10%(volume fraction) SiCp/Al-Mg composites with different Mg contents were successfully fabricated by semi-solid mechanical stirring technique under optimum processing conditions.Effects of Mg content on microstructur...10%(volume fraction) SiCp/Al-Mg composites with different Mg contents were successfully fabricated by semi-solid mechanical stirring technique under optimum processing conditions.Effects of Mg content on microstructure and mechanical properties were studied by scanning electron microscopy(SEM),X-ray diffractometry(XRD) and transmission electron microscopy(TEM).The results indicate that SiC particles disperse homogeneously in Al-Mg matrix and interfacial reaction between Al matrix and SiC particles is effectively controlled.Distribution of SiCp reinforcement and interfacial bonding are improved by adding Mg.Additionally,the mechanical properties of composites are remarkably improved with the Mg content increasing.展开更多
In this work, a facile method was adopted to synthesize molybdenum disulfide/reduced graphene oxide （MoS2/rGO） composites through an c-cysteine-assisted hydrothermal technique, The as-prepared MoS2/ rGO composites w...In this work, a facile method was adopted to synthesize molybdenum disulfide/reduced graphene oxide （MoS2/rGO） composites through an c-cysteine-assisted hydrothermal technique, The as-prepared MoS2/ rGO composites were firstly applied as adsorbents for efficient elimination of Pb（Ⅱ） ions. Batch adsorption experiments showed that the adsorption of Pb（Ⅱ） on MoS2/rGO followed pseudo-second-order kinetic model well. The adsorption of Pb（Ⅱ） was intensely pH-dependent, ionic strength-dependent at pH 〈 9.0 and ionic strength-independent at pH 〉 9,0, The presence of humic acid （HA） enhanced Pb（Ⅱ） adsorption obviously. The MoS2/rGO composites exhibited excellent adsorption capacity of 384.16 mg g 1 at pH 5.0 and T = 298.15 K, which was superior to MOS2 （279.93 mg g 1） and many other adsorbents. The thermodynamic parameters suggested that the adsorption process of Pb（Ⅱ） on MoS2/rGO composites was spontaneous （zSG＂ 〈 O） and endothermic （△H 〉 0）. The interaction of Pb（Ⅱ） and MoS2] rGO was mainly dominated by electrostatic attraction and surface comple^ation between Pb（Ⅱ） and oxygen-containing functional groups of MoS2]rGO. This work highlighted the application of MoS21rGO as novel and promising materials in the efficient elimination of Pb（Ⅱ） from contaminated water and industrial effluents in environmental pollution management.展开更多
Soft magnetic composite with micro-cellular structure was prepared by spark plasma sintering(SPS) process with Fe73.5Cu1Nb3Si13.5B9 micron-powders clad by 5wt% Zn0.5Ni0.5Fe2O4 nano-particles.The effect of SPS on the m...Soft magnetic composite with micro-cellular structure was prepared by spark plasma sintering(SPS) process with Fe73.5Cu1Nb3Si13.5B9 micron-powders clad by 5wt% Zn0.5Ni0.5Fe2O4 nano-particles.The effect of SPS on the micro structure of the Finemet powder and the micro structure of the composite were studied.It has been found that the as-prepared composite consists of Fe73.5Cu1Nb3Si13.5B9 cells and the cell-wall composed of nano Zn0.5Ni0.5Fe2O4 particles distributing around Fe73.5Cu1Nb3Si13.5B9 cell-body.The composite exhibits low eddy-current loss which is to be resulted by high resistivity of the Zn0.5Ni0.5Fe2O4 cell-wall.The sintered samples were annealed at different temperature and the magnetic properties at different frequency of the annealed samples were measured.It shows that the Zn0.5Ni0.5Fe2O4 cell-wall possesses good thermostability.展开更多
基金Project(2006CB605203-3) supported by the National Basic Research Program of China
文摘10%(volume fraction) SiCp/Al-Mg composites with different Mg contents were successfully fabricated by semi-solid mechanical stirring technique under optimum processing conditions.Effects of Mg content on microstructure and mechanical properties were studied by scanning electron microscopy(SEM),X-ray diffractometry(XRD) and transmission electron microscopy(TEM).The results indicate that SiC particles disperse homogeneously in Al-Mg matrix and interfacial reaction between Al matrix and SiC particles is effectively controlled.Distribution of SiCp reinforcement and interfacial bonding are improved by adding Mg.Additionally,the mechanical properties of composites are remarkably improved with the Mg content increasing.
基金supported by Science Challenge Project (JCKY2016212A04)the National Natural Science Fondation of China(91326202,21577032,and 21403064)+1 种基金the Fundamental Research Funds for the Central Universities(JB2015001)the National Special Water Programs(2015ZX07203-011,2015ZX07204-007)
文摘In this work, a facile method was adopted to synthesize molybdenum disulfide/reduced graphene oxide （MoS2/rGO） composites through an c-cysteine-assisted hydrothermal technique, The as-prepared MoS2/ rGO composites were firstly applied as adsorbents for efficient elimination of Pb（Ⅱ） ions. Batch adsorption experiments showed that the adsorption of Pb（Ⅱ） on MoS2/rGO followed pseudo-second-order kinetic model well. The adsorption of Pb（Ⅱ） was intensely pH-dependent, ionic strength-dependent at pH 〈 9.0 and ionic strength-independent at pH 〉 9,0, The presence of humic acid （HA） enhanced Pb（Ⅱ） adsorption obviously. The MoS2/rGO composites exhibited excellent adsorption capacity of 384.16 mg g 1 at pH 5.0 and T = 298.15 K, which was superior to MOS2 （279.93 mg g 1） and many other adsorbents. The thermodynamic parameters suggested that the adsorption process of Pb（Ⅱ） on MoS2/rGO composites was spontaneous （zSG＂ 〈 O） and endothermic （△H 〉 0）. The interaction of Pb（Ⅱ） and MoS2] rGO was mainly dominated by electrostatic attraction and surface comple^ation between Pb（Ⅱ） and oxygen-containing functional groups of MoS2]rGO. This work highlighted the application of MoS21rGO as novel and promising materials in the efficient elimination of Pb（Ⅱ） from contaminated water and industrial effluents in environmental pollution management.
基金supported by the National Natural Science Foundations of China (Grant Nos. 50771023 and 51071034)
文摘Soft magnetic composite with micro-cellular structure was prepared by spark plasma sintering(SPS) process with Fe73.5Cu1Nb3Si13.5B9 micron-powders clad by 5wt% Zn0.5Ni0.5Fe2O4 nano-particles.The effect of SPS on the micro structure of the Finemet powder and the micro structure of the composite were studied.It has been found that the as-prepared composite consists of Fe73.5Cu1Nb3Si13.5B9 cells and the cell-wall composed of nano Zn0.5Ni0.5Fe2O4 particles distributing around Fe73.5Cu1Nb3Si13.5B9 cell-body.The composite exhibits low eddy-current loss which is to be resulted by high resistivity of the Zn0.5Ni0.5Fe2O4 cell-wall.The sintered samples were annealed at different temperature and the magnetic properties at different frequency of the annealed samples were measured.It shows that the Zn0.5Ni0.5Fe2O4 cell-wall possesses good thermostability.
