The agro-pastoral ecotone has been recognized as the main distribution area of reserved land resource for cultivation. Accordingly, clarifying this assumption, as well as concerting land reclamation and ecological res...The agro-pastoral ecotone has been recognized as the main distribution area of reserved land resource for cultivation. Accordingly, clarifying this assumption, as well as concerting land reclamation and ecological restoration, is important to ensure food security and environmental improvement in the agro-pastoral ecotone. We selected Horqin Left Back Banner(HLBB) as the subject of our case study. The landscape ecological security pattern of this area was determined using the minimum cumulative resistance model. Over-cultivation, quantity of reserved land resource for cultivation, and changes in landscape indexes before and after land use adjustment were then analyzed. Over-cultivation is a serious problem in the agro-pastoral ecotone. Reserved land resource for cultivation is less than that considered previously, and the area of reserved land resource for cultivation in HLBB only accounts for 11.50% of total uncultivated land. With regard to changes in landscape indexes, the adjusted land use pattern is effective for anti-desertification. The compensation standard for abandoned cultivated land should be improved and the comprehensive results of ‘Grain for Green' should be evaluated to further implement ecological restoration in the agro-pastoral ecotone.展开更多
Geopolymer-lightweight aggregate refractory concrete (GLARC) was prepared with geopolymer and lightweight aggregate. The mechanical property and heat-resistance (950 ℃) of GLARC were investigated. The effects of size...Geopolymer-lightweight aggregate refractory concrete (GLARC) was prepared with geopolymer and lightweight aggregate. The mechanical property and heat-resistance (950 ℃) of GLARC were investigated. The effects of size of aggregate and mass ratio of geopolymer to aggregate on mechanical and thermal properties were also studied. The results show that the highest compressive strength of the heated refractory concrete is 43.3 MPa,and the strength loss is only 42%. The mechanical property and heat-resistance are influenced by the thickness of geopolymer covered with aggregate,which can be expressed as the quantity of geopolymer on per surface area of aggregate. In order to show the relationship between the thickness of geopolymer covered with aggregate and the thermal property of concrete,equal thickness model is presented,which provides a reference for the mix design of GLARC. For the haydite sand with size of 1.18-4.75 mm,the best amount of geopolymer per surface area of aggregate should be in the range of 0.300-0.500 mg/mm2.展开更多
In the present work, a novel heterogeneous photo-Fenton catalyst was prepared by iron and cerium pillared bentonite. The catalyst Fe-Ce/bentonite was characterized by X-ray diffraction (XRD), X-ray fluorescence (XR...In the present work, a novel heterogeneous photo-Fenton catalyst was prepared by iron and cerium pillared bentonite. The catalyst Fe-Ce/bentonite was characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), Brunauer-Emmett-Teller (BET) and scanning electron microscopy (SEM) methods. It is found that Fe and Ce intercalate into the silicate layers of bentonite successfully. Tetracycline was removed by heterogeneous photo-Fenton reaction using the catalyst in this work. The effects of different reaction systems, hydrogen peroxide concentration, initial pH, catalyst dosage, UV power and introduction of different anions on degradation were investigated in details. The stability of catalyst was investigated through recycling experiment. The results show that removal rate of tetracycline is 98.13% under the conditions of 15 mmol/L H202, 0.50 g/L catalyst dosage, initial pH 3.0, 11 W UV lamp power and 60 min reaction time. However, the removal rate decreases after adding some anions. The hydroxyl radical plays an important role in heterogeneous photo-assisted Fenton degradation of tetracycline. The catalyst is very stable and can be recycled many times.展开更多
A greenhouse experiment was conducted using stratified paddy field models, which were prepared by polluted soil with 12.5 cm soil dressing. The paddy models were assembled with open and closed percolation system to fo...A greenhouse experiment was conducted using stratified paddy field models, which were prepared by polluted soil with 12.5 cm soil dressing. The paddy models were assembled with open and closed percolation system to focus the effect of percolation pattern on accumulation of cupper (Cu) and cadmium (Cd) in rice plants in contaminated paddy filed with soil dressing models. Percolation pattern has significant effect on soil environment, especially redox potential that may influence mobilization of Cd, Cu and other elements. In open system percolation models, the plowsole and subsoil were in oxidative condition (600 mV), whereas reduction condition (-200 mV) was measured in closed system percolation models. Accumulations of Cu and Cd in all parts of rice plants (roots, grains, stems and leaves) were found higher in an open system percolation with the paddy field model comparatively than in a closed system percolation. The soil redox (Eh) condition influenced by the percolation pattern might be one of the main factors for uptake and accumulation of Cu and Cd in rice plants. The plant height and stem number were found lower in open system percolation comparatively to closed system percolation. In the yields section, the average panicle length, number of panicle and rice grain/hill and weight of grain/hill were lower in open system percolation than the closed system percolation.展开更多
