高效壤气汞捕集器研制

针对以往化探技术中壤气汞方法吸附材料吸附性不均一,以及操作过程中容易造成污染的问题,研制了多层捕汞管吸附技术与捕汞管富集器相结合的壤气汞捕集器。经标准气样品分析测试验证,结果表明:捕集器吸附性良好,稳定性高,测试性能满足各项指标。在含山昭关地热化探野外试验中显示,该捕集器能够有效吸附壤中气的微量气态汞,应用效果良好。该捕集器完善了化探样品的壤气汞富集分析和技术,具有良好的应用前景。

活动断裂带的壤中气汞量测量研究

在覆盖区应用壤中气汞量测量研究活动断裂是一种新方法,它不仅能较准确地确定活动断裂的位置,还可以确定其产状、规模、活动性及相对强度,甚至可以作为确定断裂力学性质的参考。本文简述了断裂带壤中气汞量测量的基本原理,并以长江三峡、长春、吉林等地利用该种方法研究活动断裂的成果为例,说明该项研究的效果及应用前景。

利用壤中汞气测量在西天山高寒山区寻找隐伏矿的研究

通过在西天山高寒山区已知火山热液型铜矿点外围矿化剖面和冰雪水沉积、洪积厚层覆盖区激电异常上的壤中汞气测量试验 ,进而扩大到面积性测量 ,均取得了显著的地质效果。结果表明 ,壤中汞气测量在高寒条件下仍是一种快速、经济、有效的方法 。

沙泉子铜镍矿壤中汞气和二氧化硫气体地球化学测量

为研究壤中汞气与二氧化硫气体地球化学测量在干旱戈壁荒漠区隐伏铜镍矿的找矿效果,设计了对沙泉子隐伏铜镍矿壤中汞气与二氧化硫气体的地球化学剖面测量试验,取得了较好的结果。壤中汞气与二氧化硫气体在隐伏矿化体上方出现不同程度的异常特征,说明这两种方法在试验区对寻找隐伏铜镍矿有一定效果,为在干旱戈壁荒漠区找矿提供了新思路。

壤中汞气测量方法在临江大松树金矿的应用

汞作为地球化学勘查中具有较大找矿潜力的远程指示元素,汞异常与金属硫化物及构造破碎带关系密切。在中低温热液型矿产普查中,尤其是对破碎带蚀变岩型金矿普查中具有更好的效果,笔者在大松树金矿普查中摸索出一些经验,并取得了较好的地质找矿成果。

Advances of study on atmospheric methane oxidation (consumption) in forest soil

Next to CO2, methane (CH4) is the second important contributor to global warming in the atmosphere and global atmospheric CH4 budget depends on both CH4 sources and sinks. Unsaturated soil is known as a unique sink for atmospheric CH4 in terrestrial ecosystem. Many comparison studies proved that forest soil had the biggest capacity of oxidizing atmospheric CH4 in various unsaturated soils. However, up to now, there is not an overall review in the aspect of atmospheric CH4 oxidation (consumption) in forest soil. This paper analyzed advances of studies on the mechanism of atmospheric CH4 oxidation, and re-lated natural factors (Soil physical and chemical characters, temperature and moisture, ambient main greenhouse gases con-centrations, tree species, and forest fire) and anthropogenic factors (forest clear-cutting and thinning, fertilization, exogenous aluminum salts and atmospheric deposition, adding biocides, and switch of forest land use) in forest soils. It was believed that CH4 consumption rate by forest soil was limited by diffusion and sensitive to changes in water status and temperature of soil. CH4 oxidation was also particularly sensitive to soil C/N, Ambient CO2, CH4 and N2O concentrations, tree species and forest fire. In most cases, anthropogenic disturbances will decrease atmospheric CH4 oxidation, thus resulting in the elevating of atmos-pheric CH4. Finally, the author pointed out that our knowledge of atmospheric CH4 oxidation (consumption) in forest soil was insufficient. In order to evaluate the contribution of forest soils to atmospheric CH4 oxidation and the role of forest played in the process of global environmental change, and to forecast the trends of global warming exactly, more researchers need to studies further on CH4 oxidation in various forest soils of different areas.

