The microstructural development and its effect on the mechanical properties of Al/Cu laminated composite produced by asymmetrical roll bonding and annealing were studied. The composite characterizations were conducted...The microstructural development and its effect on the mechanical properties of Al/Cu laminated composite produced by asymmetrical roll bonding and annealing were studied. The composite characterizations were conducted by transmission electron microscope(TEM), scanning electron microscope(SEM), peeling tests and tensile tests. It is found that the ultra-fine grained laminated composites with tight bonding interface are prepared by the roll bonding technique. The annealing prompts the atomic diffusion in the interface between dissimilar matrixes, and even causes the formation of intermetallic compounds. The interfacial bonding strength increases to the maximum value owing to the interfacial solution strengthening at 300 °C annealing, but sharply decreases by the damage effect of intermetallic compounds at elevated temperatures. The composites obtain high tensile strength due to the Al crystallization grains and Cu twins at 300 °C. At 350 °C annealing, however, the composites get high elongation by the interfacial interlayer with submicron thickness.展开更多
A new kind of laminar metal matrix nanocomposite(MMC) was fabricated by an electrodeposition process with copper and superaligned carbon nanotubes film(SACNT film).The SACNT film was put on a titanium plate and th...A new kind of laminar metal matrix nanocomposite(MMC) was fabricated by an electrodeposition process with copper and superaligned carbon nanotubes film(SACNT film).The SACNT film was put on a titanium plate and then a layer of copper was electrodeposited on it.By repeating the above process,the laminar Cu/SACNT composite which contains dozens or hundreds of layers of copper and SACNT films was obtained.The thickness of a single copper layer was controlled by adjusting the process parameter easily and the thinnest layer is less than 2 μm.The microscopic observation shows that the directional alignment structure of SACNT is retained in the composite perfectly.The mechanical and electrical properties testing results show that the tensile and yield strengths of composites are improved obviously compared with those of pure copper,and the high conductivity is retained.This technology is a potential method to make applicable MMC which characterizes high volume fraction and directional alignment of carbon nanotubes.展开更多
An effective optimization method for the shape/sizing design of composite wing structures is presented with satisfying weight-cutting results. After decoupling, a kind of two-layer cycled optimization strategy suitabl...An effective optimization method for the shape/sizing design of composite wing structures is presented with satisfying weight-cutting results. After decoupling, a kind of two-layer cycled optimization strategy suitable for these integrated shape/sizing optimization is obtained. The uniform design method is used to provide sample points, and approximation models for shape design variables. And the results of sizing optimization are construct- ed with the quadratic response surface method (QRSM). The complex method based on QRSM is used to opti- mize the shape design variables and the criteria method is adopted to optimize the sizing design variables. Compared with the conventional method, the proposed algorithm is more effective and feasible for solving complex composite optimization problems and has good efficiency in weight cutting.展开更多
Deformation behaviors of CNTs/Al alloy composite fabricated by the method of flake powder metallurgy were investigated by hot compression tests, which were performed in the temperature range of 300?550 °C and str...Deformation behaviors of CNTs/Al alloy composite fabricated by the method of flake powder metallurgy were investigated by hot compression tests, which were performed in the temperature range of 300?550 °C and strain rate range of 0.001? 10 s?1 with Gleeble?3500 thermal simulator system. Processing maps of the CNTs/Al alloy at different strains were calculated to study the optimum processing domain. Microstructures before and after hot compressions were characterized by electron backscattered diffraction (EBSD) method. Stress?strain curves indicate that the flow stress increases with the increase of strain rate and the decrease of temperature. The processing maps of the CNTs/Al alloy at different strains show that the optimum processing domain is 500?550 °C, 10 s?1 for hot working. EBSD analysis demonstrates that fully dynamic recrystallization occurs in the optimum processing domain (high strainrate 10 s?1), whereas the main soften mechanism is dynamic recovery at low strain rate (0.001 s?1).展开更多
The deformation behaviors of Al2O3/Al composites were investigated by compressive tests conducted at temperature of 300-450 °C and strain rates of 0.001-1.0 s-1 with Gleeble-1500 D thermal simulator system. The r...The deformation behaviors of Al2O3/Al composites were investigated by compressive tests conducted at temperature of 300-450 °C and strain rates of 0.001-1.0 s-1 with Gleeble-1500 D thermal simulator system. The results show that the flow stress increases with increasing strain rate and decreasing temperature. The hyperbolic sine constitutive equation can describe the flow stress behavior of Al2O3/Al composites, and the deformation activation energy and constitutive equations were calculated. The processing maps of Al2O3/Al-2 μm and Al2O3/Al-1 μm composites at strain of 0.6 were obtained and the optimum processing domains are in ranges of 300-330 °C, 0.007-0.03 s-1 and 335-360 °C, 0.015-0.06 s-1 for hot working, respectively. The instability zones of flow behavior can also be recognized by the maps.展开更多
