Dynamitron DC1500/25/04 type EBA (Electron beam accelerator), model JOB 188, was manufactured by IBA Industrial (Radiation Dynamics, Inc.) and installed at IPEN-CNEN/SP, in 1978. The technical specifications of th...Dynamitron DC1500/25/04 type EBA (Electron beam accelerator), model JOB 188, was manufactured by IBA Industrial (Radiation Dynamics, Inc.) and installed at IPEN-CNEN/SP, in 1978. The technical specifications of the EBA are: energy 0.5 to 1.5 MeV; beam current: 0.3 to 25.0 mA; beam scanning: 60 to 120 cm; beam width: 25.4 mm and frequency: 100 Hz. Nowadays, this accelerator has been used for innumerable applications, such as: For sterilization of medical, pharmaceutical and biological products, treatment of industrial and domestic effluents and sludge, preservation and disinfestations of foods and agricultural products. Other important application are lignocellulosic material irradiation as a pre-treatment to produce ethanol bio-fuel, decontamination of pesticide packing, solid residues remediation, organic compounds removal from wastewater, treatment of effluent from petroleum production units, crosslinking of foams, wires and electric cables. Electron accelerator JOB 188 is, also, very important composite and nanocomposite materials and carbon fibers irradiation, irradiated grafting ion-exchange membranes for fuel cells application, natural polymers and multilayer packages irradiation and biodegradable blends production. The energy of the electron beam is calculated as a function of the current in the accelerator high-voltage divisor, taking into account the thickness and density of the material to be irradiated. This energy is calculated considering the electron through the entire material and the distance from the titanium foil window, so that the absorbed doses at the points of entrance and exit are equivalent on the material. The dose is directly proportional to the beam current and the exposure time of the material under the electron beam and inversely proportional to the scan width. The aim of this paper is to analyze the power system parameters of the EBA Dynamitron DC 1500/25/04, such as, voltage and RMS (Root-mean-square) current in the oscillator system, high voltage generator and waveform. For this purpose software developed in the Radiation Technology Center at IPEN/CNEN-SP to simulate the energy efficiency of this industrial accelerator. Finally, it is also targeted to compare theoretical dosimetry using parameters of energy and beam current with data from the accelerator power system. This knowledge and technology will be very useful and essential for the control system upgrade of EBA, mainly Dynamitron DC 1500/25/04 taking into consideration that radiation processing technology for industrial and environmental applications has been developed and used worldwide.展开更多
In order to bring graphene materials much closer to real world applications, it is imperative to have simple, efficient and eco-friendly ways to produce processable graphene derivatives. In this study, a hydrophilic l...In order to bring graphene materials much closer to real world applications, it is imperative to have simple, efficient and eco-friendly ways to produce processable graphene derivatives. In this study, a hydrophilic low-temperature thermally functionalized graphene and its super-hydrophobic organically modified graphene derivative were fabricated. A unique structural topology was found and some of the oxygen functionalities were retained on the thermally functionalized graphene surfaces, which facilitated the subsequent highly effective organic modification reaction and led to the super-hydrophobic organically modified graphene with multi functional applications in liquid marbles and polymer nanocomposites. The organic modification reaction also restored the graphenic conjugated structure of the thermally functionalized graphene, particularly for organic modifiers having longer alkyl chains, as confirmed by various characteri- zation techniques such as electrical conductivity measurements, ultraviolet/visible spectroscopy and selected area electron diffraction. The free-standing soft liquid marble was fabricated by wrapping a water droplet with the super-hydrophobic organically modified graphene, and showed potential for use as a microreactor. As for the polymer nanocomposites, a strong interfacial adhesion is believed to exist between an organic polymer matrix and the modified graphene because of the organophilic coating formed on the graphene base, which resulted in large improvements in the thermal and mechanical properties of the polymer nanocomposites with the modified graphene, even at very low loading levels. A new avenue has therefore been opened up for large-scale production of processable graphene derivatives with various practicable applications.展开更多
