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复交换Banach代数中可约元的等价条件
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作者 殷苌茗 《长沙水电师院自然科学学报》 1990年第1期58-61,共4页
设A是一个复交换Banach代数.本文在G·Corach等人给出的“可约”概念基础上,证明了A中可约元(α,α)的几个有趣的等价条件.主要结果是:若A是一个复交换Banach代数,(α,α)∈U_(n+1)(A).则(α,α)在A中可约的充分必要条件是存在f_m∈... 设A是一个复交换Banach代数.本文在G·Corach等人给出的“可约”概念基础上,证明了A中可约元(α,α)的几个有趣的等价条件.主要结果是:若A是一个复交换Banach代数,(α,α)∈U_(n+1)(A).则(α,α)在A中可约的充分必要条件是存在f_m∈U_n(C(σ(A))),使得‖f_m-α‖Zα→0.这里‖f_m‖Zα=sup{‖f_m(h)h∈Z_α}.(m∈N). 展开更多
关键词 BANACH代数 可约元 复交换 等价
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Improvement in electrokinetic remediation of Pb-contaminated soil near lead acid battery factory 被引量:9
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作者 蔡宗平 Jeremiahvan DOREN +1 位作者 方战强 李伟善 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第9期3088-3095,共8页
To improve the conventional electrokinetic remediation of Pb-contaminated soil,the Pb-contaminated soil near a lead acid battery factory in the Pearl River Delta region of China was electrokinetically remedied with po... To improve the conventional electrokinetic remediation of Pb-contaminated soil,the Pb-contaminated soil near a lead acid battery factory in the Pearl River Delta region of China was electrokinetically remedied with polarity exchange technique.The variations in Pb removal efficiency and the soil p H value with the treatment time and the exchange polarity interval were determined.It is found that the removal efficiency of Pb reaches a maximum of 87.7% when the voltage gradient is 1 V/cm and the exchange polarity interval is 48 h.This value is far higher than that obtained with conventional electrokinetic remediation(61.8%).Additionally,the "focusing effect" which appears in the conventional electrokinetic remediation can be avoided,and thus additional chemicals are not needed for the polarity exchange technique.The mechanism of Pb electromigration behavior in soil during the treatment with the polarity exchange technique was described. 展开更多
关键词 electrokinetic remediation polarity exchanges Pb-contaminated soil
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Photosynthetic Gas Exchange and Leaflet Movement of Robinia pseudoacacia in Relation to Changing Light Environments 被引量:2
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作者 张守仁 马克平 陈灵芝 《Acta Botanica Sinica》 CSCD 2002年第7期858-863,共6页
On the sunny days, there were little diurnal changes in both azimuth and directional angle for either sun_ or shade_leaflet. However, there existed a significant diurnal change in midrib angle that reflected movements... On the sunny days, there were little diurnal changes in both azimuth and directional angle for either sun_ or shade_leaflet. However, there existed a significant diurnal change in midrib angle that reflected movements regarding evasion of light stress around noon hours. On the cloudy day, a very little diurnal difference was found in azimuth, directional and midrib angle. It is suggested that changing light environment is the main factor for inducing leaflet movement of Robinia pseudoacacia , and the rhythmical movement does not attribute to the leaflet movement. Leaf orientation control test showed that the photosynthetic rate ( Pn ), stomatal conductance ( g s ) and transpiration ( Tr ) of the artificial fixed_leaflets were significantly lower than that of control_leaflets. And the leaf temperature ( Tl ) of the fixed leaflets significantly exceeded that of control_leaflets, which may attribute to the significant difference of light interception between the fixed and control_leaflets. The light_dependent leaflet movement is the morphological adjustment of maintaining optimal physiological status. 展开更多
关键词 Robinia pseudoacacia leaflet movement photosynthetic gas exchange light environment
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Characteristics of Soluble and Exchangeable Acidity inan Extremely Acidified Acid Sulfate Soil 被引量:4
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作者 C.Lin M.D.MELVILLE 《Pedosphere》 SCIE CAS CSCD 1999年第4期323-330,共8页
An extremely acidified acid sulfate soil (ASS) was investigated to characterize its soluble and exchangeableacidity. The results showed that soluble acidity of a sample determined by titration with a KOH solutionwas m... An extremely acidified acid sulfate soil (ASS) was investigated to characterize its soluble and exchangeableacidity. The results showed that soluble acidity of a sample determined by titration with a KOH solutionwas much significantly greater than that indicated by pH measured using a PH meter, particularly for theextremely acidic soil samples. This is because the total soluble acidity of the extremely acidic soil sampleswas mainly composed of various soluble Al and Fe species, possibly in forms of Al sulfate complexes (e.g.,AISO4) and ferrous Fe (Fe2+). It is therefore suggested not to use pH alone as an indicator of soluble acidityin ASS, particularly for extremely acidic ASS. It is also likely that AISO4+ actively pericipated in cationexchange reactions. It appears that the possible involvement of this Al sulfate canon in the canon adsorptionhas significant effect on increasing the amount of acidity being adsorbed by the soils. 展开更多