SO4^2- / TiO2-La2O3, a novel solid superacid, was prepared and its catalytic activities at different synthetic conditions are discussed with esterification of n-butanoic acid and n-butyl alcohol as probing reaction. T...SO4^2- / TiO2-La2O3, a novel solid superacid, was prepared and its catalytic activities at different synthetic conditions are discussed with esterification of n-butanoic acid and n-butyl alcohol as probing reaction. The optimum conditions have also been found, mole ratio of n(La^3+):n(Ti^4+) is 1:34, the soaked consistency of H2SO4 is 0.8 tool/L, the soaked time of HESO4 is 24 h, the calcining temperature is 480 ℃, the calcining time is 3 h. Then it was applied in the catalytic synthesis often important ketals and acetals as catalyst and revealed high catalytic activity. Under these conditions on which the molar ratio of aldehyde/ketone to glycol is l: 1.5, the mass ratio of the catalyst used in the reactants is 0.5%, and the reaction time is 1.0 h, the yields of ketals and acetals can reach 41.4%-95.8%.展开更多
The material strength reserve method is practical in the study of the stability and failure mechanism of earth dam by analysing the development of failure zone of different shear strength parameters of the earth mass ...The material strength reserve method is practical in the study of the stability and failure mechanism of earth dam by analysing the development of failure zone of different shear strength parameters of the earth mass of the dam. The stability in the concrete dam and ensemble architecture has got general application while analysing. In combination with Feilaixia Multipurpose Project, application of this method to earth dam stability analysis was studied by plane Finite Element Method(FEM) for the first time. Through plane FEM, we can get the failure mechanism of earth dam and appraise to the security, for operating and managing put forward some reference suggestions.展开更多
A novel and environmentally friendly route to directly prepare metallic vanadium from NaV03 by molten salt electrolysis is proposed. The feasibility about the direct electro-reduction of NaV03 to metallic vanadi- um i...A novel and environmentally friendly route to directly prepare metallic vanadium from NaV03 by molten salt electrolysis is proposed. The feasibility about the direct electro-reduction of NaV03 to metallic vanadi- um is analyzed based on the thermodynamic calculations and experimental verifications. The theoretical decomposition voltage of NaV03 to metallic vanadium is only 0.47 V at 800 ℃ and much lower than that of the alkali and alkali earth metal chloride salts. The value is slightly higher than that of low-valence vanadium oxides such as V203, V305 and VO. However, the low-valence vanadium oxides can he further electro-reduced to metallic vanadium thermodynamically. The thermodynamic analysis is verified by the experimental results. The direct preparation of metallic vanadium from NaV03 by molten salt electrolysis is feasible.展开更多
Poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) based composite polymer electrolyte (CPE) modified with CeO2, La2O3 and Y2O3 nano-rare earth oxides was prepared by phase inversion technique. Physical...Poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) based composite polymer electrolyte (CPE) modified with CeO2, La2O3 and Y2O3 nano-rare earth oxides was prepared by phase inversion technique. Physical and chemical properties of the modified CPEs were studied by SEM, TG-DSC and electrochemical methods. The results show that the CPE modified with 10% La2O3 (mass fraction) has the best practical applicability, which indicates that the thermal and electrochemical stability can reach over 400 ℃ and 4.5 V, respectively, and temperature dependence of ionic conductivity follows Vogel-Tamman-Fulcher (VTF) relationship and ionic conductivity at room temperature is up to 3.3 mS/cm. The interfacial resistance Ri reaches a stable value about 557 Ω after 6 d storage.展开更多
Composites of montmorillonite clay and sawdust were prepared with the desired result being having new materials which burn longer than unmodified sawdust. The three forms of clay used for preparation of composites wer...Composites of montmorillonite clay and sawdust were prepared with the desired result being having new materials which burn longer than unmodified sawdust. The three forms of clay used for preparation of composites were unmodified montmorillonite, mono-ionic montmorillonite and organically modified montmorillonite. Montmorillonite clay was converted to mono-ionic clay by ion exchange with sodium using a sodium chloride solution. The mono-ionic clay was organically modified with an organic surfactant, methyl triphenyl phosphonium bromide. Nanocomposites were then prepared by combining the modified and raw forms of the clay with sawdust. The solution blending method was used to make the nanocomposites. The samples were analysed using thermogravimetric analysis and cone calorimetry. The studies showed that the nanocomposite which was made from sawdust and 1% organically modified clay had the most improved results in terms of burning time and thermal stability, as well as giving a calorific value closest to unmodified sawdust and the least amount of residue.展开更多
