A gelatin/MMT nanocomposite was prepared in an aqueous solution and investigated by XRD,FTIR and 13 C NMR,and then the intercalation mechanism was discussed.The result of XRD indicated that the gelatin molecule...A gelatin/MMT nanocomposite was prepared in an aqueous solution and investigated by XRD,FTIR and 13 C NMR,and then the intercalation mechanism was discussed.The result of XRD indicated that the gelatin molecule had already inserted into the interlayer of MMT,and the intercalation or exfoliation structure had been achieved.The result of 13 C NMR demonstrated that the ions interaction between gelatin and MMT was attributed to the driving force for intercalation.In order to confirm the role of -COO - of gelatin in the combination with MMT,lauric sodium was brought in as a model to react with MMT,and was characterized by XRD and FTIR,the result proved that there existed a kind of strong interaction between -COO - and ions of MMT.展开更多
In order to investigate the effect o f some factors on the unconfined compressive strength(UCS)for composite soil stabilizer-stabilized gravel soil(CSSSGS),the orthogonal test is adopted to set up the experimental sch...In order to investigate the effect o f some factors on the unconfined compressive strength(UCS)for composite soil stabilizer-stabilized gravel soil(CSSSGS),the orthogonal test is adopted to set up the experimental scheme.Three levels o f each factor armconsidered to obtain the change laws o f UCS,in which the binder dosages are8%,10%,and12%;the curing times ae7,14and21d;the gradation nae0.3,0.35and0.4;and the degrees of compaction are95%,97%,and99%.The range analysis clearly indicates that the influence degree o f the four factors on UCS is in such an order:dosage,age,gradation,and degree o f compaction.The variance analysis shows that only the composite soil stabilizer dosage can significantly affect UCS.In road construction,the examination o f composite soil stabilizer dosage and base-course maintenance should be given much more attention to obtain satisfactory base-course strength,compared w ith gradation floating and the change of degree o f compaction.展开更多
In order to improve the properties of HDPE, the authors used the method of suspended diffusion for purification the pelagic clay, used silane coupling agent to increase its organic activation, and prepared the composi...In order to improve the properties of HDPE, the authors used the method of suspended diffusion for purification the pelagic clay, used silane coupling agent to increase its organic activation, and prepared the composites of organic pelagic clay/HDPE by inching them in different conditions. The affections of process conditions and quantity of pelagic clay to the properties of composites were analyzed by testing their mechanical properties, thermo stability and barrier properties. According to test the structure of composites, it is indicated that pelagic clay has good compatibility with HDPE. The result shows that the pelagic clay can improve mechanical properties, thermo stability and barrier properties of HDPE properties effectively.展开更多
文摘A gelatin/MMT nanocomposite was prepared in an aqueous solution and investigated by XRD,FTIR and 13 C NMR,and then the intercalation mechanism was discussed.The result of XRD indicated that the gelatin molecule had already inserted into the interlayer of MMT,and the intercalation or exfoliation structure had been achieved.The result of 13 C NMR demonstrated that the ions interaction between gelatin and MMT was attributed to the driving force for intercalation.In order to confirm the role of -COO - of gelatin in the combination with MMT,lauric sodium was brought in as a model to react with MMT,and was characterized by XRD and FTIR,the result proved that there existed a kind of strong interaction between -COO - and ions of MMT.
基金The National Natural Science Foundation of China(No.51108081)
文摘In order to investigate the effect o f some factors on the unconfined compressive strength(UCS)for composite soil stabilizer-stabilized gravel soil(CSSSGS),the orthogonal test is adopted to set up the experimental scheme.Three levels o f each factor armconsidered to obtain the change laws o f UCS,in which the binder dosages are8%,10%,and12%;the curing times ae7,14and21d;the gradation nae0.3,0.35and0.4;and the degrees of compaction are95%,97%,and99%.The range analysis clearly indicates that the influence degree o f the four factors on UCS is in such an order:dosage,age,gradation,and degree o f compaction.The variance analysis shows that only the composite soil stabilizer dosage can significantly affect UCS.In road construction,the examination o f composite soil stabilizer dosage and base-course maintenance should be given much more attention to obtain satisfactory base-course strength,compared w ith gradation floating and the change of degree o f compaction.
文摘In order to improve the properties of HDPE, the authors used the method of suspended diffusion for purification the pelagic clay, used silane coupling agent to increase its organic activation, and prepared the composites of organic pelagic clay/HDPE by inching them in different conditions. The affections of process conditions and quantity of pelagic clay to the properties of composites were analyzed by testing their mechanical properties, thermo stability and barrier properties. According to test the structure of composites, it is indicated that pelagic clay has good compatibility with HDPE. The result shows that the pelagic clay can improve mechanical properties, thermo stability and barrier properties of HDPE properties effectively.
