To investigate the non-covalent interaction between cyclodextrins （CD） and lithium ion, a stoichiometry of α-CD, β-CD, heptakis（2,6-di-O-methyl）-β-CD （DM-β-CD）, or heptakis（2,3,6-tri-O-methyl）-β-CD （TM-...To investigate the non-covalent interaction between cyclodextrins （CD） and lithium ion, a stoichiometry of α-CD, β-CD, heptakis（2,6-di-O-methyl）-β-CD （DM-β-CD）, or heptakis（2,3,6-tri-O-methyl）-β-CD （TM-β-CD） was mixed with lithium salt, respectively, and then incubated at room temperature for 10 min to reach the equilibrium. In posi- tive mode, the electrospray ionization mass spectrometry （ESI-MS） results demonstrated that lithium ion can conjugate to α-, β-, DM-β- or TM-β-CD and form 1：1 stoichiometric non-covalent complexes. The binding of the complexes was further confirmed by collision- induced dissociation. The dissociation constants Kdl of four complexes （Li＋α-CD, Li＋β- CD, Li＋DM-β-CD, and Li＋TM-β-CD） were determined by mass spectrometric titration. The results showed Kdl were 18.7, 26.7, 33.6, 30.5 μmol/L for the complexes of Li＋ with α-CD, β-CD, DM-β-CD, and TM-β-CD, respectively. Kdl for the Li＋ complexes of/3-CD is smaller than that of DM-β-CD due to its steric effect of the partial substituted -CH3. The Kdl for the Li＋ complexes of DM-β-CD is nearly in agreement with that of TM-β-CD, indicating Li＋ is more likely to locate in the small rim of DM-β-CD＇s hydrophobic cavity. The DFT results showed through electrostatic interaction, one Li＋ can strongly conjugate to four neighboring oxygen atoms. For the （α-CD＋Li）＋ complex, one Li＋ may also situate the small rim of α-CD＇s hydrophobic cavity to form a non-specific host-guest complex.展开更多
Combining refined composite multiscale fuzzy entropy(RCMFE)and support vector machine(SVM)with particle swarm optimization(PSO)for diagnosing roller bearing faults is proposed in this paper.Compared with refined compo...Combining refined composite multiscale fuzzy entropy(RCMFE)and support vector machine(SVM)with particle swarm optimization(PSO)for diagnosing roller bearing faults is proposed in this paper.Compared with refined composite multiscale sample entropy(RCMSE)and multiscale fuzzy entropy(MFE),the smoothness of RCMFE is superior to that of those models.The corresponding comparison of smoothness and analysis of validity through decomposition accuracy are considered in the numerical experiments by considering the white and 1/f noise signals.Then RCMFE,RCMSE and MFE are developed to affect extraction by using different roller bearing vibration signals.Then the extracted RCMFE,RCMSE and MFE eigenvectors are regarded as the input of the PSO-SVM to diagnose the roller bearing fault.Finally,the results show that the smoothness of RCMFE is superior to that of RCMSE and MFE.Meanwhile,the fault classification accuracy is higher than that of RCMSE and MFE.展开更多
Two series monot ailed porphyrins, Cobalt-5- {4- [ω- （1-adamant aneamino） alkyloxy] phenyl }- 10,15,20-triphenyl porphyrinate （CoPCnA, n=4,5,6） and Nickel-5-{4-[ω-（1-adamantaneamino）alkyloxy]phenyl}-10,15.20- ...Two series monot ailed porphyrins, Cobalt-5- {4- [ω- （1-adamant aneamino） alkyloxy] phenyl }- 10,15,20-triphenyl porphyrinate （CoPCnA, n=4,5,6） and Nickel-5-{4-[ω-（1-adamantaneamino）alkyloxy]phenyl}-10,15.20- triphenyl porphyrinate （NiPCnA, n=4,5,6）, were synthesized, in which the porphyrin moiety was connected to l-adamantanamine via a flexible hydrocarbon chain. The fluorescence quenching between these donor substrates and mono-6-p-nitrobenzoyl-β-cyclodextrin （NBCD） was studied in detail. Distinct fluorescence quenching occured in these supramolecular systems. This quenching was attributed to the photoinduced electron transfer （PET） inside the supramolecular assembly between the porphyrin donors and cyclodextrin acceptors. Detailed Stern-Volmer constants were measured and they were partitioned into dynamic Stern- Volmer quenching constants and static binding constants. It was demonstrated that the PET interaction between the porphyrin subunits and NBCD is indeed effective.展开更多