关键词 acid sulfate soils aluminium sulfate complex exchangeable acidity HYDROLYSIS soluble acidity
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The retromer component SNX6 interacts with dynactin p150Glued and mediates endosome-to-TGN transport 被引量:8
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作者 Zhi Hong Yanrui Yang +4 位作者 Cheng Zhang Yang Niu Ke Li Xi Zhao Jia-JiaLiu 《Cell Research》 SCIE CAS CSCD 2009年第12期1334-1349,共16页
The retromer is a protein complex that mediates retrograde transport of transmembrane cargoes from endosomes to the trans-Golgi network (TGN). It is comprised of a cargo-selection subcomplex of Vps26, Vps29 and Vps3... The retromer is a protein complex that mediates retrograde transport of transmembrane cargoes from endosomes to the trans-Golgi network (TGN). It is comprised of a cargo-selection subcomplex of Vps26, Vps29 and Vps35 and a membrane-binding coat subcomplex of sorting nexins (SNXs). Previous studies identified SNX1/2 as one of the components of the SNX subcomplex, and SNX5/6 as candidates for the second SNX. How the retromer-associated cargoes are recognized and transported by molecular motors are largely unknown. In this study, we found that one of SNX1/2's dimerization partners, SNX6, interacts with the p150Gued subunit of the dynein/dynactin motor complex. We present evidence that SNX6 is a component of the retromer, and that recruitment of the motor complex to the membrane-associated retromer requires the SNX6-pl50Gued interaction. Disruption of the SNX6-pl50Glued interaction causes failure in formation and detachment of the tubulovesicular sorting structures from endosomes and results in block of CI-MPR retrieval from endosomes to the TGN. These observations indicate that in addition to SNX1/2, SNX6 in association with the dynein/dynactin complex drives the formation and movement of tubular retrograde intermediates. 展开更多
关键词 sorting nexin RETROMER p 150Glued retrograde transport dynein/dynactin CI-MPR
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Proton-Exchange Sulfonated Poly (ether ether ketone) (SPEEK)/SiOx-S Composite Membranes in Direct Methanol Fuel Cells 被引量:6
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作者 高启君 王宇新 +2 位作者 许莉 卫国强 王志涛 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2009年第2期207-213,共7页
A sulfonated poly(ether ether ketone) (SPEEK) membrane with a fairly high degree of sulfonation (DS) can swell excessively and even dissolve at high temperature. To solve these problems, insolvable functionalize... A sulfonated poly(ether ether ketone) (SPEEK) membrane with a fairly high degree of sulfonation (DS) can swell excessively and even dissolve at high temperature. To solve these problems, insolvable functionalized silica powder with sulfonic acid groups (SiOx-S) was added into the SPEEK matrix (DS = 55.1%) to prepare SPEEK/ SiOx-S composite membranes. The decrease in both the swelling degree and the methanol permeability of the membranes was a dose-dependent result of addition of the SiOx-S powder. Pure SPEEK membrane swelled 52.6% at 80℃, whereas the SPEEK/SiOx-S (15%, by mass) membrane swelled only 27.3% at the same temperature. From room temperature to 80℃, all SPEEK/SPEEK/SiOx-S composite membranes had methanol permeability of about one order of magnitude lower than that ofNafion115. Compared with pure SPEEK membranes, the addition of the SiOx-S powder not only leads to higher proton conductivity, but also increases the dimensional stability at higher temperatures, and greater proton conductivity can be achieved at higher temperature. The SPEEK/SiO4-S (20%, by mass) membrane could withstand temperature up to 145℃, at which in 100% relative humidity (RH) its proton conductivity exceeded slightly that of Nafion 1 15 membrane and reached 0.17 S·cm^-1, while pure SPEEK membrane dissolved at 90℃. The SPEEK/SiOx-S composite membranes are promising for use in direct methanol fuel cells because of their good dimensional stability, high proton conductivity, and low methanol permeability. 展开更多
关键词 sulfonated poly(ether ether ketone) functionalized silica composite membrane direct methanol fuel cell
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Low-cost and efficient visible-light-driven CaMg(CO_3)_2@Ag_2CO_3 microspheres fabricated via an ion exchange route 被引量:4
