墨红净油化学成分的研究

墨红净油是采用E .Guenther方法[1] ,即用低温乙醇将墨红浸膏的蜡质除去制得的精制品 ,用GC/MS法分析鉴定出七十三种化合物 ,其中主要的化学成分有 :芳樟醇 ( 4 .16 5 % )、香叶醇 ( 2 2 .6 5 % )、左旋 -香茅醇 ( 9.74 3% )、苯乙醇( 14 .817% )、甲基丁香酚 ( 2 .4 2 3% )、丁香酚 ( 2 .95 9% )、反式异丁香酚 ( 2 .116 % )、顺式异丁香酚 ( 0 .94 2 % )、苯甲酸丁香酚酯 ( 7.2 6 6 % )、棕榈酸 ( 8.2 34% )

构造油基印刷墨

在油墨制造中,一些流变性问题如油墨流动太大,一组套色版油墨中的流动性有显著差别或者是在各批生产中有时得到无效的结果(由于流动性不一致),看来具有普遍性。我们所谈的油墨流动是指在低剪切速率下的流动,如在油墨墨汁中所看到的那样。

CL-20基炸药油墨的直写成型及性能研究

以六硝基六氮杂异伍兹烷(CL-20)作为主体炸药,乙基纤维素(EC)及聚叠氮类粘结剂为粘结剂,乙酸乙酯为溶剂,配制出一种全溶性炸药油墨。采用微控直写工艺将该炸药油墨在基板上进行了书写,并对成型后所得复合物的性能进行了测试和表征。结果表明:成型样品中CL-20颗粒形貌为球形,颗粒尺寸小于1μm,均匀分布在粘结体系基体中;成型样品的密度为1.66 g/cm^3,达到理论密度的85.5%;和原料CL-20相比,复合物的撞击感度得到明显降低,特性落高比原料CL-20高出21.5cm。该配方具有良好的传爆性能,1.2mm装药宽度下,爆轰临界尺寸为0.357mm。

墨红花超临界二氧化碳香味萃取成分的色谱－质谱法测定

由墨红花提取的精油或油树脂是优质的天然香料，被广泛用于化妆品和食品工业。超临界ＣＯ２萃取墨红花精油，既可保持很好的香气，又能克服传统的有机溶剂萃取时有残余溶剂的缺点。用气相色谱－质谱联用法对超临界ＣＯ２萃取物与石油醚萃取物中的组成进行了分析比较。色谱条件为：ＯＶ－１０１固定相，氦气，０．２ｍｍ×５０ｍ石英毛细管柱，柱温７０℃２ｍｉｎ，然后以５℃／ｍｉｎ程序升温至２５０℃。超临界萃取条件为５０℃，２１ＭＰａ，ＣＯ２流量为１０ｍＬ。发现超临界萃取物中的成分包括了石油醚萃取物中的多数主要香味成分，但对香味影响较小的、分子量较大的烷烃和烯烃的含量较少。超临界二氧化碳萃取物的香气与鲜花相近。

Selective glycerol oxidation using platinum nanoparticles supported on multi-walled carbon nanotubes and nitrogen-doped graphene hybrid

Selective oxidation of glycerol is a hot topic.Increased biodiesel production has led to glycerol oxidation over Au- and Pt-based catalysts being widely studied.However,Pt catalysts suffer from deactivation because of weak metal-support interactions.In this study,multi-walled carbon nanotube（MWCNTs）-pillared nitrogen-doped graphene（NG） was prepared by direct pyrolysis of melamine on MWCNTs,and the synthesized NG-MWCNT composite was used as the support for Pt.Characterization results showed that the surface area（173 m^2/g） and pore volume of the NG-MWCNT composite were greater than those of bare MWCNTs and the separated melamine pyrolysis product（CH_x）.Pt（1.4±0.4 nm） dispersion on the NG-MWCNTs was favorable and the Pt/NG-MWCNT catalyst was highly active and selective in the oxidation of glycerol to glyceric acid（GLYA） in base-free aqueous solution.For example,the conversion of glycerol reached 64.4% with a GLYA selectivity of 81.0%,whereas the conversions of glycerol over Pt/MWCNTs and Pt/CN_x were 29.0% and 31.6%,respectively.The unique catalytic activity of the Pt/NG-MWCNTs is attributed to well-dispersed Pt clusters on the NG-MWCNTs and the electron-donating effect of the nitrogen dopant in the NG-MWCNTs.

