A multifunctional Cu2O/Ag micro-nanocomposite, which has the characteristics of high cat- alytic activities under the visible light and high surface-enhanced Raman scattering （SERS） activity, was fabricated via a fa...A multifunctional Cu2O/Ag micro-nanocomposite, which has the characteristics of high cat- alytic activities under the visible light and high surface-enhanced Raman scattering （SERS） activity, was fabricated via a facile method and employed for the in situ SERS monitoring of the photocatalytic degradation reaction of crystal violet. Through the variation of the AgNO3 concentration, Ag content on the Cu2O template can be controllably tuned, which has great influence on the SERS effect. The results indicate that Ag nanopartieles form on the Cu2O nanoframes to obtain the Cu2O/Ag nanoeomposite, which can act as an excellent bifunetional platform for in situ monitoring of photocatalytic degradation of organic pollutions by SERS.展开更多
Photocatalytic degradation is one of the most promising remediation technologies in terms of advanced oxidation processes(AOPs) for water treatment. In this study, novel graphitic carbon nitride/titanium dioxide(gC3N4...Photocatalytic degradation is one of the most promising remediation technologies in terms of advanced oxidation processes(AOPs) for water treatment. In this study, novel graphitic carbon nitride/titanium dioxide(gC3N4/Ti O2) composites were synthesized by a facile sonication method. The physicochemical properties of the photocatalyst with different mass ratios of g-C3N4 to Ti O2 were investigated by X-ray diffraction(XRD), scanning electron microscope(SEM), transmission electron microscopy(TEM), N2 sorption, Fourier transform infrared spectroscopy(FT-IR), X-ray photoelectron spectroscopy(XPS), and UV–vis DRS. The photocatalytic performances were evaluated by degradation of methylene blue. It was found that g-C3N4/Ti O2 with a mass ratio of 1.5:1 exhibited the best degradation performance. Under UV, the degradation rate of g-C3N4/Ti O2 was 6.92 and 2.65 times higher than g-C3N4 and Ti O2, respectively. While under visible light, the enhancement factors became 9.27(to g-C3N4) and 7.03(to Ti O2). The improved photocatalytic activity was ascribed to the interfacial charge transfer between g-C3N4 and Ti O2. This work suggests that hybridization can produce promising solar materials for environmental remediation.展开更多
In this paper,the mechanical degradation of natural fiber composites is studied with the consideration of the relative humidity and the temperature.A nonlinear constitutive model is established,which employs an intern...In this paper,the mechanical degradation of natural fiber composites is studied with the consideration of the relative humidity and the temperature.A nonlinear constitutive model is established,which employs an internal variable to describe the mechanical degradation related to the energy dissipation during moisture absorption.The existing experimental researches demonstrated that the mechanical degradation is an irreversible thermodynamic process induced by the degradation of fibers and the damages of interfaces between fiber and matrix,both of which depend on the variation of the relative humidity or the temperature.The evolution of the mechanical degradation is obtained through the determination of dissipation rates as a function of the relative humidity and the temperature.The theoretically predicted mechanical degradations are compared with experimental results of sisal fiber reinforced composites subject to different relative humidity and temperatures,and a good agreement is found.展开更多
基金This work was supported by tile Key Projects of Natural Science Research of Universities in Anhui Province （No.KJ2015A183, No.KJ2015A201） and Talents Foundation of Hefei University （No.15RC05）, Anhui Province Natural Science Foundation （No.1608085MD78）, the Key Projects of Anhui Province University Outstanding Youth Talent Support Program （gxyqZD2016274）, the National Natural Science Foundation of China （No.21305142, No.51403048）.
文摘A multifunctional Cu2O/Ag micro-nanocomposite, which has the characteristics of high cat- alytic activities under the visible light and high surface-enhanced Raman scattering （SERS） activity, was fabricated via a facile method and employed for the in situ SERS monitoring of the photocatalytic degradation reaction of crystal violet. Through the variation of the AgNO3 concentration, Ag content on the Cu2O template can be controllably tuned, which has great influence on the SERS effect. The results indicate that Ag nanopartieles form on the Cu2O nanoframes to obtain the Cu2O/Ag nanoeomposite, which can act as an excellent bifunetional platform for in situ monitoring of photocatalytic degradation of organic pollutions by SERS.
基金Supported by the Innovative Research Team Program by the Ministry of Education of China(IRT13070)the Nature Science Foundation of Jiangsu Province(BK2012423,BK20130925)the Opening Project of State Key Laboratory of Materials-Oriented Chemical Engineering of China(KL13-02)
文摘Photocatalytic degradation is one of the most promising remediation technologies in terms of advanced oxidation processes(AOPs) for water treatment. In this study, novel graphitic carbon nitride/titanium dioxide(gC3N4/Ti O2) composites were synthesized by a facile sonication method. The physicochemical properties of the photocatalyst with different mass ratios of g-C3N4 to Ti O2 were investigated by X-ray diffraction(XRD), scanning electron microscope(SEM), transmission electron microscopy(TEM), N2 sorption, Fourier transform infrared spectroscopy(FT-IR), X-ray photoelectron spectroscopy(XPS), and UV–vis DRS. The photocatalytic performances were evaluated by degradation of methylene blue. It was found that g-C3N4/Ti O2 with a mass ratio of 1.5:1 exhibited the best degradation performance. Under UV, the degradation rate of g-C3N4/Ti O2 was 6.92 and 2.65 times higher than g-C3N4 and Ti O2, respectively. While under visible light, the enhancement factors became 9.27(to g-C3N4) and 7.03(to Ti O2). The improved photocatalytic activity was ascribed to the interfacial charge transfer between g-C3N4 and Ti O2. This work suggests that hybridization can produce promising solar materials for environmental remediation.
基金supported by National Natural Science Foundation of China(Grant No.11572227)
文摘In this paper,the mechanical degradation of natural fiber composites is studied with the consideration of the relative humidity and the temperature.A nonlinear constitutive model is established,which employs an internal variable to describe the mechanical degradation related to the energy dissipation during moisture absorption.The existing experimental researches demonstrated that the mechanical degradation is an irreversible thermodynamic process induced by the degradation of fibers and the damages of interfaces between fiber and matrix,both of which depend on the variation of the relative humidity or the temperature.The evolution of the mechanical degradation is obtained through the determination of dissipation rates as a function of the relative humidity and the temperature.The theoretically predicted mechanical degradations are compared with experimental results of sisal fiber reinforced composites subject to different relative humidity and temperatures,and a good agreement is found.
