The primary phase evolution of ADC12 aluminum alloy rheo-processed by mechanical rotational barrel system was studied by differential scanning calorimetry（DSC）, optical microscopy（OM） and scanning electron microsc...The primary phase evolution of ADC12 aluminum alloy rheo-processed by mechanical rotational barrel system was studied by differential scanning calorimetry（DSC）, optical microscopy（OM） and scanning electron microscopy（SEM）. The semisolid slurry analyses show that the solid fraction of ADC12 aluminum alloy increases from 0.38 to 0.43 while the roundness decreases from 0.45 to 0.38 with increasing the rotational speed from 30 to 120 r/min. When the pouring temperature decreases from 620 to 580 °C, the primary α（Al） morphology changes from spheroidal to rosette-like. Besides, the average particle size of primary phase and solid fraction increase with the decrease of pouring temperature. By rheo-diecasting process, the components with fine, spherical and uniformly distributed primary α（Al） particles were obtained, and the best microstructure was contained at the pouring temperature ranging from 595 to 605 °C. The rheo-processing feasibility of ADC12 aluminum alloy can be explained by the grains controlled growth theory, and the semisolid slurry obeys the Mullins-Sekerka criterion when solidifying in the high pressure die casting machine.展开更多
Jar tests were conducted to investigate the performance of enhanced primary treatment processes for low-concentra-tion municipal wastewater from South China by using composite flocculant combined with bio-flocculants ...Jar tests were conducted to investigate the performance of enhanced primary treatment processes for low-concentra-tion municipal wastewater from South China by using composite flocculant combined with bio-flocculants Pullulan and poly-aluminum-chloride (PAC). The optimum dosage for composite flocculant and conditions for flocculation were determined. The experimental results indicated that composite flocculant had high efficiency for removing over 95% of turbidity, over 58% of CODCr (chemical oxygen demand determined with potassium dichromate), over 91% of TP (total phosphate), and over 15% of NH3-N. Moreover, it could improve sludge settling and dehydration properties, and decrease the treatment cost.展开更多
Effects of heat treatment processing on the microstructure and mechanical properties of Ti-6Al-4V-10Nb alloy were investigated. The microstructures were investigated by SEM, TEM and XRD, and the mechanical properties ...Effects of heat treatment processing on the microstructure and mechanical properties of Ti-6Al-4V-10Nb alloy were investigated. The microstructures were investigated by SEM, TEM and XRD, and the mechanical properties were evaluated by tensile tests at room and elevated temperatures. The results indicate that the lath-like and globular primary α phase, secondary α phase and β phase are obtained after forging and heat treatment processing. The size of secondary α phase is much smaller than that of primary α phase. After heat treatment, the volume fraction of primary α phase is decreased, and that of secondary α phase is increased. With the increase of solution temperature, the volume fraction of primary α phase is gradually decreased, and that of secondary α phase is obviously increased. The yield strength and tensile strength of Ti-6Al-4V-10Nb alloy are significantly enhanced with the solution temperature increasing.展开更多
The thermal stability of five commercial ion-exchange resin catalysts was studied by means of thermal gravimetric analysis （TGA） at elevated temperatures of up to 600℃ and isothermal temperatures in the range of 15...The thermal stability of five commercial ion-exchange resin catalysts was studied by means of thermal gravimetric analysis （TGA） at elevated temperatures of up to 600℃ and isothermal temperatures in the range of 150℃ and 200 ℃. Resin samples with different initial water contents were also investigated. The study indicated that TGA, as a complementary evaluating method for the plug flow reactor system approach, could be used as a fast analyzing means for study on the thermal stability of ion-exchange resin catalysts. The stoichiometric calculation of the isothermally treated resin catalysts based on the FTIR analysis and acid capacity confirmed that the weight loss of the resins at 150℃ and 200℃ was caused by the desulfonation process and that desulfonation occurred mainly at the para-position of the benzene ring in the resins. H＋ ions and moisture played an important role in the desulfonation process.展开更多