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作者 Jian Tian Zhen Wu +5 位作者 Zhen Liu Changlin Yu Kai Yang Lihua Zhu Weiya Huang Yang Zhou 《Chinese Journal of Catalysis》 CSCD 北大核心 2017年第11期1899-1908,共10页
CaMg(CO3)2microspheres were prepared and used as hard templates to fabricate a series of CaMg(CO3)2@Ag2CO3composite microspheres via a fast and low‐cost ion exchange process.The effects of ion exchange time and tempe... CaMg(CO3)2microspheres were prepared and used as hard templates to fabricate a series of CaMg(CO3)2@Ag2CO3composite microspheres via a fast and low‐cost ion exchange process.The effects of ion exchange time and temperature on the physicochemical properties and photocatalytic activities of the composite microspheres were studied through photocatalytic degradation of Acid Orange II under xenon lamp irradiation.The obtained samples were analyzed by X‐ray diffraction,scanning electron microscopy,Fourier transform infrared spectroscopy,UV‐vis diffuse reflectance spectroscopy,N2physical adsorption,and photocurrent tests.The CaMg(CO3)2@Ag2CO3sample with the highest activity was obtained with an ion exchange time of4h and temperature of40°C.The degradation rate of Acid Orange II by this sample reached83.3%after15min of light irradiation,and the sample also performed well in phenol degradation.The CaMg(CO3)2@Ag2CO3produced under these ion exchange conditions showed a well‐ordered hierarchical morphology with small particle sizes,which was beneficial to light absorption and the transfer of photoelectrons(e-)and holes(h+)to the catalyst surface.Moreover,the separation of photogenerated carriers over the composites was greatly improved relative to bare CaMg(CO3)2.Despite the very low content of Ag2CO3(2.56%),excellent photocatalytic performance was obtained over the CaMg(CO3)2@Ag2CO3microspheres. 展开更多
关键词 Hard template Ion exchange CaMg(CO3)2@Ag2CO3 microspheres Photocatalytic performance
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Synthesis, characterization and antimicrobial activity of alkaline ion-exchanged ZnO/bentonite nanocomposites 被引量:1
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作者 Hamideh Pouraboulghasem Mohammad Ghorbanpour +1 位作者 Razieh Shayegh Samaneh Lotfiman 《Journal of Central South University》 SCIE EI CAS CSCD 2016年第4期787-792,共6页
Nanocomposites of zinc/bentonite clay were synthesized for use as an antibacterial material by a quick and simple alkaline ion exchange method. The synthesis of zinc doped bentonite nanocomposite was accomplished by p... Nanocomposites of zinc/bentonite clay were synthesized for use as an antibacterial material by a quick and simple alkaline ion exchange method. The synthesis of zinc doped bentonite nanocomposite was accomplished by placing bentonite in a melting bath of ZnSO4 for 10, 20, 40, 60 and 90 rain. The complexes were characterized by XRD, SEM and DRS. XRD analyses and SEM observations confirmed the diffusion of zinc to the clay surfaces. Antibacterial activity tests against Escherichia coli showed that bentonite did not present any antibacterial properties, but after alkaline ion exchange treatment, inhibition was noted. The highest antibacterial activity was observed with ZnO/bentonite composite alkaline ion exchange for 60 and 90 rain. Interestingly, the leaching test indicated that ZnO/bentonite did not present any risk for drinking water treatment. 展开更多
关键词 alkaline ion exchange ZnO/bentonite nanocomposite antibacterial activity
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Joint Timing and Frequency Synchronization for OFDM based on Fractional Fourier Transform 被引量:5
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作者 Tang Xun Sha Xuejun 《China Communications》 SCIE CSCD 2010年第5期93-102,共10页
In this paper a joint timing and frequency synchronization method based on Fractional Fourier Transform (FIFT) is proposed for Orthogonal Frequency-Division Multiplexing (OFDM) system. The combination of two chirp... In this paper a joint timing and frequency synchronization method based on Fractional Fourier Transform (FIFT) is proposed for Orthogonal Frequency-Division Multiplexing (OFDM) system. The combination of two chirp signals with opposite chirp rates are used as the training signal, the received training signal with timing and frequency offset is transformed by FrFT and the two peaks representing two chirps in FrFT domain are detected, then the position coordinates of the two peaks are precisely corrected and substituted into an equation group to calculate timing and frequency offset simultaneously. This method only needs one FrFT calculation to implement synchronization, the computational complexity is equal to that of FFT and less than that of correlation or maximum likelihood calculation of existing methods, and estimation range of frequency offset is Large, greater than half the signal bandwidth, while the simulation results show that even at low SNR it can accurately estimate timing and frequency offset and the estimation error is less than that of existing methods. 展开更多