This paper presented a numerical approach to solving the problem of a flat-ended punch in contact with a half-space matrix embedded with multiple three dimensional arbitrary-shaped inhomogeneities.Based on the semi-an...This paper presented a numerical approach to solving the problem of a flat-ended punch in contact with a half-space matrix embedded with multiple three dimensional arbitrary-shaped inhomogeneities.Based on the semi-analytical method(SAM)and the equivalent inclusion method,numerical procedures were developed and the effects of inclusion shape and distribution were analyzed.Fast Fourier transform technique was implemented to accelerate the calculation of surface deformation and subsurface stress.Interactions of inter-inclusions and inclusion-matrix were taken into account.Numerical results showed the presence of inhomogeneities(i.e.,microstructures in solids)indeed had a great effect on local contact pressure and a strong disturbance to the subsurface stress field in the vicinity of inclusions.The effects were dependent on the shape and distribution of inclusions and inter-inclusion interactions.The physical significance of this study is to provide an insight into the relation between the material microstructure and its response to the external load,and the solution approach and procedures may find useful applications,for example,the analysis of fatigue and crack propagation for composite materials,prediction of stress field in solids containing material defects,and study of the mechanism of chemical-mechanical polish(CMP)for inhomogeneous materials,etc.展开更多
Periodic composites with band gaps that prevent the propagation of elastic waves in certain frequency ranges can be used to control waves for a variety of engineering applications. Although studies on the characterist...Periodic composites with band gaps that prevent the propagation of elastic waves in certain frequency ranges can be used to control waves for a variety of engineering applications. Although studies on the characteristics of these materials, which are called phononic crystals (PCs), have yielded a large number of positive results in recent years, there is still a lack of effective design methods. In this work, a multi-objective optimization approach based on the band gap mechanism and an intelligent algorithm is used to design a one-dimensional (1D) slab construction of PCs. The design aims to fit pre-determined bands by arranging the available materials properly. Obtained by analyzing the wave transmission in periodic layers, the objective functions are linked to the optimization program to obtain a proper solution set. The results of the numerical simulations demonstrate that without constructing complicated structures, the design method is able to produce PCs that overcome the limitations of two-component PCs and hence can feasibly and effectively achieve the design targets. The design approach presented in this paper can be extended to two-or three-dimensional systems and has great potential for the development of sound/ultrasound isolation structures, multiple band frequency filters, and other applications.展开更多
文摘Dynamitron DC1500/25/04 type EBA (Electron beam accelerator), model JOB 188, was manufactured by IBA Industrial (Radiation Dynamics, Inc.) and installed at IPEN-CNEN/SP, in 1978. The technical specifications of the EBA are: energy 0.5 to 1.5 MeV; beam current: 0.3 to 25.0 mA; beam scanning: 60 to 120 cm; beam width: 25.4 mm and frequency: 100 Hz. Nowadays, this accelerator has been used for innumerable applications, such as: For sterilization of medical, pharmaceutical and biological products, treatment of industrial and domestic effluents and sludge, preservation and disinfestations of foods and agricultural products. Other important application are lignocellulosic material irradiation as a pre-treatment to produce ethanol bio-fuel, decontamination of pesticide packing, solid residues remediation, organic compounds removal from wastewater, treatment of effluent from petroleum production units, crosslinking of foams, wires and electric cables. Electron accelerator JOB 188 is, also, very important composite and nanocomposite materials and carbon fibers irradiation, irradiated grafting ion-exchange membranes for fuel cells application, natural polymers and multilayer packages irradiation and biodegradable blends production. The energy of the electron beam is calculated as a function of the current in the accelerator high-voltage divisor, taking into account the thickness and density of the material to be irradiated. This energy is calculated considering the electron through the entire material and the distance from the titanium foil window, so that the absorbed doses at the points of entrance and exit are equivalent on the material. The dose is directly proportional to the beam current and the exposure time of the material under the electron beam and inversely proportional to the scan width. The aim of this paper is to analyze the power system parameters of the EBA Dynamitron DC 1500/25/04, such as, voltage and RMS (Root-mean-square) current in the oscillator system, high voltage generator and waveform. For this purpose software developed in the Radiation Technology Center at IPEN/CNEN-SP to simulate the energy efficiency of this industrial accelerator. Finally, it is also targeted to compare theoretical dosimetry using parameters of energy and beam current with data from the accelerator power system. This knowledge and technology will be very useful and essential for the control system upgrade of EBA, mainly Dynamitron DC 1500/25/04 taking into consideration that radiation processing technology for industrial and environmental applications has been developed and used worldwide.
