Using T106 numerical products, MM5 simulations in conjunction of Q-vector scheme-computed NCEP results, observations and satellite cloud images, study is undertaken for an exceptionally intense rainstorm event afflict...Using T106 numerical products, MM5 simulations in conjunction of Q-vector scheme-computed NCEP results, observations and satellite cloud images, study is undertaken for an exceptionally intense rainstorm event afflicting the Wenzhou region of Zhejiang province far away from the tropical storm center happening early on the morning of September 4, 1999 (TS9909 hereinafter). Evidence suggests that, like previously-studied typhoons landing in autumn south of Xiamen to the eastern part of Guangdong, TS9909 has an inverted trough in the central south of the coastal belt of Zhejiang province that produces the rainstorm from the meso convective complex (MCC) on the warm, moist shear inside; the time and order of the magnitude of the rainfall are bound up with the development of the pattern of strong Q-vector divergence gradients during the event for the study area; the NE - SW coastline and the unique topography of the Yandang mountains inside the region are favorable for air lifting are the major contributors to the torrential rains.展开更多
Multi-sensor coordinate unification in dimensional metrology is used in order to get holistic, more accurate and reliable information about a workpiece based on several or multiple measurement values from ...Multi-sensor coordinate unification in dimensional metrology is used in order to get holistic, more accurate and reliable information about a workpiece based on several or multiple measurement values from one or more sensors. Because of the problem that standard ball is deficient as a standard artifact in the coordinate unification of high-precision composite measurement in two dimensions (2D) , a new method is proposed in this paper which uses angle gauge blocks as standard artifacts to achieve coordinate unification between the image sensor and the tactile probe. By comparing the standard ball with the angle gauge block as a standard artifact, theoretical analysis and experimental results are given to prove that it is more precise and more convenient to use angle gauge blocks as standard artifacts to achieve coordinate unification of high-precision composite measurement in two dimensions.展开更多
A novel TiNi/AlSi composite with high compressive strength and high damping capacity was obtained by infiltrating Al-12%Si alloy into porous TiNi alloy.It had been found that the high compressive strength (440 MPa) of...A novel TiNi/AlSi composite with high compressive strength and high damping capacity was obtained by infiltrating Al-12%Si alloy into porous TiNi alloy.It had been found that the high compressive strength (440 MPa) of TiNi/AlSi composite is due to the increase of effective carrying area after infiltrating Al-12%Si alloy,while the high damping capacity is contributed to TiNi carcass,Al-12%Si filling material and micro- slipping at the interface.展开更多
B2O3-BaO-ZnO glass was prepared by using conventional melt quenching technology. The forming regularity and the relationship between the composition and the property of B2O3BaOZnO glass were investigated. The results ...B2O3-BaO-ZnO glass was prepared by using conventional melt quenching technology. The forming regularity and the relationship between the composition and the property of B2O3BaOZnO glass were investigated. The results show that the composition range for forming B2O3BaOZnO glass is very wide, but the content of B2O3 has a limit within mole fraction of 25%75%. When the content of B2O3 is over the limit, the melt will be divided into two phases with different compositions and structures, whereas too low content of B2O3 will result in the crystallization of the melt during the cooling process. The thermal expansion coefficient, the transition temperature and the resistivity of the glass at room temperature are (510)×10 -6℃ -1, 480620℃ and (1.53.0)×10 10Ω·m, respectively.展开更多
In order to solve the problem of depth classification of the underwater target in a very low frequency acoustic field, the active component of cross spectra of particle pressure and horizontal velocity (ACCSPPHV) is...In order to solve the problem of depth classification of the underwater target in a very low frequency acoustic field, the active component of cross spectra of particle pressure and horizontal velocity (ACCSPPHV) is adopted to distinguish the surface vessel and the underwater target. According to the effective depth of a Pekeris waveguide, the placing depth forecasting equations of passive vertical double vector hydrophones are proposed. Numerical examples show that when the sum of depths of two hydro- phones is the effective depth, the sign distribution of ACCSPPHV has nothing to do with horizontal distance; in addition, the sum of the first critical surface and the second critical