塑岩:成因、分布与微塑料释放特征

塑料污染是受到全球广泛关注的环境问题,对人体健康与生态系统造成潜在威胁.已有证据表明,塑料能够与自然界的岩石发生稳定结合,成为人类活动作为一种新的地质营力影响地球地质周期的直接证据.在这些发现的基础上,本文提出并定义了一种新的沉积岩类型——塑岩.塑岩是塑料与碎屑物质胶结形成的沉积岩;在塑岩中,肉眼可见的塑料与沉积岩原始物质成分在地壳表层的条件下,经熔化-凝固、蒸发、吸附等物理、化学过程,发生了不可逆的结合.在前期发现的基础上,针对2022年7月在广西壮族自治区河池市采集得到的陆地生态系统塑岩样品,进一步研究其在干湿循环情形下微塑料的释放与粒径分布特征.研究表明,在干湿循环老化情形下,从塑岩中释放得到的微塑料的粒径分布可以被条件概率老化模型刻画.从塑岩中剥离的低密度聚乙烯(LDPE)和聚丙烯(PP)塑料的破碎维数总体在1.5~2.5之间浮动,呈现出二维破碎的特征;LDPE的破碎过程存在先加剧后减缓的过程,但PP的破碎维数恒定在2附近,预示塑岩结合的PP塑料具有长期释放微塑料的能力.除此之外,在塑岩释放的微塑料中,超过60%为具有较高迁移性的圆球状微塑料,其平均粒径显著低于其他形状,具有较高的迁移性,预示着潜在的生态风险.需要指出的是,目前针对塑岩的相关报道对其胶结成岩过程以及在自然界中的长期环境行为仍不甚明确,后续研究需要对其在自然环境中的成岩过程、赋存规律与长期归趋开展进一步研究与观测.

Numerical analysis of deformation and failure characteristics of deep roadway surrounding rock under static-dynamic coupling stress

In actual production,deep coal mine roadways are often under typical static-dynamic coupling stress(SDCS)conditions with high ground stress and strong dynamic disturbances.With the increasing number of disasters and accidents induced by SDCS conditions,the safe and efficient production of coal mines is seriously threatened.Therefore,it is of great practical significance to study the deformation and failure characteristics of the roadway surrounding rock under SDCS.In this paper,the effects of different in-situ stress fields and dynamic load conditions on the surrounding rock are studied by numerical simulations,and the deformation and failure characteristics are obtained.According to the simulation results,the horizontal stress,vertical stress and dynamic disturbance have a positive correlation with the plastic failure of the surrounding rock.Among these factors,the influence of the dynamic disturbance is the most substantial.Under the same stress conditions,the extents of deformation and plastic failure of the roof and ribs are always greater than those of the floor.The effect of horizontal stresses on the roadway deformation is more notable than that of vertical stresses.The results indicate that for the roadway under high-stress conditions,the in-situ stress test must be strengthened first.After determining the magnitude of the in-situ stress,the location of the roadway should be reasonably arranged in the design to optimize the mining sequence.For roadways that are strongly disturbed by dynamic loads,rock supports(rebar/cable bolts,steel set etc.)that are capable of maintaining their effectiveness without failure after certain dynamic loads are required.The results of this study contribute to understanding the characteristics of the roadway deformation and failure under SDCS,and can be used to provide a basis for the support design and optimization under similar geological and geotechnical circumstances.

Plastic zone distribution laws and its types of surrounding rock in large-span roadway

In order to study the distribution laws and types of plastic zone of surrounding rock in large-span roadway, we analyzed the distribution laws with different spans and lateral pressures using FLAC3D numerical calcu- lation software. Based on the roadway support difficulty and distribution laws of the plastic zone of sur- rounding rock, we defined the large-span roadway and classified the types of large-span rectangular roadways. As a result, the distribution laws of the plastic zone on surrounding rock in a rectangular roadway with different spans and lateral pressures were obtained. The results show that the area of the plastic zone on surrounding rock increased with the increase of the spans and lateral pressures, and the plastic zone was symmetrical to the center line of roadway. At λ=0.5, 1.0, 1.5, and 2.0, the plastic zone presented ＂addle- shape＂ distribution, ＂ellipse＂ distribution, ＂thin and high＂ distribution and ＂inverse trapezium＂ distribu- tion, respectively. In addition, we classified the roadways into four types according to the different lateral pressures and spans, including small-span, moderate-span, large-span and extreme-large-span roadways.