A hip joint simulator was employed to predict the clinical wear behaviour of carbon/carbon (C/C) composites with needled carbon cloth preform and carbon felt preform. Wear particles generated from the two kinds of C...A hip joint simulator was employed to predict the clinical wear behaviour of carbon/carbon (C/C) composites with needled carbon cloth preform and carbon felt preform. Wear particles generated from the two kinds of C/C composites were isolated and characterised by the size distribution and morphology. The evolvement of wear particles in the hip joint simulator was proposed. The results show that the wear particles from two kinds of C/C composites have a size ranging from submicron to tens of micrometers. The wear particles have various morphologies including broken fiber, fragment fiber, slice pyrolytic carbon and spherical pyrolytic carbon. C/C composites with needled carbon cloth preforms have larger size range and more broken fiber particles and slice pyrolytic carbon particles in comparison with C/C composites with carbon felt preforms. The evolvement of pyrolytic carbon particles is caused by surface regularization, whereas, the evolvement of carbon fiber particles is related to stress direction in the hip joint simulator.展开更多
The hollow α-MnO2 nanoneedle-based microspheres coated with Pd nanoparticles were reported as a novel catalyst for rechargeable lithium-air batteries. The hollow microspheres are composed ofα-MnO2 nanoneedles. Pd na...The hollow α-MnO2 nanoneedle-based microspheres coated with Pd nanoparticles were reported as a novel catalyst for rechargeable lithium-air batteries. The hollow microspheres are composed ofα-MnO2 nanoneedles. Pd nanoparticles are deposited on the hollow microspheres through an aqueous-solution reduction of PdCl2 with NaBH4 at room temperature. The results of TEM, XRD, and EDS show that the Pd nanoparticles are coated on the surface ofα-MnO2 nanoneedles uniformly and the mass fraction of Pd in the Pd-coated α-MnO2 catalyst is about 8.88%. Compared with the counterpart of the hollow α-MnO2 catalyst, the hollow Pd-coated α-MnO2 catalyst improves the energy conversion efficiency and the charge-discharge cycling performance of the air electrode. The initial specific discharge capacity of an air electrode composed of Super P carbon and the as-prepared Pd-coatedα-MnO2 catalyst is 1220 mA·h/g (based on the total electrode mass) at a current density of 0.1 mA/cm2, and the capacity retention rate is about 47.3% after 13 charge-discharge cycles. The results of charge-discharge cycling tests demonstrate that this novel Pd-coatedα-MnO2 catalyst with a hierarchical core-shell structure is a promising catalyst for the lithium-air battery.展开更多
[Objective]The aim was to analyze QTL of agronomic traits in soybean and provide reference for a discussion on soybean genetic mechanism and genetic breeding. [Method]The composite interval mapping method was used for...[Objective]The aim was to analyze QTL of agronomic traits in soybean and provide reference for a discussion on soybean genetic mechanism and genetic breeding. [Method]The composite interval mapping method was used for QTL location and genetic effects analysis on 5 quantitative traits including protein content,fat content,yield,100-grain weight and growth period. [Result]The control of these traits 4,4,1,2,5,a total of 16 QTL loci was detected. The genetic contribution rate was in 7.4%-33.7%,among which,a large main-effect QTL of the genetic contribution rate were located in linkage group I Satt562-Sat_219,Sat_219-Satt496,Sat_219-Satt496 interval of the three control protein content QTL sites,their genetic contribution rates were 29.15%,33.7 % and 31.67% respectively,all from the female parent Hefeng 25 plus minor gene; still in O linkage group Satt477-Satt331,Satt331-Satt153 interval of two control growing period QTL loci,their genetic contribution rates were up to 24.69% and 24.96%,also from the female parent Hefeng 25 plus minor gene. In addition,six QTL sites from M linkage group Satt175 (protein),A1 linkage group Satt684 (oil),F linkage group Satt348 (oil),J linkage group Sat_412 (oil),C1 linkage group Sat_416 (100-grain weight) and C1 linkage group Sat_416 (growth period) marks only 0.01 cm were detected. [Conclusion]QTL sites which had effects on the 5 important agronomic traits in soybean were located.展开更多
基金Projects(50971038,51174058)supported by the National Natural Science Foundation of China
文摘The microstructural development and its effect on the mechanical properties of Al/Cu laminated composite produced by asymmetrical roll bonding and annealing were studied. The composite characterizations were conducted by transmission electron microscope(TEM), scanning electron microscope(SEM), peeling tests and tensile tests. It is found that the ultra-fine grained laminated composites with tight bonding interface are prepared by the roll bonding technique. The annealing prompts the atomic diffusion in the interface between dissimilar matrixes, and even causes the formation of intermetallic compounds. The interfacial bonding strength increases to the maximum value owing to the interfacial solution strengthening at 300 °C annealing, but sharply decreases by the damage effect of intermetallic compounds at elevated temperatures. The composites obtain high tensile strength due to the Al crystallization grains and Cu twins at 300 °C. At 350 °C annealing, however, the composites get high elongation by the interfacial interlayer with submicron thickness.