surface is equal to the effective depth. By setting the first critical surface less than the difference between the effective water depth and the actual water depth, that is, the second critical surface is greater than the actual depth, the three positive and negative regions of the whole ocean volume are equivalent to two positive and negative regions and therefore the depth classification of the underwater target is obtained. Besides, when the 20 m water depth is taken as the first critical surface in the simulation of underwater targets (40 Hz, 50 Hz, and 60 Hz respectively), the effectiveness of the algorithm and the cor- reemess of relevant conclusions are verified, and the analysis of the corresponding forecasting performance is conducted.展开更多
Hydrogen sulfide in rural biogas was removed with liquid-phase catalytic oxidation.By using rare earth as catalyst,and sulfosalicylic acid as stabilizer,H2S purification efficiency could increase as high as 96%,and su...Hydrogen sulfide in rural biogas was removed with liquid-phase catalytic oxidation.By using rare earth as catalyst,and sulfosalicylic acid as stabilizer,H2S purification efficiency could increase as high as 96%,and sulfur capacity of the composite solution was about 3 g/L.The results show that purification efficiency was affected by catalyst addition,pH,experimental temperature,and sulfur capacity.The parameters effects on catalytic oxidation were studied,and the optimized conditions were that Fe3+ concentration 0.08 mg/L,reaction temperature 70°C,pH 9.0,with a absorption solution volume of 50 mL,a gas flow rate 200 mL/min,and H2S mass concentration of 1.58-2.02 mg/m3.展开更多
In order to improve the anchoring force of anchors for carbon fiber reinforced polymer(CFRP) tendons further, a new wedge-bond-type anchor for CFRP tendons was developed. The increment in anchoring force induced by th...In order to improve the anchoring force of anchors for carbon fiber reinforced polymer(CFRP) tendons further, a new wedge-bond-type anchor for CFRP tendons was developed. The increment in anchoring force induced by the clamping segment of anchor was studied. Taking the deformation of all parts in clamping segment in the transverse direction into consideration, the calculation formula for the increment of anchoring force was proposed based on the linear elastic hypotheses. The proposed model is verified by experiments and conclusions are drawn that the anchoring force is influenced mainly by the inclination angle of clamping pieces, the length of clamping part and the thickness of bonding medium. Especially, the thickness of bonding medium should be lowered in design to improve the synergistic effect of anchors.展开更多
We propose a way to measure the strength of quantum nonlocal correlation (QNC) based on the characteristic function, which is defined as a response function under the local quantum measurement in a composite system. I...We propose a way to measure the strength of quantum nonlocal correlation (QNC) based on the characteristic function, which is defined as a response function under the local quantum measurement in a composite system. It is found that the strength of QNC based on the characteristic function is a half-positive-definite function and does not change under any LU operation. Generally, we give a new definition for quantum entanglement using the strength function. Furthermore, we also give a separability-criterion for 2×m-dimensional mixed real matrix. This paper proposes an alternative way for QNC further research.展开更多
Lithium-sulfur(Li-S) batteries have attracted considerable attention due to their high energy density(2600 Wh kg-1). However, its commercialization is hindered seriously by the low loading and utilization rate of sulf...Lithium-sulfur(Li-S) batteries have attracted considerable attention due to their high energy density(2600 Wh kg-1). However, its commercialization is hindered seriously by the low loading and utilization rate of sulfur cathodes. Herein, we designed the cellulose-based graphene carbon composite aerogel(CCA) self-standing electrode to enhance the performance of Li-S batteries. The CCA contributes to the mass loading and utilization efficiency of sulfur, because of its unique physical structure: low density(0.018 g cm-3), large specific surface area(657.85 m2 g-1), high porosity(96%), and remarkable electrolyte adsorption(42.25 times). Compared to Al(about 49%), the CCA displayed excellent sulfur use efficiency(86%) and could reach to high area capacity of 8.60 mAh cm-2 with 9.11 mgS loading. Meanwhile,the CCA exhibits the excellent potential for pulse sensing applications due to its flexibility and superior sensitivity to electrical response signals.展开更多
