The explosion inside tunnel would generate blast wave which transmits through the longitudinal tunnel. Because of the close-in effects of the tunnel and the reflection by the confining tunnel structure, blast wave pro...The explosion inside tunnel would generate blast wave which transmits through the longitudinal tunnel. Because of the close-in effects of the tunnel and the reflection by the confining tunnel structure, blast wave propagation inside tunnel is distinguished from that in air. When the explosion happens inside tunnel, the overpressure peak is higher than that of explosion happening in air. The continuance time of the blast wave also becomes longer. With the help of the numerical simulation finite element software LS-DYNA, a three-dimensional nonlinear dynamic simulation analysis for an explosion experiment inside tunnel was carried out. LS-DYNA is a fully integrated analysis program specifically designed for nonlinear dynamics and large strain problems. Compared with the experimental results, the simulation results have made the material parameters of numerical simulation model available. By using the model and the same material parameters, many results were adopted by calculating the model under different TNT explosion dynamites. Then the method of dimensional analysis was used for the simulation results. As overpressures of the explosion blast wave are the governing factor in the tunnel responses, a formula for the explosion blast wave over-pressure at a certain distance from the detonation center point inside the tunnel was derived by using the dimensional analysis theory. By comparing the results computed by the formula with experimental results which were obtained before, the formula was proved to be very applicable at some instance. The research may be helpful to estimate rapidly the effect of internal explosion of tunnel on the structure.展开更多
Rapid and cost effective quantification of lignocellulosic components （cellulose, hemicelluloses and lignin） of agricultural biomass （barley, canola, oat and wheat） is essential to determine the effect of various ...Rapid and cost effective quantification of lignocellulosic components （cellulose, hemicelluloses and lignin） of agricultural biomass （barley, canola, oat and wheat） is essential to determine the effect of various pre-treatments （such as steam explosion） on biomass used as feedstock for the biofuel industry. Fourier Transformed Infrared （FTIR） spectroscopy was considered as an option to achieve this objective. Regression equations having R2 values of 0.89, 0.99 and 0.98 were developed to predict the cellulose, hemicelluloses and lignin compounds of biomass, respectively. The average absolute difference in predicted and measured cellulose, hemicellulose and lignin in agricultural biomass was 7.5%, 2.5%, and 3.8%, respectively.展开更多
Based on the full optimized molecular geometrical structures at the DFT-B3LYP/6- 311＋G^＊＊ level, there exists intramolecular hydrogen bond interaction for cyclic 2-diazo- 4,6-dinitrophenol. The assigned infrared sp...Based on the full optimized molecular geometrical structures at the DFT-B3LYP/6- 311＋G^＊＊ level, there exists intramolecular hydrogen bond interaction for cyclic 2-diazo- 4,6-dinitrophenol. The assigned infrared spectrum is obtained and used to compute the thermodynamic properties. The results show that there are four main characteristic regions in the calculated IR spectra of the title compound. The detonation velocities and pressures are also evaluated by using Kamlet-Jacobs equations based on the calculated density and condensed phase heat of formation. Thermal stability and the pyrolysis mechanism of 2- diazo-4,6-dinitrophenol are investigated by calculating the bond dissociation energies at the B3LYP/6-311＋G^＊＊ level.展开更多
基金Supported by National Natural Science Foundation of China(No.50678094)
文摘The explosion inside tunnel would generate blast wave which transmits through the longitudinal tunnel. Because of the close-in effects of the tunnel and the reflection by the confining tunnel structure, blast wave propagation inside tunnel is distinguished from that in air. When the explosion happens inside tunnel, the overpressure peak is higher than that of explosion happening in air. The continuance time of the blast wave also becomes longer. With the help of the numerical simulation finite element software LS-DYNA, a three-dimensional nonlinear dynamic simulation analysis for an explosion experiment inside tunnel was carried out. LS-DYNA is a fully integrated analysis program specifically designed for nonlinear dynamics and large strain problems. Compared with the experimental results, the simulation results have made the material parameters of numerical simulation model available. By using the model and the same material parameters, many results were adopted by calculating the model under different TNT explosion dynamites. Then the method of dimensional analysis was used for the simulation results. As overpressures of the explosion blast wave are the governing factor in the tunnel responses, a formula for the explosion blast wave over-pressure at a certain distance from the detonation center point inside the tunnel was derived by using the dimensional analysis theory. By comparing the results computed by the formula with experimental results which were obtained before, the formula was proved to be very applicable at some instance. The research may be helpful to estimate rapidly the effect of internal explosion of tunnel on the structure.
文摘Rapid and cost effective quantification of lignocellulosic components （cellulose, hemicelluloses and lignin） of agricultural biomass （barley, canola, oat and wheat） is essential to determine the effect of various pre-treatments （such as steam explosion） on biomass used as feedstock for the biofuel industry. Fourier Transformed Infrared （FTIR） spectroscopy was considered as an option to achieve this objective. Regression equations having R2 values of 0.89, 0.99 and 0.98 were developed to predict the cellulose, hemicelluloses and lignin compounds of biomass, respectively. The average absolute difference in predicted and measured cellulose, hemicellulose and lignin in agricultural biomass was 7.5%, 2.5%, and 3.8%, respectively.
文摘Based on the full optimized molecular geometrical structures at the DFT-B3LYP/6- 311＋G^＊＊ level, there exists intramolecular hydrogen bond interaction for cyclic 2-diazo- 4,6-dinitrophenol. The assigned infrared spectrum is obtained and used to compute the thermodynamic properties. The results show that there are four main characteristic regions in the calculated IR spectra of the title compound. The detonation velocities and pressures are also evaluated by using Kamlet-Jacobs equations based on the calculated density and condensed phase heat of formation. Thermal stability and the pyrolysis mechanism of 2- diazo-4,6-dinitrophenol are investigated by calculating the bond dissociation energies at the B3LYP/6-311＋G^＊＊ level.
