A correlation equation between the UV absorption wavenumbers of 1,4-disubstituted benzenes and the excited-state substituent constant was obtained. For 80 sorts of 1,4- disubstituted benzenes, the correlation coeffici...A correlation equation between the UV absorption wavenumbers of 1,4-disubstituted benzenes and the excited-state substituent constant was obtained. For 80 sorts of 1,4- disubstituted benzenes, the correlation coefficient was 0.9805, and the standard deviation was only 672.27 cm^-1. The results imply that the excited-state substituent constant can be used productively for research on UV energy of 1,4-disubstituted benzenes. The present method provides a new avenue to study the UV absorption spectra of aromatic systems with the excited-state substituent constant, and it is helpful to understand the effect of substituent electrostatic effects on the chemical and physical properties of conjugated compounds with multiple substituents in excited state.展开更多
Based on the location of bromine substituents and conjugation matrix, a new substituent po- sition index ~X not only was defined, but also molecular shape indexes Km and electronega- tivity distance vectors Mm of diph...Based on the location of bromine substituents and conjugation matrix, a new substituent po- sition index ~X not only was defined, but also molecular shape indexes Km and electronega- tivity distance vectors Mm of diphenylamine and 209 kinds of polybrominated diphenylamine （PBDPA） molecules were calculated. Then the quantitative structure-property relationships （QSPR） among the thermodynamic properties of 210 organic pollutants and 0X, K3, M29, M36 were founded by Leaps-and-Bounds regression. Using the four structural parameters as input neurons of the artificial neural network, three satisfactory QSPR models with network structures of 4：21：1, 4：24：1, and 4：24：1 respectively, were achieved by the back-propagation algorithm. The total correlation coefficients R were 0.9999, 0.9997, and 0.9995 respectively and the standard errors S were 1.036, 1.469, and 1.510 respectively. The relative mean deviation between the predicted value and the experimental value of Sθ, AfHe and △fGθ- were 0.11%, 0.34% and 0.24% respectively, which indicated that the QSPR models had good stability and superior predictive ability. The results showed that there were good nonlinear correlations between the thermodynamic properties of PBDPAs and the four structural pa- rameters. Thus, it was concluded that the ANN models established by the new substituent position index were fully applicable to predict properties of PBDPAs.展开更多
In this paper,We give the forms of AR sequences of a tilted algebra with terms all belonging to x(A_T),or all belonging to y(A_T).The sink maps of a tilted algebra which end at the indecompos able projective modules a...In this paper,We give the forms of AR sequences of a tilted algebra with terms all belonging to x(A_T),or all belonging to y(A_T).The sink maps of a tilted algebra which end at the indecompos able projective modules and the source maps of starting at the indecomposable injective modules are also obtained.These results together with the connecting sequecnes given in [3] determine the AR quiver of the tilted algcbra,morever,this can be done directly from the AR quiver of the correspond ing hereditary algebra.展开更多
Effects of meta-substituent of 3,4＇/4,3＇/3,3＇-substituted benzylideneanilines （XBAYs） on the electrochemical reduction potentials （E（Red）） were investigated, in which 49 samples of target compounds were synth...Effects of meta-substituent of 3,4＇/4,3＇/3,3＇-substituted benzylideneanilines （XBAYs） on the electrochemical reduction potentials （E（Red）） were investigated, in which 49 samples of target compounds were synthesized, and their reduction potentials were measured by cyclic voltammetry. The substituent effects on the E（Red） of target compounds were analyzed and an optimality equation with four parameters （Hammett constant a of X, Hammett constant a of Y, excited-state substituent constant σexCC of X, and the substituent specific cross-interaction effect △σexCC2 between X and Y） was obtained. The results show that the factors affecting the E（Red） of 3,4＇/4,31/3,3P-substituted XBAYs are different from those of 4,4＇-substituted XBAYs. For 3,4＇/4,3＇/3,3＇-substituted XBAYs, σ（X） and σ（Y） must be employed, and the contribution of △σexCC2 is important and not negligible. Compared with 4,4＇-substituted XBAYs, X group contributes less to 3,4＇/4,3＇/3,3＇-substituted XBAYs, while Y group contributes more to them. Additionally, it was observed that either para-substituted XBAYs or meta-substituted XBAYs, the substituent effects of X are larger than those of Y on the E（Red） of substituted XBAYs.展开更多
Pyridoxal kinase （PLK） （EC 2.7.1.35） catalyzes the ATP-dependent phosphorylation of pyridoxal, generating pyridoxal-5＇-phosphate （PLP）, an important cofactor for many enzymatic reactions. Bombyx mori, similar t...Pyridoxal kinase （PLK） （EC 2.7.1.35） catalyzes the ATP-dependent phosphorylation of pyridoxal, generating pyridoxal-5＇-phosphate （PLP）, an important cofactor for many enzymatic reactions. Bombyx mori, similar to mammals, relies on a nutritional source of vitamin B6 to synthesize PLP. This article describes how a cDNA encoding PLK was cloned from Bombyx mori using the PCR method （GenBank accession number： DQ452397）. The cDNA has an 894 bp open reading frame and encodes a protein of 298 amino acid residues with a molecular mass of 33.1 k.Da. The amino acid sequence shares 48.6% identity with that of human PLK, and it also contains signature conserved motifs of the PLK family. However, the protein is 10 or more amino acids shorter than the PLK from mammals and plants, and several amino acid residues conserved in the PLK from mammals and plants are changed in the protein. The cDNA cloned was expressed successfully in Escherichia coli using the T7 promoter/T7 RNA polymerase expression system, and the crude extracts containing the expressed product were found to have strong PLK enzymatic activity with a value of 30 nmol/min/mg, confirming that the cDNA encodes the functional PLK of Bombyx mori. This is the first identification of a gene encoding PLK in insects.展开更多