The year 1990 marks a line of rupture in the history of Algeria in general by the fundamental changes that have occurred, especially in the fields of urbanism and the land use planning, which has an important impact o...The year 1990 marks a line of rupture in the history of Algeria in general by the fundamental changes that have occurred, especially in the fields of urbanism and the land use planning, which has an important impact on space of the city and its environment. However, the absence of directives based on the reality of upstream territories and sometimes the conflict and the weakness of the instruments created at different levels: national, regional and local, have accelerated the galloping development of urbanization (the irrational consumption of land reserves inside and around the city), often at the expense of the agricultural land. On the other hand, the involvement of new actors in the production of the framework built in the Algerian town was made without compliance with the rules of architecture and urbanism contained in the build permit and in the MPU (Master Plan of Land Use and Urbanism) and the SOP (Soil Occupation Plan) approved. The analyses conducted in the cities such as the capital Algiers and Setif illustrate this situation well. This article presents these situations of paradox, identifies their causes and suggests the recommendations to implement in the framework of studies and actions to take, to correct and regulate their mutations.展开更多
During the hydration process, the Ultra-fine Cements present specific physical and chemical characteristics; they are, very short setting time and high heat release. For special applications, such as rapid hardening a...During the hydration process, the Ultra-fine Cements present specific physical and chemical characteristics; they are, very short setting time and high heat release. For special applications, such as rapid hardening and early high strength mortars or concretes, these characteristics can be considered advantageous. Some commercial products used for concrete reinforcement and repairs are the Rapid Hardening Mortars, these mortars must develop a time of setting up to 3 h and an initial compressive strength of about 3.5 MPa once the hardening of the paste is reached. The objective of the present research work is to use Ultra-fine Cement for the preparation of a series of different Rapid Hardening Mortars (with different percentages of Ultra-fine Cement), these mortars required the addition of a polycarboxylate-base specification F Superplasticizer. It was observed that the optimum water/cement (W/C) ratio for the hydration of the Ultra-fine Cements is W/C = 0.385. The Ultra-fine Cements were obtained by the High Energy Ball-milling technique at laboratory scale, 90% of the Particle Size Distribution is below 11 μm and the Blaine Specific Surface Area is over 9000 cm^2/g.展开更多
Grassland devoted about 90% of agricultural Irish land. Anion retention capacity of most agriculture soils is less than cation retention capacity, therefore chemical analyzed for anion (NO3 (nitrate), CI- (chlorid...Grassland devoted about 90% of agricultural Irish land. Anion retention capacity of most agriculture soils is less than cation retention capacity, therefore chemical analyzed for anion (NO3 (nitrate), CI- (chloride), SO42 (sulphate) and HPO4 (biphosphate)) in different water flow types (overland flow, interflow and vertical flow or drainage) samples. In this work, simple equipment was used to operationally distinguish between overland flow and interflow while vertical flow collected in different depths using soil water sampler equipments. Episodes of overland flow and interflow occurred even though the site is located in the lowest rainfall in Ireland and on well-drained soil. Samples of different origin showed marked differences in their anion contents, while HPO4 concentrations were almost equal to zero in all water flow types, nitrate where relatively high in overland and interflow samples and was very high in drainage samples. No sampling was carried out below the root zone but it must be assumed that the high concentrations measured in drainage samples would constitute a threat to groundwater resources. When overland flow and interflow did occur, NO3 concentrations were usually close to or in excess of the maximum admissible concentrations for drinking water and it will be constituted a threat to inland surface water bodies.展开更多
In Italy, the hydro-geological protection of the Apennine territories is a well-known issue. For this reason, at the end of the 19th century, a new reforestation technique was proposed by the Inspector of Forest Servi...In Italy, the hydro-geological protection of the Apennine territories is a well-known issue. For this reason, at the end of the 19th century, a new reforestation technique was proposed by the Inspector of Forest Service, Pietro Montanari to cope with difficult soil conditions of the mountain areas. This new approach was the first application of the so-called "gradoni" (small terraces) method of soil preparation. Each "gradone" was 100-120 cm wide and made with a slight counter slope (ca 10-15 degrees) to promote the accumulation of water and organic matter. Along each "gradone", bare root black pine seedlings (Pinus nigra Am.) were planted at a distance of 1 m from each other with a density of more than 3,000/ha. Nowadays, 19,158 hectares of black pine forests are growing in the Apennine of the Abruzzi region, largely resulting from those reforestation projects realized since the beginning of the 20th century. A case study of Monte Plaia (42°00′ 12″ N 13°53′39″ E), that illustrates the situation after 70-110 years in consequence of lacking of silvicultural treatment and the application of aforest restoration method is presented.展开更多
