Titanium aluminum nitride (TiAlN) film, as a possible substitute for the conventional tantalum nitride (TAN) or tantalum-aluminum (TaAl) heater resistor in inkjet printheads, was deposited on a Si(100) substra...Titanium aluminum nitride (TiAlN) film, as a possible substitute for the conventional tantalum nitride (TAN) or tantalum-aluminum (TaAl) heater resistor in inkjet printheads, was deposited on a Si(100) substrate at 400 ℃ by radio frequency (RF) magnetron co-sputtering using titanium nitride (TIN) and aluminum nitride (AlN) as ceramic targets. The temperature coefficient of resistivity (TCR) and oxidation resistance, which are the most important properties of a heat resistor, were studied depending on the plasma power density applied during sputtering. With the increasing plasma power density, the crystallinity, grain size and surface roughness of the applied film increased, resulting in less grain boundaries with large grains. The Ti, Al and N binding energies obtained from X-ray photoelectron spectroscopy analysis disclosed the nitrogen deficit in the TiAlN stoichiometry that makes the films more electrically resistive. The highest oxidation resistance and the lowest TCR of-765.43×10^-6 K-l were obtained by applying the highest plasma power density.展开更多
Re-vegetation plays a fundamental role for erosion control and plant recovery in lands affected by gully erosion. Bioengineered practices facilitate the gullies rehabilitation. Objectives of the research were: 1) Iden...Re-vegetation plays a fundamental role for erosion control and plant recovery in lands affected by gully erosion. Bioengineered practices facilitate the gullies rehabilitation. Objectives of the research were: 1) Identify taxonomically the pioneer vegetation on each gully section; 2) Characterize vegetation distribution preferences and 3) Assess structural/functional traits to recognize erosion control key species. Bioengineering was applied in a watershed belonging to Sierra Madre del Sur, at Oaxaca, Mexico, on eight gullies, with local support and minimal investment. "La Mixteca" is a poor ecological and socio-economic region, comparable to other regions of the world. The Initial Floristic Composition(IFC) inventory is the baseline of the successional process. The transect method was used to determine the colonization of species. Cover abundance of registered species was estimated using the semi-quantitative scale of Braun-Blanquet. This procedure was repeated in five different positions(floor, hillslopes and tops), in the cross section of the gully. Throughcorrespondence analysis and clustering, the distribution of species was analyzed. Adequate responses were obtained in soil retention(quantity) and plant cover(existence and diversity); as measurable indicators of the bioengeneering works efficiency. Occupation of soil by native species from the Tropical Deciduous Forest was favored using live barriers. We detected species guilds with spatial distribution preferences in the gullies cross section. Plant cover characterization includes: native colonizer species, herbaceous, shrubby and trees of the forest community bordering the gully area, with cover abundance and structural/functional traits, useful to protect degraded areas. This spatial occupation process of plants responds to a secondary succession in gullies, where the proposed IFC model is correctly represented through bioengineering. Natural establishment of plants was successful by traits of species such as extensive root system and sexual/vegetative reproduction.展开更多
A novel morphology-controlled strategy has been developed to fabricate sulfonated graphene/polyaniline (SGEP) nanocomposites by liquid/liquid interracial polymerization. Sulfonated graphene (SGE) sheets were synth...A novel morphology-controlled strategy has been developed to fabricate sulfonated graphene/polyaniline (SGEP) nanocomposites by liquid/liquid interracial polymerization. Sulfonated graphene (SGE) sheets were synthesized and used as both a macromolecular acid dopant and substrate for the polymerization of polyaniline (PANI), affording the SGEP nanocomposites. The morphology of PAN! in the nanocomposites can be controlled to be either nanorods or nanogranules by varying the synthesis conditions. The morphology of SGEP and the shape of PANI can be tuned by adding an additional dopant and varying the amount of SGE used, and this had a significant influence on the electrochemical performance of the nanocomposites as supercapacitor electrode materials. The SGEP nanocomposite with PANI nanorods exhibited a specific capacitance of 763 F/g with a capacity retention of 96% after 100 cycles and good rate properties. Composites obtained with HCI as an additional acid dopant with two different ratios of SGE to PANI showed higher specific capacitances of 793 and 931 F/g, but lower capacity retention after 100 cycles of 77% and 76%, respectively.展开更多
Effects of an electric field on CO oxidation of Au-embedded graphene are investigated using first-principles method. Results of our calculations show that the initial step of the reaction is more likely to proceed via...Effects of an electric field on CO oxidation of Au-embedded graphene are investigated using first-principles method. Results of our calculations show that the initial step of the reaction is more likely to proceed via the Langmuir-Hinshelwood mechanism in the presence of the field, and the reaction barrier can be tuned continuously by the electric field. However, the applied electric field makes it more difficult for the product of the reaction, CO2, to desorb from the reaction site. These two competing effects make an electric field not entirely advantageous in controlling the activity of Au-embedded graphene for CO oxidation reaction. Nevertheless, the findings of our study provide a basis for further investigation on control of chemical reactions by electric fields.展开更多