Rules of distribution in a plastic zone of rocks surrounding a roadway affected by tectonic stress

In order to study the rules of distribution in a plastic zone of rocks, surrounding a roadway, affected by tectonic stress, we first analyzed the mechanics of a roadway affected by tectonic stress and derived a theoretical formula for the plastic zone of rocks surrounding a roadway. We also analyzed the distribution characteristics of the plastic zone under different levels of tectonic stress, vertical pressure, cohesion and friction angle of the surrounding rock. Secondly, we used numerical simulation to analyze the range and shape features of the plastic zone of rocks surrounding the roadway, given different tectonic stress levels. Finally we used a rock drilling detector to carry out field measurements on the broken state of rock surrounding the roadway at the –700 substation and channels in the Xinzhuang mine of the Shenhuo mining area. Given the measured ground stress, we analyzed the relationship between tectonic stress and the distribution of this plastic zone. Our results show that the range of the plastic zone at the top and bottom of the roadway increases with an increase in tectonic stress and this increase is especially obvious at the roadway corner.

Theoretical analysis of a new segmented anchoring style in weakly cemented soft surrounding rock

According to the tensile failure of rock bolt in weakly cemented soft rock, this paper presents a new segmented anchoring style in order to weaken the cumulative effect of anchoring force associated with the large deformation. Firstly, a segmented mechanical model was established in which free and anchoring section of rock bolt were respectively arranged in different deformation zones. Then, stress and displacement in elastic non-anchoring zone, elastic anchoring zone, elastic sticking zone, softening sticking zone and broken zone were derived respectively based on neural theory and tri-linear strain softening constitutive model of soft rock. Results show that the anchoring effect can be characterized by a supporting parameter b. With its increase, the peak value of tangential stress gradually moves to the roadway wall, and the radial stress significantly increases, which means the decrease of equivalent plastic zone and improvement of confining effect provided by anchorage body. When b increases to 0.72, the equivalent plastic zone disappears, and stresses tend to be the elastic solutions. In addition, the anchoring effect on the displacement of surrounding rock can be quantified by a normalization factor δ.

Sensitivity analysis of influencing parameters in cavern stability

In order to analyze the stability of the underground rock structures,knowing the sensitivity of geomechanical parameters is important.To investigate the priority of these geomechanical properties in the stability of cavern,a sensitivity analysis has been performed on a single cavern in various rock mass qualities according to RMR using Phase 2.The stability of cavern has been studied by investigating the side wall deformation.Results showed that most sensitive properties are coefficient of lateral stress and modulus of deformation.Also parameters of Hoek-Brown criterion and r c have no sensitivity when cavern is in a perfect elastic state.But in an elasto-plastic state,parameters of Hoek-Brown criterion and r c affect the deformability;such effect becomes more remarkable with increasing plastic area.Other parameters have different sensitivities concerning rock mass quality(RMR).Results have been used to propose the best set of parameters for study on prediction of sidewall displacement.

Elasto-plastic Analysis of Circular Tunnels in Jointed Rock Masses Satisfy the Hoek-Brown Failure Criterion

The relationship between the Hoek-Brown parameters and the mechanical response of circular tunnels is il-lustrated. Closed-form and approximate solutions are given for the extent of the plastic zone and the stress and dis-placement fields under axisymmetrical and asymmetric stress conditions. For the same rock masses and under axisym-metrical stress conditions,the radius of the plastic zone in terms of Hoek-Brown criterion is generally an approximation of the radius in terms of the Mohr-Coulomb criterion. The radius in terms of the Hoek-Brown criterion is larger under low stress conditions. For poor quality rock masses (GSI<25),measures (such as grouting,setting rock bolts,etc.) that improve the GSI of rock masses are effective in improving the stability of tunnels. It is not advisable to improve the sta-bility of the tunnels by providing a small support resistance p through shotcrete,except for very poor quality jointed rock masses. Without reference to the quality of the rock mass,the disturbance factor D should not less than 0.5. Meas-ures which disturb rock masses during tunnel construction should be taken carefully when the tunnel depth increases.

