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盘状苯并菲丙烯酸酯中间体的合成与液晶相行为研究
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作者 慕斌 陈科扬 谌东中 《液晶与显示》 CAS CSCD 北大核心 2017年第6期424-432,共9页
本文主要报道了一系列不对称取代的苯并菲丙烯酸酯类盘状液晶中间体化合物的合成及其液晶相行为研究。首先,从单羟基苯并菲类衍生物出发,针对不同长度烷基间隔基体系的反应活性差异,采用不同方法引入可聚合丙烯酸酯基官能团,对亚甲基间... 本文主要报道了一系列不对称取代的苯并菲丙烯酸酯类盘状液晶中间体化合物的合成及其液晶相行为研究。首先,从单羟基苯并菲类衍生物出发,针对不同长度烷基间隔基体系的反应活性差异,采用不同方法引入可聚合丙烯酸酯基官能团,对亚甲基间隔基数目从0到10的苯并菲丙烯酸酯进行全系列合成,并通过核磁共振波谱(NMR)和质谱(MS)对合成目标产物进行化学结构确认。通过差示扫描量热法(DSC)、偏光显微镜(POM)和小角/广角X射线散射(SAXS/WAXS)表征并分析该系列盘状苯并菲丙烯酸酯中间体的液晶相行为及组装的柱状有序结构。结果表明,大多数己氧基苯并菲类丙烯酸酯中间体只形成结晶;而丁氧基苯并菲类中间体则大都能呈现单向或双向互变型热致六方柱状液晶相,以及一类典型的具有三维(3D)位置有序的六方柱状塑晶相。该类不对称取代的苯并菲丙烯酸酯盘状液晶相态结构与相行为关系的阐明,将对(甲基)丙烯酸酯类可聚合功能性单体的设计合成以及加深对聚合制得侧链盘状液晶聚合物的多级有序相结构的认识和理解具有重要意义。 展开更多
关键词 盘状液晶 苯并菲 丙烯酸酯 柱状塑晶相 六方柱状
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半氟烃链作桥链的对称酯类二聚体的合成及介晶性 被引量:1
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作者 徐丽 赵可清 +2 位作者 余文浩 汪必琴 胡平 《四川师范大学学报(自然科学版)》 CAS CSCD 北大核心 2011年第1期95-100,共6页
合成全氟烃链或半氟烃链作为中心桥链的二聚体化合物可能出现新的性能,作为液晶材料具有较大的研究价值.合成了7个以半氟烃链作为桥链的对称酯类二聚体化合物H2n+1CnO-C6H4-COOCH2C6 F12CH2OOC-C6H4-OCnH2n+1(n=4,1a;6,1b;10,1c),H2n+1 ... 合成全氟烃链或半氟烃链作为中心桥链的二聚体化合物可能出现新的性能,作为液晶材料具有较大的研究价值.合成了7个以半氟烃链作为桥链的对称酯类二聚体化合物H2n+1CnO-C6H4-COOCH2C6 F12CH2OOC-C6H4-OCnH2n+1(n=4,1a;6,1b;10,1c),H2n+1 CnO-C6H4-C6H4-COOCH2C6F12 CH2OOC-C6H4-C6H4-OCnH2n+1(n=4,2a;6,2b;12,2c)和C6F13CH2CH2COOCH2C6F12CH2OOCCH2CH2C6F13(3).差示扫描量热法(DSC)和偏光显微镜(POM)对其介晶性研究发现:化合物2a具有典型的焦锥扇形织构SA相,化合物2b出现塑晶相.分别比较结构相类似的化合物1a~1c,2a~2c的熔点,发现随着烷氧基链的增长,存在降低趋势.三段半氟烃链的对称酯类二聚体化合物3未观察到介晶性. 展开更多
关键词 液晶 半氟烃链 塑晶相 二聚体
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Improving in plasticity of orthorhombic Ti_2AlNb-based alloys sheet by high density electropulsing 被引量:6
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作者 宋辉 王忠金 赫晓东 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第1期32-37,共6页
In order to optimize the ductility of orthorhombic Ti2AlNb-based alloys sheet,Ti22Al27Nb sheet was treated by high density electropulsing(J max =6.80 7.09 kA/mm2,tp =110 μs) under ambient condition.Microstructures ... In order to optimize the ductility of orthorhombic Ti2AlNb-based alloys sheet,Ti22Al27Nb sheet was treated by high density electropulsing(J max =6.80 7.09 kA/mm2,tp =110 μs) under ambient condition.Microstructures were observed by SEM,and the tensile properties were also studied using uniaxial tension tests.The experimental results show that electropulsing can refine the microstructures of Ti22Al27Nb sheets.The specimen with the fine and homogeneous microstructures has good plasticity,and its elongation reaches 19.4%.The mechanism about the effect of electropulsing treatment on the microstructure of Ti22Al27Nb sheets was discussed.It was thought that the increase in nucleation rate during phase transformation and a very short treating time were regarded as the main reasons of producing smaller grains and increase in the plasticity by electropulsing. 展开更多
关键词 Ti2AlNb-based alloys electropulsing treatment PLASTICITY grain refinement microstructure nucleation rate phase transformation
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Fine-grained Mg−1Mn−0.5Al−0.5Ca−0.5Zn alloy with high strength and good ductility fabricated by conventional extrusion 被引量:3
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作者 Guang-lin GU Xiang-nan KE +5 位作者 Fa-ping HU Shu-jie ZHAO Guo-bin WEI Yan YANG Xiao-dong PENG Wei-dong XIE 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2022年第2期483-492,共10页
Mg−1Mn−0.5Al−0.5Ca−0.5Zn(wt.%)alloy was fabricated by conventional extrusion at 673 K with an extrusion ratio of 25:1,followed by aging at 473 K.The microstructure was characterized by scanning electron microscopy,ele... Mg−1Mn−0.5Al−0.5Ca−0.5Zn(wt.%)alloy was fabricated by conventional extrusion at 673 K with an extrusion ratio of 25:1,followed by aging at 473 K.The microstructure was characterized by scanning electron microscopy,electron back-scattered diffraction,and transmission electron microscopy.The mechanical properties were determined by the tensile test.The peak-aged sample shows fine recrystallized grains with an average grain size of 1.7μm.Area fraction of Al−Ca particles in the alloy increases significantly after peak aging.Meanwhile,botháañandác+añdislocations were observed to remain in the alloy after hot extrusion.Thus,the peak-aged sample exhibits simultaneously high strength and good ductility with the ultimate tensile stress,tensile yield stress,and tension fracture elongation of 320 MPa,314 MPa,and 19.0%,respectively. 展开更多
关键词 Mg−Mn−Al−Ca−Zn alloy fine grain PRECIPITATE strength DUCTILITY
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Effect of microvoids on microplasticity behavior of dual-phase titanium alloy under high cyclic loading(Ⅰ):Crystal plasticity analysis 被引量:3
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作者 Kai-di LI Xiao-ning HAN +2 位作者 Bin TANG Meng-qi ZHANG Jin-shan LI 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2022年第2期513-523,共11页