基金Project(20111080980)supported by the Initiative Scientific Research Program,Tsinghua University,China
文摘A new kind of laminar metal matrix nanocomposite(MMC) was fabricated by an electrodeposition process with copper and superaligned carbon nanotubes film(SACNT film).The SACNT film was put on a titanium plate and then a layer of copper was electrodeposited on it.By repeating the above process,the laminar Cu/SACNT composite which contains dozens or hundreds of layers of copper and SACNT films was obtained.The thickness of a single copper layer was controlled by adjusting the process parameter easily and the thinnest layer is less than 2 μm.The microscopic observation shows that the directional alignment structure of SACNT is retained in the composite perfectly.The mechanical and electrical properties testing results show that the tensile and yield strengths of composites are improved obviously compared with those of pure copper,and the high conductivity is retained.This technology is a potential method to make applicable MMC which characterizes high volume fraction and directional alignment of carbon nanotubes.
文摘An effective optimization method for the shape/sizing design of composite wing structures is presented with satisfying weight-cutting results. After decoupling, a kind of two-layer cycled optimization strategy suitable for these integrated shape/sizing optimization is obtained. The uniform design method is used to provide sample points, and approximation models for shape design variables. And the results of sizing optimization are construct- ed with the quadratic response surface method (QRSM). The complex method based on QRSM is used to opti- mize the shape design variables and the criteria method is adopted to optimize the sizing design variables. Compared with the conventional method, the proposed algorithm is more effective and feasible for solving complex composite optimization problems and has good efficiency in weight cutting.
基金Project(2012AA030311)supported by the National High-tech Research and Development Program of ChinaProject(51421001)supported by the National Natural Science Foundation of ChinaProject(106112015CDJXY130002)supported by the Fundamental Research Funds for the Central Universities,China
文摘Deformation behaviors of CNTs/Al alloy composite fabricated by the method of flake powder metallurgy were investigated by hot compression tests, which were performed in the temperature range of 300?550 °C and strain rate range of 0.001? 10 s?1 with Gleeble?3500 thermal simulator system. Processing maps of the CNTs/Al alloy at different strains were calculated to study the optimum processing domain. Microstructures before and after hot compressions were characterized by electron backscattered diffraction (EBSD) method. Stress?strain curves indicate that the flow stress increases with the increase of strain rate and the decrease of temperature. The processing maps of the CNTs/Al alloy at different strains show that the optimum processing domain is 500?550 °C, 10 s?1 for hot working. EBSD analysis demonstrates that fully dynamic recrystallization occurs in the optimum processing domain (high strainrate 10 s?1), whereas the main soften mechanism is dynamic recovery at low strain rate (0.001 s?1).
基金Project(2012AA030311)supported by the National High-tech Research and Development Program of ChinaProject(2010BB4074)supported by the Natural Science Foundation of Chongqing Municipality,ChinaProject(2010ZD-02)supported by the State Key Laboratory for Advanced Metals and Materials,China
文摘The deformation behaviors of Al2O3/Al composites were investigated by compressive tests conducted at temperature of 300-450 °C and strain rates of 0.001-1.0 s-1 with Gleeble-1500 D thermal simulator system. The results show that the flow stress increases with increasing strain rate and decreasing temperature. The hyperbolic sine constitutive equation can describe the flow stress behavior of Al2O3/Al composites, and the deformation activation energy and constitutive equations were calculated. The processing maps of Al2O3/Al-2 μm and Al2O3/Al-1 μm composites at strain of 0.6 were obtained and the optimum processing domains are in ranges of 300-330 °C, 0.007-0.03 s-1 and 335-360 °C, 0.015-0.06 s-1 for hot working, respectively. The instability zones of flow behavior can also be recognized by the maps.