Plastic zone analysis and support optimization of shallow roadway with weakly cemented soft strata

Based on a shallow roadway with weakly cemented soft strata in western China, this paper studies the range and degree of plastic zones in soft strata roadways with weak cementation. Geological radars were used to monitor the loose range and level of surrounding rocks. A mechanical model of weakly cemented roadway was established, including granular material based on the measured results. The model was then used to determine the plastic zone radium. The predicted results agree well with measured results which provide valuable theoretical references for the analysis of surrounding rock stability and support reinforcing design of weakly cemented roadways. Finally, a combined supporting scheme of whole section bolting and grouting was proposed based on the original supporting scheme. It is proved that this support plan can effectively control the deformation and plastic zone expansion of the roadway surrounding rock and thus ensure the long-term stable and safe mining.

Stress distribution and its influencing factors of bottom-hole rock in underbalanced drilling

The underbalanced drilling has been widely used due to its advantages of high drilling efficiency and low cost etc., especially for hard formation drilling. These advantages, however, are closely related to the stress state of the bottom-hole rock; therefore, it is significant to research the stress distribution of bottom-hole rock for the correct understanding of the mechanism of rock fragmentation and high penetration rate. The stress condition of bottom-hole rock is very complicated while under the co-action of overburden pressure, horizontal in-situ stresses, drilling mud pressure, pore pressure and temperature etc. In this paper, the fully coupled simulation model is established and the effects of overburden pressure, horizontal in-situ stresses, drilling mud pressure, pore pressure and temperature on stress distribution of bottom-hole rock are studied. The research shows that： in air drilling, as the well depth increases, the more easily the bottom-hole rock is broken; the mud pressure has a great effect on the bottom hole rock. The bigger the mud pressure is, the more difficult to break the bottom-hole rock; the max principle stress of the bottom-hole increased with the increasing of mud pressure, well depth and temperature difference. The bottom-hole rock can be divided into 3 regions respectively according to the stress state, 3 direction stretch zone, 2 direction compression area and 3 direction compression zone; the corresponding fragmentation degree of difficulty is easily, normally and hardly.

Numerical Analysis of Finite Deformation of Overbroken Rock Mass in Gob Area Based on Euler Model of Control Volume

The overbroken rock mass of gob areas is made up of broken and accumulated rock blocks compressed to some extent by the overlying strata. The beating pressure of the gob can directly affect the safety of mining fields, formarion of road retained along the next goaf and seepage of water and methane through the gob. In this paper, the software RFPA＇2000 is used to construct numerical models. Especially the Euler method of control volume is proposed to solve the simulation difficulty arising from plastically finite deformations. The results show that three characteristic regions occurred in the gob area： （1） a naturally accumulated region, 0-10 m away from unbroken surrounding rock walls, where the beating pressure is nearly zero; （2） an overcompacted region, 10-20 m away from unbroken walls, where the beating pressure results in the maximum value of the gob area; （3） a stable compaction region, more than 20 m away from unbroken walls and occupying absolutely most of the gob area, where the beating pressures show basically no differences. Such a characteristic can exolain the easy-seeoaged “O”-ring phenomena around mining fields very well.

The study of slip line field and upper bound method based on associated flow and non-associated flow rules

At present, associated flow rule of traditional plastic theory is adopted in the slip line field theory and upper bound method of geotechnical materials. So the stress characteristic line conforms to the velocity line. It is proved that geotechnical materials do not abide by the associated flow rule. It is impossible for the stress characteristic line to conform to the velocity line. Generalized plastic mechanics theoretically proved that plastic potential surface intersects the Mohr-Coulomb yield surface with an angle, so that the velocity line must be studied by non-associated flow rule. According to limit analysis theory, the theory of slip line field is put forward in this paper, and then the ultimate beating capacity of strip footing is obtained based on the associated flow rule and the non-associated flow nile individually. These two results are identical since the ultimate bearing capacity is independent of flow role. On the contrary, the velocity fields of associated and non-associated flow rules are different which shows the velocity field based on the associat- ed flow rule is incorrect.

