Coherent vibrational dynamics can be observed in atomically precise gold nanoclusters using femtosecond time-resolved pump-probe spectroscopy.It can not only reveal the coupling between electrons and vibrations,but al...Coherent vibrational dynamics can be observed in atomically precise gold nanoclusters using femtosecond time-resolved pump-probe spectroscopy.It can not only reveal the coupling between electrons and vibrations,but also reflect the mechanical and electronic properties of metal nanoclusters,which holds potential applications in biological sensing and mass detection.Here,we investigated the coherent vibrational dynamics of[Au_(25)(SR)_(18)]^(-)nanoclusters by ultrafast spectroscopy and revealed the origins of thesecoherent vibrations by analyzing their frequency,phase and probe wavelength distributions.Strong coherent oscillations with frequency of 40 cm^(-1) and 80 cm^(-1) can be reproduced in the excited state dynamics of[Au_(25)(SR)_(18)]^(-),which should originate from acoustic vibrations of the Au13 metal core.Phase analysis on the oscillations indicates that the 80 cm^(-1) mode should arise from the frequency modulation of the electronic states while the 40 cm^(-1) mode should originate from the amplitude modulation of the dynamic spectrum.Moreover,it is found that the vibration frequencies of[Au_(25)(SR)_(18)]^(-)obtained in pump-probe measurements are independent of the surface ligands so that they are intrinsic properties of the metal core.These results are of great value to understand the electron-vibration coupling of metal nanoclusters.展开更多
This paper presents and verifies a new idea for constructing an ultrasonic motor （USM）. The stator contains several vibrators fabricated by bonding piezoelectric ceramics （PZTs） to a metal base. When two alternati...This paper presents and verifies a new idea for constructing an ultrasonic motor （USM）. The stator contains several vibrators fabricated by bonding piezoelectric ceramics （PZTs） to a metal base. When two alternating current （AC） voltages with a 90° phase difference are applied to the PZTs, longitudinal and bending modes are excited in the vibrator. The bending vibrations of the vibrators are stacked to form the torsional vibration of the stator, ultimately generating longitudinal-torsional composite vibration. Both vibrators and the stator are excited to the resonance state. A standing wave is formed by superposition of longitudinal and torsional modes. The proposed motor is an in-plane vibration motor because the vibrations of the stator are in the circumferential plane. The finite element method （FEM） is used to validate the feasibility of the proposed motor. The fabricated stator contains five vibrators. The tested resonance frequencies of longitudinal and torsional modes are 44.42 kHz and 43.83 kHz, respectively. The stall torque is 0.3 N＇m and no-load speed is 45 r/min. The highest efficiency is 30%. The applied driving voltage is 100 Vo.p （peak voltage） at 43.9 kHz. The designed motor is a parallel-actuated integral motor. It allows the vibrators to operate synchronously, and overcomes asynchronous issues that occur in traditional multi-vibrator motors.展开更多
The structural and vibrational properties of two-dimensional hexagonal silicon （silicene） and germanium （germanene） are investigated by means of first-principles calculations. It is predicted that the silicene （g...The structural and vibrational properties of two-dimensional hexagonal silicon （silicene） and germanium （germanene） are investigated by means of first-principles calculations. It is predicted that the silicene （germanene） structure with a small buckling of 0.44 ,~ （0.7/k） and bond lengths of 2.28 ,~ （2.44 .~） is energetically the most favorable, and it does not exhibit imaginary phonon mode. The calculated non-resonance Raman spectra of silicene are characterized by a main peak at about 575 cm-1, namely the G-like peak. For germanene, the highest peak is at about 290 cm-1. Extensive calculations on armchair silicene nanoribbons and armchair germanene nanoribbons are also performed, with and without hydrogenation of the edges. The studies reveal other Raman peaks mainly distributed at lower frequencies than the G-like peak which could be attributed to the defects at the edges of the ribbons, thus not present in the Raman spectra of non-defective silicene and germanene. Particularly the Raman peak corresponding to the D mode is found to be located at around 515 cm-1 for silicene and 270 cm-1 for germanene. The calculated G-like and the D peaks are likely the fingerprints of the Raman spectra of the low-buckled structures of silicene and germanene.展开更多
Developing an understanding of the physics underlying vibrational phonon modes,which are strongly related to thermal transport,has attracted significant research interest.Herein,we report the successful synthesis of b...Developing an understanding of the physics underlying vibrational phonon modes,which are strongly related to thermal transport,has attracted significant research interest.Herein,we report the successful synthesis of bulk SbCrSe_(3)single crystal and its thermal transport property over the temperature range from 2 to 300 K.Using angle-resolved polarized Raman spectroscopy(ARPRS)and group theory calculation,the vibrational symmetry of each observed Raman mode in the cleaved(001)crystal plane of SbCrSe_(3)is identified for the first time,and then further verified through firstprinciples calculations.The ARPRS results of some Raman modes(e.g.,Ag2~64 cm-1 and Ag 7~185 cm-1)can be adopted to determine the crystalline orientation.More importantly,the temperature dependence of the lattice thermal conductivity(κL)is revealed to be more accurately depicted by the three-phonon scattering processes throughout the measured temperature range,substantiated by in-situ Raman spectroscopy analysis and the model-predictedκL.These results reveal the fundamental physics of thermal transport for SbCrSe_(3)from a completely new perspective and should thus ignite research interest in the thermal properties of other lowdimensional materials using the same strategy.展开更多
基金supported by the startup funding from University of Science and Technology of China(KY2340000137)the startup funding from Chinese Academy of Sciences
文摘Coherent vibrational dynamics can be observed in atomically precise gold nanoclusters using femtosecond time-resolved pump-probe spectroscopy.It can not only reveal the coupling between electrons and vibrations,but also reflect the mechanical and electronic properties of metal nanoclusters,which holds potential applications in biological sensing and mass detection.Here,we investigated the coherent vibrational dynamics of[Au_(25)(SR)_(18)]^(-)nanoclusters by ultrafast spectroscopy and revealed the origins of thesecoherent vibrations by analyzing their frequency,phase and probe wavelength distributions.Strong coherent oscillations with frequency of 40 cm^(-1) and 80 cm^(-1) can be reproduced in the excited state dynamics of[Au_(25)(SR)_(18)]^(-),which should originate from acoustic vibrations of the Au13 metal core.Phase analysis on the oscillations indicates that the 80 cm^(-1) mode should arise from the frequency modulation of the electronic states while the 40 cm^(-1) mode should originate from the amplitude modulation of the dynamic spectrum.Moreover,it is found that the vibration frequencies of[Au_(25)(SR)_(18)]^(-)obtained in pump-probe measurements are independent of the surface ligands so that they are intrinsic properties of the metal core.These results are of great value to understand the electron-vibration coupling of metal nanoclusters.