Soils developed from the Quaternary loesslike loams have been studied in the south of the forest-steppe zone on the Central Russian Upland. A polygenetic nature of the soil profile on the loesslike loams is shown. The...Soils developed from the Quaternary loesslike loams have been studied in the south of the forest-steppe zone on the Central Russian Upland. A polygenetic nature of the soil profile on the loesslike loams is shown. The modem pedogenetic processes in this soil ensure its eluvial-illuvial differentiation with the development of multilayered coatings in the illuvial horizon. The middle horizons in the studied soil profiles are referred to as textural (clay-illuvial) horizons. Differences in physical soil properties (bulk density, airconductivity, texture, water content, and temperature dynamics) were studied in the soil on the loesslike loam.展开更多
In 1997, the Ohio Senate passed Senate Bill 102 which established the Ohio School Facilities Commission as a separate agency to oversee the rebuilding projects of the public schools in Ohio. The bill also exempted the...In 1997, the Ohio Senate passed Senate Bill 102 which established the Ohio School Facilities Commission as a separate agency to oversee the rebuilding projects of the public schools in Ohio. The bill also exempted the construction contractors from paying prevailing wages on these projects on the hypothesis that this exemption would lower the construction cost. The purpose of this study is to investigate this hypothesis through the statistical analysis of 8,093 bids received from the years 2000 through 2007 for the schools' construction. Union contractors who paid their workers union wages and non-union contractors who did not pay prevailing wages bid these projects. The hypothesis, that prevailing wage laws increased the construction cost, was tested by comparing the bids/SF (square foot) from both groups (union and nonunion) for the different construction trades. The study indicated that there was statistical significant difference between the bids/square foot for union contractors and the bids/square foot for non-union contractors for only the following trades: earthwork, existing conditions, plumbing, electrical and HVAC (heating, ventilation and air conditioning). The averages of bids/SF from the union contractors were higher than those from the non-union contractors for earthwork, existing conditions and plumbing works, and the opposite for electrical and HVAC works. There was no statistical significant difference in the bids from the communications, concrete, conveying equipment, electronic safety and security, equipment, finishes, fire suppression, furnishings, masonry, openings, structural steel, thermal and moisture protection, plastics and composites and wood works.展开更多
A simple and economical chemical process for obtaining high purity neodymium oxide is discussed. The raw material in the form of RE (rare earth) carbonates is produced industrially in Brazil from monazite. Using thi...A simple and economical chemical process for obtaining high purity neodymium oxide is discussed. The raw material in the form of RE (rare earth) carbonates is produced industrially in Brazil from monazite. Using this concentrate as the feed material, ion exchange with a strong cationic resin, commonly used for water treatment, and without the use of retention ions was used for the fractionating of the REE (rare earth elements). The eluent was ammonium salt of EDTA (ethylenediaminetetraacetic acid) at pH 4.0. The complex of EDTA-neodymium was transformed into neodymium oxides via oxalate precipitation. We produced 99.9% pure Nd203 in yields greater than or equal to 80%. Molecular absorption spectrophotometry was used to monitor the neodymium content during the process and sector field inductively coupled plasma mass spectrometry was used to certify the purity of the neodymium oxides. The typical neodymium oxides obtained contained the followings contaminants in micrograms per gram: Sc (4.09); Y (0.39); La (0.78); Ce (5.62); Pr (4.56); Sm (11.10); Eu (1.10); Gd (14.30); Tb (29.3); Dy (4.15); Ho (8.39); Er (13.80); Tm (0.23); Yb (2.29); Lu (0.39). High purity neodymium oxides obtained from this procedure replaced the imported product used in research and development work on rare earth at IPEN/CNEN-SP (Instituto de Pesquisas Energeticas e Nucleares/Comissfio Nacional de Eneergia Nuclear-Sao Paulo).展开更多