基金Projects (50832004, 51202194) supported by National Natural Science Foundation of ChinaProject (11-BZ-2012) supported by the Research Fund of the State Key Laboratory of Solidification Processing (NWPU), China+1 种基金Project (T201107) supported by Shenzhen Key Laboratory of Special Functional Materials, Shenzhen University, ChinaProject (B08040) supported by 111 Project of China
文摘A hip joint simulator was employed to predict the clinical wear behaviour of carbon/carbon (C/C) composites with needled carbon cloth preform and carbon felt preform. Wear particles generated from the two kinds of C/C composites were isolated and characterised by the size distribution and morphology. The evolvement of wear particles in the hip joint simulator was proposed. The results show that the wear particles from two kinds of C/C composites have a size ranging from submicron to tens of micrometers. The wear particles have various morphologies including broken fiber, fragment fiber, slice pyrolytic carbon and spherical pyrolytic carbon. C/C composites with needled carbon cloth preforms have larger size range and more broken fiber particles and slice pyrolytic carbon particles in comparison with C/C composites with carbon felt preforms. The evolvement of pyrolytic carbon particles is caused by surface regularization, whereas, the evolvement of carbon fiber particles is related to stress direction in the hip joint simulator.
基金Project(20973124)supported by the National Natural Science Foundation of ChinaProject(KLAEMC-OP201101)supported by the Open Project of Key Laboratory of Advanced Energy Materials Chemistry of Ministry of Education(Nankai University),China
文摘The hollow α-MnO2 nanoneedle-based microspheres coated with Pd nanoparticles were reported as a novel catalyst for rechargeable lithium-air batteries. The hollow microspheres are composed ofα-MnO2 nanoneedles. Pd nanoparticles are deposited on the hollow microspheres through an aqueous-solution reduction of PdCl2 with NaBH4 at room temperature. The results of TEM, XRD, and EDS show that the Pd nanoparticles are coated on the surface ofα-MnO2 nanoneedles uniformly and the mass fraction of Pd in the Pd-coated α-MnO2 catalyst is about 8.88%. Compared with the counterpart of the hollow α-MnO2 catalyst, the hollow Pd-coated α-MnO2 catalyst improves the energy conversion efficiency and the charge-discharge cycling performance of the air electrode. The initial specific discharge capacity of an air electrode composed of Super P carbon and the as-prepared Pd-coatedα-MnO2 catalyst is 1220 mA·h/g (based on the total electrode mass) at a current density of 0.1 mA/cm2, and the capacity retention rate is about 47.3% after 13 charge-discharge cycles. The results of charge-discharge cycling tests demonstrate that this novel Pd-coatedα-MnO2 catalyst with a hierarchical core-shell structure is a promising catalyst for the lithium-air battery.
基金Supported by National Natural Science Foundation of China(30490250)~~
文摘[Objective]The aim was to analyze QTL of agronomic traits in soybean and provide reference for a discussion on soybean genetic mechanism and genetic breeding. [Method]The composite interval mapping method was used for QTL location and genetic effects analysis on 5 quantitative traits including protein content,fat content,yield,100-grain weight and growth period. [Result]The control of these traits 4,4,1,2,5,a total of 16 QTL loci was detected. The genetic contribution rate was in 7.4%-33.7%,among which,a large main-effect QTL of the genetic contribution rate were located in linkage group I Satt562-Sat_219,Sat_219-Satt496,Sat_219-Satt496 interval of the three control protein content QTL sites,their genetic contribution rates were 29.15%,33.7 % and 31.67% respectively,all from the female parent Hefeng 25 plus minor gene; still in O linkage group Satt477-Satt331,Satt331-Satt153 interval of two control growing period QTL loci,their genetic contribution rates were up to 24.69% and 24.96%,also from the female parent Hefeng 25 plus minor gene. In addition,six QTL sites from M linkage group Satt175 (protein),A1 linkage group Satt684 (oil),F linkage group Satt348 (oil),J linkage group Sat_412 (oil),C1 linkage group Sat_416 (100-grain weight) and C1 linkage group Sat_416 (growth period) marks only 0.01 cm were detected. [Conclusion]QTL sites which had effects on the 5 important agronomic traits in soybean were located.