Metal matrix composites reinforced with graphite particles provide better machinability and tribological properties. The present study attempts to find the optimal level of machining parameters for multi-performance c...Metal matrix composites reinforced with graphite particles provide better machinability and tribological properties. The present study attempts to find the optimal level of machining parameters for multi-performance characteristics in turning of Al-SiC-Gr hybrid composites using grey-fuzzy algorithm. The hybrid composites with 5%, 7.5% and 10% combined equal mass fraction of SiC-Gr particles were used for the study and their corresponding tensile strength values are 170, 210, 204 MPa respectively. Al-10%（SiC-Gr） hybrid composite provides better machinability when compared with composites with 5% and 7.5% of SiC-Gr. Grey-fuzzy logic approach offers improved grey-fuzzy reasoning grade and has less uncertainties in the output when compared with grey relational technique. The confirmatory test reveals an increase in grey-fuzzy reasoning grade from 0.619 to 0.891, which substantiates the improvement in multi-performance characteristics at the optimal level of process parameters setting.展开更多
The leading character, Alexandra Bergson, in Willa Cather＇s O, Pioneer! has aroused much discussion concerning her sexual orientation. By looking at how this character grows from a woman suffering from sexual ambigui...The leading character, Alexandra Bergson, in Willa Cather＇s O, Pioneer! has aroused much discussion concerning her sexual orientation. By looking at how this character grows from a woman suffering from sexual ambiguity to one who achieves an composite of masculinity and femininity, this essay means to prove that although the writer＇s lesbianism influences her characterization to a certain degree, by endowing her characters with androgyny, Cather always attempts to create a group of characters who are striving for human beings wholeness.展开更多
In the present paper, Charpy impact resistance of aluminum-epoxy laminated composites in both crack divider and crack ar-rester configurations has been investigated. In both configurations, an analytical investigation...In the present paper, Charpy impact resistance of aluminum-epoxy laminated composites in both crack divider and crack ar-rester configurations has been investigated. In both configurations, an analytical investigation has been carried out to evaluate the effects of layers thickness on impact resistance of the specimens. A model based on fuzzy logic for predicting impact re-sistance of the specimens has been presented. For purpose of building the model, training and testing using experimental re-sults from 126 specimens produced from two basic composites were conducted. The data used for the input data in fuzzy logic models are arranged in a format of 7 input parameters that cover the thickness of layers, the number of layers, the adhesive type, the crack tip configuration, the content of SiC particles, the content of methacrylated butadiene-styrene particles and the number of test trial. According to these input parameters, in the fuzzy logic model, the impact resistance of each specimen was predicted. The training and testing results in the fuzzy logic model have shown a strong potential for predicting impact resis-tance of aluminum-epoxy laminated composites.展开更多
文摘To investigate the non-covalent interaction between cyclodextrins （CD） and lithium ion, a stoichiometry of α-CD, β-CD, heptakis（2,6-di-O-methyl）-β-CD （DM-β-CD）, or heptakis（2,3,6-tri-O-methyl）-β-CD （TM-β-CD） was mixed with lithium salt, respectively, and then incubated at room temperature for 10 min to reach the equilibrium. In posi- tive mode, the electrospray ionization mass spectrometry （ESI-MS） results demonstrated that lithium ion can conjugate to α-, β-, DM-β- or TM-β-CD and form 1：1 stoichiometric non-covalent complexes. The binding of the complexes was further confirmed by collision- induced dissociation. The dissociation constants Kdl of four complexes （Li＋α-CD, Li＋β- CD, Li＋DM-β-CD, and Li＋TM-β-CD） were determined by mass spectrometric titration. The results showed Kdl were 18.7, 26.7, 33.6, 30.5 μmol/L for the complexes of Li＋ with α-CD, β-CD, DM-β-CD, and TM-β-CD, respectively. Kdl for the Li＋ complexes of/3-CD is smaller than that of DM-β-CD due to its steric effect of the partial substituted -CH3. The Kdl for the Li＋ complexes of DM-β-CD is nearly in agreement with that of TM-β-CD, indicating Li＋ is more likely to locate in the small rim of DM-β-CD＇s hydrophobic cavity. The DFT results showed through electrostatic interaction, one Li＋ can strongly conjugate to four neighboring oxygen atoms. For the （α-CD＋Li）＋ complex, one Li＋ may also situate the small rim of α-CD＇s hydrophobic cavity to form a non-specific host-guest complex.