There is a growing demand for hybrid supercapacitor systems to overcome the energy density limitation of existing-generation electric double layer capacitors (EDLCs), leading to next generation-Ⅱ supercapacitors wi...There is a growing demand for hybrid supercapacitor systems to overcome the energy density limitation of existing-generation electric double layer capacitors (EDLCs), leading to next generation-Ⅱ supercapacitors with minimum sacrifice in power density and cycle life. Here, an advanced graphene-based hybrid system, consisting of a graphene-inserted Li4Ti5O12 (LTO) composite anode (G-LTO) and a three-dimensional porous graphene-sucrose cathode, has been fabricated for the purpose of combining both the benefits of Li-ion batteries (energy source) and supercapacitors (power source). Graphene-based materials play a vital role in both electrodes in respect of the high performance of the hybrid supercapacitor. For example, compared with the theoretical capacity of 175 mA-h.g-1 for pure LTO, the G-LTO nanocomposite delivered excellent reversible capacities of 207, 190, and 176 mA·1h·g-1 at rates of 0.3, 0.5, and 1 C, respectively, in the potential range 1.0-2.5 V vs. Li/Li+; these are among the highest values for LTO-based nano- composites at the same rates and potential range. Based on this, an optimized hybrid supercapacitor was fabricated following the standard industry procedure; this displayed an ultrahigh energy density of 95 Wh·kg-1 at a rate of 0.4 C (2.5 h) over a wide voltage range (0-3 V), and still retained an energy density of 32 Wh·kg-1 at a high rate of up to 100 C, equivalent to a full discharge in 36 s, which is exceptionally fast for hybrid supercapacitors. The excellent performance of this Li-ion hybrid supercapacitor indicates that graphene-based materials may indeed play a significant role in next-generation supercapacitors with excellent electrochemical performance.展开更多
Spectroscopic ellipsometry (SE), photocarrier radiometry (PCR) and photoluminescence (PL) techniques were employed to measure the ultra-shallow junction (USJ) wafers. These USJ wafers were prepared by As+ ion implanta...Spectroscopic ellipsometry (SE), photocarrier radiometry (PCR) and photoluminescence (PL) techniques were employed to measure the ultra-shallow junction (USJ) wafers. These USJ wafers were prepared by As+ ion implantation at energies of 0.5-5 keV, at a dose of 1×1015 As+ /cm 2 and spike annealing. Experimentally the damaged layer of the as-implanted wafer and the recrystallization and activation of the post-annealed wafer were evaluated by SE in the spectral range from 0.27 to 20 m. The PCR amplitude decreased monotonically with the increasing implantation energy. The experimental results also showed that the PCR amplitudes of post-annealed USJ wafers were greatly enhanced, compared to the non-implanted and non-annealed substrate wafer. The PL measurements showed the enhanced PCR signals were attributed to the band-edge emissions of silicon. For explaining the PL enhancement, the electronic transport properties of USJ wafers were extracted via multi-wavelength PCR experiment and fitting. The fitted results showed the decreasing surface recombination velocity and the decreasing diffusion coefficient of the implanted layer contributed to the PCR signal enhancement with the decreasing implantation energy. SE, PCR and PL were proven to be non-destructive metrology tools for characterizing ultra-shallow junctions.展开更多
Flexible supercapacitors (SCs) are attractive energy storage devices for wearable electronics, but their applications are hindered by their low volumetric energy densities. Two dimensional (2D) non-carbon nanomaterial...Flexible supercapacitors (SCs) are attractive energy storage devices for wearable electronics, but their applications are hindered by their low volumetric energy densities. Two dimensional (2D) non-carbon nanomaterials are the most promising pseudocapacitive materials for high volumetric capacitance electrodes. However, they are poorly conductive and prone to self-stacking, which results in unsatisfactory electrochemical performance. In this work, large-scale V2O5·nH2O ultrathin nanosheets are synthesized by a facile and scalable method and transformed into layered and compact composite films with one-dimensional carbon nanotubes (CNTs). The self-standing films show an optimized volumetric capacitance of 521.0Fcm^-3 with only 10 wt% of CNTs, which is attributed to dramatically enhanced electrical conductivity beyond the electrical percolation threshold, high dispersion of pseudocapacitive V2O5·nH2O nanosheets, and high mass density of the films. All-solid-state flexible SCs made of V2O5·nH2O/CNTs films show a maximum energy density of 17.4WhL^-1.展开更多
