For evaluation of the rheological and mechanical properties of highly filled wood plastic composites (WPCs), polypropylene/polyethylene (PP/PE) blends were grafted with maleic anhydride (MAH) to enhance the inte...For evaluation of the rheological and mechanical properties of highly filled wood plastic composites (WPCs), polypropylene/polyethylene (PP/PE) blends were grafted with maleic anhydride (MAH) to enhance the interfacial adhesion between wood fiber and matrix. WPCs were prepared from wood fiber up to 60 wt.% and modified PP/PE was blended by extrusion. The rheological properties were studied by using dynamic measurement. According to the strain sweep test, the linear viscoelastic region of composites in the melt was determined. The result showed that the storage modulus was independent of the strain at low strain region (〈0.1%). The frequency sweep resuits indicated that all composites exhibited shear thinning behavior, and both the storage modulus and complex viscosity of MAH modified composites were decreased comparing to those unmodified. Flexural properties and impact strength of the prepared WPCs were measured according to the relevant standard specifications. The flexural and impact strength of the manufactured composites significantly increased and reached a maximum when MAH dosage was 1.0 wt%, whereas the flexural modulus after an initial decreased, also increased with MAH dosage. The increase in mechanical properties indicated that the presence of anhydride groups enhanced the interracial adhesion between wood fiber and PP/PE blends.展开更多
Expanded bed adsorption (EBA) has been widely used in industrial downstream bioprocessing. Solid matrix is the principal pillar supporting the successful application of EBA. A novel spherical cellulose-titanium dioxid...Expanded bed adsorption (EBA) has been widely used in industrial downstream bioprocessing. Solid matrix is the principal pillar supporting the successful application of EBA. A novel spherical cellulose-titanium dioxide composite matrix was prepared through the method of water-in-oil suspension thermal regeneration. Its typical physical properties were wet density 1.18g.cm-3, diameters in the range of 100-300um, porosity 85.5%, and water content 72.3%. Expansion characteristics and liquid mixing performance of the matrix in expanded bed were investigated using water and 10% (by mass) glycerol solution as mobile phases. The results indicate that the custom-assembled matrix has a stable flow hydrodynamics and exhibits the same degree of liquid-phase mixing or column efficiency as the commercially available Streamline adsorbent.展开更多
A new hydrometallurgical process of chlorination-distillation at low temperatures about 100 °C was developed for recovery of valuable metal and environmental protection. This process was used to treat flue dust c...A new hydrometallurgical process of chlorination-distillation at low temperatures about 100 °C was developed for recovery of valuable metal and environmental protection. This process was used to treat flue dust containing arsenic and antimony and satisfactory results were obtained. Over 99% of arsenic and antimony were recovered, and high purity As2O3 and SbCl3 were produced. A metallic alcoholate technique was developed and proved to be of significant to the utilization of antimony resources. Using this technique, a number of antimony oxide powders were prepared, such as high purity and ultrafine Sb2O3, ultrafine Sb2O3-Sb2O5 and Sb2O3-SnO2 composite powders.展开更多
The spacial distribution characteristics, activity and degradation capability of the biofilm in integrated vertical-flow constructed wetland were investigated. Results showed that the biofilm widely distributed in the...The spacial distribution characteristics, activity and degradation capability of the biofilm in integrated vertical-flow constructed wetland were investigated. Results showed that the biofilm widely distributed in the substrate of integrated vertical-flow constructed wetland and mainly in the 0-10 cm top layer where the activity ofdehydrogenase of the biofilm was also higher than that of other layers. The water quality could also affect the activity of the biofilm, for the TF(1,3,5-Triphenylformazan) amount reduced by the biofim incubated in water of the higher eutrophication was larger, too. The PCP (pentachlorophenol) removal rate by the substrate with biofilm was 1.5 times that without biofilm. In total, the biofilm of the down-flow chamber appeared larger biomass, higher dehydrogenase activity and stronger degradation capability of organic contamination than that in up-flow chamber and it was the major place for removal of the organic matters in waste water.展开更多