A new matrix Lie algebra and its corresponding Loop algebra are constructed firstly,as its application,the multi-component TC equation hierarchy is obtained,then by use of trace identity the Hamiltonian structure of t...A new matrix Lie algebra and its corresponding Loop algebra are constructed firstly,as its application,the multi-component TC equation hierarchy is obtained,then by use of trace identity the Hamiltonian structure of the above system is presented.Finally,the integrable couplings of the obtained system is worked out by the expanding matrix Loop algebra.展开更多
In this paper we define an equivalence relation on the set of all xj in order to form a basis for a new descent algebra of Weyl groups of type A,. By means of this, we construct a new commutative and semi-simple desce...In this paper we define an equivalence relation on the set of all xj in order to form a basis for a new descent algebra of Weyl groups of type A,. By means of this, we construct a new commutative and semi-simple descent algebra for Weyl groups of type An generated by equivalence classes arising from this equivalence relation.展开更多
In this paper, we study the rank of matrices over GF(2~p),and propose two construction methods for algebraic-based nonbinary LDPC codes from an existing LDPC code, referred to as the original code. By multiplying all ...In this paper, we study the rank of matrices over GF(2~p),and propose two construction methods for algebraic-based nonbinary LDPC codes from an existing LDPC code, referred to as the original code. By multiplying all elements of each column of the binary parity-check matrix H corresponding to the original code with the same nonzero element of any field, the first class of nonbinary LDPC codes with flexible field order is proposed. The second method is to replace the nonzero elements of some columns in H with different nonzero field elements in a given field, and then another class of nonbinary LDPC codes with various rates is obtained. Simulation results show that the proposed nonbinary LDPC codes perform well over the AWGN channel with the iterative decoding algorithms.展开更多
Based on the basis of the constructed Lie super algebra, the super-isospectral problem of KN hierarchy is considered. Under the frame of the zero curvature equation, the super-KN hierarchy is obtained. Furthermore, it...Based on the basis of the constructed Lie super algebra, the super-isospectral problem of KN hierarchy is considered. Under the frame of the zero curvature equation, the super-KN hierarchy is obtained. Furthermore, its super-Hamiltonian structure is presented by using super-trace identity and it has super-bi-Hamiltonian structure.展开更多
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China （No.20772028 and No.20472019）, the Natural Science Foundation of Hunan Province （No.06JJ2002）, and the Scientific Research Fund of Hunan Provincial Education Commission.
文摘A correlation equation between the UV absorption wavenumbers of 1,4-disubstituted benzenes and the excited-state substituent constant was obtained. For 80 sorts of 1,4- disubstituted benzenes, the correlation coefficient was 0.9805, and the standard deviation was only 672.27 cm^-1. The results imply that the excited-state substituent constant can be used productively for research on UV energy of 1,4-disubstituted benzenes. The present method provides a new avenue to study the UV absorption spectra of aromatic systems with the excited-state substituent constant, and it is helpful to understand the effect of substituent electrostatic effects on the chemical and physical properties of conjugated compounds with multiple substituents in excited state.
文摘Based on the location of bromine substituents and conjugation matrix, a new substituent po- sition index ~X not only was defined, but also molecular shape indexes Km and electronega- tivity distance vectors Mm of diphenylamine and 209 kinds of polybrominated diphenylamine （PBDPA） molecules were calculated. Then the quantitative structure-property relationships （QSPR） among the thermodynamic properties of 210 organic pollutants and 0X, K3, M29, M36 were founded by Leaps-and-Bounds regression. Using the four structural parameters as input neurons of the artificial neural network, three satisfactory QSPR models with network structures of 4：21：1, 4：24：1, and 4：24：1 respectively, were achieved by the back-propagation algorithm. The total correlation coefficients R were 0.9999, 0.9997, and 0.9995 respectively and the standard errors S were 1.036, 1.469, and 1.510 respectively. The relative mean deviation between the predicted value and the experimental value of Sθ, AfHe and △fGθ- were 0.11%, 0.34% and 0.24% respectively, which indicated that the QSPR models had good stability and superior predictive ability. The results showed that there were good nonlinear correlations between the thermodynamic properties of PBDPAs and the four structural pa- rameters. Thus, it was concluded that the ANN models established by the new substituent position index were fully applicable to predict properties of PBDPAs.