We apply polyelectrolyte multilayer films by consecutive alternate adsorption of positively charged polyallylamine hydrochloride and negatively charged sodium polystyrene sulfonate to the surface of graphene field eff...We apply polyelectrolyte multilayer films by consecutive alternate adsorption of positively charged polyallylamine hydrochloride and negatively charged sodium polystyrene sulfonate to the surface of graphene field effect transistors. Oscillations in the Dirac voltage shift with alternating positive and negative layers clearly demonstrate the electrostatic gating effect in this simple model system. A simple electrostatic model accounts well for the sign and magnitude of the Dirac voltage shift. Using this system, we are able to create p-type or n-type graphene at will. This model serves as the basis for understanding the mechanism of charged polymer sensing using graphene devices, a potentially technologically important application of graphene in areas such as DNA sequencing, biomarker assays for cancer detection, and other protein sensing applications.展开更多
Herein, we describe a strategy for fabricating ordered mesoporous In2O3-reduced graphene oxide(r GO)nanocomposite through ultrasonic mixing, where ordered mesoporous In2O3 nanoparticles are synthesized via the nanocas...Herein, we describe a strategy for fabricating ordered mesoporous In2O3-reduced graphene oxide(r GO)nanocomposite through ultrasonic mixing, where ordered mesoporous In2O3 nanoparticles are synthesized via the nanocasting route by using mesoporous silica as a hard template, which possess ordered mesostructure with a large surface area of 81 m2g-1, and r GO nanosheets are synthesized from graphite via graphene oxide(GO) as intermediate. After coupled with r GO, mesoporous In2O3 could maintain its ordered mesostructure. We subsequently investigate the gas-sensing properties of all the In2O3 specimens with or without r GO for different gases. The results exhibit the ordered mesoporous In2O3-r GO nanocomposite possesses significantly enhanced response to ethanol even at low concentration levels, superior over pure mesoporous In2O3 nanoparticles. Similar strategy could be extended to other ordered mesoporous metal oxide–r GO nanocomposite for improving the gas-sensing property.展开更多
As a traditional writing instrument for calligraphy and painting, the Chinese brush has enjoyed a high reputation over the last 5,000 years due to its ability to controllably handle liquid ink, and has been widely use...As a traditional writing instrument for calligraphy and painting, the Chinese brush has enjoyed a high reputation over the last 5,000 years due to its ability to controllably handle liquid ink, and has been widely used to deposit ink into certain characters or figures as a means of cultural communication. In this mini-review, we first show how the key to the controllable liquid transfer in a Chinese brush lies in the anisotropic multi-scale structural features of the freshly emergent hairs. Then, drawing inspiration from this, applications in controllable liquid pumping, highly efficient liquid transfer and template-free printing microlines are addressed. We envision that the fundamentals of Chinese brushes and their applications in liquid manipulation mentioned in this review may also be extended to other liquid phase functional material systems.展开更多
We report the gate-modulated Raman spectrum of defective graphene. We show that the intensity of the D peak can be reversibly tuned by applying a gate voltage. This effect is attributed to chemical functionalization o...We report the gate-modulated Raman spectrum of defective graphene. We show that the intensity of the D peak can be reversibly tuned by applying a gate voltage. This effect is attributed to chemical functionalization of the graphene crystal lattice, generated by an electrochemical reaction involving the water layer trapped at the interface between silicon and graphene.展开更多
The quest for materials and devices that are capable of controlling heat flux continues to fuel research on thermal controlling devices. In this letter, using molecular dynamics simulations, we demonstrate that a part...The quest for materials and devices that are capable of controlling heat flux continues to fuel research on thermal controlling devices. In this letter, using molecular dynamics simulations, we demonstrate that a partially clamped singlelayer graphene can serve as a thermal modulator. The mismatch in phonon dispersion between the unclamped and clamped graphene sections results in phonon interface scattering, and the strength of interface scattering is tunable by controlling the clamp-graphene distance via applying the external pressure. Owing to the ultra-thin structure of graphene and its highly sensitive phonon dispersion to external physical interaction, the modulation efficiency--which is defined as the ratio of the highest to lowest heat flux-can reach as high as 150% at a moderate pressure of 50 GPa. This modulation efficiency can be further enhanced by arranging a number of clamps in series along the direction of the heat flux.展开更多