The effect of ultrasonic treatment on the formation of primary Al3Zr was investigated by applying ultrasound to an Al?0.4Zr alloy.Three temperature ranges were selected,i.e.,830to790°C(above liquidus),790to750...The effect of ultrasonic treatment on the formation of primary Al3Zr was investigated by applying ultrasound to an Al?0.4Zr alloy.Three temperature ranges were selected,i.e.,830to790°C(above liquidus),790to750°C(cross liquidus)and750to710°C(below liquidus)for ultrasonication.Using the scanning electron microscopy,both the size and morphology of the primary Al3Zr particles were examined.It was found that the size was significantly reduced and the morphology changed from large throwing-star shape to small compact tablet shape.The mechanisms for refinement of primary Al3Zr were discussed.It is suggested that sonocrystallization theory via activation of aluminium oxide particles is responsible for the refinement of primary Al3Zr when ultrasonic melt treatment(UST)is applied within the fully liquid state.The refinement of primary Al3Zr particles when UST is applied in the slurry(growth stage)is due to the sonofragmentation.展开更多
A simple and efficient sonochemical method was developed for the degradation of organic matter and ammonia nitrogen in azodicarbonamide wastewater.The effects of initial pH,ultrasound format and peripheral water level...A simple and efficient sonochemical method was developed for the degradation of organic matter and ammonia nitrogen in azodicarbonamide wastewater.The effects of initial pH,ultrasound format and peripheral water level on the sonolysis of hydrazine,urea,COD and ammonia nitrogen were investigated.It is found that the initial pH has a significant influence on the degradation of hydrazine and ammonia nitrogen,whereas this impact to urea is relatively small.It also shows that a noticeable enhancement of ammonia nitrogen removal could be achieved in a proper intermittent ultrasound operation mode,i.e.,1/1 min on/off mode.The height difference between the periph-eral water level and the inner water level of the flask affects the efficiency of ultrasonic treatment as well.展开更多
Biodegradation parameters and kinetic characteristics for pre-treating waste strains of Klebsiella pneu-moniae were studied in laboratory scale with an insulated reactor by an innovative technique,autothermal thermo-p...Biodegradation parameters and kinetic characteristics for pre-treating waste strains of Klebsiella pneu-moniae were studied in laboratory scale with an insulated reactor by an innovative technique,autothermal thermo-philic aerobic digestion(ATAD) . Based on an Arrhenius-type equation,an empirical model was developed to corre-late the removal of total suspended solid(TSS) with the initial TSS concentration,influent reaction temperature,aeration rate and stirring rate. The reaction temperatures of the ATAD system could be raised from the ambient temperatures of 25 °C to a maximum temperature of 65 °C. The exponentials for the initial TSS concentration,aeration rate and stirring rate were 1.579,-0.8175 and-0.6549,respectively,and the apparent activation energy was 6.8774 kJ·mol-1. The correlation coefficient for the pre-exponential factor was 0.9223. The TSS removal effi-ciency predicted by the model was validated with an actual test,showing a maximum relative deviation of 10.79%. The new model has a good practicability.展开更多
An embedded system generally comprises gffour parts （embedded microprocessor unit, peripheral hardware equipment, embedded operating system, and user application）, and its core function is to complete the control of...An embedded system generally comprises gffour parts （embedded microprocessor unit, peripheral hardware equipment, embedded operating system, and user application）, and its core function is to complete the control of different equipments as well as necessary monitoring and management measures. Initialization is to set a variable as ＂default value＂, including system initialization, software initialization and hardware initialization. However, these three types of initialization are classified in accordance with different layers. This is studied in this paper.展开更多
The effluents of textile dyes are highly colored, and disposal of the wastes into receiving waters cause damage to the environment, therefore dyes removal is of great importance. In this research, removal of Orange II...The effluents of textile dyes are highly colored, and disposal of the wastes into receiving waters cause damage to the environment, therefore dyes removal is of great importance. In this research, removal of Orange II, Remazol Blue, Methyl red, Malachite green and Safranin dyes by Pseudomonas fluorescens was studied in batch system as function of temperature, pH and initial dye concentration. The rate of removal dyes was studied by using pectrophotometer. The optimum value was determined as pH 7 for all dyes tested about 87.8-72.7%, and optimum temperature for removal of all tested dyes was 30℃ about 86.6-60.8%. Higher removal of dyes observed at 25 mL for all tested dyes about 91.9-72,7%. In general, the increase in dye concentration inhibited the growth of bacteria. Pseudomonasfluorescens showed higher removal of Orange II among the dyes tested.展开更多