特种打印机用的消耗材料(三)

(上接2003年第2期) 5、局部背碳复写纸 局部背碳复写纸是在纸的背面需要复写的部位涂印上专用转印涂料,达到多联复写目的的物理转移型记录纸,应用于多联复写票据.如:税务缴款书、海关收款书、银行存款利息清单、转帐传票、航空人身保险单、飞机单、邮件清单、出租车专用发票、饭店饮品供应通知单、洗衣烫衣单、物资调拨单、收料领料单、铁路货运单据、职工工资明细表、医院门诊收据及多种商业汇票等单据.

连铸机结晶器高温润滑材料剖析及发展

本文对连铸机结晶器高温润滑材料保护渣、植物油及其代用品、氧氟石墨油的性质、使用进行了剖析。

Surface Modification of Pyrolytic Carbon Black from Waste Tires and Its Use as Pigment for Offset Printing Ink

Pyrolysis has the potential of transforming waste into valuable products. Pyrolytic carbon black (PCB) is one of the most important products resulting from the pyrolysis of used tires. One of the most significant applica-tions of modified pyrolytic carbon black is its use as pigment for offset printing ink to obtain high added values. Inverse gas chromatography (IGC) results show that a large quantity of inorganic matters and carbonaceous deposit are removed by treating the pyrolytic carbon black with nitric acid solution. Plenty of active sites originally occu-pied by inorganic ash and coke are recovered. The surface energy of pyrolytic carbon black (TWPC)modified by titanate-coupling agent-especially the specific interaction γ sspdetermined by the specific probe molecule, tolu-ene-shows the strong interaction between the TWPC and the synthetic resins. The offset printing ink performance confirms the IGC prediction. And TWPC has the great potential of applications in printing ink industry as pigment.

Preparation of low-temperature sintered high conductivity inks based on nanosilver self-assembled on surface of graphene

Finer nanoplates of silver are prepared by self-assembly on the surface of graphene,and the low-temperature sintered high conductivity ink containing the silver nanoplates is prepared.Most importantly,graphene is added to the solution before the chemical reduction reaction occurs.Firstly,it is found that silver nanoplates have self-assembly phenomenon on the surface of graphene.Secondly,the Ag nano hexagonal platelets(AgNHPs)with small particle sizes(10 nm),narrow distribution and good dispersion are prepared.Especially,smaller sizes(10 nm)and narrower particle size distribution of AgNHPs particles can be easily controlled by using this process.Finally,the conductivity of the ink is excellent.For example,when the printed patterns were sintering at 150℃,the resistivity of the ink(GE:0.15 g/L)reached the minimum value of 2.2×10^-6 cm.And the resistivity value was 3.7×10^-6Ωcm,when it was sintered at 100℃ for 30 min.The conductive ink prepared can be used for the field of printing electronics as ink-jet printing ink.

Effect of filler on the self-lubrication performance of graphite antimony composites

Graphite antimony composites were prepared using a mechanical pressure infiltration method to force molten antimony into graphite preforms having a percolation micro-structure and a hop-pocket power filler. The micro-structural and macroscopic properties of the graphite antimony composites were analysed. Observations included metallographic analysis, physical properties and friction and wear behaviour. The results show that the wear loss is decreased by 12.24% and that the friction coefficient is re-duced by 32.61% after hop-pocket power was used. The research indicates that the hop-pocket power method gives a useful way to reduce friction coefficients and wear loss, and to increase service life and self-lubrication properties, of the graphite antimony seal-ing material as compared to carbon black.

New Compacton Solutions and Solitary Pattern Solutions for Modified Nonlinearly Dispersive mK(m,n,a,b) Equation

In this paper exact solutions of a new modified nonlinearly dispersive equation （simply called inK（m, n, a, b） Ua Ub equation）, u^m-1 ut ＋ α（ u^n）x ＋β（u^a（u^b）xx）x = 0, is investigated by using some direct algorithms. As a result, abundant new compacton solutions （solitons with the absence of infinite wings） and solitary pattern solutions （having infinite slopes or cusps） are obtained.

Adsorption mechanism of expanded graphite for oil and dyes

Expanded graphite （r-;G） shows higher adsorption capacity for oils than for dyes. To illustrate the different adsorption mechanism of EG for these pollutants, adsorption capacities of dyes and oil on EG were firstly studied. And then stepwise adsorption for oils was carried out with EG which has been saturated firstly by dyes, the difference between adsorbance of oil on EG was checked with deviation analysis. Scanning electronic microscopy （SEM） analysis was used to show structure difference of EG adsorbed different adsorbates. These used adsorbates were SD300 oil, basic fuchsine, Auramine lake yellow O and acid brilliant red 3B. The adsorption isotherm of dyes on EG is type 11 or type 1, and their equilibrium adsorbances are less than 1.0 g/g. While, adsorbance for SD300 oil can reach 104.5 g/g. Deviation analysis for stepwise adsorbances of oil shows no statistical significance. EG saturated firstly by dyes, still has an average adsorption capacity of 35 g/g for SD300 oil, and it does not change with the initial dyes concentration. SEM photos illustrate the adsorption of oil on EG is mainly filling, In the adsorption of dyes, there is severe breakage of the V-type pore and shrinkage of the particle. Kinetic difference is analyzed also.