In this paper, we report a one-step electrodeposited synthesis strategy for directly growing NiCoSe2/Ni3Se2 lamella arrays(LAs) on N-doped graphene nanotubes(N-GNTs) as advanced free-standing positive electrode for as...In this paper, we report a one-step electrodeposited synthesis strategy for directly growing NiCoSe2/Ni3Se2 lamella arrays(LAs) on N-doped graphene nanotubes(N-GNTs) as advanced free-standing positive electrode for asymmetric supercapacitors. Benefiting from the synergetic contribution between the distinctive electroactive materials and the skeletons, the as-constructed N-GNTs@NiCoSe2/Ni3-Se2LAs present a specific capacitance of ~1308 F g^-1 at a current density of 1 A g^-1. More importantly, the hybrid electrode also reveals excellent rate capability(~1000 F g^-1 even at 100 A g^-1) and appealing cycling performance(~103.2% of capacitance retention over 10,000 cycles). Furthermore, an asymmetric supercapacitor is fabricated by using the obtained N-GNTs@NiCoSe2/Ni3Se2LAs and active carbon(AC) as the positive and negative electrodes respectively,which holds a high energy density of 42.8 W h kg^-1 at 2.6 k W kg^-1, and superior cycling stability of ~94.4% retention over 10,000 cycles. Accordingly, our fabrication technique and new insight herein can both widen design strategy of multicomponent composite electrode materials and promote the practical applications of the latest emerging transition metal selenides in next-generation high-performance supercapacitors.展开更多
A novel all-solid-state, coaxial, fiber-shaped asymmetric supercapacitor has been fabricated by wrapping a conducting carbon paper on a MnO2-modified nanoporous gold wire. This energy wire exhibits high capacitance of...A novel all-solid-state, coaxial, fiber-shaped asymmetric supercapacitor has been fabricated by wrapping a conducting carbon paper on a MnO2-modified nanoporous gold wire. This energy wire exhibits high capacitance of 12 mF.cm^-2 and energy density of 5.4 μW.h.cm^-2 with excellent cycling stability. Hierarchical nanostructures and coaxial architectural design facilitate effective contacts between the two core@sheath electrodes and active layers with high flexibility and high performance. This work provides the first example of coaxial fiber- shaped asymmetric supercapacitors with an operation voltage of 1.8 V, and holds great potential for future flexible electronic devices.展开更多
The identification of the imperfection originating from finite-temperature-difference heat transfer is an indispensable step for both the performance analysis and the better design of a heat exchanger network (HEN) ...The identification of the imperfection originating from finite-temperature-difference heat transfer is an indispensable step for both the performance analysis and the better design of a heat exchanger network (HEN) with the aim of energy saving. This study develops a convenient area method for visualizing the heat-transfer imperfection of a HEN in terms of temperature-heat flow diagrams ( T-Q diagrams) by combining the composite curves that have already been used in pinch analysis and the re- cently developed entransy analysis. It is shown that the area between the hot and cold composite curves and the hot and cold utility lines on a T-Q diagram is just equal to the total entransy dissipation rate during the multi-stream heat transfer process occurred in a HEN, and this area can be used to graphically represent the total heat-transfer imperfection of the HEN. The increase in heat recovery or decrease in energy requirements with decreasing the minimum temperature difference, ATmin, of a HEN can then be attributed to a lower entransy dissipation rate, quantitatively represented by the decrease of the area between the composite curves and the utility lines. In addition, the differences between the T-Q diagram and the pre-existing energy level-enthalpy flow diagram (12-H diagram) in the roles of visualizing process imperfection and designing HENs are dis- cussed.展开更多
Lithium sulfur(Li-S)batteries have been regarded as a promising next-generation energy storage system with high theoretical specific capacity and energy density,but still facing challenges.In order to make Li-S batter...Lithium sulfur(Li-S)batteries have been regarded as a promising next-generation energy storage system with high theoretical specific capacity and energy density,but still facing challenges.In order to make Li-S batteries more competitive,combination of trapping sites and electrocatalytic properties for polysulfides is an effective way to improve the battery performance.In this study,we prepare a type of multifunctional V3S4-nanowire/graphene composites(V3S4-G)by uniformly dispersing V3S4 nanowires on the graphene substrate.This structure contributes to the sufficient exposure of multifunctional V3S4 active sites which can anchor polysulfides and accelerate reaction kinetics.Thus,the Li-S batteries based on the multifunctional V3S4-G sulfur cathode deliver a stable cycling performance and good rate capability.Even at sulfur loading of 3 mg cm^−2,the V3S4-G sulfur cathode possesses a low capacity decay rate of 0.186%per cycle at 0.5 C.展开更多
基金sponsored jointly by the Natural Science Foundation of China (Grant 4040950009402050084)the Project of Planned National Key Basic Research/Development (2004CB418301)