We investigate the bipartite entanglement dynamics of the system composed by three qubits A,B,and C.There is no interaction between A and B,and that of C and B is Dzyaloshinskii-Moriya (DM) spin-orbit interaction.We f...We investigate the bipartite entanglement dynamics of the system composed by three qubits A,B,and C.There is no interaction between A and B,and that of C and B is Dzyaloshinskii-Moriya (DM) spin-orbit interaction.We find that the purity of qubits A and B and the initial state of the qubit C are the two effective parameters tocontrol the entanglement dynamics of the bipartite subsystems.This study sheds some lights on the control of quantumentanglement,which would be helpful for quantum information processing.展开更多
In the present study,we aimed to prepare sustained-release microspheres for injection of neurokinin-1(NK-1)receptor antagonist APT011,and to evaluate their physicochemical properties,in vitro sustained-release effect ...In the present study,we aimed to prepare sustained-release microspheres for injection of neurokinin-1(NK-1)receptor antagonist APT011,and to evaluate their physicochemical properties,in vitro sustained-release effect and preliminary stability.APT011-loaded sustained-release microspheres were prepared using W/O/W double emulsion-solvent evaporation technique.The L9(34)orthogonal experiment was used to optimize the APT011 sustained-release microsphere formulation.Microscope photographs showed that APT011-loaded microspheres were spherical,and the particle size was^90μm with uniform size distribution.XRD results indicated that APT011 existed in the microspheres in an amorphous form.DSC results showed that there was no significant interaction between APT011 and blank microspheres.APT011-loaded microspheres had a significant sustained-release effect,which maintained release for at least 2 months.Preliminary study results indicated that the loading content and release percentage at 0.5 h were not markedly altered below 40°C and under high lighting condition.APT011-loaded microspheres prepared in our study exhibited excellent physicochemical properties and sustained-release characteristics and preliminary stability,demonstrating real potential for the clinical practice.展开更多
基金Project(51404153) supported by the National Natural Science Foundation of China
文摘The primary phase evolution of ADC12 aluminum alloy rheo-processed by mechanical rotational barrel system was studied by differential scanning calorimetry（DSC）, optical microscopy（OM） and scanning electron microscopy（SEM）. The semisolid slurry analyses show that the solid fraction of ADC12 aluminum alloy increases from 0.38 to 0.43 while the roundness decreases from 0.45 to 0.38 with increasing the rotational speed from 30 to 120 r/min. When the pouring temperature decreases from 620 to 580 °C, the primary α（Al） morphology changes from spheroidal to rosette-like. Besides, the average particle size of primary phase and solid fraction increase with the decrease of pouring temperature. By rheo-diecasting process, the components with fine, spherical and uniformly distributed primary α（Al） particles were obtained, and the best microstructure was contained at the pouring temperature ranging from 595 to 605 °C. The rheo-processing feasibility of ADC12 aluminum alloy can be explained by the grains controlled growth theory, and the semisolid slurry obeys the Mullins-Sekerka criterion when solidifying in the high pressure die casting machine.
基金Project (No. 2005AA601010) supported by the Hi-Tech Research and Development Program (863) of China
文摘Jar tests were conducted to investigate the performance of enhanced primary treatment processes for low-concentra-tion municipal wastewater from South China by using composite flocculant combined with bio-flocculants Pullulan and poly-aluminum-chloride (PAC). The optimum dosage for composite flocculant and conditions for flocculation were determined. The experimental results indicated that composite flocculant had high efficiency for removing over 95% of turbidity, over 58% of CODCr (chemical oxygen demand determined with potassium dichromate), over 91% of TP (total phosphate), and over 15% of NH3-N. Moreover, it could improve sludge settling and dehydration properties, and decrease the treatment cost.