Analysis of ink flow channel between two rotating ink rollers

In order to research how the size of the ink flow channel is affected by the interaction of adjacent ink areas,according to the method of fluid-solid interaction,this paper analyzes the size of the ink flow channel of two ink rollers' rotation.Firstly,this paper simulates the situation of only one ink area.Secondly,this paper simulates the situation of five adjacent ink areas.Then,through comparing the simulation results of two above situations,it' s obvious that the interaction of adjacent ink areas has big effects on the ink pressure and the size of ink flow channel.At last,this paper gets the main factor that affects the size of ink flow channel in the different situations.

Ink Applied Research of Element Graphic Design Teaching in Intangible Cultural Context

With spreading and deepening of intangible cultural heritage protection movement in this century, Chinese ink art is among the Masterpieces of the Oral and Intangible Heritage of Humanity. Institutions of higher education is an academic heritage, culture, communication, personnel training platform and carrier, we assume an important role in the protection of heritage and ink art. Modem design teaching is in order to better local cultural heritage, but also to change their design education, more and more traditional elements are used in the classroom student design works. This paper aims to cultural connotations of traditional Chinese ink painting itself carrying elements and aesthetic charm of the excavation, analysis and sorting, which will be teaching in their designs into modem art. The contemporary art and design are to make cultural connotation and aesthetic meaning, making a good combination of tradition and art.

A Hybrid Dielectric Ink Consisting of up to 50 wt% of TiO2 Nanoparticles in Polyvinyl Alcohol （PVA）

PVA （Polyvinyl Alcohol） is a water soluble organic dielectric, easily solution processed to fabricate films by spin coating, dip coating or inkjet printing. It has been used as a dielectric layer in OTFTs （organic thin film transistors）, and its dielectric constant is around 3.5-10. For OTFTs operating at lower voltage, it is desirable to increase the dielectric constant. Here, we report a technique to incorporate upto 50 wt% of TiO2 nanoparticles （15-25 nm） in PVA to increase its dielectric constant. Rutile phase of TiO2 is used, because of its higher dielectric constant （e = 114） compared to anatase phase （E = 31）. We have made inks containing 10 and 50 wt% （of PVA） TiO2 nanoparticles, which is stable upto six months. PVA-TiO2 dispersions and PVA （without TiO2） were spin coated on indium tin oxide coated polyethylene terephthalate substrate. Film structure was studied using SEM （scanning electron microscopy）. Absorption study of the films confirms presence of TiO2 nanoparticles. M-I-M capacitors were fabricated by thermally evaporating aluminium on top of the dielectric films. We observed enhancement in dielectric constant by a factor of 2 for PVA containing 50 wt% TiO2 in comparison to PVA＇s dielectric constant. There is no concomitant increase in the leakage current.

Turbidite Petroleum Geology Updates in the Deepwater and Subsalt Gulf of Mexico

The past six years （2008-2014） was a prosperous time for exploration and production in the dGOM （deepwater Gulf of Mexico）. Recent exploration and production activities can be divided into three major categories： drilling new wildcat wells, appraising and developing newly discovered fields and enhanced oil recovery of mature fields. Seismic imaging, complex geology, high pressure drilling, greater depth, and higher temperature are key challenges for the exploration and production of dGOM reservoirs. Complex geology includes salt-related structures and traps, reservoir compartmentalization, and the sequence stratigraphy of turbidite reservoirs. Turbidite sequence stratigraphy helps the asset team to fred the best target intervals. Sheet and channelized sandstones with good downdip aquifer support are preferred reservoir conditions. All the drilling, development and production challenges are related to high pressure, greater depth, higher temperature and lack of existing field analogs. Various IOR （improved oil recovery） methods are studied and applied in the development stage of the Wilcox fields, which have an average primary recovery factor of 10%-15%. With ideal tabular reservoir geometry and IOR methods, recovery factor of the Wilcox reservoirs can reach up to 42% of OOIP （origional oil in place） through the field life cycle.