基金Project supported by the National Natural Science Foundation of China （No. 11174206）, the Open Fund of State Key Laboratory of Ocean Engineering （No. 0507）, and the Shanghai Aerospace Science and Technology Innovation Fund （No. 201347）, China
文摘This paper presents and verifies a new idea for constructing an ultrasonic motor （USM）. The stator contains several vibrators fabricated by bonding piezoelectric ceramics （PZTs） to a metal base. When two alternating current （AC） voltages with a 90° phase difference are applied to the PZTs, longitudinal and bending modes are excited in the vibrator. The bending vibrations of the vibrators are stacked to form the torsional vibration of the stator, ultimately generating longitudinal-torsional composite vibration. Both vibrators and the stator are excited to the resonance state. A standing wave is formed by superposition of longitudinal and torsional modes. The proposed motor is an in-plane vibration motor because the vibrations of the stator are in the circumferential plane. The finite element method （FEM） is used to validate the feasibility of the proposed motor. The fabricated stator contains five vibrators. The tested resonance frequencies of longitudinal and torsional modes are 44.42 kHz and 43.83 kHz, respectively. The stall torque is 0.3 N＇m and no-load speed is 45 r/min. The highest efficiency is 30%. The applied driving voltage is 100 Vo.p （peak voltage） at 43.9 kHz. The designed motor is a parallel-actuated integral motor. It allows the vibrators to operate synchronously, and overcomes asynchronous issues that occur in traditional multi-vibrator motors.
文摘The structural and vibrational properties of two-dimensional hexagonal silicon （silicene） and germanium （germanene） are investigated by means of first-principles calculations. It is predicted that the silicene （germanene） structure with a small buckling of 0.44 ,~ （0.7/k） and bond lengths of 2.28 ,~ （2.44 .~） is energetically the most favorable, and it does not exhibit imaginary phonon mode. The calculated non-resonance Raman spectra of silicene are characterized by a main peak at about 575 cm-1, namely the G-like peak. For germanene, the highest peak is at about 290 cm-1. Extensive calculations on armchair silicene nanoribbons and armchair germanene nanoribbons are also performed, with and without hydrogenation of the edges. The studies reveal other Raman peaks mainly distributed at lower frequencies than the G-like peak which could be attributed to the defects at the edges of the ribbons, thus not present in the Raman spectra of non-defective silicene and germanene. Particularly the Raman peak corresponding to the D mode is found to be located at around 515 cm-1 for silicene and 270 cm-1 for germanene. The calculated G-like and the D peaks are likely the fingerprints of the Raman spectra of the low-buckled structures of silicene and germanene.
基金the National Natural Science Foundation of China(11904348,11604032,51772035,51672270 and 52071041)the Fundamental Research Funds for the Central Universities(106112016CDJZR308808)。
文摘Developing an understanding of the physics underlying vibrational phonon modes,which are strongly related to thermal transport,has attracted significant research interest.Herein,we report the successful synthesis of bulk SbCrSe_(3)single crystal and its thermal transport property over the temperature range from 2 to 300 K.Using angle-resolved polarized Raman spectroscopy(ARPRS)and group theory calculation,the vibrational symmetry of each observed Raman mode in the cleaved(001)crystal plane of SbCrSe_(3)is identified for the first time,and then further verified through firstprinciples calculations.The ARPRS results of some Raman modes(e.g.,Ag2~64 cm-1 and Ag 7~185 cm-1)can be adopted to determine the crystalline orientation.More importantly,the temperature dependence of the lattice thermal conductivity(κL)is revealed to be more accurately depicted by the three-phonon scattering processes throughout the measured temperature range,substantiated by in-situ Raman spectroscopy analysis and the model-predictedκL.These results reveal the fundamental physics of thermal transport for SbCrSe_(3)from a completely new perspective and should thus ignite research interest in the thermal properties of other lowdimensional materials using the same strategy.