基金Projects(2015GB107003,2015GB119001)supported by the International Thermonuclear Experimental Reactor(ITER)Program,ChinaProjects(51474155,11672200,51674175)supported by the National Natural Science Foundation of China
文摘Effects of heat treatment processing on the microstructure and mechanical properties of Ti-6Al-4V-10Nb alloy were investigated. The microstructures were investigated by SEM, TEM and XRD, and the mechanical properties were evaluated by tensile tests at room and elevated temperatures. The results indicate that the lath-like and globular primary α phase, secondary α phase and β phase are obtained after forging and heat treatment processing. The size of secondary α phase is much smaller than that of primary α phase. After heat treatment, the volume fraction of primary α phase is decreased, and that of secondary α phase is increased. With the increase of solution temperature, the volume fraction of primary α phase is gradually decreased, and that of secondary α phase is obviously increased. The yield strength and tensile strength of Ti-6Al-4V-10Nb alloy are significantly enhanced with the solution temperature increasing.
基金supported financially by the Purolite Company and Chinese National Natural Science Foundation(20674069)
文摘The thermal stability of five commercial ion-exchange resin catalysts was studied by means of thermal gravimetric analysis （TGA） at elevated temperatures of up to 600℃ and isothermal temperatures in the range of 150℃ and 200 ℃. Resin samples with different initial water contents were also investigated. The study indicated that TGA, as a complementary evaluating method for the plug flow reactor system approach, could be used as a fast analyzing means for study on the thermal stability of ion-exchange resin catalysts. The stoichiometric calculation of the isothermally treated resin catalysts based on the FTIR analysis and acid capacity confirmed that the weight loss of the resins at 150℃ and 200℃ was caused by the desulfonation process and that desulfonation occurred mainly at the para-position of the benzene ring in the resins. H＋ ions and moisture played an important role in the desulfonation process.
基金support from UK Engineering and Physical Science Research Council (EPSRC) for the Ultra-Cast project (grant EP/L019884/1, EP/L019825/1, EP/L019965/1)
文摘The effect of ultrasonic treatment on the formation of primary Al3Zr was investigated by applying ultrasound to an Al?0.4Zr alloy.Three temperature ranges were selected,i.e.,830to790°C(above liquidus),790to750°C(cross liquidus)and750to710°C(below liquidus)for ultrasonication.Using the scanning electron microscopy,both the size and morphology of the primary Al3Zr particles were examined.It was found that the size was significantly reduced and the morphology changed from large throwing-star shape to small compact tablet shape.The mechanisms for refinement of primary Al3Zr were discussed.It is suggested that sonocrystallization theory via activation of aluminium oxide particles is responsible for the refinement of primary Al3Zr when ultrasonic melt treatment(UST)is applied within the fully liquid state.The refinement of primary Al3Zr particles when UST is applied in the slurry(growth stage)is due to the sonofragmentation.
基金Supported by the National Natural Science Foundation of China (21121064,20990224)National Science and Technology Ministry of China (2008BAE64B02)
文摘A simple and efficient sonochemical method was developed for the degradation of organic matter and ammonia nitrogen in azodicarbonamide wastewater.The effects of initial pH,ultrasound format and peripheral water level on the sonolysis of hydrazine,urea,COD and ammonia nitrogen were investigated.It is found that the initial pH has a significant influence on the degradation of hydrazine and ammonia nitrogen,whereas this impact to urea is relatively small.It also shows that a noticeable enhancement of ammonia nitrogen removal could be achieved in a proper intermittent ultrasound operation mode,i.e.,1/1 min on/off mode.The height difference between the periph-eral water level and the inner water level of the flask affects the efficiency of ultrasonic treatment as well.