Effects of axial cyclic loading at constant confining pressures on deformational characteristics of anisotropic argillite

Triaxial cyclic loading tests have been performed to assess the influence of plastic deformation on inelastic deformational properties of anisotropic argillite with bedding planes which is regarded as a kind of transversely isotropic media.Considering argillite's anisotropy and inelastic deformational properties,theoretical formulae for calculating oriented elastic parameters were deduced by the unloading curves,which can be better fitted for the description of its elasticity than loading curves.Test results indicate that with the growth of accumulated plastic,strain,the apparent elastic modulus of argillite decreases in a form of exponential decay function,whereas the apparent Poisson ratio increase in a form of power equation.A ratio of unloading recoverable strain to the total strain increment occurred during a loading cycle is defined to illustrate the characteristic relations between anisotropic coupled elasto-plastic deformation and plastic strain.It is significant to observe that high stress level and plastic history have an inhibiting effect on argillite anisotropy.

Modeling of state parameter and hardening function for granular materials

A modified plastic strain energy as hardening state parameter for dense sand was proposed, based on the results front a series of drained plane strain tests on saturated dense Japanese Toyoura sand with precise stress and strain measurements along many stress paths. In addition, a unique hardening function between the plastic strain energy and the instantaneous stress path was also presented, which was independent of stress history. The proposed state parameter and hardening function was directly verified by the simple numerical integration method. It is shown that the proposed hardening function is independent of stress history and stress path and is appropriate to be used as the hardening rule in constitutive modeling for dense sand, and it is also capable of simulating the effects on the de-formation characteristics of stress history and stress path for dense sand.

PLASTIC LIMIT ANALYSIS OF DISCONTINUOUS LINING UNDERGROUND PRESSURE

Discontinuous lining is a special form of support in underground excavation. Based on the method of plastic limit analysis, it is found the upper and the lower bound solution of the pressure of circular discontinuous lining and discussed support parameter of discontinuous lining and its applicable conditions , which provides theoretical basis for the design and calculation of discontinuous lining.

Elastoplastic model for discontinuous shear deformation of deep rock mass

Deep rock mass possesses some unusual properties due to high earth stress,which further result in new problems that have not been well understood and explained up to date.In order to investigate the deformation mechanism,the complete deformation process of deep rock mass,with a great emphasis on local shear deformation stage,was analyzed in detail.The quasi continuous shear deformation of the deep rock mass is described by a combination of smooth functions:the averaged distribution of the original deformation field,and the local discontinuities along the slip lines.Hence,an elasto-plastic model is established for the shear deformation process,in which the rotational displacement is taken into account as well as the translational component.Numerical analysis method was developed for case study.Deformation process of a tunnel under high earth stress was investigated for verification.

An elastic mechanics model and computation method for geotechnical material

Internal friction characteristic is one of the basic properties of geotechnical materials and it exists in mechanical elements all the time. However,until now internal friction is only considered in limit analysis and plastic mechanics but not included in elastic theory for rocks and soils. We consider that internal friction exists in both elastic state and plastic state of geotechnical materials,so the mechanical unit of friction material is constituted. Based on study results of soil tests,the paper also proposes that cohesion takes effect first and internal friction works gradually with the increment of deformation. By assuming that the friction coefficient is proportional to the strain,the internal friction is computed. At last,by imitating the linear elastic mechanics,the nonlinear elastic mechanics model of friction material is established,where the shear modulus G is not a constant. The new model and the traditional elastic model are used simultaneously to analyze an elastic foundation. The results indicate that the displacements computed by the new model are less than those from the traditional method,which agrees with the fact and shows that the mechanical units of friction material are suitable for geotechnical material.

Influences of strain softening and seepage on elastic and plastic solutions of circular openings in nonlinear rock masses

Considering the influence of strain softening, the solutions of stress, displacement, plastic softening region radius and plastic residual region radius were derived for circular openings in nonlinear rock masses subjected to seepage. The radial stress distribution curve, ground reaction curve, and relation curve between plastic softening region radius and supporting force in three different conditions were drawn respectively. From the comparisons among these results for different conditions, it is found that when the supporting force is the same, the displacement of tunnel wall considering both seepage and strain softening is 85.71% greater than that only considering seepage. The increase values of radial displacement at 0.95 m and plastic softening region radius at 6.6 m show that the seepage and strain softening have the most unfavorable effects on circular opening stability in strain softening rock masses.