Soil carbon dioxide fluxes of a typical broad-leaved/Korean pine mixed forest in Changbai Mountain, China

The forest ecosystem plays an important role in the global carbon cycling. A study was conducted to evaluate soil CO2 flux and its seasonal and diurnal variation with the air and soil temperatures by using static closed chamber technique in a typical broad-leaved/Korean pine mixed forest area on the northern slope of Changbai Mountain, Jilin Province, China. The experiment was carried out through the day and night in the growing season (from June to September) in situ and sample gas was analyzed by a gas chromatograph. Results showed that the forest floor was a large net source of carbon, and soil CO2 fluxes had an obvi-ous law of seasonal and diel variation. The soil CO2 flux of broad-leaved/Korean pine mixed forest was in the range of 0.302.42 mmol穖-2穝-1 with the mean value of 0.98 mmol穖-2穝-1. An examination on the seasonal pattern of soil CO2 emission suggested that the variability in soil CO2 flux could be correlated with variations in soil temperature, and the maximum of mean CO2 flux occurred in July ((1.27±23%) mmol穖-2穝-1) and the minimum was in September ((0.50±28%) mmol穖-2穝-1). The fluctuations in diel soil CO2 flux were also correlated with changes in soil temperature; however, there existed a factor for a time lag. Soil CO2 flux from the forest floor was strongly related to soil temperature and had the highest correlation with temperature at 6-cm depth of soil. Q10 values based on air temperature and soil temperature of different soil depths were at the ranges of 2.09–3.40.

Research Advance on Sod Culture in Peach Orchard

Sod culture in peach orchards is an advanced soil management. The significances of sod culture in peach orchard are introduced, as well as the sod ways. The effects of sod culture in a peach orchard on soil, microclimate and growth and development of peach tree, and disease, pest and weed are reviewed. The problems in sod culture in peach orchard in China are summarized. Sod culture could increase soil fertility, improve soil physical properties, relieve soil temperature change, increase soil microbial growth and soil enzyme activity, improve microclimate and fruit quality, reduce physiological disease, insect pests and weeds.

Landscape patterns of overstory litterfall and related nutrient fluxes in a cool-temperate forest watershed in northern Hokkaido,Japan

Within a forested watershed at the Uryu Experimental Forest of Hokkaido University in northern Hokkaido, overstory litterfall and related nutrient fluxes were measured at different landscape zones over two years. The wetland zone covered with Picea glehnii pure stand. The riparian zone was deciduous broad-leaved stand dominated by Alnus hirsuta and Salix spp., while the mixture of deciduous broadleaf and evergreen conifer dominated by Betula platyphylla, Quercus crispula and Abies sachalinensis distributed on the upland zone. Annual litterfall averaged 1444, 5122, and 4123 kg.hm^-2·a^-1 in the wetland, riparian and upland zones, respectively. Litterfall production peaked in September-October, and foliage litter contributed the greatest amount （73.4%-87.6 %） of the annual total litterfall. Concentrations of nutrients analyzed in foliage litter of the dominant species showed a similar seasonal variation over the year except for N in P glehnii and A. hirsuta. The nutrient fluxes for all elements analyzed were greatest on riparian zone and lowest in wetland zone. Nutrient fluxes via litterfall followed the decreasing sequence： N （11-129 kg.hm-2.aq） 〉 Ca （9-69） 〉 K （5-20） 〉 Mg （3-15） 〉 P （0.4-4.7） for all stands. Significant differences were found in litterfall production and nutrient fluxes among the different landscape components. There existed significant differences in soil chemistry between the different landscape zones. The consistently low soil C：N ratios at the riparian zone might be due to the higher-quality litter inputs （largely N-fixing alder）.

Characteristics of Fluoride Contents in Plants and Soils in Kaili City Under Air Pollution

Fluoride contents in plants and soils in Kaili City were measured with fluorinion as per electrode method and the related characteristics were analyzed in order to explore effects of air fluoride pollution on plant and soil.The results indicated that fluoride content in plants tended to be volatile in 135.62-1 420.97 μg/g and averaged 513.99 μg/g;fluoride content in soils changed from 240.50-340.36 μg/g and averaged 279.60 μg/g.The contents of plant and soil both exceeded background value,suggesting that plants and soils in the region have been polluted.In addition,fluoride contents differ significantly upon plants.In detail,the maximal content was in Camelliaolelfera Abel and the minimal in Camelliaolelfera Abel.The contents of fluoride in different plant species vary,as follows：shrub vine herbaceous plant arbor;evergreen plants deciduous plant;fluoride contents in plants and soils also differ in varying degrees upon research sites.

