The Nd Fe B/Co multilayer films were prepared by magnetron sputtering. After that, the samples were annealed at 600 ℃ for 20 min. The surface morphology, phase structures and magnetic properties of Mo（50 nm）/[Nd F...The Nd Fe B/Co multilayer films were prepared by magnetron sputtering. After that, the samples were annealed at 600 ℃ for 20 min. The surface morphology, phase structures and magnetic properties of Mo（50 nm）/[Nd Fe B（100 nm）/Co（y）]×10/Mo（50 nm） thin films were researched by AFM, XRD and VSM, respectively. The results show that the films show stronger perpendicular magnetic anisotropy. When the thickness of Co layers is 10 nm, the coercivity Hc⊥ is the maximum, 295 k A/m. However, for y=10-20, the reduced remanence M/Ms of films has increased. When the thickness of Co layers is 20-30 nm, the Nd Fe B/Co multilayer films obtained more superior magnetic properties with M/Ms =0.95.展开更多
Benzoic acid residue is solid waste produced from the production of benzoic acid by oxidizing toluene.Because it contained important chemical raw materials such as benzoic acid,benzyl benzoate and fluorenone,it is nec...Benzoic acid residue is solid waste produced from the production of benzoic acid by oxidizing toluene.Because it contained important chemical raw materials such as benzoic acid,benzyl benzoate and fluorenone,it is necessary to recover them from the residue.In this work the technique featured with high efficiency evaporation and vacuum distillation was developed to obtain total recovery and utilization of the benzoic acid residue.By controlling the operation temperature at 260℃ and the pressure of 16kPa in the rising and falling film evaporators,heavy components separated efficiently from the residue can be polymerized and the light components consisting of 63% of the residue entered into a benzoic acid vacuum distillation column.Keeping the temperature of polymerization at(280±10)℃,coumarone resin was produced after adjusting the softening point according to the market requirements.Vacuum distillation was operated under the following conditions:top temperature at 186℃,top pressure of 16kPa,bottom temperature at 240-250℃,reflux ratio being 3︰1.Benzoic acid of 98% purity was distilled out from the column as a side stream and the bottom product was crude benzyl benzoate.By the developed technique,the benzoic acid residue was splitted into three products,benzoic acid,crude benzyl benzoate and coumarone resin without any surplus waste.展开更多
Using the compound materials and double e-gun evaporation,the compound optical films have been successfully deposited on K9 glass substrate.The refractive index of optical compund films deposited in diffeent parameter...Using the compound materials and double e-gun evaporation,the compound optical films have been successfully deposited on K9 glass substrate.The refractive index of optical compund films deposited in diffeent parameters have been measured and theoretical formula for calculation refractive index of compound films have been derived.It is shown that the experimental curve for the variation of refractive index with wavelength in 0.4￣1.4 μm region and the theoretical one agree very well.Using these films,the laser reflecting mirror has been successfully coated.展开更多
Liquid metal(LM) has shown potential values in different areas. Attempts to implement LM are tending to develop new functions and make it versatile to improve its performance for practical applications.Here, we presen...Liquid metal(LM) has shown potential values in different areas. Attempts to implement LM are tending to develop new functions and make it versatile to improve its performance for practical applications.Here, we present an unprecedented LM-integrated ultra-elastic microfiber with distinctive features for wearable electronics. The microfiber with a polyurethane shell and an LM core was continuously generated by using a sequenced microfluidic spinning and injection method. Due to the precise fluid manipulation of microfluidics, the resultant microfiber could be tailored with tunable morphologies and responsive conductivities. We have demonstrated that the microfiber could act as dynamic force sensor and motion indicator when it was embedded into elastic films. In addition, the values of the LMintegrated ultra-elastic microfiber on energy conversions such as electro-magnetic or electro-thermal conversions have also been realized. These features indicate that LM-integrated microfiber will open up new frontiers in LM-integrated materials and the wearable electronics field.展开更多
文摘The Nd Fe B/Co multilayer films were prepared by magnetron sputtering. After that, the samples were annealed at 600 ℃ for 20 min. The surface morphology, phase structures and magnetic properties of Mo（50 nm）/[Nd Fe B（100 nm）/Co（y）]×10/Mo（50 nm） thin films were researched by AFM, XRD and VSM, respectively. The results show that the films show stronger perpendicular magnetic anisotropy. When the thickness of Co layers is 10 nm, the coercivity Hc⊥ is the maximum, 295 k A/m. However, for y=10-20, the reduced remanence M/Ms of films has increased. When the thickness of Co layers is 20-30 nm, the Nd Fe B/Co multilayer films obtained more superior magnetic properties with M/Ms =0.95.
文摘Benzoic acid residue is solid waste produced from the production of benzoic acid by oxidizing toluene.Because it contained important chemical raw materials such as benzoic acid,benzyl benzoate and fluorenone,it is necessary to recover them from the residue.In this work the technique featured with high efficiency evaporation and vacuum distillation was developed to obtain total recovery and utilization of the benzoic acid residue.By controlling the operation temperature at 260℃ and the pressure of 16kPa in the rising and falling film evaporators,heavy components separated efficiently from the residue can be polymerized and the light components consisting of 63% of the residue entered into a benzoic acid vacuum distillation column.Keeping the temperature of polymerization at(280±10)℃,coumarone resin was produced after adjusting the softening point according to the market requirements.Vacuum distillation was operated under the following conditions:top temperature at 186℃,top pressure of 16kPa,bottom temperature at 240-250℃,reflux ratio being 3︰1.Benzoic acid of 98% purity was distilled out from the column as a side stream and the bottom product was crude benzyl benzoate.By the developed technique,the benzoic acid residue was splitted into three products,benzoic acid,crude benzyl benzoate and coumarone resin without any surplus waste.
文摘Using the compound materials and double e-gun evaporation,the compound optical films have been successfully deposited on K9 glass substrate.The refractive index of optical compund films deposited in diffeent parameters have been measured and theoretical formula for calculation refractive index of compound films have been derived.It is shown that the experimental curve for the variation of refractive index with wavelength in 0.4￣1.4 μm region and the theoretical one agree very well.Using these films,the laser reflecting mirror has been successfully coated.
基金supported by the National Natural Science Foundation of China (61927805)the Natural Science Foundation of Jiangsu (BE2018707)+1 种基金the Scientific Research Foundation of Nanjing Universitythe Scientific Research Foundation of Drum Tower Hospital。
文摘Liquid metal(LM) has shown potential values in different areas. Attempts to implement LM are tending to develop new functions and make it versatile to improve its performance for practical applications.Here, we present an unprecedented LM-integrated ultra-elastic microfiber with distinctive features for wearable electronics. The microfiber with a polyurethane shell and an LM core was continuously generated by using a sequenced microfluidic spinning and injection method. Due to the precise fluid manipulation of microfluidics, the resultant microfiber could be tailored with tunable morphologies and responsive conductivities. We have demonstrated that the microfiber could act as dynamic force sensor and motion indicator when it was embedded into elastic films. In addition, the values of the LMintegrated ultra-elastic microfiber on energy conversions such as electro-magnetic or electro-thermal conversions have also been realized. These features indicate that LM-integrated microfiber will open up new frontiers in LM-integrated materials and the wearable electronics field.
