AISI 316L奥氏体不锈钢低温离子-气体复合渗碳温度对渗碳层的影响

采用离子轰击去除不锈钢表面钝化膜并活化表面,然后在不同的渗碳温度条件下,用氢气和乙炔混合气体对AISI 316L奥氏体不锈钢进行硬化处理,研究了渗碳温度对不锈钢渗碳层组织和性能的影响。结果表明:AISI 316L奥氏体不锈钢低温离子-乙炔气体渗碳的临界温度为540℃。在440~540℃温度范围内,渗碳层中具有单一γc相结构,无铬的碳化物析出,硬化层厚度与硬度均随渗碳温度的升高而增加。当渗碳温度超过540℃,渗碳层中不仅含有γc相,而且会有新相生成(如Cr23C6、Cr7C3、Cr C、Fe3C、Fe2C),从而引起不锈钢耐蚀性能降低。

汽车传动轴热锻模复合强化处理的研究

本文就4Cr2NiMoV 钢的工艺性能、锻造及其传动轴热锻模复合渗碳强化处理进行了介绍。与原5CrMnMo 钢常规热处理相比,消除了早中期失效,使用寿命提高了4～6倍。

Effect of solid carburization on surface microstructure and hardness of Ti-6Al-4V alloy and(TiB+La_2O_3)/Ti-6Al-4V composite

Solid carburization was employed to improve the hardness of Ti-6Al-4V alloy and （TiB＋La2O3）/Ti composite. The samples wrapped in graphite powder were placed in sealed quartz tubes, followed by solid carburization at 1227 K for 24 h. Microstructure and phase analysis indicated that TiC reinforcements and Ti-C solid solutions were introduced after solid carburization. Moreover, the volume fraction of equiaxedα-Ti phase in diffusion layer decreased obviously with increasing sample depth. Hardness testing results indicated that both the carburized surfaces performed significant improvement of about 100% in micro-hardness compared with untreated materials. The variation of carbon contents with increasing sample depth resulted in a hardened layer of 300 μm in the carburized samples. Meanwhile, slight influence on the internal microstructure and hardness indicated that solid carburization was an effective method in strengthening the surface of titanium alloy and titanium matrix composite.

Effect of specific pressure on fabrication of 2D-C_f/Al composite by vacuum and pressure infiltration

Carbon fiber reinforced aluminum matrix （Cf/Al） composite has many excellent properties, and it has received more and more attention. Two-dimensional （2D） Cf/Al composites were fabricated by vacuum and pressure infiltration, which was an integrated technique and could provide high vacuum and high infiltration pressure. The effect of specific pressure on the infiltration quality of the obtained composites was comparatively evaluated through microstructure observation. The experimental results show that satisfied Cf/Al composites could be fabricated at the specific pressure of 75 MPa. In this case, the preform was infiltrated much more completely by aluminum alloy liquid, and the residual porosity was seldom found. It is found that the ultimate tensile strength of the obtained Cf/Al composite reached maximum at the specific pressure of 75 MPa, which was improved by 138.9% compared with that of matrix alloy.

Threshold pressure and infiltration behavior of liquid metal into fibrous preform

A dynamic measuring apparatus was developed to investigate the infiltration process of liquid metal into the fibrous preform. 10% （volume fraction） chopped carbon fiber preforms were infiltrated with magnesium alloy under different infiltration pressures. The threshold pressure and flow behavior of liquid metal infiltrating into the preforms were calculated and measured. The microstructure of obtained Ct4Mg composites was observed. The results indicate that the measured threshold pressure for infiltration was 0.048 MPa, which was larger than the calculated value. The infiltration rate increased with the increase of infiltration pressure, but the increase amplitude decreased gradually. The tiny pores in the composites could be eliminated by increasing the infiltration pressure. When the infiltration pressure rose to 0.6 MPa, high quality C1/Mg composite was obtained.

Ceramic Supported PDMS and PEGDA Composite Membranes for CO2 Separation

Composite membranes have attracted increasing attentions owing to their potential applications for CO2 separation. In this work, ceramic supported polydimethylsiloxane （PDMS） and poly （ethylene glycol） diacrylate （PEGDA） composite membranes were prepared. The microstructure and physicochemical properties of the compos- ite membranes were characterized. Preparation conditions were systematically optimized. The gas separation performance of the as-prepared membranes was studied by pure gas and binary gas permeation measurement of CO〉 N2 and H〉 Experiments showed that PDMS, as silicone rubber, exhibited larger permeance and lower separation factors. Conversely, PEGDA composite membrane presented smaller gas permeance but higher ideal selectivity for CO2/N2. Compared to the performance of those membranes using polymeric supports or freestanding membranes, the two kinds of ceramic supported composite membranes exhibited higher gas permeance and acceptable selectivity. Therefore, the ceramic supported composite membrane can be expected as a candidate for CO2 separation from light gases.

Effect of nanofibers at surface of carbon fibers on microstructure of carbon/carbon composites during chemical vapor infiltration

Before densification by chemical vapor infiltration,carbon or SiC nanofibers were grown on the surface of carbon fibers by catalytic chemical vapor deposition using electroplated Ni as catalyst.The modification and mechanism of nanofibers on the pyrocarbon deposition during chemical vapor infiltration were investigated.The results show that the nanofibers improve the surface activity of the carbon fibers and become active nucleation centers during chemical vapor infiltration.They can induce the ordered deposition of pyrocarbon and adjust the interface bonding between pyrocarbon and carbon fibers during the infiltration.

C61900铜合金表面镀渗复合工艺改性

对C61900铜合金镀钛-渗碳复合工艺进行了研究,首先采用了闭合场非平衡磁控溅射镀钛膜,再利用等离子体渗碳在铝青铜合金表面制备出了镀钛渗碳改性层;然后对改性层表面进行了硬度、摩擦磨损、SEM、EDS、XRD表征。结果显示:最佳等离子渗碳工艺参数为650℃保温时间6 h,将铝青铜表面硬度提高到了300 HV0.01以上,是铝青铜基体的3.8倍以上,并使其磨损率降低了近90%,解决了C61900铜合金表面硬度低耐磨性差的问题。

60Si2MnA钢簧片失效分析及热处理工艺

对60S i2MnA钢簧片分别进行普通淬火、真空淬火、薄层渗碳复合热处理试验,采用回零试验检验零件弹性合格情况,并测试了力学性能和表面残余应力。结果表明,簧片经复合热处理后合格率最高,普通淬火由于表面脱碳零件合格率最低,真空淬火因为淬火强化效果降低合格率一般。簧片失效原因在于热处理表面质量差,加载后表面产生塑性变形。薄层渗碳复合热处理工艺能改善簧片表面质量及性能,特别是提高了表面残余压应力,有效地提高了产品合格率。