The Effects of Climate,Soil and Cultivar on the Content of Surface Trichome Exudates from Fresh Flue-cured Leaves

[Objective] The aim was to study the effect of climate and soil on the content of surface trichome exudates from fresh flue-cured leaves. [Method] The experiment was conducted in 2009 in Longgang, Weining and Tianzhu of Guizhou Province with flue-cured tobacco variety Yun 85. Mature tobacco leaves were taken from lower, middle and upper plant positions respectively and major cuticular com-ponents of the leaves were extracted with methylene chloride and their chemical compositions were analyzed with GC-MS. [Result] The result showed that there was large difference among trichome exudates of leaves grown under different climatic conditions. The leaf trichome exudates from Tianzhu were quite higher than those from Weining and Longgang, and trichome exudates difference between Tianzhu and Longgang was significant. Soil conditions had considerable effect on the content of tobacco leaf surface trichome exudates, leaf from Longgang soil had highest con-tent, fol owed by Tianzhu soil leaf, Weining soil leaf had lowest content. Under vari-ous climatic conditions, the contents of leaf trichome exudates of same soil were in-consistent, indicating the presence of certain climate and soil factor interaction; The contents of leaf trichome exudates from four cultivars in Longgang showed large difference, Nanjiang 3 was the lowest, fol owed by K326, Guiyan 201 was high, and Yunyan85 the highest. The content of leaf trichome exudates of Yunyan85 was more than two times of that of Nanjiang 3. [Conclusion] The Effect of climate factor on the content of leaf trichome exudates was greater than that of cultivar, which was then larger than soil condition.

Research Progress on Ecological Safety Assessment of the Farming-pastoral Ecotone in China

[Objective] The study was conducted to overview the farming-pastoral ecotone research progress in China.[Methods] Started from the influences on soil,precipitation and water conservation,climate and mulching of different land use types,the paper summarized the current research situation on several hot issues and proposed suggestions for future study.[Results] Researches on farming-pastoral ectone in China have achieved great progress,but still require more deep and comprehensive studies.Suggestions：Current studies should focus on solutions for degradation of farmland and grassland;Conduct deeper analysis on the relatively weaker aspects in a multi-domain fusion type;Implement the study results on eco-environmental recovery,production improvement and other practical activities;Lift the research of ecotone to a national or even global level,and make them far more comprehensive.[Conclusion] Provide theoretical basis for ecological protection of farming-pastoral ecotone in our country.

Dynamics of Soil CO_2 Profiles of Pinus sylvestris var. sylvestriformis Seedlings Under CO_2 Concentration Doubled

The gas_well system permanently installed in the soil was adopted for studying the dynamic relationship between CO 2 profiles and seedling root growth of Pinus sylvestris var. sylvestriformis (Takenouchi) Cheng et C. D. Chu. The study was conducted in the Open Research Station of Changbai Mountain Forest Ecological System, The Chinese Academy of Sciences from 1999 to 2001. Four treatments were arranged in the rectangular open_top chambers (OTCs): ambient CO 2+no_seedling, 700 μmol/mol CO 2+no_seedling, ambient CO 2 +seedlings, 700 μmol/mol CO 2+seedlings. By collecting and analyzing soil gas synchronously, it was found that the dynamics of CO 2 profiles were related to the biological activity of seedlings. There were more roots distributed in the top soil and the boundary layer across soil and sand, which made more contributions to the CO 2 profiles due to respiration root. Compared with the ambient CO 2, elevated CO 2 led to the peak of CO 2 concentration distribution shifted from soil surface layer to the boundary layer as seasonally growing of seedling roots. It is suggested the gas_well system is an inexpensive, non_destructive and relatively sensitive method for study of soil CO 2 concentration profiles.

Adaptive responses of Acer ginnala, Pyrus ussuriensis and Prunus davidiana seedlings to soil moisture stress

One-year-old seedlings of Amur maple (Acer ginnala Maxim), Ussurian pear (Pyrus ussuriensis Maxim) and David peach (Prunus davidiana Carr) were planted in pots in greenhouse and treated with four different soil moisture contents (75.0%, 61.1%, 46.4% and 35.4%). The results showed that net photosynthesis rate (NPR), transpiration rate (TR) and stomatal conductance (Sc) of seedlings of the three species decreased with the decease of soil moisture content, and Amur maple seedlings had the greatest change in those physiological indices, followed by Ussurian pear, David peach. Amur maple and Ussurian pear seedlings also presented a decrease tendency in water use efficiency (WUE) under lower soil moisture content, whereas this was reversed for David peach. Under water stress the biomass allocation to seedling root had a significant increase for all the experimental species. As to root/shoot ratio, Amur maple seedlings had the biggest increase, while David peach had the smallest increase. The leaf plasticity of Amur maple seedlings was greater, the leaf size and total leaf area decreased significantly as the stress was intensified. No significant change of leaf size and total leaf area was found in seedlings of Ussurian pear and David peach. It was concluded that Amur maple was more tolerant to soil moisture stress in comparison with David peach and Ussurian pear.