Because of the incomparable merits (nontoxicity, non-remainder, fast transfer mass) of supercritical carbon dioxide fluid technique(SC-CO2), it was used to developed a series of novel biodegradable tissue engineer...Because of the incomparable merits (nontoxicity, non-remainder, fast transfer mass) of supercritical carbon dioxide fluid technique(SC-CO2), it was used to developed a series of novel biodegradable tissue engineering scaffold materials in this research. The novel PLA/chitosan composite materials could be molded to different shapes, and the porosity of the materials were over 200 lam and connected. Chondrocyte cultivation, subcutaneous and intramuscular implantation were mainly discussed this paper. The results showed that the cells could well adhere, grow and multiplicate on the surface of the materials, which indicated good biocompatibility of the composite materials. The plantation test revealed that the PLA materials had already dismissed 2 month late in the body, while the composite materials could still keep certain strength and shape, and the most important things is the response of the tissue toward the implanted PLA/chitosan composite materials was mild and had far less inflammation than PLA materials. 8 to 16 weeks later, fiber membrane was stable; degradation of the materials was seen clear and tissue had already spread into it.展开更多
The logistics routes allocation discusses optimal routing from origin to destination through distribution center (DC) on condition that both transport and distribution cost should be taken into account. The problem ...The logistics routes allocation discusses optimal routing from origin to destination through distribution center (DC) on condition that both transport and distribution cost should be taken into account. The problem can be solved by the iterative non-linear programming (INLP), in which the transport cost and distribution cost are assumed to be linear and non-linear, respectively. The method works well in most situations. However, when the distribution cost predominates in the total cost, the method falls, and the solution given by the method is not a global minimum but a local minimum. Further study reveals that the INLP method is still a kind of transport routing method like vehicle routing problem (VRP), and the failure of the method must happen when the distribution cost is a major one. On such a condition, further computation on other extreme points, which physically means forcing all routes to pass through one DC one by one, should be carried out. By comparing values on these extreme points, the global optimal solution can be got. The method has both theoretical and practical meaning. In theoretical field, it might force us to seek new method; in practice, it reminds us to do such kind of check when the transport distance is short and warehousing work is major that often happens in local consolidation center or de-vanning center.展开更多
文摘For evaluation of the rheological and mechanical properties of highly filled wood plastic composites (WPCs), polypropylene/polyethylene (PP/PE) blends were grafted with maleic anhydride (MAH) to enhance the interfacial adhesion between wood fiber and matrix. WPCs were prepared from wood fiber up to 60 wt.% and modified PP/PE was blended by extrusion. The rheological properties were studied by using dynamic measurement. According to the strain sweep test, the linear viscoelastic region of composites in the melt was determined. The result showed that the storage modulus was independent of the strain at low strain region (〈0.1%). The frequency sweep resuits indicated that all composites exhibited shear thinning behavior, and both the storage modulus and complex viscosity of MAH modified composites were decreased comparing to those unmodified. Flexural properties and impact strength of the prepared WPCs were measured according to the relevant standard specifications. The flexural and impact strength of the manufactured composites significantly increased and reached a maximum when MAH dosage was 1.0 wt%, whereas the flexural modulus after an initial decreased, also increased with MAH dosage. The increase in mechanical properties indicated that the presence of anhydride groups enhanced the interracial adhesion between wood fiber and PP/PE blends.
基金Supported by the National Natural Science Foundation of China(No.20076042,No.20206029)and the Scientific Research Foundation of the State Education Ministry for the Returned Overseas Chinese Scholars(No.2002-247).