关键词 SYNCHRONIZATION Fractional Fourier transform chirp signal OFDM
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A novel wavelength assignment scheme in OBS network for contention avoidance
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作者 单广军 《High Technology Letters》 EI CAS 2009年第3期325-330,共6页
Conventional optical burst switching(OBS)technique adopts purely statistical multiplex mechanismso that the bursts collide with each other very easily.To address this problem,a novel proactive con-tention avoidance sc... Conventional optical burst switching(OBS)technique adopts purely statistical multiplex mechanismso that the bursts collide with each other very easily.To address this problem,a novel proactive con-tention avoidance scheme is proposed,which assigns dedicated wavelengths to each ingress node,then st-numbering algorithm is used to construct the traffic load balanced spanning trees .In this way,contentioncan be eliminated at ingress nodes,and the amount of bursts that could be accommodated by ingressnodes will be maximized.Further,those unused wavelengths left by traffic load balanced spanning treeare also organized as partial trees to carry bursts,thus the link utilization can be improved effectively.Simulation result shows that our scheme can improve the burst loss performance significantly without thewavelength converters or optical buffers comparing to other popular routing and wavelength assignment(RWA)algorithms. 展开更多
关键词 optical burst switching (OBS) contention avoidance link utilization burst loss per- formance routing and wavelength assignment (RWA)
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Key substitution attacks on some verifiably encrypted signature schemes
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作者 夏琦 Xu Chunxiang Yu Yong 《High Technology Letters》 EI CAS 2011年第2期191-195,共5页
As a special kind of digital signature, verifiably encrypted signatures are used as a building block to construct optimistic fair exchange. Many verifiably encrypted signature schemes have been proposed so far and mos... As a special kind of digital signature, verifiably encrypted signatures are used as a building block to construct optimistic fair exchange. Many verifiably encrypted signature schemes have been proposed so far and most of them were proven secure under certain complexity assumptions. In this paper, however, we find that although some schemes are secure in a single-user setting, they are not secure in a multi-user setting any more. We show that Zhang, et al. ' s scheme, Gorantla, et al. ' s scheme and Ming, et al. ' s scheme are vulnerable to key substitution attacks, where an adversary can generate new keys satisfying legitimate verifiably encrypted signatures created by the legitimate users. We also show that this kind of attacks can breach the fairness when they are used in fair exchange in a multi-user setting. 展开更多
关键词 CRYPTOGRAPHY fair exchange verifiably encrypted signature key substitution attack
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The Performance Analysis of the Wavelet-OFDM New Scheme in AWGN Channel
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作者 Alaa Ghaith Rima Hatoum Hiba Mradand Ali Alaeddine 《Journal of Physical Science and Application》 2014年第2期100-106,共7页
Orthogonal frequency division multiplexing (OFDM) is a special form of multi-carrier transmission that uses the policy of divide and rule. In this scheme, a large number of orthogonal, overlapping, narrow band sub-c... Orthogonal frequency division multiplexing (OFDM) is a special form of multi-carrier transmission that uses the policy of divide and rule. In this scheme, a large number of orthogonal, overlapping, narrow band sub-channels (subcarriers) are transmitted in parallel and divide the available transmission bandwidth. This techniqueis originally based on the Fast Fourier Transform of the information data. In order to improve the performance of the OFDM and overcome some limitations, an alternative OFDM approach based on the Wavelet Transform is proposed. In this paper, we study the performance of such systems in additive white Gaussian channel (AWGN). MATLAB simulations are realized and performance comparisons are presented. 展开更多
关键词 Multi-carrier modulation discrete wavelet transform OFDM. wavelet packet transform Fourier-based OFDM wavelet-based
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Exchange Interactions at the Interface FMIAFM Nanocomposite Obtained by Mechanochemical Synthesis