Effects of Limestone Powder on Rheological Properties of Cement - Fly Ash Mortar

This article studies the effects of limestone powder on rheological properties of cement - fly ash mortar with RHEOLAB QC type rotation viscometer. The Bingham fluid model is introduced to fit the yielding stress and plastic viscosity of the mortar. The POWER LAW fluid model is introduced to fit the rheological index of the mortar. The results show that, adding limestone powder and fly ash to the cement mortar significantly decreases the yield stress of the mortar, changes the plastic viscosity of the mortar, increases the rheological index, decreases the degree of shear thinning of the mortar, and thereby improves the mortar＇ s workability. In the case of cement - fly ash mortar, with the increase of limestone powder content, both the yield stress and plastic viscosity of the mortar increase. When the limestone powder content is not higher than 14%, the increase of yield stress is not significant. When the limestone powder content is lower than 8%, the increase of plastic viscosity is not significant. When the content of limestone powder is higher than 22%, the rheological index of the mortar decreases and the degree of shear thinning increases. The effects of limestone powder＇ s packing density, shape and size, specific surface area, and fluid volume, are found to be the four major factors responsible for the changes ofrheological properties of the mortar.

Stability and reinforcement analysis of rock slope based on elasto-plastic finite element method

The rigid body limit equilibrium method(RBLEM) and finite element method(FEM) are two widely used approaches for rock slope's stability analysis currently. RBLEM introduced plethoric assumptions; while traditional FEM relied on artificial factors when determining factor of safety(FOS) and sliding surfaces. Based on the definition of structure instability that an elasto-plastic structure is not stable if it is unable to satisfy simultaneously equilibrium condition, kinematical admissibility and constitutive equations under given external loads, deformation reinforcement theory(DRT) is developed. With this theory, plastic complementary energy(PCE) can be used to evaluate the overall stability of rock slope, and the unbalanced force beyond the yield surface could be the identification of local failure. Compared with traditional slope stability analysis approaches, the PCE norm curve to strength reduced factor is introduced and the unbalanced force is applied to the determination of key sliding surfaces and required reinforcement. Typical and important issues in rock slope stability are tested in TFINE(a three-dimensional nonlinear finite element program), which is further applied to several representatives of high rock slope's stability evaluation and reinforcement engineering practice in southwest of China.

Water-enhanced plastic deformation in felsic rocks

Using Fourier transform infrared spectroscopy(FTIR),we measured water contents in quartz and feldspar for four kinds of felsic rocks,i.e.,undeformed granite,banded granitic gneiss,fine-grained felsic mylonite,and fine-grained quartz-mica schist,collected from Pengguan Complex and Kangding Complex in the Longmenshan tectonic zone,Sichuan,China.The absorbance spectra suggest that water in coarse-grained quartz and feldspar of undeformed granite and banded granitic gneiss occurs mainly as hydroxyl in crystal defects,and water in most of fine-grained quartz and feldspar of felsic mylonite is molecular water in inclusions and liquid-type water in grain boundaries,but in some cases it still occurs as hydroxyl in crystal defects.Water content of quartz in undeformed granite is 0.001 wt%-0.009 wt %,and that of feldspar 0.005 wt%-0.02 wt%.The banded granitic gneiss shows water contents of 0.002 wt%-0.011 wt% in quartz and 0.012 wt%-0.036 wt% in feldspar.Quartz ribbon and feldspar ribbon in fine-grained felsic mylonite show that their water contents are similar to those of coarse-grained quartz and feldspar in granite,0.002 wt%-0.011 wt%,and 0.004 wt%-0.02 wt%,respectively.Water contents of fine-grained quartz and feldspar are respectively 0.004 wt%-0.02 wt% and 0.012 wt%-0.06 wt%.Water content of quartz in fine-grained quartz-mica schist is 0.007 wt%-0.15 wt%.Water-bearing minerals display much higher water contents than those of nominally anhydrous minerals,and the percentage of water-bearing minerals in felsic rocks increases with the strain of rocks.These new data indicate that hydroxyl in crystal defects has basically not been released during the shear deformation,and on the contrary,the increase in molecular water in inclusions and liquid-type water in grain boundaries as well as water-bearing minerals after shear deformation leads to a significant increase of the water content in deformed rocks.Based on data of creep tests,it is inferred here that the fine-grained mylonites with more water have much lower strength than that of the weakly deformed coarse-grained rocks in the middle crust,and this indicates that trace amount of water significantly helped develop the ductile shear zone.