In order to investigate the influence of three key molar ratios (n(SiO2)/n(Al2O3), n(K2O)/n(Al2O3) and n(H2O)/n(K2O)), a total of nine potassium poly-sialate-disiloxo (K-PSDS) geopolymeric cement matri...In order to investigate the influence of three key molar ratios (n(SiO2)/n(Al2O3), n(K2O)/n(Al2O3) and n(H2O)/n(K2O)), a total of nine potassium poly-sialate-disiloxo (K-PSDS) geopolymeric cement matrices were designed according to orthogonal design principle. Subsequently, XRD, ESEM-EDXA and MAS-NMR techniques were employed to further characterize the microstructure of the most fully reacted geopolymeric cement matrix. The experimental results show that n(K2O)/n(Al2O3) has the most significant effect on compressive strength amongst the three ratios. The highest compressive strength (20.1 MPa) can be achieved when n(SiO2)/n(Al2O3)=6.5, n(K2O)/n(Al2O3)=0.8 and n(HEO)/n(K2O)=10.0. The FTIR spectra of nine PSDS geopolymeric cement matrices also indicate that geopolymeric cement matrix with the highest strength is the most fully reacted one and possesses the largest amount of geopolymeric cement products. The microscopic analysis reveals that PSDS geopolymeric cement matrix possesses structural characteristics similar to gel substances in having a wide range of Si endowments, but predominantly the framework molecular chains of Si partially replaced by 4-coordinated Al tetrahedral.展开更多
基金Foundation item:Under the auspices of the Special Scientific Research of the Ministry of Land and Resources of China(No.201411009)
文摘The agro-pastoral ecotone has been recognized as the main distribution area of reserved land resource for cultivation. Accordingly, clarifying this assumption, as well as concerting land reclamation and ecological restoration, is important to ensure food security and environmental improvement in the agro-pastoral ecotone. We selected Horqin Left Back Banner(HLBB) as the subject of our case study. The landscape ecological security pattern of this area was determined using the minimum cumulative resistance model. Over-cultivation, quantity of reserved land resource for cultivation, and changes in landscape indexes before and after land use adjustment were then analyzed. Over-cultivation is a serious problem in the agro-pastoral ecotone. Reserved land resource for cultivation is less than that considered previously, and the area of reserved land resource for cultivation in HLBB only accounts for 11.50% of total uncultivated land. With regard to changes in landscape indexes, the adjusted land use pattern is effective for anti-desertification. The compensation standard for abandoned cultivated land should be improved and the comprehensive results of ‘Grain for Green' should be evaluated to further implement ecological restoration in the agro-pastoral ecotone.
基金Project(2009CB623201) supported by the National Basic Research Program of ChinaProject(G0510) supported by the Key Laboratory for Refractories and High-temperature Ceramics of Hubei Province, China
文摘Geopolymer-lightweight aggregate refractory concrete (GLARC) was prepared with geopolymer and lightweight aggregate. The mechanical property and heat-resistance (950 ℃) of GLARC were investigated. The effects of size of aggregate and mass ratio of geopolymer to aggregate on mechanical and thermal properties were also studied. The results show that the highest compressive strength of the heated refractory concrete is 43.3 MPa,and the strength loss is only 42%. The mechanical property and heat-resistance are influenced by the thickness of geopolymer covered with aggregate,which can be expressed as the quantity of geopolymer on per surface area of aggregate. In order to show the relationship between the thickness of geopolymer covered with aggregate and the thermal property of concrete,equal thickness model is presented,which provides a reference for the mix design of GLARC. For the haydite sand with size of 1.18-4.75 mm,the best amount of geopolymer per surface area of aggregate should be in the range of 0.300-0.500 mg/mm2.
基金Project(51004053)supported by National Natural Science Foundation of ChinaProject(2009J01033)supported by Natural Science Foundation of Fujian Province,China+2 种基金Project(3502Z20116008)supported by the Science and Technology Research Project of Xiamen City,ChinaProject(JA11146)supported by Program for Fostering Distinguished Young Scholars in University of Fujian Province,ChinaProject(2011B003)supported by the Foundation for Young Professors of Jimei University,China
文摘In the present work, a novel heterogeneous photo-Fenton catalyst was prepared by iron and cerium pillared bentonite. The catalyst Fe-Ce/bentonite was characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), Brunauer-Emmett-Teller (BET) and scanning electron microscopy (SEM) methods. It is found that Fe and Ce intercalate into the silicate layers of bentonite successfully. Tetracycline was removed by heterogeneous photo-Fenton reaction using the catalyst in this work. The effects of different reaction systems, hydrogen peroxide concentration, initial pH, catalyst dosage, UV power and introduction of different anions on degradation were investigated in details. The stability of catalyst was investigated through recycling experiment. The results show that removal rate of tetracycline is 98.13% under the conditions of 15 mmol/L H202, 0.50 g/L catalyst dosage, initial pH 3.0, 11 W UV lamp power and 60 min reaction time. However, the removal rate decreases after adding some anions. The hydroxyl radical plays an important role in heterogeneous photo-assisted Fenton degradation of tetracycline. The catalyst is very stable and can be recycled many times.