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作者 Lenine Campos Miranda Fabio Cavalcanti Lopes +1 位作者 Andre Galembeck Eduardo Padron Hemaindez 《Journal of Chemistry and Chemical Engineering》 2013年第12期1149-1155,共7页
This paper presents a study of the relationship between the magnetic properties and microstructure of nanocomposite Ni/MnO, Ni/CoO, Co/MnO, Co/CoO. The objective is to understand how the coupling interface FM/AFM (fe... This paper presents a study of the relationship between the magnetic properties and microstructure of nanocomposite Ni/MnO, Ni/CoO, Co/MnO, Co/CoO. The objective is to understand how the coupling interface FM/AFM (ferromagnetic/anti-ferromagnetic) manifests itself in magnetic response of these materials to an applied field. Sample preparation was performed using mechanochemical synthesis by means of a ball mill planetary type high power at normal atmosphere. The characterization was done by XRD (X-ray diffraction), SEM (scanning electron microscopy) and VSM (vibrating sample magnetometry). Analyzing the XRD peaks of the samples studied, there was a decrease in the average particle diameter with increasing milling time, which is important in the magnetic interactions of the atoms of the surface. In addition, the diffraction pattern showed formation of new phases by oxidation interfering with the magnetic measurements. Analyses by SEM show chipboard multiform nano- and micrometer-sized grains on the surface of the clusters being responsible for the interaction. The magnetic measurements show a strong coupling between the phases present in nanocomposites showing once again that the MS (mechanosynthesis) is a powerful technique for this kind of purpose. The effect of the decrease in crystallite size leads to large variations of magnetic properties of the material which have been specifically observed changes in HC (coercive field) in the RM (remanent magnetization) and SM (saturation magnetization). The decrease in crystallite size in the course of grinding intensifies the effects that depend on the surface-to-volume ratio of the material. M vs. T measures were taken for different values of applied field and found a jump in the moment of the sample near the N6el temperature of the antiferromagnetic. 展开更多
关键词 NANOCOMPOSITES mechanical alloying hysteresis curve coupling FM/AFM N6el temperature.
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The decoupling between gas exchange and water potential of Cinnamomum camphora seedlings during drought recovery and its relation to ABA accumulation in leaves 被引量:2
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作者 Honglang Duan Defu Wang +7 位作者 Xiaohua Wei Guomin Huang Houbao Fan Shuangxi Zhou Jianping Wu Wenfei Liu David TTissue Songze Wan 《Journal of Plant Ecology》 SCIE CSCD 2020年第6期683-692,共10页
Aims Drought stress and the degree of drought severity are predicted to rise under highly variable patterns of precipitation due to climate change,while the capacity of trees to cope with drought recovery through phys... Aims Drought stress and the degree of drought severity are predicted to rise under highly variable patterns of precipitation due to climate change,while the capacity of trees to cope with drought recovery through physiological and biochemical adjustment remains unclear.We aimed to examine the coupling of physiology and biochemistry in trees during drought and the following recovery.Methods Potted seedlings of Cinnamomum camphora were grown under well watered conditions prior to the experimental drought stress,which was initiated by withholding water.Seedlings were rewatered following attainment of two drought severities:mild drought(stomatal closure)and moderate drought(ψxylem=−1.5 MPa).We measured leaf-level water potential,gas exchange(photosynthesis and stomatal conductance),abscisic acid(ABA),proline and non-structural carbohydrates(NSCs)concentrations in seedlings of C.camphora during drought and a 4-day recovery.Important Findings We found that drought severity largely determined physiological and biochemical responses and affected the rate of recovery.Stomatal closure occurred at the mild drought stress,accompanied with ABA accumulation in leaves and decline in water potential,while leaf proline accumulation and variable NSC were evident at the moderate drought stress.More severe drought stress led to delayed recovery of gas exchange,but it did not have significant effect on water potential recovery.The relationships of water potential and gas exchange differed during drought stress and post-drought recovery.There was tight coupling between water potential and gas exchange during drought,but not during rewatering due to high ABA accumulation in leaves,thereby delaying recovery of stomatal conductance.Our results demonstrate that ABA could be an important factor in delaying the recovery of stomatal conductance following rewatering and after water potential recovery of C.camphora.Furthermore,greater drought severity had significant impacts on the rate of recovery of tree physiology and biochemistry. 展开更多