We study the thermal transport of few-layer graphene nanoribbons in the presence of the transversal pressure by using molecular dynamics simulations. It is reported that the pressure can improve the thermal conductivi...We study the thermal transport of few-layer graphene nanoribbons in the presence of the transversal pressure by using molecular dynamics simulations. It is reported that the pressure can improve the thermal conductivity of few-layer graphene nanoribbons. This improvement can reach 37.5% in the low temperature region. The pressure dependence of thermal conductivity is also investigated for different length, width and thickness of few-layer graphene. Our results provide an alternative option to tuning thermal conductivity of few-layer graphene nanoribbons, b-arthermore, it maybe indicate a so-called pressure-thermM effect in nanomaterials.展开更多
基金Project (M-2009-01-0029) supported by Fundamental R&D Program for Core Technology of Materials, Korea
文摘Titanium aluminum nitride (TiAlN) film, as a possible substitute for the conventional tantalum nitride (TAN) or tantalum-aluminum (TaAl) heater resistor in inkjet printheads, was deposited on a Si(100) substrate at 400 ℃ by radio frequency (RF) magnetron co-sputtering using titanium nitride (TIN) and aluminum nitride (AlN) as ceramic targets. The temperature coefficient of resistivity (TCR) and oxidation resistance, which are the most important properties of a heat resistor, were studied depending on the plasma power density applied during sputtering. With the increasing plasma power density, the crystallinity, grain size and surface roughness of the applied film increased, resulting in less grain boundaries with large grains. The Ti, Al and N binding energies obtained from X-ray photoelectron spectroscopy analysis disclosed the nitrogen deficit in the TiAlN stoichiometry that makes the films more electrically resistive. The highest oxidation resistance and the lowest TCR of-765.43×10^-6 K-l were obtained by applying the highest plasma power density.
基金World Wildlife Fund (WWF) for providing financial support for the conduction of the research through Oaxaca Community Foundationthe National Council for Science and Technology supported the first author through grant for two years
文摘Re-vegetation plays a fundamental role for erosion control and plant recovery in lands affected by gully erosion. Bioengineered practices facilitate the gullies rehabilitation. Objectives of the research were: 1) Identify taxonomically the pioneer vegetation on each gully section; 2) Characterize vegetation distribution preferences and 3) Assess structural/functional traits to recognize erosion control key species. Bioengineering was applied in a watershed belonging to Sierra Madre del Sur, at Oaxaca, Mexico, on eight gullies, with local support and minimal investment. "La Mixteca" is a poor ecological and socio-economic region, comparable to other regions of the world. The Initial Floristic Composition(IFC) inventory is the baseline of the successional process. The transect method was used to determine the colonization of species. Cover abundance of registered species was estimated using the semi-quantitative scale of Braun-Blanquet. This procedure was repeated in five different positions(floor, hillslopes and tops), in the cross section of the gully. Throughcorrespondence analysis and clustering, the distribution of species was analyzed. Adequate responses were obtained in soil retention(quantity) and plant cover(existence and diversity); as measurable indicators of the bioengeneering works efficiency. Occupation of soil by native species from the Tropical Deciduous Forest was favored using live barriers. We detected species guilds with spatial distribution preferences in the gullies cross section. Plant cover characterization includes: native colonizer species, herbaceous, shrubby and trees of the forest community bordering the gully area, with cover abundance and structural/functional traits, useful to protect degraded areas. This spatial occupation process of plants responds to a secondary succession in gullies, where the proposed IFC model is correctly represented through bioengineering. Natural establishment of plants was successful by traits of species such as extensive root system and sexual/vegetative reproduction.
文摘A novel morphology-controlled strategy has been developed to fabricate sulfonated graphene/polyaniline (SGEP) nanocomposites by liquid/liquid interracial polymerization. Sulfonated graphene (SGE) sheets were synthesized and used as both a macromolecular acid dopant and substrate for the polymerization of polyaniline (PANI), affording the SGEP nanocomposites. The morphology of PAN! in the nanocomposites can be controlled to be either nanorods or nanogranules by varying the synthesis conditions. The morphology of SGEP and the shape of PANI can be tuned by adding an additional dopant and varying the amount of SGE used, and this had a significant influence on the electrochemical performance of the nanocomposites as supercapacitor electrode materials. The SGEP nanocomposite with PANI nanorods exhibited a specific capacitance of 763 F/g with a capacity retention of 96% after 100 cycles and good rate properties. Composites obtained with HCI as an additional acid dopant with two different ratios of SGE to PANI showed higher specific capacitances of 793 and 931 F/g, but lower capacity retention after 100 cycles of 77% and 76%, respectively.
