Using low-cost FePO4·2H2O as iron source,Na2FePO4F/C composite is prepared by alcohol-assisted ball milling and solid-state reaction method.The XRD pattern of Na2FePO4F/C composite demonstrates sharp peaks,indica...Using low-cost FePO4·2H2O as iron source,Na2FePO4F/C composite is prepared by alcohol-assisted ball milling and solid-state reaction method.The XRD pattern of Na2FePO4F/C composite demonstrates sharp peaks,indicating high crystalline and phase purity.The SEM and TEM images reveal that diameter of the spherical-like Na2FePO4F/C particles ranges from 50 to 300 nm,and HRTEM image shows that the surface of Na2FePO4F/C composite is uniformly coated by carbon layer with a average thickness of about 3.6 nm.The carbon coating constrains the growth of the particles and effectively reduces the agglomeration of nanoparticles.Using lithium metal as anode,the composite delivers a discharge capacities of 102.8,96.4 and 90.3 mA·h/g at rates of 0.5C,1C and 2C,respectively.After 100 cycles at 0.5C,a discharge capacity of 98.9 mA·h/g is maintained with capacity retention of 96.2%.The Li+diffusion coefficient(D)of Na2FePO4F/C composite is calculated as 1.71×10^–9 cm^2/s.This study reveals that the simple solid state reaction could be a practical and effective synthetic route for the industrial production of Na2FePO4F/C material.展开更多
This study investigated the promotion effect of A.ferrooxidans on complex heavy metals coprecipitation process.A.ferrooxidans significantly enhanced the ferrous oxidation,which also promoted the formation of iron-oxyh...This study investigated the promotion effect of A.ferrooxidans on complex heavy metals coprecipitation process.A.ferrooxidans significantly enhanced the ferrous oxidation,which also promoted the formation of iron-oxyhydroxysulphate.Cu(II)concentration reduced to0.058mmol/L in A.ferrooxidans inoculated system,and Cd also reduced to the lowest concentration(0.085mmol/L).Pb was mainly immobilized as anglesite and iron-oxyhydroxysulphate promoted the removal of remanent Pb in solution.The precipitates are characterized by XRD,SEM,and FTIR analysis.The main component of the iron-oxyhydroxysulphate was well crystallized jarosite.A.ferrooxidans contributed to the formation of schwertmannite in later monovalent cation lack stage.Higher ferrous iron oxidation rate and Fe(III)supply rate in A.ferrooxidans inoculated system facilitated polyhedron crystal formation and the increase of particle diameter.Complex heavy metals could be incorporated into iron oxyhydroxysulphate crystal,and efficiently removed from acidic wastewater through A.ferrooxidans mediated coprecipitation.展开更多
基金Projects(51472211,51502256)supported by the National Natural Science Foundation of ChinaProjects(2016GK4005,2016GK4030)supported by the Strategic New Industry of Hunan Province,ChinaProject(13C925)supported by the Research Foundation of Education Bureau of Hunan Province,China
文摘Using low-cost FePO4·2H2O as iron source,Na2FePO4F/C composite is prepared by alcohol-assisted ball milling and solid-state reaction method.The XRD pattern of Na2FePO4F/C composite demonstrates sharp peaks,indicating high crystalline and phase purity.The SEM and TEM images reveal that diameter of the spherical-like Na2FePO4F/C particles ranges from 50 to 300 nm,and HRTEM image shows that the surface of Na2FePO4F/C composite is uniformly coated by carbon layer with a average thickness of about 3.6 nm.The carbon coating constrains the growth of the particles and effectively reduces the agglomeration of nanoparticles.Using lithium metal as anode,the composite delivers a discharge capacities of 102.8,96.4 and 90.3 mA·h/g at rates of 0.5C,1C and 2C,respectively.After 100 cycles at 0.5C,a discharge capacity of 98.9 mA·h/g is maintained with capacity retention of 96.2%.The Li+diffusion coefficient(D)of Na2FePO4F/C composite is calculated as 1.71×10^–9 cm^2/s.This study reveals that the simple solid state reaction could be a practical and effective synthetic route for the industrial production of Na2FePO4F/C material.
基金Project(51174239)supported by the National Natural Science Foundation of ChinaProject supported by the Shanghai Tongji Gao Tingyao Environment Protection Science&Technology Development Foundation,China+2 种基金Project supported by the Hunan Provincial Co-Innovation Center for Clean and Efficient Utilization of Strategic Metal Mineral Resources,ChinaProject(2017M610506)supported by Postdoctoral Foundation for MG from Chinese PD Science Foundation,ChinaProject(185690)supported by PD Research Funding Plan in Hunan and Central South University,China
文摘This study investigated the promotion effect of A.ferrooxidans on complex heavy metals coprecipitation process.A.ferrooxidans significantly enhanced the ferrous oxidation,which also promoted the formation of iron-oxyhydroxysulphate.Cu(II)concentration reduced to0.058mmol/L in A.ferrooxidans inoculated system,and Cd also reduced to the lowest concentration(0.085mmol/L).Pb was mainly immobilized as anglesite and iron-oxyhydroxysulphate promoted the removal of remanent Pb in solution.The precipitates are characterized by XRD,SEM,and FTIR analysis.The main component of the iron-oxyhydroxysulphate was well crystallized jarosite.A.ferrooxidans contributed to the formation of schwertmannite in later monovalent cation lack stage.Higher ferrous iron oxidation rate and Fe(III)supply rate in A.ferrooxidans inoculated system facilitated polyhedron crystal formation and the increase of particle diameter.Complex heavy metals could be incorporated into iron oxyhydroxysulphate crystal,and efficiently removed from acidic wastewater through A.ferrooxidans mediated coprecipitation.
