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金属胶束催化:单核配合物催化α-吡啶甲酸对硝基苯酚酯水解反应动力学 被引量:1
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作者 蒋维东 向庆华 +2 位作者 蒋炳英 相艳 曾宪诚 《四川大学学报(自然科学版)》 CAS CSCD 北大核心 2003年第4期732-735,共4页
实验合成了单核配合物4 氯 2,6 二(N 羟已基氨基甲基)苯酚合铜,研究了不同pH条件下在不同的3种表面活性剂(CTAB,LSS,Brij35)所生成的胶束溶液中催化PNPP水解的动力学 结果表明,阳离子表面活性剂(CTAB)加快了PNPP的水解,两性离子表面活性... 实验合成了单核配合物4 氯 2,6 二(N 羟已基氨基甲基)苯酚合铜,研究了不同pH条件下在不同的3种表面活性剂(CTAB,LSS,Brij35)所生成的胶束溶液中催化PNPP水解的动力学 结果表明,阳离子表面活性剂(CTAB)加快了PNPP的水解,两性离子表面活性剂(LSS)对反应先催化后抑制,而非离子表面活性剂(Brij35)则抑制了反应的进行 用三元复合物模型进行动力学处理。 展开更多
关键词 单核配合物 表面活性剂 PNPP的水解 三元复合动力学模型
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两种长链吡啶类金属配合物催化PNPP和PNPA水解的动力学研究 被引量:1
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作者 杜娟 曾宪诚 李慎新 《四川大学学报(自然科学版)》 CAS CSCD 北大核心 2002年第5期904-908,共5页
用分光光度法研究了一种长链取代吡啶类配体 (L)及其铜 (II)和锌 (II)的配合物在2 5℃及 pH 6 .5~ 8.5的条件下 ,在CTAB胶束缓冲溶液中催化PNPP和PNPA水解的反应 .结果表明 ,活化的配体羟基可以作为反应过程中有效的亲核物种 ,锌 (II)... 用分光光度法研究了一种长链取代吡啶类配体 (L)及其铜 (II)和锌 (II)的配合物在2 5℃及 pH 6 .5~ 8.5的条件下 ,在CTAB胶束缓冲溶液中催化PNPP和PNPA水解的反应 .结果表明 ,活化的配体羟基可以作为反应过程中有效的亲核物种 ,锌 (II)配合物比铜 (II)配合物能更有效地催化PNPP的水解 ,这种情况可以解释为锌 (II)配合物中活化的配体羟基具有更强的亲核进攻能力 .作者推导了包括配体、金属离子和底物在内的金属配合物催化PNPP水解的三元复合物动力学模型 ,提出了金属配合物催化PNPA水解的双分子催化动力学模型 ,并得到了相应的热力学及动力学参数 。 展开更多
关键词 长链吡啶类金属配合物 PNPP PNPA 水解动力学 三元复合动力学模型 双分子催化动力学模型 水解机理 羧酸酯
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全生物基三元DES预处理促进芦竹酶解机理研究 被引量:1
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作者 李海潮 罗宇欣 +3 位作者 苗国华 李文静 游婷婷 许凤 《中国造纸学报》 CAS CSCD 北大核心 2022年第4期31-38,共8页
针对二元中性低共熔溶剂(DES)体系效率低的问题,构建新型全生物基三元DES(氯化胆碱/乙酰丙酸/1,4-丁二醇)体系,并用于芦竹(Arundo donax L.)预处理;采用成分分析、扫描电子显微镜(SEM)、X射线衍射仪(XRD)、傅里叶变换红外光谱仪(FT-IR)... 针对二元中性低共熔溶剂(DES)体系效率低的问题,构建新型全生物基三元DES(氯化胆碱/乙酰丙酸/1,4-丁二醇)体系,并用于芦竹(Arundo donax L.)预处理;采用成分分析、扫描电子显微镜(SEM)、X射线衍射仪(XRD)、傅里叶变换红外光谱仪(FT-IR)对预处理前后芦竹化学成分、结构及表面形貌变化等进行分析,结合复合动力学模型探究预处理促进芦竹酶解机理。结果表明,三元DES是高效的预处理体系,在140℃下处理3 h后,木质素和半纤维素的脱除率分别达46.4%和75.6%,残渣纤维素和聚木糖酶解率高达~100%和96.6%;建立的复合动力学模型可准确地描述三元DES预处理耦合酶解过程中葡萄糖和木糖变化行为(R2>0.99)。由预处理温度升高引起的半纤维素和木质素高效脱除、纤维表面粗糙度增大及纤维素结晶结构破坏是促进芦竹酶解的主要原因。 展开更多
关键词 芦竹 三元DES 预处理 酶水解 复合动力学模型
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Research on an inertial piezoelectric actuator for a micro in-pipe robot 被引量:1
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作者 杨志欣 孙宝元 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2006年第4期473-476,共4页
A new kind of inertial piezoelectric actuator for a micro in-pipe robot is proposed and studied. The actuator is composed of a body, corresponding to a mass rod, and four elastic legs. Each leg is a composite piezoele... A new kind of inertial piezoelectric actuator for a micro in-pipe robot is proposed and studied. The actuator is composed of a body, corresponding to a mass rod, and four elastic legs. Each leg is a composite piezoelectric bimorph beam, made up of a middle metal element, an upper and lower piezoelectric elements. The mechanism is driven by an asymmetric waveform voltage, such as saw-toothed waveform, and utilizes the dynamic relationship between the maximum static friction force and the inertial force. To study the actuator, firstly, the constituent equation of a composite piezoelectric bimorph under both applied voltage and external force was inferred by thermodynamics. Secondly, the dvnamic model of the actuator was established analyzing the relationship between the locomotive states, viz. displacement and velocity, and design parameters, such as piezoelectric strain constant, elastic modulus,length, width and thickness of the piezoelectric element, actuator mass, and driving vohage. At last, the dynamic equation was solved and the theoretical calculation of the inherent frequency was more consistent with the experimental data, which proved the rationality of the model. All these lay a theoretical foundation of the micro actuator parameter optimization and more research on a micro robot. 展开更多