文摘Using T106 numerical products, MM5 simulations in conjunction of Q-vector scheme-computed NCEP results, observations and satellite cloud images, study is undertaken for an exceptionally intense rainstorm event afflicting the Wenzhou region of Zhejiang province far away from the tropical storm center happening early on the morning of September 4, 1999 (TS9909 hereinafter). Evidence suggests that, like previously-studied typhoons landing in autumn south of Xiamen to the eastern part of Guangdong, TS9909 has an inverted trough in the central south of the coastal belt of Zhejiang province that produces the rainstorm from the meso convective complex (MCC) on the warm, moist shear inside; the time and order of the magnitude of the rainfall are bound up with the development of the pattern of strong Q-vector divergence gradients during the event for the study area; the NE - SW coastline and the unique topography of the Yandang mountains inside the region are favorable for air lifting are the major contributors to the torrential rains.
基金National Key Scientific Instrument and Equipment Development Project(No.2013YQ170539)
文摘Multi-sensor coordinate unification in dimensional metrology is used in order to get holistic, more accurate and reliable information about a workpiece based on several or multiple measurement values from one or more sensors. Because of the problem that standard ball is deficient as a standard artifact in the coordinate unification of high-precision composite measurement in two dimensions (2D) , a new method is proposed in this paper which uses angle gauge blocks as standard artifacts to achieve coordinate unification between the image sensor and the tactile probe. By comparing the standard ball with the angle gauge block as a standard artifact, theoretical analysis and experimental results are given to prove that it is more precise and more convenient to use angle gauge blocks as standard artifacts to achieve coordinate unification of high-precision composite measurement in two dimensions.
文摘A novel TiNi/AlSi composite with high compressive strength and high damping capacity was obtained by infiltrating Al-12%Si alloy into porous TiNi alloy.It had been found that the high compressive strength (440 MPa) of TiNi/AlSi composite is due to the increase of effective carrying area after infiltrating Al-12%Si alloy,while the high damping capacity is contributed to TiNi carcass,Al-12%Si filling material and micro- slipping at the interface.
文摘B2O3-BaO-ZnO glass was prepared by using conventional melt quenching technology. The forming regularity and the relationship between the composition and the property of B2O3BaOZnO glass were investigated. The results show that the composition range for forming B2O3BaOZnO glass is very wide, but the content of B2O3 has a limit within mole fraction of 25%75%. When the content of B2O3 is over the limit, the melt will be divided into two phases with different compositions and structures, whereas too low content of B2O3 will result in the crystallization of the melt during the cooling process. The thermal expansion coefficient, the transition temperature and the resistivity of the glass at room temperature are (510)×10 -6℃ -1, 480620℃ and (1.53.0)×10 10Ω·m, respectively.
基金supported by Public Science and Technology Research Funds Projects of Ocean(201405036-4)the National Natural Science Foundation of China(Grant Nos.11404406,51179034,41072176 and 11204109)+1 种基金Defense Technology Research(JSJC2013604C012)Postdoctoral Science Foundation of China(Grant No.2013 M531015)
文摘In order to solve the problem of depth classification of the underwater target in a very low frequency acoustic field, the active component of cross spectra of particle pressure and horizontal velocity (ACCSPPHV) is adopted to distinguish the surface vessel and the underwater target. According to the effective depth of a Pekeris waveguide, the placing depth forecasting equations of passive vertical double vector hydrophones are proposed. Numerical examples show that when the sum of depths of two hydro- phones is the effective depth, the sign distribution of ACCSPPHV has nothing to do with horizontal distance; in addition, the sum of the first critical surface and the second critical surface is equal to the effective depth. By setting the first critical surface less than the difference between the effective water depth and the actual water depth, that is, the second critical surface is greater than the actual depth, the three positive and negative regions of the whole ocean volume are equivalent to two positive and negative regions and therefore the depth classification of the underwater target is obtained. Besides, when the 20 m water depth is taken as the first critical surface in the simulation of underwater targets (40 Hz, 50 Hz, and 60 Hz respectively), the effectiveness of the algorithm and the cor- reemess of relevant conclusions are verified, and the analysis of the corresponding forecasting performance is conducted.