Streamflow and Soil Moisture of Agroforestry and Grass Watersheds in Hilly Area

A study was conducted in a hilly area of Sichuan Province,Southwestern China, to compare the streamflow and soil moisture in two upland watersheds with different land use patterns. One was an agroforestry watershed, which consisted mainly of trees with alder (Alnus cremastogyne Burkill) and cypress (Cupressus funebris Endl.) planted in belts or strips with a coverage of about 46%, and the other was a grassland primarily composed of lalang grass (Imperata cylindrica var. major (Nees) C. E. Hubb.), filamentary clematis (Clematis filamentosa Dunn) and common eulaliopsis (Eulaliopsis binata (Retz.) C. E. Hubb) with a coverage of about 44%. Streamflow measurement with a hydrograph established at the watershed outlet showed that the average annual streamflow per 100 mm rainfall from 1983 to 1992 was 0.36 and 1.08 L s-1 km-2 for the agroforestry watershed and the grass watershed, respectively. This showed that the streamflow of the agroforestry watershed was reduced by 67% when compared to that of the grass watershed. The peak average monthly streamflow in the agroforestry watershed was over 5 times lower than that of the grass watershed and lagged by one month. In addition, the peak streamflow during a typical rainfall event of 38.3 mm in August 1986 was 37% lower in the agroforestry watershed than in the grass watershed. Results of the moisture contents of the soil samples from 3 slope locations (upper, middle and lower slopes) indicated that the agroforestry watershed maintained generally higher soil moisture contents than the grass watershed within 0-20 and 20-80 cm soil depths for the upper slope, especially for the period from May through July. For the other (middle and lower) slopes, soil moisture contents within 20-80 cm depth in the agroforestry watershed was generally lower than those in the grass watershed, particularly in September, revealing that water consumption by trees took place mainly below the plow layer. Therefore, agroforestry land use types might offer a complimentary model for tree-annual crop water utilization.

Comparisons of the effects of different drying methods on soil nitrogen fractions:Insights into emissions of reactive nitrogen gases(HONO and NO)

Reactive nitrogen(Nr)emission from soils,e.g.,nitrous acid(HONO)and nitric oxide(NO),is a key process of the global nitrogen(N)cycle and has significant implications for atmospheric chemistry.To understand the underlying mechanisms of soil Nr emissions,air-dried or oven-dried soils are commonly used in the laboratory.To date,few studies have compared the effects of different drying methods on soil Nr gas fluxes and N fractions.Here,the authors studied soil water content,pH,(in)organic N content,and Nr gas fluxes of air-dried,freeze-dried,oven-dried,and fresh soils from different land-use types.The results showed that the soil pH of air-dried and oven-dried samples was significantly lower compared with fresh soil from farmland and grassland,but higher compared with forest soil.The difference in soil pH between freeze-dried and fresh soil(mean±standard deviation:0.52±0.31)was the lowest.In general,all drying methods increased the soil NH4+-N,NO3−-N,and dissolved organic N contents compared with fresh soil(P<0.05).The maximum HONO and NO flux and total emissions during a full wetting–drying cycle of fresh soil were also increased by air-drying and oven-drying(P<0.001),but comparable with freeze-dried soil(P>0.2).In conclusion,all drying methods should be considered for use in studies on the land–atmosphere interface and biogeochemical N cycling,whereas the freeze-drying method might be better for studies involving the measurement of soil Nr gas fluxes.

Kinetic Mass Transfer Between Non-aqueous Phase Liquid and Gas During Soil Vapor Extraction

The mass transfer between non-aqueous phase liquid(NAPL) phase and soil gas phase in soil vapor extraction(SVE) process has been investigated by one-dimensional venting experiments. During quasi-steady volatilization of three single-component NAPLs in a sandy soil, constant initial lumped mass transfer coefficient (λgN,0) canbe obtained if the relative saturation (ξ) between NAPL phase and gas phase is higher than a critical value (ξc), andthe lumped mass transfer coefficient decreases with ξ when ξ＜ξc. It is also shown that the lumped mass transfercoefficient can be increased by blending porous micro-particles into the sandy soil because of the increasing of theinterfacial area.