关键词 micro actuator composite piezoelectric bimorph dynamic model
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Dynamic analytic model of mechanism with links fabricated from symmetric laminates
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作者 蔡敢为 常平平 +2 位作者 马存志 王汝贵 李兆军 《Journal of Central South University of Technology》 EI 2006年第6期624-630,共7页
A four-bar linkage mechanism with links fabricated from symmetric laminates was studied. The mass matrix of the beam dement was obtained in light of the mass distribution characteristics of composite materials. The st... A four-bar linkage mechanism with links fabricated from symmetric laminates was studied. The mass matrix of the beam dement was obtained in light of the mass distribution characteristics of composite materials. The stiffness matrix of the beam element was derived from the constitutive equations of each layer and the relationship between the strain distribution and the node displacement of the beam element. The specific damping capacity of the beam element was analyzed according to the strain distribution of the beam element and the strain energy dissipation caused by vibration in each direction of each layer; and the damping coefficients were obtained according to the principle that the total energy dissipation of the beam element was equal to the work done by the equivalent damping force during a cycle of vibration, from which the damping matrix of the dynamic equations was obtained. Using the finite element method, the dynamic analytic model of the mechanism was obtained. The dynamic responses and natural frequency of the mechanism were obtained by simulation, respectively, and those of the simulation obtained by the proposed model were analyzed and compared with the results obtained by the conventional model. The work provides theoretical basis to a certain extent for the further research on nonlinear vibration characteristics and optimum design of this kind of mechanism. 展开更多
关键词 linkage mechanism finite element method composite materials DAMPING dynamic analysis
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A Novel Method for the Fabrication of Granular Hydroxyapatite-bentonite Composite Adsorbents for the Removal of Pb2+ from an Aqueous Solution
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作者 ThiMinh Hieu Do Pham ThanhThao Tran AnhKhoaTon Minh Vien Le 《Journal of Environmental Science and Engineering(B)》 2016年第7期371-378,共8页
Granular HApB composite adsorbents, with dimensions of 4 mm × 4 mm, were prepared for the removal of lead from an aqueous solution. The effectiveness of the composites for Pb2+ removal from an aqueous solution w... Granular HApB composite adsorbents, with dimensions of 4 mm × 4 mm, were prepared for the removal of lead from an aqueous solution. The effectiveness of the composites for Pb2+ removal from an aqueous solution with different initial concentrations, adsorbent doses and reaction times were examined. The Langmuir isotherms, Freundlich isotherm models and pseudo-second order kinetic model were used in this analysis. It was found that the Langmuir model fitted the experimental data better than the Freundlich model, with a maximum adsorption capacity of 93.37 mg.g-1. The pseudo-second order kinetic model also fit the experiment data well with an adsorption capacity of 70.73 mg.g-1 after being reused for 3 times. Furthermore, the composites may possibly be used in processes for industrial water treatment. 展开更多
关键词 Environment AFFORESTATION poplar plantations timber marketing.
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