文摘In order to bring graphene materials much closer to real world applications, it is imperative to have simple, efficient and eco-friendly ways to produce processable graphene derivatives. In this study, a hydrophilic low-temperature thermally functionalized graphene and its super-hydrophobic organically modified graphene derivative were fabricated. A unique structural topology was found and some of the oxygen functionalities were retained on the thermally functionalized graphene surfaces, which facilitated the subsequent highly effective organic modification reaction and led to the super-hydrophobic organically modified graphene with multi functional applications in liquid marbles and polymer nanocomposites. The organic modification reaction also restored the graphenic conjugated structure of the thermally functionalized graphene, particularly for organic modifiers having longer alkyl chains, as confirmed by various characteri- zation techniques such as electrical conductivity measurements, ultraviolet/visible spectroscopy and selected area electron diffraction. The free-standing soft liquid marble was fabricated by wrapping a water droplet with the super-hydrophobic organically modified graphene, and showed potential for use as a microreactor. As for the polymer nanocomposites, a strong interfacial adhesion is believed to exist between an organic polymer matrix and the modified graphene because of the organophilic coating formed on the graphene base, which resulted in large improvements in the thermal and mechanical properties of the polymer nanocomposites with the modified graphene, even at very low loading levels. A new avenue has therefore been opened up for large-scale production of processable graphene derivatives with various practicable applications.
基金supported by the National Basic Research Program of China(Grant Nos.2009CB724200,2011CB013404 and 2011CB706602)
文摘This paper presented a numerical approach to solving the problem of a flat-ended punch in contact with a half-space matrix embedded with multiple three dimensional arbitrary-shaped inhomogeneities.Based on the semi-analytical method(SAM)and the equivalent inclusion method,numerical procedures were developed and the effects of inclusion shape and distribution were analyzed.Fast Fourier transform technique was implemented to accelerate the calculation of surface deformation and subsurface stress.Interactions of inter-inclusions and inclusion-matrix were taken into account.Numerical results showed the presence of inhomogeneities(i.e.,microstructures in solids)indeed had a great effect on local contact pressure and a strong disturbance to the subsurface stress field in the vicinity of inclusions.The effects were dependent on the shape and distribution of inclusions and inter-inclusion interactions.The physical significance of this study is to provide an insight into the relation between the material microstructure and its response to the external load,and the solution approach and procedures may find useful applications,for example,the analysis of fatigue and crack propagation for composite materials,prediction of stress field in solids containing material defects,and study of the mechanism of chemical-mechanical polish(CMP)for inhomogeneous materials,etc.
基金supported by the National Natural Science Foundation of China(Grant Nos. 51179171 and 51079127)
文摘Periodic composites with band gaps that prevent the propagation of elastic waves in certain frequency ranges can be used to control waves for a variety of engineering applications. Although studies on the characteristics of these materials, which are called phononic crystals (PCs), have yielded a large number of positive results in recent years, there is still a lack of effective design methods. In this work, a multi-objective optimization approach based on the band gap mechanism and an intelligent algorithm is used to design a one-dimensional (1D) slab construction of PCs. The design aims to fit pre-determined bands by arranging the available materials properly. Obtained by analyzing the wave transmission in periodic layers, the objective functions are linked to the optimization program to obtain a proper solution set. The results of the numerical simulations demonstrate that without constructing complicated structures, the design method is able to produce PCs that overcome the limitations of two-component PCs and hence can feasibly and effectively achieve the design targets. The design approach presented in this paper can be extended to two-or three-dimensional systems and has great potential for the development of sound/ultrasound isolation structures, multiple band frequency filters, and other applications.