Measurement and Result of Soil Gas Radon and Soil Gas Mercury in the Exploration of Haihe Hidden Fault

In the exploration of the hidden Haihe fault,radon and mercury in soil gas were measured by using FG-3017 radon detector and XG-4 mercury analyzer.In this paper,based on the measurement results of 12 fault gas profiles,and integrating with the exploration results of artificial seismic prospecting,the relationship between anomalous site of fault gas and fault location is analyzed.Using the relationship between anomalous strength of fault gas and fault activity,the activity of Haihe fault is studied,thus the location and activity segmentation of the Haihe fault in Tianjin region are presented.This study shows that the method of fault gas detection can not only identify the preliminary location of fault,but also make preliminary segmentation of fault activity.The fault detected by the method of fault gas measurement is shown as a band.Through contrasting with exploration results of artificial seismic prospecting and analyzing,we find that the fault is located inside the band.According to the measurements of soil gas radon,the Haihe fault can be divided into east and west segments and the activity of the east segment of Haihe fault is stronger than that of the west segment.This is only a relative result,and it is difficult to judge whether the fault is active or not with this result.

The influence of atmospheric Hg on Hg contaminations in rice and paddy soil in the Xunyang Hg mining district,China

To date, the Xunyang mercury(Hg) mining district is the only ongoing large-scale Hg mining district in China. To understand the influence of Hg contamination mode from the Hg mining and smelting activities, 27 sampling sites in the Xunyang Hg mining district were chosen in this study. Total gaseous mercury(TGM) in ambient air was measured using a Lumex-RA915 automatic Hg analyzer in2011. Rice samples and soil samples from rhizosphere were collected systematically and simultaneously. Total Hg(THg) and methylmercury(Me Hg) concentrations in rice grain and soil samples and Hg speciation with modified sequential selective extractions were measured. The local environment was seriously polluted with Hg. The TGM(302 ± 376 ng·m-3, ranging from 24 to 2220 ng·m^(-3)) in the local ambient air, THg(28 ± 30 mg·kg^(-1), ranging from 0.31 to 121 mg·kg^(-1)) and Me Hg(2.3 ± 1.9 lg·kg^(-1),ranging from 0.24 to 8.9 lg·kg^(-1)) in soil samples were at the sample level with Hg contaminated area. The THg concentration(26 ± 16 lg·kg^(-1)ranging from 4.5 to 71 lg·kg^(-1)) in most of the rice grain samples clearly exceeds the threshold level(20 lg·kg^(-1)) in the Chinese national guidelines for cereals(NY 861-2004). The inorganic mercury(IHg)(9.1 ± 5.6 lg·kg^(-1), ranging from 1.2 to 24 lg·kg^(-1)) and Me Hg(14 ± 9.8 lg·kg^(-1), ranging from 2.1 to 59 lg·kg^(-1))concentration in rice grain samples were at the same level with Hg contaminated area. The main species of Hg in paddy soils reveal strong complex Hg and residue Hg. According to the correlation analysis, a Hg pollution mode from local Hg mining and smelting was hypothesized, including Hg emission, transportation, methylation, and uptake process.

A STUDY ON THE RELATIONSHIP BETWEEN SPRING SOIL MOISTURE OVER CHINA AND EAST ASIA SUMMER MONSOON

The correlation analysis has been used to study the relationship between spring soil moisture over China and East Asian summer monsoon (EASM). It is shown that EASM has a strong positive correlation with spring soil moisture over southwest China and the Great Bend region of the Yellow River. A standard soil moisture index (SMI) has been defined using the observed soil moisture of the two regions. The results show that SMI has a strong correlation with EASM. The years of strong (weak) SMI are associated with stronger (weaker) summer monsoon circulation. In the years of strong SMI, the west Pacific subtropical high is much northward in position and weaker in intensity;the westerlies zone is also more to the north. All of these make EASM circulation move northward and cause the rainfall belt to relocate to North China and Northeast China. SMI can reflect the variation of the summer rainfall anomaly over eastern China. In the years of strong SMI, the rainfall belt is mainly located over the northern part of China. However, during the weak years, the summer rainfall belt is largely located over the mid-and lower-reaches of the Yangtze River. Additionally, the SMI has obvious oscillations of quasi 4-6 years and quasi 2 years. Moreover, negative SMI predicts EASM better than positive SMI.