关键词 DROUGHT RECOVERY gas exchange ABA NSC PROLINE
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Theory of several paravector variables:Bochner-Martinelli formula and Hartogs theorem 被引量:5
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作者 REN GuangBin WANG HaiYan 《Science China Mathematics》 SCIE 2014年第11期2347-2360,共14页
The aim of this article is to extend the theory of several complex variables to the non-commutative realm. Some basic results,such as the Bochner-Martinelli formula,the existence theorem of the solutions to the non-ho... The aim of this article is to extend the theory of several complex variables to the non-commutative realm. Some basic results,such as the Bochner-Martinelli formula,the existence theorem of the solutions to the non-homogeneous Cauchy-Riemann equations,and the Hartogs theorem,are generalized from complex analysis in several variables to Clifford analysis in several paravector variables. In particular,the Bochner-Martinelli formula in several paravector variables unifies the corresponding formulas in the theory of one complex variable,several complex variables,and several quaternionic variables with suitable modifications. 展开更多
关键词 several paravector variables Bochner-Martinelli formula Hartogs theorem
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Wedge Operations and Doubling Operations of Real Toric Manifolds
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作者 Hanchul PARK 《Chinese Annals of Mathematics,Series B》 SCIE CSCD 2017年第6期1321-1334,共14页
This paper deals with two things. First, the cohomology of canonical extensions of real topological toric manifolds is computed when coefficient ring G is a commutative ring in which 2 is unit in G. Second, the author... This paper deals with two things. First, the cohomology of canonical extensions of real topological toric manifolds is computed when coefficient ring G is a commutative ring in which 2 is unit in G. Second, the author focuses on a specific canonical extensions called doublings and presents their various properties. They include existence of infinitely many real topological toric manifolds admitting complex structures, and a way to construct infinitely many real toric manifolds which have an odd torsion in their cohomology groups.Moreover, some questions about real topological toric manifolds related to Halperin's toral rank conjecture are presented. 展开更多
关键词 Real toric manifold Small cover Real topological toric manifold Coho-mology ring Doubling Simplicial wedge Rational homology sphere
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SWITCHING CONTROL: FROM SIMPLE RULES TO COMPLEX CHAOTIC SYSTEMS
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作者 LU Jinhu(Institute of Systems Sciences, Academy of Mathematics and System Sciences, Chinese Academy of Sciences, Beijing 100080, China ) 《Journal of Systems Science & Complexity》 SCIE EI CSCD 2003年第3期404-413,共10页
This paper reviews and introduces some simple switching piecewise-linear controllers, which can generate complex chaotic behaviors from simple switching systems.The mechanism of simple switching rules creating complex... This paper reviews and introduces some simple switching piecewise-linear controllers, which can generate complex chaotic behaviors from simple switching systems.The mechanism of simple switching rules creating complex chaotic behaviors is further investigated. 展开更多
关键词 switching control simple rules complex systems
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Highly conductive and robust composite anion exchange membranes by incorporating quaternized MIL-101(Cr) 被引量:2
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作者 Xueyi He Mingyue Gang +6 位作者 Zhen Li Guangwei He Yongheng Yin Li Cao Bei Zhang Hong Wu Zhongyi Jiang 《Science Bulletin》 SCIE EI CAS CSCD 2017年第4期266-276,共11页
