The absorption of sulfur dioxide in simulated flue gas by using liquid-containing membrane was investigated.The process of sulfur dioxide desorption from the absorbent of citrate solution was explored.The influence of...The absorption of sulfur dioxide in simulated flue gas by using liquid-containing membrane was investigated.The process of sulfur dioxide desorption from the absorbent of citrate solution was explored.The influence of the gas-phase,and the liquid-phase on absorption efficiency of sulfur dioxide and the influence of ultrasonic frequency,ultrasonic power and stirring speed on desorption efficiency of sulfur dioxide were examined.The results indicate that the absorption efficiency decreases with increasing flow velocity and sulfur dioxide content in gas-phase,and can be improved by increasing the concentration and the pH value of citrate solution.It is concluded that lower ultrasonic frequency results in a better degassing efficiency.The using of ultrasound in desorbing sulfur dioxide from citrate solution improves the desorbing efficiency in the some conditions,without changing the essence of chemical reaction.展开更多
Because of the former gas chemistry examination method defects, tunable diode laser absorption spectrum technology (TDLAS) was used. It used an isolated absorption spectrum of the gas molecule to measure the gas abs...Because of the former gas chemistry examination method defects, tunable diode laser absorption spectrum technology (TDLAS) was used. It used an isolated absorption spectrum of the gas molecule to measure the gas absorption spectrum in order to distinguish the gas conveniently. The second harmonic (20 was measured in this system. Due to the fact which the harmonious signal is proportional to the concentration of the absorption gas, the gas concentration may be obtained through examining harmonious signal. The theoretical analysis and the experimental result indicate that under the same level of pressure, survey with the signal-to-noise ratio(SNR) of 2fsignal increases the accuracy by one order of magnitude and may reach 10 ^-3 and the sensitivity may reach the 10^-6 level compared to that of direct absorption. 5% methane density and a 30 cm absorption cell were used in the experiment. It has several advantages including high sensitivity, best resolution, and faster response and so on. The gas concentration monitoring of coal mine may be accomplished.展开更多
基金Projects(50874087,50978212) supported by the National Natural Science Foundation of China
文摘The absorption of sulfur dioxide in simulated flue gas by using liquid-containing membrane was investigated.The process of sulfur dioxide desorption from the absorbent of citrate solution was explored.The influence of the gas-phase,and the liquid-phase on absorption efficiency of sulfur dioxide and the influence of ultrasonic frequency,ultrasonic power and stirring speed on desorption efficiency of sulfur dioxide were examined.The results indicate that the absorption efficiency decreases with increasing flow velocity and sulfur dioxide content in gas-phase,and can be improved by increasing the concentration and the pH value of citrate solution.It is concluded that lower ultrasonic frequency results in a better degassing efficiency.The using of ultrasound in desorbing sulfur dioxide from citrate solution improves the desorbing efficiency in the some conditions,without changing the essence of chemical reaction.
基金Supported by National Natural Science Foundation of China (50574005) Natural Science Foundation of Education Department of Anhui, China (2005KJ081)
文摘Because of the former gas chemistry examination method defects, tunable diode laser absorption spectrum technology (TDLAS) was used. It used an isolated absorption spectrum of the gas molecule to measure the gas absorption spectrum in order to distinguish the gas conveniently. The second harmonic (20 was measured in this system. Due to the fact which the harmonious signal is proportional to the concentration of the absorption gas, the gas concentration may be obtained through examining harmonious signal. The theoretical analysis and the experimental result indicate that under the same level of pressure, survey with the signal-to-noise ratio(SNR) of 2fsignal increases the accuracy by one order of magnitude and may reach 10 ^-3 and the sensitivity may reach the 10^-6 level compared to that of direct absorption. 5% methane density and a 30 cm absorption cell were used in the experiment. It has several advantages including high sensitivity, best resolution, and faster response and so on. The gas concentration monitoring of coal mine may be accomplished.