文摘In this paper,We give the forms of AR sequences of a tilted algebra with terms all belonging to x(A_T),or all belonging to y(A_T).The sink maps of a tilted algebra which end at the indecompos able projective modules and the source maps of starting at the indecomposable injective modules are also obtained.These results together with the connecting sequecnes given in [3] determine the AR quiver of the tilted algcbra,morever,this can be done directly from the AR quiver of the correspond ing hereditary algebra.
文摘Effects of meta-substituent of 3,4＇/4,3＇/3,3＇-substituted benzylideneanilines （XBAYs） on the electrochemical reduction potentials （E（Red）） were investigated, in which 49 samples of target compounds were synthesized, and their reduction potentials were measured by cyclic voltammetry. The substituent effects on the E（Red） of target compounds were analyzed and an optimality equation with four parameters （Hammett constant a of X, Hammett constant a of Y, excited-state substituent constant σexCC of X, and the substituent specific cross-interaction effect △σexCC2 between X and Y） was obtained. The results show that the factors affecting the E（Red） of 3,4＇/4,31/3,3P-substituted XBAYs are different from those of 4,4＇-substituted XBAYs. For 3,4＇/4,3＇/3,3＇-substituted XBAYs, σ（X） and σ（Y） must be employed, and the contribution of △σexCC2 is important and not negligible. Compared with 4,4＇-substituted XBAYs, X group contributes less to 3,4＇/4,3＇/3,3＇-substituted XBAYs, while Y group contributes more to them. Additionally, it was observed that either para-substituted XBAYs or meta-substituted XBAYs, the substituent effects of X are larger than those of Y on the E（Red） of substituted XBAYs.
基金This work was supported by the Foundation of Talented Person Development of Anhui Province in 2004.
文摘Pyridoxal kinase （PLK） （EC 2.7.1.35） catalyzes the ATP-dependent phosphorylation of pyridoxal, generating pyridoxal-5＇-phosphate （PLP）, an important cofactor for many enzymatic reactions. Bombyx mori, similar to mammals, relies on a nutritional source of vitamin B6 to synthesize PLP. This article describes how a cDNA encoding PLK was cloned from Bombyx mori using the PCR method （GenBank accession number： DQ452397）. The cDNA has an 894 bp open reading frame and encodes a protein of 298 amino acid residues with a molecular mass of 33.1 k.Da. The amino acid sequence shares 48.6% identity with that of human PLK, and it also contains signature conserved motifs of the PLK family. However, the protein is 10 or more amino acids shorter than the PLK from mammals and plants, and several amino acid residues conserved in the PLK from mammals and plants are changed in the protein. The cDNA cloned was expressed successfully in Escherichia coli using the T7 promoter/T7 RNA polymerase expression system, and the crude extracts containing the expressed product were found to have strong PLK enzymatic activity with a value of 30 nmol/min/mg, confirming that the cDNA encodes the functional PLK of Bombyx mori. This is the first identification of a gene encoding PLK in insects.
基金supported by Science Foundation of the Educational Department of Shandong Province of China
文摘A new matrix Lie algebra and its corresponding Loop algebra are constructed firstly,as its application,the multi-component TC equation hierarchy is obtained,then by use of trace identity the Hamiltonian structure of the above system is presented.Finally,the integrable couplings of the obtained system is worked out by the expanding matrix Loop algebra.
文摘In this paper we define an equivalence relation on the set of all xj in order to form a basis for a new descent algebra of Weyl groups of type A,. By means of this, we construct a new commutative and semi-simple descent algebra for Weyl groups of type An generated by equivalence classes arising from this equivalence relation.
基金supported in part by National Basic Research Program of China under Grant No.2012CB316100National Natural Science Foundation of China under Grants 61372074 and 91438101+1 种基金Joint Funds of the National Natural Science Foundation of China under Grant No.U1504601Science and Technology on Communication Networks Laboratory under Grant KX132600032
文摘In this paper, we study the rank of matrices over GF(2~p),and propose two construction methods for algebraic-based nonbinary LDPC codes from an existing LDPC code, referred to as the original code. By multiplying all elements of each column of the binary parity-check matrix H corresponding to the original code with the same nonzero element of any field, the first class of nonbinary LDPC codes with flexible field order is proposed. The second method is to replace the nonzero elements of some columns in H with different nonzero field elements in a given field, and then another class of nonbinary LDPC codes with various rates is obtained. Simulation results show that the proposed nonbinary LDPC codes perform well over the AWGN channel with the iterative decoding algorithms.
基金＊Supported by the Natural Science Foundation of China under Grant Nos. 61072147, 11071159, the Natural Science Foundation of Shanghai urlder Grant No. 09ZR1410800, the Shanghai Leading Academic Discipline Project under Grant No. J50101, and the National Key Basic Research Project of China under Grant No. KLMM0806
文摘Based on the basis of the constructed Lie super algebra, the super-isospectral problem of KN hierarchy is considered. Under the frame of the zero curvature equation, the super-KN hierarchy is obtained. Furthermore, its super-Hamiltonian structure is presented by using super-trace identity and it has super-bi-Hamiltonian structure.
