The water characteristic curve for aeolian sand in two processes of wetting and drying was obtained by the negative water column technique.The values of fitting parameters were calculated according to Van Genuchten fo...The water characteristic curve for aeolian sand in two processes of wetting and drying was obtained by the negative water column technique.The values of fitting parameters were calculated according to Van Genuchten formula and the parameters that characterized the prosperities of aeolian sand such as the unsaturated infiltration coefficient and specific water capacity were obtained.The results showed that the water characteristic curve for aeolian sand in wetting process had greater hysteresis quality than ...展开更多
Bauxite residue is a highly alkaline waste product from refining bauxite ore.Bioremediation driven by microbial activities has been evidently effective in lowering the alkalinity of bauxite residues,which is critical ...Bauxite residue is a highly alkaline waste product from refining bauxite ore.Bioremediation driven by microbial activities has been evidently effective in lowering the alkalinity of bauxite residues,which is critical to the initiation of pedogenesis under engineered conditions.The present study investigated the changes of alkalinity and aggregation of bauxite residue at different depth in response to the colonization of Penicillium oxalicum in columns.The results demonstrated that the inoculation of P.oxalicum decreased the residue’s pH to about 7 after 30 d only at the surface layer,which was exposed to aerobic conditions.The formation of aggregates was improved overall in the organic matter treated bauxite residue.However,the EC of bauxite residue increased with time under the incubation condition,probably due to accelerated hydrolysis of sodium-rich minerals.The inoculation of P.oxalicum had no effects on urease activity,but increased cellulose enzyme activity at surface layer only.展开更多
The shortcomings of the present two formulae for describing column holdup are analyzed and deductions are made to find a new formula. The column holdup, Hw, described by the new formula is dimensional, and related to ...The shortcomings of the present two formulae for describing column holdup are analyzed and deductions are made to find a new formula. The column holdup, Hw, described by the new formula is dimensional, and related to soil solute transport kinesis and column physical properties. Compared with the other two column holdups, Hw is feasible to describe dimensional column holdup during solute transport process. The relationships between Hw and retardation factor, R, in different solute transport boundary conditions are established.展开更多
A thorough understanding of bacteria transport in soil and groundwater is vital to the successful practice of environmental bioremediation.In this work,a dual-process adsorption with growth and decay model of bacteria...A thorough understanding of bacteria transport in soil and groundwater is vital to the successful practice of environmental bioremediation.In this work,a dual-process adsorption with growth and decay model of bacterial transport was proposed.The onsite soil and the high efficiency methyl tertbutyl ether (MTBE) degrading bacterium Chryseobacterium sp.A-3,was used in the experiments.The model was validated using one-dimensional soil column experiments.The results show that the dual-process adsorption with growth and decay model proposed well describes the migration mechanism of microorganisms in soil and groundwater environment.According to the model analysis and simulation,the bacterial transport is enhanced as flow velocity and inlet cell concentration increase.Compared with the contaminant MTBE,the bacteria show stronger transport capacity but the irreversible straining in soil prevents the bacteria from transporting longer than MTBE.The results have certain instructive significance to the insitu contamination remediation operation.展开更多
Human health has been potentially threatened by cadmium (Cd) contained in sewage irrigation water.Previous studies of Cd transport in soils were mainly conducted using small soil cores with pH values less than 6.The o...Human health has been potentially threatened by cadmium (Cd) contained in sewage irrigation water.Previous studies of Cd transport in soils were mainly conducted using small soil cores with pH values less than 6.The objectives of this study were to determine the parameters of the convection-dispersion equation (CDE) for Cd transport in relatively larger columns with neutral and alkaline soils,and to investigate the parameters' variability with depth.The soil columns were 50 cm in length and 12.5 cm in diameter.Ceramic suction lysimeters were buried at depths of 2.5,7.5,17.5,27.5,and 37.5 cm to abstract soil solution.Cd concentration in the soil solution samples were subsequently analyzed to obtain breakthrough curves (BTCs).Equilibrium and nonequilibrium models in CXTFIT program were used to estimate parameters of the CDE.The results suggested that both equilibrium and non-equilibrium models performed well in modeling Cd transport.The hydrodynamic dispersion coefficient (D) ranged from 0.18 to 10.70 cm 2 h 1,showing large differences among different depths.The retardation factor (R d) ranged from 25.4 to 54.7 and the standard deviation of R d value was lower than 30% of the mean value.Precipitation coefficient (R p) decreased consistently with increasing depth,varying from 1.000 × 10 10 to 0.661 h 1.Sensitivity tests showed that D was less sensitive than R d.These results would be helpful in understanding the transport and retention of Cd in non-acidic soils.展开更多