基金Project(2008ZX07105-002) supported by the Erhai Lake Project of National Science and Technology Major Project in the 11th Five years Plan of China
文摘Hydrogen sulfide in rural biogas was removed with liquid-phase catalytic oxidation.By using rare earth as catalyst,and sulfosalicylic acid as stabilizer,H2S purification efficiency could increase as high as 96%,and sulfur capacity of the composite solution was about 3 g/L.The results show that purification efficiency was affected by catalyst addition,pH,experimental temperature,and sulfur capacity.The parameters effects on catalytic oxidation were studied,and the optimized conditions were that Fe3+ concentration 0.08 mg/L,reaction temperature 70°C,pH 9.0,with a absorption solution volume of 50 mL,a gas flow rate 200 mL/min,and H2S mass concentration of 1.58-2.02 mg/m3.
基金Project(BK20140553)supported by Jiangsu Province Science Foundation for Youths,ChinaProject(51478209)supported by the National Natural Science Foundation of China
文摘In order to improve the anchoring force of anchors for carbon fiber reinforced polymer(CFRP) tendons further, a new wedge-bond-type anchor for CFRP tendons was developed. The increment in anchoring force induced by the clamping segment of anchor was studied. Taking the deformation of all parts in clamping segment in the transverse direction into consideration, the calculation formula for the increment of anchoring force was proposed based on the linear elastic hypotheses. The proposed model is verified by experiments and conclusions are drawn that the anchoring force is influenced mainly by the inclination angle of clamping pieces, the length of clamping part and the thickness of bonding medium. Especially, the thickness of bonding medium should be lowered in design to improve the synergistic effect of anchors.
基金supported by the National Basic Research Program of China (Grant No.G2009CB929300)
文摘We propose a way to measure the strength of quantum nonlocal correlation (QNC) based on the characteristic function, which is defined as a response function under the local quantum measurement in a composite system. It is found that the strength of QNC based on the characteristic function is a half-positive-definite function and does not change under any LU operation. Generally, we give a new definition for quantum entanglement using the strength function. Furthermore, we also give a separability-criterion for 2×m-dimensional mixed real matrix. This paper proposes an alternative way for QNC further research.
基金This work was financially supported by the National Natural Science Foundation of China(51773165,51973171)Innovation Capability Support Program of Shaanxi(2018PT-28,2019PT-05).
文摘Lithium-sulfur(Li-S) batteries have attracted considerable attention due to their high energy density(2600 Wh kg-1). However, its commercialization is hindered seriously by the low loading and utilization rate of sulfur cathodes. Herein, we designed the cellulose-based graphene carbon composite aerogel(CCA) self-standing electrode to enhance the performance of Li-S batteries. The CCA contributes to the mass loading and utilization efficiency of sulfur, because of its unique physical structure: low density(0.018 g cm-3), large specific surface area(657.85 m2 g-1), high porosity(96%), and remarkable electrolyte adsorption(42.25 times). Compared to Al(about 49%), the CCA displayed excellent sulfur use efficiency(86%) and could reach to high area capacity of 8.60 mAh cm-2 with 9.11 mgS loading. Meanwhile,the CCA exhibits the excellent potential for pulse sensing applications due to its flexibility and superior sensitivity to electrical response signals.
基金The authors gratefully acknowledge financial support from Ministry of Science and Technology of the People's Republic of China (MOST) (Grants Nos. 2012CB933401 and 2011DFB50300), and National Natural Science Foundation of China (NSFC) (Grants Nos. 50933003 and 51273093).
