Density （ρ） and viscosity （η） measurements were carried out for 4-aminobutyric acid in 0.0041,0.0125 and 0.0207 mol·L-1 aqueous salbutamol sulphate at T=308.15,313.15 and 318.15K.The measured values of dens...Density （ρ） and viscosity （η） measurements were carried out for 4-aminobutyric acid in 0.0041,0.0125 and 0.0207 mol·L-1 aqueous salbutamol sulphate at T=308.15,313.15 and 318.15K.The measured values of density and viscosity were used to estimate some important parameters such as apparent molar volume Vφ,limiting apparent molar volume Vφ0,transfer volume △Vφ0,hydration number Hn,second derivative of infinite dilution of partial molar volume with temperature 2Vφ0/T2,viscosity B-coefficients,variation of B with temperature dB/dT,free energy of activation per mole of solvent △μ10＊ and solute △μ20＊,activation entropy △S20＊ and activation enthalpy △H20＊ of the amino acids.These parameters have been interpreted in terms of solute-solute and solute-solvent interactions and structure making/breaking ability of solutes in the given solution.展开更多
The densities, conductivities, and viscosities were measured for ternary solutions of N-hexyl,methylpyrrolidinium bromide([PP1,6]Br)- N-butyl,methylpyrrolidinium bromide([PP1,4]Br)-H2 O and its binary subsystems [PP1,...The densities, conductivities, and viscosities were measured for ternary solutions of N-hexyl,methylpyrrolidinium bromide([PP1,6]Br)- N-butyl,methylpyrrolidinium bromide([PP1,4]Br)-H2 O and its binary subsystems [PP1,6]Br-H2 O and [PP1,4]Br-H2 O at(298.15, 303.15, 308.15, and 313.15) K, respectively. The results were used to test the predictability of the simple equations established for the prediction of density, conductivity,and viscosity of the mixed electrolyte solutions. The results show that the examined simple equations can offer good predictions for density, conductivity, and viscosity of the mixed ionic liquid solutions in terms of the corresponding properties of its binary subsystems of equal ionic strength.展开更多
In this paper, the rigid structural thermosensitive polymer （made in lab） of NBS （N-butyl styrene）, N, N-DEAM （diethyl acrylamide） and AM （acrylamide） was prepared. The influence of viscosity for copolymer sol...In this paper, the rigid structural thermosensitive polymer （made in lab） of NBS （N-butyl styrene）, N, N-DEAM （diethyl acrylamide） and AM （acrylamide） was prepared. The influence of viscosity for copolymer solution under different reaction conditions such as temperatures and inorganic salt （monovalent salt and divalent salt） was analyzed. The experiment studies the combination of polymer situation and three different types of surfactants under certain conditions of the room temperature （25℃） and the formation temperature （76℃）. At last, the influence of the surfactant kinds and concentration on the viscosity of the polymer solution are studied. The results show that： The copolymer solution, the apparent viscosity of which decreases with the increasement of temperature, but its viscosity has suddenly increased and thereafter dropped in the transition temperature. So the temperature sensitive effect ofcopolymer is very significantly. When the concentration of inorganic salt and surfactant can be controlled in certain extent, the copolymer solution, the effect increases with the increasement of the concentration, but the viscosity of which decreases with the increasement of shear rate. Shear rate can be controlled in certain extent, shearing stability properties of the copolymer solution are proved.展开更多
Density（ρ）and viscosity（η）are measured for glycine,DL-α-alanine DL-α-valine,and DL-α-leucine in 0.05,0.10,0.15 and 0.20 mol·L^-1aqueous metformin hydrochloride at 308.15,313.15 and 318.15 K.The measured ...Density（ρ）and viscosity（η）are measured for glycine,DL-α-alanine DL-α-valine,and DL-α-leucine in 0.05,0.10,0.15 and 0.20 mol·L^-1aqueous metformin hydrochloride at 308.15,313.15 and 318.15 K.The measured values are used to estimate some important parameters,such as partial molal volume Vφ,standard partial molal volume Vφ^0,transfer volume ΔVφ^0,hydration number nH,the second derivative of infinite dilution of partial molal volume with respect to temperature,viz., ^2 Vφ^0 /T^2,viscosity B-coefficient,variation of B with temperature,viz., dB/dT,free energy of activation per mole of solvent Δμ1^＊0 and solute Δμ2^0＊ of the amino acids.These parameters are interpreted in terms of solute-solute and solute-solvent interactions and structure making/breaking ability of solutes in the given solution.In addition,Vφ^0,0 ΔVφ^0,viscosity B-coefficient,ΔB and Δμ2 ^0＊ are split into group contributions（NH3^＋ COO ^-）and -CH2 of the amino acids using their linear correlation and their behavior is discussed.展开更多
文摘Density （ρ） and viscosity （η） measurements were carried out for 4-aminobutyric acid in 0.0041,0.0125 and 0.0207 mol·L-1 aqueous salbutamol sulphate at T=308.15,313.15 and 318.15K.The measured values of density and viscosity were used to estimate some important parameters such as apparent molar volume Vφ,limiting apparent molar volume Vφ0,transfer volume △Vφ0,hydration number Hn,second derivative of infinite dilution of partial molar volume with temperature 2Vφ0/T2,viscosity B-coefficients,variation of B with temperature dB/dT,free energy of activation per mole of solvent △μ10＊ and solute △μ20＊,activation entropy △S20＊ and activation enthalpy △H20＊ of the amino acids.These parameters have been interpreted in terms of solute-solute and solute-solvent interactions and structure making/breaking ability of solutes in the given solution.