In Burkina Faso, significant amounts of endosulfan are applied to cotton fields; in addition, urban vegetable agriculture is often characterised by high fertiliser inputs, such as urban solid wastes containing heavy m...In Burkina Faso, significant amounts of endosulfan are applied to cotton fields; in addition, urban vegetable agriculture is often characterised by high fertiliser inputs, such as urban solid wastes containing heavy metals(e.g., Cu and Cd). Thus, the relevance of surrounding cotton and urban vegetable plots with vetiver(Vetiveria zizanioides) hedges to reduce environmental pollution by micropollutants was investigated using a leaching experiment, with outdoor lysimeters filled with two representative agricultural soils of Burkina Faso: Vertisol and Lixisol. After 6 months, little Cu was found in the leachates(< 0.010% of the applied amount) due to its high adsorption coefficient and its tendency to remain at the soil surface. Despite leachate and bromide recoveries being greater in soils planted with vetiver grass than in the bare soils, smaller amounts of endosulfan and Cd were found in the effluents from the planted soils(0.01% to 0.70% of the applied amount) than in those from the bare soils(0.01% to 1.48% of the applied amount), in agreement with their adsorption coefficients. These results may also be explained by a greater degradation of endosulfan in planted soils compared to bare soils and the absorption of Cd by vetiver. Thus, vetiver may decrease the risk of groundwater contamination,especially for Cd and endosulfan, which are more mobile than Cu. In addition, despite the smaller amounts of endosulfan and Cd measured in the Vertisol leachates(0.01% and 0.04% of the applied amount, respectively) compared to the Lixisol leachates, vetiver was more effective in decreasing the leaching of micropollutants if planted on Lixisol rather than on Vertisol. Further field monitoring is necessary to demonstrate the effectiveness of vetiver under the climatic conditions of Burkina Faso.展开更多
This work presents an analysis of the influence of stress anisotropy on cylindrical cavity expansions in an undrained elastic-perfectly plastic soil. This problem was formulated by assuming a large strain in both the ...This work presents an analysis of the influence of stress anisotropy on cylindrical cavity expansions in an undrained elastic-perfectly plastic soil. This problem was formulated by assuming a large strain in both the elastic and plastic zones around the cavity and a plain strain condition during the cavity expansion process. The solutions for the limit pressure, stress, and excess pore pressure were obtained by introducing the anisotropic initial stress coefficient K_0 into the conventional cylindrical cavity expansion method.The proposed solutions were then used to interpret the piezocone penetration test, and the suitability of the solutions was verified by comparing the prediction with the piezocone penetration test data. Subsequently, parametric studies were carried out to investigate the influence of stress anisotropy on the stress, excess pores pressure distributions around an expanding cylindrical cavity, and limit pressure. The results show that the proposed cylindrical cavity expansion method under stress anisotropy is suitable and can be used to investigate the piezocone cone test. The present work improves upon the conventional theoretical framework of cavity expansion and can be applied to the determination of the stresses around axially loaded piles and around in-situ testing devices such as penetrometers.展开更多
基金Supported by Key Project of Science and Technology Research of Ministry of Education(308021)Chang Jiang Scholars Innovation Team of Ministry of Education(IRT0811)Geological Survey Project of China Geological Survey(1212010331302)~~
文摘The water characteristic curve for aeolian sand in two processes of wetting and drying was obtained by the negative water column technique.The values of fitting parameters were calculated according to Van Genuchten formula and the parameters that characterized the prosperities of aeolian sand such as the unsaturated infiltration coefficient and specific water capacity were obtained.The results showed that the water characteristic curve for aeolian sand in wetting process had greater hysteresis quality than ...
基金Projects(41877511,41842020)supported by the National Natural Science Foundation of ChinaProject(2018zzts421)supported by the Innovative Project of Independent Exploration of Central South University,China
文摘Bauxite residue is a highly alkaline waste product from refining bauxite ore.Bioremediation driven by microbial activities has been evidently effective in lowering the alkalinity of bauxite residues,which is critical to the initiation of pedogenesis under engineered conditions.The present study investigated the changes of alkalinity and aggregation of bauxite residue at different depth in response to the colonization of Penicillium oxalicum in columns.The results demonstrated that the inoculation of P.oxalicum decreased the residue’s pH to about 7 after 30 d only at the surface layer,which was exposed to aerobic conditions.The formation of aggregates was improved overall in the organic matter treated bauxite residue.However,the EC of bauxite residue increased with time under the incubation condition,probably due to accelerated hydrolysis of sodium-rich minerals.The inoculation of P.oxalicum had no effects on urease activity,but increased cellulose enzyme activity at surface layer only.
基金Project (No. 49901009) supported by the National Natural Science Foundation of China.
文摘The shortcomings of the present two formulae for describing column holdup are analyzed and deductions are made to find a new formula. The column holdup, Hw, described by the new formula is dimensional, and related to soil solute transport kinesis and column physical properties. Compared with the other two column holdups, Hw is feasible to describe dimensional column holdup during solute transport process. The relationships between Hw and retardation factor, R, in different solute transport boundary conditions are established.