A crystal plasticity finite element(CPFE)model was established and 2D simulations were carried out to study the relationship between microvoids and the microplasticity deformation behavior of the dual-phase titanium a... A crystal plasticity finite element(CPFE)model was established and 2D simulations were carried out to study the relationship between microvoids and the microplasticity deformation behavior of the dual-phase titanium alloy under high cyclic loading.Results show that geometrically necessary dislocations(GND)tend to accumulate around the microvoids,leading to an increment of average GND density.The influence of curvature in the tip plastic zone(TPZ)on GND density is greater than that of the size of the microvoid.As the curvature in TPZ and the size of the microvoid increase,the cumulative shear strain(CSS)in the primaryα,secondaryα,andβphases increases.Shear deformation in the prismatic slip system is dominant in the primaryαphase.As the distance between the microvoids increases,the interactive influence of the microvoids on the cumulative shear strain decreases. 展开更多
关键词 crystal plasticity dual-phase Ti alloy MICROVOIDS high cyclic loading cumulative shear strain geometrically necessary dislocation
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Simulation of strain induced abnormal grain growth in aluminum alloy by coupling crystal plasticity and phase field methods
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作者 Ru-xue LIU Kai LI +4 位作者 Guo-wei ZHOU Wei-qin TANG Yao SHEN Ding TANG Da-yong LI 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2022年第12期3873-3886,共14页
A mesoscale modeling methodology is proposed to predict the strain induced abnormal grain growth in the annealing process of deformed aluminum alloys. Firstly, crystal plasticity finite element(CPFE) analysis is perfo... A mesoscale modeling methodology is proposed to predict the strain induced abnormal grain growth in the annealing process of deformed aluminum alloys. Firstly, crystal plasticity finite element(CPFE) analysis is performed to calculate dislocation density and stored deformation energy distribution during the plastic deformation. A modified phase field(PF) model is then established by extending the continuum field method to consider both stored energy and local interface curvature as driving forces of grain boundary migration. An interpolation mapping approach is adopted to transfer the stored energy distribution from CPFE to PF efficiently. This modified PF model is implemented to a hypothetical bicrystal firstly for verification and then the coupled CPFE-PF framework is further applied to simulating the 2D synthetic polycrystalline microstructure evolution in annealing process of deformed AA3102 aluminum alloy.Results show that the nuclei with low stored energy embedded within deformed matrix tend to grow up, and abnormal large grains occur when the deformation is close to the critical plastic strain, attributing to the limited number of recrystallized nuclei and inhomogeneity of the stored energy. 展开更多
关键词 abnormal grain growth stored deformation energy RECRYSTALLIZATION crystal plasticity phase field
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Austenite/martensite structure and corresponding ultrahigh strength and high ductility of steels processed by Q&P techniques 被引量:5
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作者 WANG CunYu ZHANG YuJie +3 位作者 CAO WenQuan SHI Jie WANG MaoQiu DONG Han 《Science China(Technological Sciences)》 SCIE EI CAS 2012年第7期1844-1851,共8页
The microstructure of steels treated by Q&P(quenching and partitioning) process was characterized,a method of controlling retained austenite fraction based on inhomogeneous martensitic transformation was proposed,... The microstructure of steels treated by Q&P(quenching and partitioning) process was characterized,a method of controlling retained austenite fraction based on inhomogeneous martensitic transformation was proposed,and the mechanical properties of steels treated by Q&P process were measured.The results show that the microstructure of the studied steels is mainly composed of initial martensite,fresh martensite and retained austenite.The initial marteniste formed at the first quenching step is easily etched;the fresh martensite formed at the final quenching step looks like 'blocky' type phase,and the retained austenite is mainly located on the packet boundary and initial austenite grain boundary.The inhomogeneous microstructure causes the experimental optimum quenching temperature corresponding to maximum retained austenite fraction to be higher than the calculation based on CPE(constrained paraequilibrium) model.The product of tensile strength and total tensile elongation is 47.5 GPa%,and tensile strength of 1760 MPa was obtained for the steel with carbon content of 0.51 wt%.The TRIP(transformation induced plasticity) effects of the large fractioned metastable austenite make a main contribution to the high ductility improvement,and the martensitic matrix provides high strength. 展开更多
关键词 MARTENSITE retained austenite Q&P ultrahigh strength steel ductility heat treatment
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