基金Projects(City U 11201315,T32-101/15-R)supported by the Research Grants Council of the Hong Kong Special Administrative Region,China
文摘Combining refined composite multiscale fuzzy entropy(RCMFE)and support vector machine(SVM)with particle swarm optimization(PSO)for diagnosing roller bearing faults is proposed in this paper.Compared with refined composite multiscale sample entropy(RCMSE)and multiscale fuzzy entropy(MFE),the smoothness of RCMFE is superior to that of those models.The corresponding comparison of smoothness and analysis of validity through decomposition accuracy are considered in the numerical experiments by considering the white and 1/f noise signals.Then RCMFE,RCMSE and MFE are developed to affect extraction by using different roller bearing vibration signals.Then the extracted RCMFE,RCMSE and MFE eigenvectors are regarded as the input of the PSO-SVM to diagnose the roller bearing fault.Finally,the results show that the smoothness of RCMFE is superior to that of RCMSE and MFE.Meanwhile,the fault classification accuracy is higher than that of RCMSE and MFE.
基金V. ACKN0WLEDGMENT This work was supported Science Foundation of China by the National Natural （No.20472079）.
文摘Two series monot ailed porphyrins, Cobalt-5- {4- [ω- （1-adamant aneamino） alkyloxy] phenyl }- 10,15,20-triphenyl porphyrinate （CoPCnA, n=4,5,6） and Nickel-5-{4-[ω-（1-adamantaneamino）alkyloxy]phenyl}-10,15.20- triphenyl porphyrinate （NiPCnA, n=4,5,6）, were synthesized, in which the porphyrin moiety was connected to l-adamantanamine via a flexible hydrocarbon chain. The fluorescence quenching between these donor substrates and mono-6-p-nitrobenzoyl-β-cyclodextrin （NBCD） was studied in detail. Distinct fluorescence quenching occured in these supramolecular systems. This quenching was attributed to the photoinduced electron transfer （PET） inside the supramolecular assembly between the porphyrin donors and cyclodextrin acceptors. Detailed Stern-Volmer constants were measured and they were partitioned into dynamic Stern- Volmer quenching constants and static binding constants. It was demonstrated that the PET interaction between the porphyrin subunits and NBCD is indeed effective.
文摘Metal matrix composites reinforced with graphite particles provide better machinability and tribological properties. The present study attempts to find the optimal level of machining parameters for multi-performance characteristics in turning of Al-SiC-Gr hybrid composites using grey-fuzzy algorithm. The hybrid composites with 5%, 7.5% and 10% combined equal mass fraction of SiC-Gr particles were used for the study and their corresponding tensile strength values are 170, 210, 204 MPa respectively. Al-10%（SiC-Gr） hybrid composite provides better machinability when compared with composites with 5% and 7.5% of SiC-Gr. Grey-fuzzy logic approach offers improved grey-fuzzy reasoning grade and has less uncertainties in the output when compared with grey relational technique. The confirmatory test reveals an increase in grey-fuzzy reasoning grade from 0.619 to 0.891, which substantiates the improvement in multi-performance characteristics at the optimal level of process parameters setting.
文摘The leading character, Alexandra Bergson, in Willa Cather＇s O, Pioneer! has aroused much discussion concerning her sexual orientation. By looking at how this character grows from a woman suffering from sexual ambiguity to one who achieves an composite of masculinity and femininity, this essay means to prove that although the writer＇s lesbianism influences her characterization to a certain degree, by endowing her characters with androgyny, Cather always attempts to create a group of characters who are striving for human beings wholeness.
文摘In the present paper, Charpy impact resistance of aluminum-epoxy laminated composites in both crack divider and crack ar-rester configurations has been investigated. In both configurations, an analytical investigation has been carried out to evaluate the effects of layers thickness on impact resistance of the specimens. A model based on fuzzy logic for predicting impact re-sistance of the specimens has been presented. For purpose of building the model, training and testing using experimental re-sults from 126 specimens produced from two basic composites were conducted. The data used for the input data in fuzzy logic models are arranged in a format of 7 input parameters that cover the thickness of layers, the number of layers, the adhesive type, the crack tip configuration, the content of SiC particles, the content of methacrylated butadiene-styrene particles and the number of test trial. According to these input parameters, in the fuzzy logic model, the impact resistance of each specimen was predicted. The training and testing results in the fuzzy logic model have shown a strong potential for predicting impact resis-tance of aluminum-epoxy laminated composites.