基金Supported by the National High Technology Research and Development Program of China(2009AA063102)
文摘A thorough understanding of bacteria transport in soil and groundwater is vital to the successful practice of environmental bioremediation.In this work,a dual-process adsorption with growth and decay model of bacterial transport was proposed.The onsite soil and the high efficiency methyl tertbutyl ether (MTBE) degrading bacterium Chryseobacterium sp.A-3,was used in the experiments.The model was validated using one-dimensional soil column experiments.The results show that the dual-process adsorption with growth and decay model proposed well describes the migration mechanism of microorganisms in soil and groundwater environment.According to the model analysis and simulation,the bacterial transport is enhanced as flow velocity and inlet cell concentration increase.Compared with the contaminant MTBE,the bacteria show stronger transport capacity but the irreversible straining in soil prevents the bacteria from transporting longer than MTBE.The results have certain instructive significance to the insitu contamination remediation operation.
基金Supported by the National Natural Science Foundation of China (No. 51179166)the National Basic Research Program(973 Program) of China (No. 2006CB403406)
文摘Human health has been potentially threatened by cadmium (Cd) contained in sewage irrigation water.Previous studies of Cd transport in soils were mainly conducted using small soil cores with pH values less than 6.The objectives of this study were to determine the parameters of the convection-dispersion equation (CDE) for Cd transport in relatively larger columns with neutral and alkaline soils,and to investigate the parameters' variability with depth.The soil columns were 50 cm in length and 12.5 cm in diameter.Ceramic suction lysimeters were buried at depths of 2.5,7.5,17.5,27.5,and 37.5 cm to abstract soil solution.Cd concentration in the soil solution samples were subsequently analyzed to obtain breakthrough curves (BTCs).Equilibrium and nonequilibrium models in CXTFIT program were used to estimate parameters of the CDE.The results suggested that both equilibrium and non-equilibrium models performed well in modeling Cd transport.The hydrodynamic dispersion coefficient (D) ranged from 0.18 to 10.70 cm 2 h 1,showing large differences among different depths.The retardation factor (R d) ranged from 25.4 to 54.7 and the standard deviation of R d value was lower than 30% of the mean value.Precipitation coefficient (R p) decreased consistently with increasing depth,varying from 1.000 × 10 10 to 0.661 h 1.Sensitivity tests showed that D was less sensitive than R d.These results would be helpful in understanding the transport and retention of Cd in non-acidic soils.
基金financially supported in part by a CORUS Ⅱ Projecta Gabonese Government Fellowship
文摘In Burkina Faso, significant amounts of endosulfan are applied to cotton fields; in addition, urban vegetable agriculture is often characterised by high fertiliser inputs, such as urban solid wastes containing heavy metals(e.g., Cu and Cd). Thus, the relevance of surrounding cotton and urban vegetable plots with vetiver(Vetiveria zizanioides) hedges to reduce environmental pollution by micropollutants was investigated using a leaching experiment, with outdoor lysimeters filled with two representative agricultural soils of Burkina Faso: Vertisol and Lixisol. After 6 months, little Cu was found in the leachates(< 0.010% of the applied amount) due to its high adsorption coefficient and its tendency to remain at the soil surface. Despite leachate and bromide recoveries being greater in soils planted with vetiver grass than in the bare soils, smaller amounts of endosulfan and Cd were found in the effluents from the planted soils(0.01% to 0.70% of the applied amount) than in those from the bare soils(0.01% to 1.48% of the applied amount), in agreement with their adsorption coefficients. These results may also be explained by a greater degradation of endosulfan in planted soils compared to bare soils and the absorption of Cd by vetiver. Thus, vetiver may decrease the risk of groundwater contamination,especially for Cd and endosulfan, which are more mobile than Cu. In addition, despite the smaller amounts of endosulfan and Cd measured in the Vertisol leachates(0.01% and 0.04% of the applied amount, respectively) compared to the Lixisol leachates, vetiver was more effective in decreasing the leaching of micropollutants if planted on Lixisol rather than on Vertisol. Further field monitoring is necessary to demonstrate the effectiveness of vetiver under the climatic conditions of Burkina Faso.
基金supported by the National Natural Science Foundation of China(Grant Nos.51420105013&51708063)the State Key Laboratory for Geomechanics and Deep Underground Engineering,China University of Mining and Technology(Grant No.SKLGDUEK1713)Chongqing Research Program of Basic Research and Frontier Technology(Grant No.cstc2017jcyjAX0261)
文摘This work presents an analysis of the influence of stress anisotropy on cylindrical cavity expansions in an undrained elastic-perfectly plastic soil. This problem was formulated by assuming a large strain in both the elastic and plastic zones around the cavity and a plain strain condition during the cavity expansion process. The solutions for the limit pressure, stress, and excess pore pressure were obtained by introducing the anisotropic initial stress coefficient K_0 into the conventional cylindrical cavity expansion method.The proposed solutions were then used to interpret the piezocone penetration test, and the suitability of the solutions was verified by comparing the prediction with the piezocone penetration test data. Subsequently, parametric studies were carried out to investigate the influence of stress anisotropy on the stress, excess pores pressure distributions around an expanding cylindrical cavity, and limit pressure. The results show that the proposed cylindrical cavity expansion method under stress anisotropy is suitable and can be used to investigate the piezocone cone test. The present work improves upon the conventional theoretical framework of cavity expansion and can be applied to the determination of the stresses around axially loaded piles and around in-situ testing devices such as penetrometers.