文摘Expanded bed adsorption (EBA) has been widely used in industrial downstream bioprocessing. Solid matrix is the principal pillar supporting the successful application of EBA. A novel spherical cellulose-titanium dioxide composite matrix was prepared through the method of water-in-oil suspension thermal regeneration. Its typical physical properties were wet density 1.18g.cm-3, diameters in the range of 100-300um, porosity 85.5%, and water content 72.3%. Expansion characteristics and liquid mixing performance of the matrix in expanded bed were investigated using water and 10% (by mass) glycerol solution as mobile phases. The results indicate that the custom-assembled matrix has a stable flow hydrodynamics and exhibits the same degree of liquid-phase mixing or column efficiency as the commercially available Streamline adsorbent.
文摘A new hydrometallurgical process of chlorination-distillation at low temperatures about 100 °C was developed for recovery of valuable metal and environmental protection. This process was used to treat flue dust containing arsenic and antimony and satisfactory results were obtained. Over 99% of arsenic and antimony were recovered, and high purity As2O3 and SbCl3 were produced. A metallic alcoholate technique was developed and proved to be of significant to the utilization of antimony resources. Using this technique, a number of antimony oxide powders were prepared, such as high purity and ultrafine Sb2O3, ultrafine Sb2O3-Sb2O5 and Sb2O3-SnO2 composite powders.
文摘The spacial distribution characteristics, activity and degradation capability of the biofilm in integrated vertical-flow constructed wetland were investigated. Results showed that the biofilm widely distributed in the substrate of integrated vertical-flow constructed wetland and mainly in the 0-10 cm top layer where the activity ofdehydrogenase of the biofilm was also higher than that of other layers. The water quality could also affect the activity of the biofilm, for the TF(1,3,5-Triphenylformazan) amount reduced by the biofim incubated in water of the higher eutrophication was larger, too. The PCP (pentachlorophenol) removal rate by the substrate with biofilm was 1.5 times that without biofilm. In total, the biofilm of the down-flow chamber appeared larger biomass, higher dehydrogenase activity and stronger degradation capability of organic contamination than that in up-flow chamber and it was the major place for removal of the organic matters in waste water.
基金This work was supported by the national key project“973”program of China.(No.G1999054306)“863”program of ministry of education in China(2OOlAA625050)Guangdong Science and technology bureau(No.A302020104).
文摘Because of the incomparable merits (nontoxicity, non-remainder, fast transfer mass) of supercritical carbon dioxide fluid technique(SC-CO2), it was used to developed a series of novel biodegradable tissue engineering scaffold materials in this research. The novel PLA/chitosan composite materials could be molded to different shapes, and the porosity of the materials were over 200 lam and connected. Chondrocyte cultivation, subcutaneous and intramuscular implantation were mainly discussed this paper. The results showed that the cells could well adhere, grow and multiplicate on the surface of the materials, which indicated good biocompatibility of the composite materials. The plantation test revealed that the PLA materials had already dismissed 2 month late in the body, while the composite materials could still keep certain strength and shape, and the most important things is the response of the tissue toward the implanted PLA/chitosan composite materials was mild and had far less inflammation than PLA materials. 8 to 16 weeks later, fiber membrane was stable; degradation of the materials was seen clear and tissue had already spread into it.
基金the National Science Foundation,Ministry of Education and Science, Japan (No. 17330089)
文摘The logistics routes allocation discusses optimal routing from origin to destination through distribution center (DC) on condition that both transport and distribution cost should be taken into account. The problem can be solved by the iterative non-linear programming (INLP), in which the transport cost and distribution cost are assumed to be linear and non-linear, respectively. The method works well in most situations. However, when the distribution cost predominates in the total cost, the method falls, and the solution given by the method is not a global minimum but a local minimum. Further study reveals that the INLP method is still a kind of transport routing method like vehicle routing problem (VRP), and the failure of the method must happen when the distribution cost is a major one. On such a condition, further computation on other extreme points, which physically means forcing all routes to pass through one DC one by one, should be carried out. By comparing values on these extreme points, the global optimal solution can be got. The method has both theoretical and practical meaning. In theoretical field, it might force us to seek new method; in practice, it reminds us to do such kind of check when the transport distance is short and warehousing work is major that often happens in local consolidation center or de-vanning center.