基金Supported by the National Natural Science Foundation of China(21276271,21076224,21176248)the Science Foundation of China University of Petroleum,Beijing(qzdx-2011-01)
文摘The densities, conductivities, and viscosities were measured for ternary solutions of N-hexyl,methylpyrrolidinium bromide([PP1,6]Br)- N-butyl,methylpyrrolidinium bromide([PP1,4]Br)-H2 O and its binary subsystems [PP1,6]Br-H2 O and [PP1,4]Br-H2 O at(298.15, 303.15, 308.15, and 313.15) K, respectively. The results were used to test the predictability of the simple equations established for the prediction of density, conductivity,and viscosity of the mixed electrolyte solutions. The results show that the examined simple equations can offer good predictions for density, conductivity, and viscosity of the mixed ionic liquid solutions in terms of the corresponding properties of its binary subsystems of equal ionic strength.
文摘In this paper, the rigid structural thermosensitive polymer （made in lab） of NBS （N-butyl styrene）, N, N-DEAM （diethyl acrylamide） and AM （acrylamide） was prepared. The influence of viscosity for copolymer solution under different reaction conditions such as temperatures and inorganic salt （monovalent salt and divalent salt） was analyzed. The experiment studies the combination of polymer situation and three different types of surfactants under certain conditions of the room temperature （25℃） and the formation temperature （76℃）. At last, the influence of the surfactant kinds and concentration on the viscosity of the polymer solution are studied. The results show that： The copolymer solution, the apparent viscosity of which decreases with the increasement of temperature, but its viscosity has suddenly increased and thereafter dropped in the transition temperature. So the temperature sensitive effect ofcopolymer is very significantly. When the concentration of inorganic salt and surfactant can be controlled in certain extent, the copolymer solution, the effect increases with the increasement of the concentration, but the viscosity of which decreases with the increasement of shear rate. Shear rate can be controlled in certain extent, shearing stability properties of the copolymer solution are proved.
文摘Density（ρ）and viscosity（η）are measured for glycine,DL-α-alanine DL-α-valine,and DL-α-leucine in 0.05,0.10,0.15 and 0.20 mol·L^-1aqueous metformin hydrochloride at 308.15,313.15 and 318.15 K.The measured values are used to estimate some important parameters,such as partial molal volume Vφ,standard partial molal volume Vφ^0,transfer volume ΔVφ^0,hydration number nH,the second derivative of infinite dilution of partial molal volume with respect to temperature,viz., ^2 Vφ^0 /T^2,viscosity B-coefficient,variation of B with temperature,viz., dB/dT,free energy of activation per mole of solvent Δμ1^＊0 and solute Δμ2^0＊ of the amino acids.These parameters are interpreted in terms of solute-solute and solute-solvent interactions and structure making/breaking ability of solutes in the given solution.In addition,Vφ^0,0 ΔVφ^0,viscosity B-coefficient,ΔB and Δμ2 ^0＊ are split into group contributions（NH3^＋ COO ^-）and -CH2 of the amino acids using their linear correlation and their behavior is discussed.