文摘There is a growing demand for hybrid supercapacitor systems to overcome the energy density limitation of existing-generation electric double layer capacitors (EDLCs), leading to next generation-Ⅱ supercapacitors with minimum sacrifice in power density and cycle life. Here, an advanced graphene-based hybrid system, consisting of a graphene-inserted Li4Ti5O12 (LTO) composite anode (G-LTO) and a three-dimensional porous graphene-sucrose cathode, has been fabricated for the purpose of combining both the benefits of Li-ion batteries (energy source) and supercapacitors (power source). Graphene-based materials play a vital role in both electrodes in respect of the high performance of the hybrid supercapacitor. For example, compared with the theoretical capacity of 175 mA-h.g-1 for pure LTO, the G-LTO nanocomposite delivered excellent reversible capacities of 207, 190, and 176 mA·1h·g-1 at rates of 0.3, 0.5, and 1 C, respectively, in the potential range 1.0-2.5 V vs. Li/Li+; these are among the highest values for LTO-based nano- composites at the same rates and potential range. Based on this, an optimized hybrid supercapacitor was fabricated following the standard industry procedure; this displayed an ultrahigh energy density of 95 Wh·kg-1 at a rate of 0.4 C (2.5 h) over a wide voltage range (0-3 V), and still retained an energy density of 32 Wh·kg-1 at a high rate of up to 100 C, equivalent to a full discharge in 36 s, which is exceptionally fast for hybrid supercapacitors. The excellent performance of this Li-ion hybrid supercapacitor indicates that graphene-based materials may indeed play a significant role in next-generation supercapacitors with excellent electrochemical performance.
基金supported by the National Natural Science Foundation of China(Grant Nos. 61076090 and 60676058)
文摘Spectroscopic ellipsometry (SE), photocarrier radiometry (PCR) and photoluminescence (PL) techniques were employed to measure the ultra-shallow junction (USJ) wafers. These USJ wafers were prepared by As+ ion implantation at energies of 0.5-5 keV, at a dose of 1×1015 As+ /cm 2 and spike annealing. Experimentally the damaged layer of the as-implanted wafer and the recrystallization and activation of the post-annealed wafer were evaluated by SE in the spectral range from 0.27 to 20 m. The PCR amplitude decreased monotonically with the increasing implantation energy. The experimental results also showed that the PCR amplitudes of post-annealed USJ wafers were greatly enhanced, compared to the non-implanted and non-annealed substrate wafer. The PL measurements showed the enhanced PCR signals were attributed to the band-edge emissions of silicon. For explaining the PL enhancement, the electronic transport properties of USJ wafers were extracted via multi-wavelength PCR experiment and fitting. The fitted results showed the decreasing surface recombination velocity and the decreasing diffusion coefficient of the implanted layer contributed to the PCR signal enhancement with the decreasing implantation energy. SE, PCR and PL were proven to be non-destructive metrology tools for characterizing ultra-shallow junctions.
基金supported by the National Natural Science Foundation of China (51702048 and 21603157)the National Basic Research Program of China (2015CB932600)Jiangxi Provincial Department of Education (GJJ170459 and GJJ170457)
文摘Flexible supercapacitors (SCs) are attractive energy storage devices for wearable electronics, but their applications are hindered by their low volumetric energy densities. Two dimensional (2D) non-carbon nanomaterials are the most promising pseudocapacitive materials for high volumetric capacitance electrodes. However, they are poorly conductive and prone to self-stacking, which results in unsatisfactory electrochemical performance. In this work, large-scale V2O5·nH2O ultrathin nanosheets are synthesized by a facile and scalable method and transformed into layered and compact composite films with one-dimensional carbon nanotubes (CNTs). The self-standing films show an optimized volumetric capacitance of 521.0Fcm^-3 with only 10 wt% of CNTs, which is attributed to dramatically enhanced electrical conductivity beyond the electrical percolation threshold, high dispersion of pseudocapacitive V2O5·nH2O nanosheets, and high mass density of the films. All-solid-state flexible SCs made of V2O5·nH2O/CNTs films show a maximum energy density of 17.4WhL^-1.