基金Supported by the Doctoral Foundation of Northeast Dianli University (BSJXM-200814)Foundations of Bureau of Jilin Province (2008424)
文摘Biodegradation parameters and kinetic characteristics for pre-treating waste strains of Klebsiella pneu-moniae were studied in laboratory scale with an insulated reactor by an innovative technique,autothermal thermo-philic aerobic digestion(ATAD) . Based on an Arrhenius-type equation,an empirical model was developed to corre-late the removal of total suspended solid(TSS) with the initial TSS concentration,influent reaction temperature,aeration rate and stirring rate. The reaction temperatures of the ATAD system could be raised from the ambient temperatures of 25 °C to a maximum temperature of 65 °C. The exponentials for the initial TSS concentration,aeration rate and stirring rate were 1.579,-0.8175 and-0.6549,respectively,and the apparent activation energy was 6.8774 kJ·mol-1. The correlation coefficient for the pre-exponential factor was 0.9223. The TSS removal effi-ciency predicted by the model was validated with an actual test,showing a maximum relative deviation of 10.79%. The new model has a good practicability.
文摘An embedded system generally comprises gffour parts （embedded microprocessor unit, peripheral hardware equipment, embedded operating system, and user application）, and its core function is to complete the control of different equipments as well as necessary monitoring and management measures. Initialization is to set a variable as ＂default value＂, including system initialization, software initialization and hardware initialization. However, these three types of initialization are classified in accordance with different layers. This is studied in this paper.
文摘The effluents of textile dyes are highly colored, and disposal of the wastes into receiving waters cause damage to the environment, therefore dyes removal is of great importance. In this research, removal of Orange II, Remazol Blue, Methyl red, Malachite green and Safranin dyes by Pseudomonas fluorescens was studied in batch system as function of temperature, pH and initial dye concentration. The rate of removal dyes was studied by using pectrophotometer. The optimum value was determined as pH 7 for all dyes tested about 87.8-72.7%, and optimum temperature for removal of all tested dyes was 30℃ about 86.6-60.8%. Higher removal of dyes observed at 25 mL for all tested dyes about 91.9-72,7%. In general, the increase in dye concentration inhibited the growth of bacteria. Pseudomonasfluorescens showed higher removal of Orange II among the dyes tested.
基金Supported by the National Natural Science Foundation of China under Grant Nos.10535010 and 10775123Research Fund of Education Ministry under Grant No.20070284016+1 种基金the Natural Science and Technology Foundation of Guizhou Province under Grant Nos.[2009]2267the Doctor funding of Guizhou Normal University
文摘We investigate the bipartite entanglement dynamics of the system composed by three qubits A,B,and C.There is no interaction between A and B,and that of C and B is Dzyaloshinskii-Moriya (DM) spin-orbit interaction.We find that the purity of qubits A and B and the initial state of the qubit C are the two effective parameters tocontrol the entanglement dynamics of the bipartite subsystems.This study sheds some lights on the control of quantumentanglement,which would be helpful for quantum information processing.
基金National Science&Technology Major Project“Key New Drug Creation and Manufacturing”(Grant No.2019ZX09201001-003-007)。
文摘In the present study,we aimed to prepare sustained-release microspheres for injection of neurokinin-1(NK-1)receptor antagonist APT011,and to evaluate their physicochemical properties,in vitro sustained-release effect and preliminary stability.APT011-loaded sustained-release microspheres were prepared using W/O/W double emulsion-solvent evaporation technique.The L9(34)orthogonal experiment was used to optimize the APT011 sustained-release microsphere formulation.Microscope photographs showed that APT011-loaded microspheres were spherical,and the particle size was^90μm with uniform size distribution.XRD results indicated that APT011 existed in the microspheres in an amorphous form.DSC results showed that there was no significant interaction between APT011 and blank microspheres.APT011-loaded microspheres had a significant sustained-release effect,which maintained release for at least 2 months.Preliminary study results indicated that the loading content and release percentage at 0.5 h were not markedly altered below 40°C and under high lighting condition.APT011-loaded microspheres prepared in our study exhibited excellent physicochemical properties and sustained-release characteristics and preliminary stability,demonstrating real potential for the clinical practice.