文摘A greenhouse experiment was conducted using stratified paddy field models, which were prepared by polluted soil with 12.5 cm soil dressing. The paddy models were assembled with open and closed percolation system to focus the effect of percolation pattern on accumulation of cupper (Cu) and cadmium (Cd) in rice plants in contaminated paddy filed with soil dressing models. Percolation pattern has significant effect on soil environment, especially redox potential that may influence mobilization of Cd, Cu and other elements. In open system percolation models, the plowsole and subsoil were in oxidative condition (600 mV), whereas reduction condition (-200 mV) was measured in closed system percolation models. Accumulations of Cu and Cd in all parts of rice plants (roots, grains, stems and leaves) were found higher in an open system percolation with the paddy field model comparatively than in a closed system percolation. The soil redox (Eh) condition influenced by the percolation pattern might be one of the main factors for uptake and accumulation of Cu and Cd in rice plants. The plant height and stem number were found lower in open system percolation comparatively to closed system percolation. In the yields section, the average panicle length, number of panicle and rice grain/hill and weight of grain/hill were lower in open system percolation than the closed system percolation.
基金Project supported by the National Natural Science Foundation of China (No. 20471044), and the Natural Science Foundation of Hubei Province (No. 2005ABA053), China
文摘SO4^2- / TiO2-La2O3, a novel solid superacid, was prepared and its catalytic activities at different synthetic conditions are discussed with esterification of n-butanoic acid and n-butyl alcohol as probing reaction. The optimum conditions have also been found, mole ratio of n(La^3+):n(Ti^4+) is 1:34, the soaked consistency of H2SO4 is 0.8 tool/L, the soaked time of HESO4 is 24 h, the calcining temperature is 480 ℃, the calcining time is 3 h. Then it was applied in the catalytic synthesis often important ketals and acetals as catalyst and revealed high catalytic activity. Under these conditions on which the molar ratio of aldehyde/ketone to glycol is l: 1.5, the mass ratio of the catalyst used in the reactants is 0.5%, and the reaction time is 1.0 h, the yields of ketals and acetals can reach 41.4%-95.8%.
文摘The material strength reserve method is practical in the study of the stability and failure mechanism of earth dam by analysing the development of failure zone of different shear strength parameters of the earth mass of the dam. The stability in the concrete dam and ensemble architecture has got general application while analysing. In combination with Feilaixia Multipurpose Project, application of this method to earth dam stability analysis was studied by plane Finite Element Method(FEM) for the first time. Through plane FEM, we can get the failure mechanism of earth dam and appraise to the security, for operating and managing put forward some reference suggestions.
基金Supported by the National Basic Research Program of China(2013CB632606)the National Natural Science Foundation of China(51474200)+1 种基金the Youth Innovation Promotion AssociationCAS(2015036)
文摘A novel and environmentally friendly route to directly prepare metallic vanadium from NaV03 by molten salt electrolysis is proposed. The feasibility about the direct electro-reduction of NaV03 to metallic vanadi- um is analyzed based on the thermodynamic calculations and experimental verifications. The theoretical decomposition voltage of NaV03 to metallic vanadium is only 0.47 V at 800 ℃ and much lower than that of the alkali and alkali earth metal chloride salts. The value is slightly higher than that of low-valence vanadium oxides such as V203, V305 and VO. However, the low-valence vanadium oxides can he further electro-reduced to metallic vanadium thermodynamically. The thermodynamic analysis is verified by the experimental results. The direct preparation of metallic vanadium from NaV03 by molten salt electrolysis is feasible.
基金Project(2011FJ1005)supported by the Major Provincial Science and Technology Program of Hunan Province,ChinaProject(2010qzzd0101)supported by the Central College on the 2010 Operational Costs of Basic Research Program,China
文摘Poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) based composite polymer electrolyte (CPE) modified with CeO2, La2O3 and Y2O3 nano-rare earth oxides was prepared by phase inversion technique. Physical and chemical properties of the modified CPEs were studied by SEM, TG-DSC and electrochemical methods. The results show that the CPE modified with 10% La2O3 (mass fraction) has the best practical applicability, which indicates that the thermal and electrochemical stability can reach over 400 ℃ and 4.5 V, respectively, and temperature dependence of ionic conductivity follows Vogel-Tamman-Fulcher (VTF) relationship and ionic conductivity at room temperature is up to 3.3 mS/cm. The interfacial resistance Ri reaches a stable value about 557 Ω after 6 d storage.