基金supported by the National Natural Science Foundation of China (51672144, 51572137 and 51702181)the Natural Science Foundation of Shandong Province (ZR2017BB013 and ZR2019BEM042)+2 种基金Higher Educational Science and Technology Program of Shandong Province (J17KA014, J18KA001 and J18KA033)Taishan Scholars Program of Shandong Province (ts201511034)Overseas Taishan Scholars Program
文摘In this paper, we report a one-step electrodeposited synthesis strategy for directly growing NiCoSe2/Ni3Se2 lamella arrays(LAs) on N-doped graphene nanotubes(N-GNTs) as advanced free-standing positive electrode for asymmetric supercapacitors. Benefiting from the synergetic contribution between the distinctive electroactive materials and the skeletons, the as-constructed N-GNTs@NiCoSe2/Ni3-Se2LAs present a specific capacitance of ~1308 F g^-1 at a current density of 1 A g^-1. More importantly, the hybrid electrode also reveals excellent rate capability(~1000 F g^-1 even at 100 A g^-1) and appealing cycling performance(~103.2% of capacitance retention over 10,000 cycles). Furthermore, an asymmetric supercapacitor is fabricated by using the obtained N-GNTs@NiCoSe2/Ni3Se2LAs and active carbon(AC) as the positive and negative electrodes respectively,which holds a high energy density of 42.8 W h kg^-1 at 2.6 k W kg^-1, and superior cycling stability of ~94.4% retention over 10,000 cycles. Accordingly, our fabrication technique and new insight herein can both widen design strategy of multicomponent composite electrode materials and promote the practical applications of the latest emerging transition metal selenides in next-generation high-performance supercapacitors.
文摘A novel all-solid-state, coaxial, fiber-shaped asymmetric supercapacitor has been fabricated by wrapping a conducting carbon paper on a MnO2-modified nanoporous gold wire. This energy wire exhibits high capacitance of 12 mF.cm^-2 and energy density of 5.4 μW.h.cm^-2 with excellent cycling stability. Hierarchical nanostructures and coaxial architectural design facilitate effective contacts between the two core@sheath electrodes and active layers with high flexibility and high performance. This work provides the first example of coaxial fiber- shaped asymmetric supercapacitors with an operation voltage of 1.8 V, and holds great potential for future flexible electronic devices.
基金supported by the National Natural Science Foundation of China(Grant Nos.51206079,51356001)
文摘The identification of the imperfection originating from finite-temperature-difference heat transfer is an indispensable step for both the performance analysis and the better design of a heat exchanger network (HEN) with the aim of energy saving. This study develops a convenient area method for visualizing the heat-transfer imperfection of a HEN in terms of temperature-heat flow diagrams ( T-Q diagrams) by combining the composite curves that have already been used in pinch analysis and the re- cently developed entransy analysis. It is shown that the area between the hot and cold composite curves and the hot and cold utility lines on a T-Q diagram is just equal to the total entransy dissipation rate during the multi-stream heat transfer process occurred in a HEN, and this area can be used to graphically represent the total heat-transfer imperfection of the HEN. The increase in heat recovery or decrease in energy requirements with decreasing the minimum temperature difference, ATmin, of a HEN can then be attributed to a lower entransy dissipation rate, quantitatively represented by the decrease of the area between the composite curves and the utility lines. In addition, the differences between the T-Q diagram and the pre-existing energy level-enthalpy flow diagram (12-H diagram) in the roles of visualizing process imperfection and designing HENs are dis- cussed.
基金We acknowledge the financial support from the National Key R&D Program of China(2016YFA0200102 and 2017YFA0206301)the National Natural Science Foundation of China(51631001,51590882,51672010 and 81421004).
文摘Lithium sulfur(Li-S)batteries have been regarded as a promising next-generation energy storage system with high theoretical specific capacity and energy density,but still facing challenges.In order to make Li-S batteries more competitive,combination of trapping sites and electrocatalytic properties for polysulfides is an effective way to improve the battery performance.In this study,we prepare a type of multifunctional V3S4-nanowire/graphene composites(V3S4-G)by uniformly dispersing V3S4 nanowires on the graphene substrate.This structure contributes to the sufficient exposure of multifunctional V3S4 active sites which can anchor polysulfides and accelerate reaction kinetics.Thus,the Li-S batteries based on the multifunctional V3S4-G sulfur cathode deliver a stable cycling performance and good rate capability.Even at sulfur loading of 3 mg cm^−2,the V3S4-G sulfur cathode possesses a low capacity decay rate of 0.186%per cycle at 0.5 C.