behaviors of the peak frequency of attenuation.The associated transition frequency can provide detailed information about the trend of LFF;therefore,research on the transition frequency of LFF and its relationship with the peak frequency of the corresponding attenuation（i.e.,inverse of quality factor） facilitates the detailed understanding of the effect of inner structures and boundary conditions in porous media.In this study,we firstly obtain the transition frequency of fluid flux based on Biot＇s theory of poroelasticity and the fast Fourier transform algorithm in a sample containing one repeating unit cell（RUC）.We then analyze changes of these two frequencies in porous media with different porous properties.Finally,we extend our analysis to the influence of the undrained boundary condition on the transition frequency and peak frequency in porous media with multiple RUCs.This setup can facilitate the understanding of the effect from the undrained boundary condition.Results demonstrate that these two frequencies have the same trend at low water saturation,but amplitude variations differ between the frequencies as the amount of saturation increases.However,for cases of high water saturation,both the trend and the amplitude variation of these two frequencies fit well with each other.
基金supported by the National Key Research and Development Program of China (2016YFA0204000)the National Natural Science Foundation of China (U1632118, 21571129)+2 种基金Shanghai Tech Start-Up Funding1000 Young Talent program,Science and Technology Commission of Shanghai Municipality (16JC1402100, 16520720700)
文摘Controlling the nucleation and growth of organic-inorganic hybrids perovskite is of key importance to improve the morphology and crystallinity of perovskite films. However, the growth mechanism of perovskite films based on classical crystallization theory is not fully understood. Here, we develop a supersaturation controlled strategy(SCS) to balance the nucleation and crystal growth speeds. By this strategy, we are able to find an ideal supersaturation region to realize a balance of nucleation and crystal growth, which yields highly crystallized perovskite films with micrometer-scale grains. Besides, we provide a thoughtful analysis of nucleation and growth based on the fabrication of the perovskite films. As a result, the highest photovoltaic power conversion efficiencies(PCE) of 19.70% and 20.31% are obtained for the planar and the meso-superstructured devices, respectively. This strategy sheds some light for understanding the film growth mechanism of high quality perovskite film, and it provides a facile strategy to fabricate high efficiency perovskite solar cells.