文摘Composites of montmorillonite clay and sawdust were prepared with the desired result being having new materials which burn longer than unmodified sawdust. The three forms of clay used for preparation of composites were unmodified montmorillonite, mono-ionic montmorillonite and organically modified montmorillonite. Montmorillonite clay was converted to mono-ionic clay by ion exchange with sodium using a sodium chloride solution. The mono-ionic clay was organically modified with an organic surfactant, methyl triphenyl phosphonium bromide. Nanocomposites were then prepared by combining the modified and raw forms of the clay with sawdust. The solution blending method was used to make the nanocomposites. The samples were analysed using thermogravimetric analysis and cone calorimetry. The studies showed that the nanocomposite which was made from sawdust and 1% organically modified clay had the most improved results in terms of burning time and thermal stability, as well as giving a calorific value closest to unmodified sawdust and the least amount of residue.
文摘The year 1990 marks a line of rupture in the history of Algeria in general by the fundamental changes that have occurred, especially in the fields of urbanism and the land use planning, which has an important impact on space of the city and its environment. However, the absence of directives based on the reality of upstream territories and sometimes the conflict and the weakness of the instruments created at different levels: national, regional and local, have accelerated the galloping development of urbanization (the irrational consumption of land reserves inside and around the city), often at the expense of the agricultural land. On the other hand, the involvement of new actors in the production of the framework built in the Algerian town was made without compliance with the rules of architecture and urbanism contained in the build permit and in the MPU (Master Plan of Land Use and Urbanism) and the SOP (Soil Occupation Plan) approved. The analyses conducted in the cities such as the capital Algiers and Setif illustrate this situation well. This article presents these situations of paradox, identifies their causes and suggests the recommendations to implement in the framework of studies and actions to take, to correct and regulate their mutations.
文摘During the hydration process, the Ultra-fine Cements present specific physical and chemical characteristics; they are, very short setting time and high heat release. For special applications, such as rapid hardening and early high strength mortars or concretes, these characteristics can be considered advantageous. Some commercial products used for concrete reinforcement and repairs are the Rapid Hardening Mortars, these mortars must develop a time of setting up to 3 h and an initial compressive strength of about 3.5 MPa once the hardening of the paste is reached. The objective of the present research work is to use Ultra-fine Cement for the preparation of a series of different Rapid Hardening Mortars (with different percentages of Ultra-fine Cement), these mortars required the addition of a polycarboxylate-base specification F Superplasticizer. It was observed that the optimum water/cement (W/C) ratio for the hydration of the Ultra-fine Cements is W/C = 0.385. The Ultra-fine Cements were obtained by the High Energy Ball-milling technique at laboratory scale, 90% of the Particle Size Distribution is below 11 μm and the Blaine Specific Surface Area is over 9000 cm^2/g.
文摘Grassland devoted about 90% of agricultural Irish land. Anion retention capacity of most agriculture soils is less than cation retention capacity, therefore chemical analyzed for anion (NO3 (nitrate), CI- (chloride), SO42 (sulphate) and HPO4 (biphosphate)) in different water flow types (overland flow, interflow and vertical flow or drainage) samples. In this work, simple equipment was used to operationally distinguish between overland flow and interflow while vertical flow collected in different depths using soil water sampler equipments. Episodes of overland flow and interflow occurred even though the site is located in the lowest rainfall in Ireland and on well-drained soil. Samples of different origin showed marked differences in their anion contents, while HPO4 concentrations were almost equal to zero in all water flow types, nitrate where relatively high in overland and interflow samples and was very high in drainage samples. No sampling was carried out below the root zone but it must be assumed that the high concentrations measured in drainage samples would constitute a threat to groundwater resources. When overland flow and interflow did occur, NO3 concentrations were usually close to or in excess of the maximum admissible concentrations for drinking water and it will be constituted a threat to inland surface water bodies.
文摘In Italy, the hydro-geological protection of the Apennine territories is a well-known issue. For this reason, at the end of the 19th century, a new reforestation technique was proposed by the Inspector of Forest Service, Pietro Montanari to cope with difficult soil conditions of the mountain areas. This new approach was the first application of the so-called "gradoni" (small terraces) method of soil preparation. Each "gradone" was 100-120 cm wide and made with a slight counter slope (ca 10-15 degrees) to promote the accumulation of water and organic matter. Along each "gradone", bare root black pine seedlings (Pinus nigra Am.) were planted at a distance of 1 m from each other with a density of more than 3,000/ha. Nowadays, 19,158 hectares of black pine forests are growing in the Apennine of the Abruzzi region, largely resulting from those reforestation projects realized since the beginning of the 20th century. A case study of Monte Plaia (42°00′ 12″ N 13°53′39″ E), that illustrates the situation after 70-110 years in consequence of lacking of silvicultural treatment and the application of aforest restoration method is presented.