Scalable preparation of functionalized graphite nanoplatelets via magnetic grinding as lubricity-enhanced additive

Graphite nanoplatelets were prepared by a novel magnetic-grinding method using self-made equipments. Under a variant magnetic field, magnetic needles collided at a high rotating speed and exfoliated pristine graphite into graphite nanoplatelets with high efficiency. The obtained graphite nanoplatelets are highly crystalline, and the thickness is less than 10 nm. Moreover, the surface area could reached 738.1 m^2/g with a grinding time of 4 h. Silanized graphite nanoplatelets can disperse well in SG 15W-40 engine oil and serve as lubricant additive. Tribological results indicate that the friction coefficient and wear-scar of the friction pairs are lower than 76% and 41%, respectively, by adding 1.5‰(mass fraction) of silanized graphite nanoplatelets. Notably, the functionalized graphite nanoplatelets can realize large-scale production and commercial application.

An Evaluation of Nearshore Sediment Data after the Deepwater Horizon Blowout

The deepwater horizon blowout led to the release of 4.9 million barrels of crude oil into the Gulf of Mexico （GOM）. Here the paper analyzes available sediment datasets to determine whether changes in petrogenic contaminants are evident in GOM sediment following the blowout. Locations sampled by EPA （Environmental Protection Agency）, British Petroleum （BP） and NOAA （National Oceanic and Atmospheric Administration） were reduced and grouped into 46 similar locations and analyzed. Eleven groups suggested an increase in PAIl （polycyclic aromatic hydrocarbon） and nickel, one group showed a statistically significant increase in Phenanthrene. Four locations were analyzed for time trends and differences between initial and peak concentrations of oil range organics （ORO）, diesel range organics （DRO）, vanadium and nickel. One location had significant increases in ORO, DRO and vanadium and a suggestive increase in nickel. Correlations between ORO/DRO, ORO/V, ORO/Ni, V/Ni were computed （RE= 0.85, 0.67, 0.64, 0.92, respectively）. Overall, the analyses suggest that future monitoring should employ a sampling strategy that coordinates response sampling to previously sampled locations, such that baseline datasets can be used in detection of event associated contamination.

Graphene-Based Conducting Inks for Direct Inkjet Printing of Flexible Conductive Patterns and Their Applications in Electric Circuits and Chemical Sensors

A series of inkjet printing processes have been studied using graphene-based inks. Under optimized conditions, using water-soluble single-layered graphene oxide （GO） and few-layered graphene oxide （FGO）, various high image quality patterns could be printed on diverse flexible substrates, including paper, poly（ethylene terephthalate） （PET） and polyimide （PI）, with a simple and low-cost inkjet printing technique. The graphene-based patterns printed on plastic substrates demonstrated a high electrical conductivity after thermal reduction, and more importantly, they retained the same conductivity over severe bending cycles. Accordingly, flexible electric circuits and a hydrogen peroxide chemical sensor were fabricated and showed excellent performances, demonstrating the applications of this simple and practical inkjet printing technique using graphene inks. The results show that graphene materials--which can be easily produced on a large scale and possess outstanding electronic properties--have great potential for the convenient fabrication of flexible and low-cost graphene- based electronic devices, by using a simple inkjet printing technique.

Compatible hybrid 3D printing of metal and nonmetal inks for direct manufacture of end functional devices

The currently available 3D printing still cannot simultaneously deal with the metal and nonmetal inks together due to their huge difference in the melting points and poor compatible printability between each other. Here through introducing the low melting point alloy Bi35In48.6Sn16Zno.4 and silicone rubber as functional inks, we proposed a compatible hybrid 3D printing method for manufacturing the desired device, the supporting substrate and the allied package structure together. The principle of pneumatic-typed 3D printing of multiple inks was described and typical physical properties of the ink Bi35In48.6Sn16Zno.4 were measured. Several key factors dominating the printing quality such as the temperature of the printing head, the air pressure exerted upon the liquid metal ink in the syringe, the moving velocity and the height of the printing head etc. were clarified. A general way of directly printing out 3D structured electronic devices consisting of both metal and nonmetal materials was demonstrated. Such hybrid objects were patterned and formed up layer by layer with Bi35In48.6Sn16Zno.4 alloy and silicone rub- ber which would become solidified after standing for a period of time under room temperature. To illustrate the compatible printability of these printing inks, a three-layer tricolor LED stereo circuit with controlled lighting capability was further man- ufactured and evaluated. The present study opens an important hybrid 3D printing way for directly manufacturing functional and structural end devices in an easy and low cost way.