基金supported by the National Research Foundation (Singapore) Competitive Research Program (Grant No. NRF-G-CRP 2007-05)
文摘Effects of an electric field on CO oxidation of Au-embedded graphene are investigated using first-principles method. Results of our calculations show that the initial step of the reaction is more likely to proceed via the Langmuir-Hinshelwood mechanism in the presence of the field, and the reaction barrier can be tuned continuously by the electric field. However, the applied electric field makes it more difficult for the product of the reaction, CO2, to desorb from the reaction site. These two competing effects make an electric field not entirely advantageous in controlling the activity of Au-embedded graphene for CO oxidation reaction. Nevertheless, the findings of our study provide a basis for further investigation on control of chemical reactions by electric fields.
文摘We apply polyelectrolyte multilayer films by consecutive alternate adsorption of positively charged polyallylamine hydrochloride and negatively charged sodium polystyrene sulfonate to the surface of graphene field effect transistors. Oscillations in the Dirac voltage shift with alternating positive and negative layers clearly demonstrate the electrostatic gating effect in this simple model system. A simple electrostatic model accounts well for the sign and magnitude of the Dirac voltage shift. Using this system, we are able to create p-type or n-type graphene at will. This model serves as the basis for understanding the mechanism of charged polymer sensing using graphene devices, a potentially technologically important application of graphene in areas such as DNA sequencing, biomarker assays for cancer detection, and other protein sensing applications.
基金supported by the National Natural Science Foundation of China(21006116,51362024)the Natural Science Foundation of Ningxia(NZ12111,NZ14010)the Prophase Research Special Project of the National Basic Research Program of China(2012CB723106)
文摘Herein, we describe a strategy for fabricating ordered mesoporous In2O3-reduced graphene oxide(r GO)nanocomposite through ultrasonic mixing, where ordered mesoporous In2O3 nanoparticles are synthesized via the nanocasting route by using mesoporous silica as a hard template, which possess ordered mesostructure with a large surface area of 81 m2g-1, and r GO nanosheets are synthesized from graphite via graphene oxide(GO) as intermediate. After coupled with r GO, mesoporous In2O3 could maintain its ordered mesostructure. We subsequently investigate the gas-sensing properties of all the In2O3 specimens with or without r GO for different gases. The results exhibit the ordered mesoporous In2O3-r GO nanocomposite possesses significantly enhanced response to ethanol even at low concentration levels, superior over pure mesoporous In2O3 nanoparticles. Similar strategy could be extended to other ordered mesoporous metal oxide–r GO nanocomposite for improving the gas-sensing property.
文摘As a traditional writing instrument for calligraphy and painting, the Chinese brush has enjoyed a high reputation over the last 5,000 years due to its ability to controllably handle liquid ink, and has been widely used to deposit ink into certain characters or figures as a means of cultural communication. In this mini-review, we first show how the key to the controllable liquid transfer in a Chinese brush lies in the anisotropic multi-scale structural features of the freshly emergent hairs. Then, drawing inspiration from this, applications in controllable liquid pumping, highly efficient liquid transfer and template-free printing microlines are addressed. We envision that the fundamentals of Chinese brushes and their applications in liquid manipulation mentioned in this review may also be extended to other liquid phase functional material systems.
文摘We report the gate-modulated Raman spectrum of defective graphene. We show that the intensity of the D peak can be reversibly tuned by applying a gate voltage. This effect is attributed to chemical functionalization of the graphene crystal lattice, generated by an electrochemical reaction involving the water layer trapped at the interface between silicon and graphene.
文摘The quest for materials and devices that are capable of controlling heat flux continues to fuel research on thermal controlling devices. In this letter, using molecular dynamics simulations, we demonstrate that a partially clamped singlelayer graphene can serve as a thermal modulator. The mismatch in phonon dispersion between the unclamped and clamped graphene sections results in phonon interface scattering, and the strength of interface scattering is tunable by controlling the clamp-graphene distance via applying the external pressure. Owing to the ultra-thin structure of graphene and its highly sensitive phonon dispersion to external physical interaction, the modulation efficiency--which is defined as the ratio of the highest to lowest heat flux-can reach as high as 150% at a moderate pressure of 50 GPa. This modulation efficiency can be further enhanced by arranging a number of clamps in series along the direction of the heat flux.
基金Supported in part by the National Natural Science Foundation of China under Grant Nos.11004082 and 11175067the Natural Science Foundation of Guangdong Province under Grant Nos.10451063201005249 and S201101000332the Fundamental Research Funds for the Central Universities,JNU under Grant Nos.21611437 and 50421288
文摘We study the thermal transport of few-layer graphene nanoribbons in the presence of the transversal pressure by using molecular dynamics simulations. It is reported that the pressure can improve the thermal conductivity of few-layer graphene nanoribbons. This improvement can reach 37.5% in the low temperature region. The pressure dependence of thermal conductivity is also investigated for different length, width and thickness of few-layer graphene. Our results provide an alternative option to tuning thermal conductivity of few-layer graphene nanoribbons, b-arthermore, it maybe indicate a so-called pressure-thermM effect in nanomaterials.