文摘Soils developed from the Quaternary loesslike loams have been studied in the south of the forest-steppe zone on the Central Russian Upland. A polygenetic nature of the soil profile on the loesslike loams is shown. The modem pedogenetic processes in this soil ensure its eluvial-illuvial differentiation with the development of multilayered coatings in the illuvial horizon. The middle horizons in the studied soil profiles are referred to as textural (clay-illuvial) horizons. Differences in physical soil properties (bulk density, airconductivity, texture, water content, and temperature dynamics) were studied in the soil on the loesslike loam.
文摘In 1997, the Ohio Senate passed Senate Bill 102 which established the Ohio School Facilities Commission as a separate agency to oversee the rebuilding projects of the public schools in Ohio. The bill also exempted the construction contractors from paying prevailing wages on these projects on the hypothesis that this exemption would lower the construction cost. The purpose of this study is to investigate this hypothesis through the statistical analysis of 8,093 bids received from the years 2000 through 2007 for the schools' construction. Union contractors who paid their workers union wages and non-union contractors who did not pay prevailing wages bid these projects. The hypothesis, that prevailing wage laws increased the construction cost, was tested by comparing the bids/SF (square foot) from both groups (union and nonunion) for the different construction trades. The study indicated that there was statistical significant difference between the bids/square foot for union contractors and the bids/square foot for non-union contractors for only the following trades: earthwork, existing conditions, plumbing, electrical and HVAC (heating, ventilation and air conditioning). The averages of bids/SF from the union contractors were higher than those from the non-union contractors for earthwork, existing conditions and plumbing works, and the opposite for electrical and HVAC works. There was no statistical significant difference in the bids from the communications, concrete, conveying equipment, electronic safety and security, equipment, finishes, fire suppression, furnishings, masonry, openings, structural steel, thermal and moisture protection, plastics and composites and wood works.
文摘A simple and economical chemical process for obtaining high purity neodymium oxide is discussed. The raw material in the form of RE (rare earth) carbonates is produced industrially in Brazil from monazite. Using this concentrate as the feed material, ion exchange with a strong cationic resin, commonly used for water treatment, and without the use of retention ions was used for the fractionating of the REE (rare earth elements). The eluent was ammonium salt of EDTA (ethylenediaminetetraacetic acid) at pH 4.0. The complex of EDTA-neodymium was transformed into neodymium oxides via oxalate precipitation. We produced 99.9% pure Nd203 in yields greater than or equal to 80%. Molecular absorption spectrophotometry was used to monitor the neodymium content during the process and sector field inductively coupled plasma mass spectrometry was used to certify the purity of the neodymium oxides. The typical neodymium oxides obtained contained the followings contaminants in micrograms per gram: Sc (4.09); Y (0.39); La (0.78); Ce (5.62); Pr (4.56); Sm (11.10); Eu (1.10); Gd (14.30); Tb (29.3); Dy (4.15); Ho (8.39); Er (13.80); Tm (0.23); Yb (2.29); Lu (0.39). High purity neodymium oxides obtained from this procedure replaced the imported product used in research and development work on rare earth at IPEN/CNEN-SP (Instituto de Pesquisas Energeticas e Nucleares/Comissfio Nacional de Eneergia Nuclear-Sao Paulo).
基金Project(2009CB623200) supported by the National Basic Research Program of ChinaProjects(50702014, 50878043) supported by the National Natural Science Foundation of ChinaProject(NCET-08-0116) supported by the Program for New Century Excellent Talents in University of Ministry of Education, China
文摘In order to investigate the influence of three key molar ratios (n(SiO2)/n(Al2O3), n(K2O)/n(Al2O3) and n(H2O)/n(K2O)), a total of nine potassium poly-sialate-disiloxo (K-PSDS) geopolymeric cement matrices were designed according to orthogonal design principle. Subsequently, XRD, ESEM-EDXA and MAS-NMR techniques were employed to further characterize the microstructure of the most fully reacted geopolymeric cement matrix. The experimental results show that n(K2O)/n(Al2O3) has the most significant effect on compressive strength amongst the three ratios. The highest compressive strength (20.1 MPa) can be achieved when n(SiO2)/n(Al2O3)=6.5, n(K2O)/n(Al2O3)=0.8 and n(HEO)/n(K2O)=10.0. The FTIR spectra of nine PSDS geopolymeric cement matrices also indicate that geopolymeric cement matrix with the highest strength is the most fully reacted one and possesses the largest amount of geopolymeric cement products. The microscopic analysis reveals that PSDS geopolymeric cement matrix possesses structural characteristics similar to gel substances in having a wide range of Si endowments, but predominantly the framework molecular chains of Si partially replaced by 4-coordinated Al tetrahedral.