With well-defined channels and tunable functionality, metal-organic frameworks (MOFs) have inspired the design of a new class of ion-conductive compounds. In contrast to the extensive studies on proton- conductive M... With well-defined channels and tunable functionality, metal-organic frameworks (MOFs) have inspired the design of a new class of ion-conductive compounds. In contrast to the extensive studies on proton- conductive MOFs and related membranes attractive for fuel cells, rare reports focus on MOFs in preparation of anion exchange membranes. In this study, chloromethylated MIL-101 (Cr) was prepared and incor- porated into chloromethylated poly (ether ether ketone) (PEEK) as a multifunctional filler to prepare imidazolium PEEK/imidazolium MIL-101(Cr) (ImPEEK/ImMIL-101(Cr)) anion exchange membrane after synchronous quaternization. The successful synthesis and chloromethylation of MIL-101(Cr) were veri- fied by transmission electron microscopy, X-ray diffraction and Fourier transform infrared spectroscopy while the enhanced performance of composite membranes in hydroxide conductivity, mechanical strength and dimensional stability were evaluated by alternating-current impedance, electronic stretching machine and measurement of swelling ratio. Specifically, incorporating 5.0wt% ImMIL-101(Cr) afforded a 71.4% increase in hydroxide conductivity at 20℃, 100% RH. Besides, the composite membranes exhibited enhanced dimensional stability and mechanical strength due to the rigid framework of ImMIL- 101(Cr). At room temperature and the ImM1L-101(Cr) content of 10wt%, the swelling ratio of the ImPEEK/lmMIL-101(Cr) was 70.04% lower while the tensile strength was 47.5% higher than that of the pure membrane. 展开更多
关键词 MIL-101(Cr)Poly (ether ether ketone) Chloromethylation Quaternization Composite anion exchange membranes
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SC-IrO_2 NR-carbon hybrid:A catalyst with high electrochemical stability for oxygen reduction 被引量:3
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作者 WANG GuangJin CHENG Feng +3 位作者 YU Yi LIANG Cong XU Tian PAN Mu 《Science China Chemistry》 SCIE EI CAS 2013年第1期131-136,共6页
The enhanced electrochemical stability of the synthesized hybrid catalyst has been demonstrated by the introduction of the synergistic effect between carbon powder additive and the prepared catalyst.Single crystal IrO... The enhanced electrochemical stability of the synthesized hybrid catalyst has been demonstrated by the introduction of the synergistic effect between carbon powder additive and the prepared catalyst.Single crystal IrO 2 nanorod (SC-IrO 2 NR) catalyst was prepared by a sol-gel method.The structure and performance of the catalyst sample were characterized by X-ray diffraction spectroscopy (XRD),scanning electron microscope (SEM),transmission electron microscope (TEM),rotating disk electrode (RDE) and cyclic voltammetry (CV) measurements.XRD patterns and TEM images indicate that the catalyst sample has a rutile IrO 2 single crystal nanorod structure.The onset potential for oxygen reduction reaction (ORR) of the SC-IrO 2 NR-carbon hybrid catalyst specimen is 0.75 V (vs.RHE) in RDE measurement.CV and RDE test results show that the SC-IrO 2 NR-carbon hybrid catalyst has a better electrochemical stability in comparison with the commercial Pt/C catalyst,with attenuation ratios of 17.67% and 44.60% for the SC-IrO 2 NR-carbon hybrid catalyst and the commercial Pt/C catalyst after 1500 cycles,respectively.Therefore,in terms of stability,the SC-IrO 2 NR-carbon hybrid catalyst has a promising potential in the application of the proton exchange membrane fuel cell. 展开更多
关键词 single crystal nanorods IrO 2 electrochemical stability oxygen reduction reaction
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Fabrication of hybrid Co_3O_4/NiCo_2O_4 nanosheets sandwiched by nanoneedles for high-performance supercapacitors using a novel electrochemical ion exchange
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作者 郝加新 彭尚龙 +7 位作者 秦天锋 王子磊 温昱祥 贺德衍 张加驰 张稚雅 范晓彦 曹国忠 《Science China Materials》 SCIE EI CSCD 2017年第12期1168-1178,共11页
Electrochemical ion exchange has been used to tailor the composition of transition metal oxides (Co3O4) electrode with enhanced capacity while maintaining its crystal structure and morphology. Specifically, Ni ions ... Electrochemical ion exchange has been used to tailor the composition of transition metal oxides (Co3O4) electrode with enhanced capacity while maintaining its crystal structure and morphology. Specifically, Ni ions were incorporated to C03O4 nanosheets sandwiched by nanoneedles to form Co3O4/NiCo2O4 composite. As positive electrode for supercapacitors, the Co3O4/NiCo2O4 composite presents a high areal capacitance of 3.2 F cm^-2 (1060 F g^-1) at a current density of 5 mA cm^-2 and outstanding rate capability as well as long cycle stability. Moreover, the assembled aqueous asymmetric supercapacitor based on Co3O4/NiCo2O4//carbon cloth electrodes delivers a considerable energy density of 3.0 mW hcm^-3 at power density of 136 mW cm^-3, and high rate capability (85% retention at a current density of 30 mA cm^-2). A safety light composed of ten green LEDs in parallel was lit for -360 s using two identical supercapacitors in series, indicating a promising practical application. 展开更多
关键词 electrochemical ion exchange cobalt oxide nickel cobalt oxide asymmetric supercapacitors
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