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六氟环氧丙烷三聚体羧酸(HFPO-TA)污染现状和生物毒性研究进展
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作者 刘梦琳 王冰菁 +3 位作者 宿琪 索秉旭 冯精兰 余浩 《环境化学》 CAS CSCD 北大核心 2024年第5期1415-1428,共14页
全氟/多氟化合物(per-and polyfluoroalkyl substances,PFAS)是一类具有优良表面活性和稳定性的有机化合物,广泛应用于工业和消费领域,全氟辛烷羧酸(perfluorooctanoic acid,PFOA)是具有代表性的一类PFAS.由于具有持久性、生物蓄积性、... 全氟/多氟化合物(per-and polyfluoroalkyl substances,PFAS)是一类具有优良表面活性和稳定性的有机化合物,广泛应用于工业和消费领域,全氟辛烷羧酸(perfluorooctanoic acid,PFOA)是具有代表性的一类PFAS.由于具有持久性、生物蓄积性、长距离迁移和生物毒性,PFOA已被限制生产和使用.六氟环氧丙烷三聚体羧酸(hexafluoropropylene oxide trimer acid,HFPO-TA)是一类新型的PFOA替代品.HFPO-TA在全球范围内的环境介质中广泛存在,在一些介质中的浓度接近甚至高于PFOA.HFPOTA能在生物体内蓄积并可产生生物毒性效应,由于其独特的化学结构和理化性质,HFPO-TA的生物积累潜能和生物毒性强于PFOA.本文从HFPO-TA的生产、用途、环境归趋、环境介质和生物体内的污染现状、生物毒性和降解进行综述,并对未来研究趋势和发展方向进行展望,为研究HFPO-TA在生物体内富集与转化机制和毒理学评价提供参考依据. 展开更多
关键词 六氟环氧丙烷三聚体羧酸 多介质分布 生物富集 生物毒性 降解
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巢湖生态系统中微量有机污染物的研究进展 被引量:5
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作者 贺勇 徐福留 +4 位作者 何伟 秦宁 孔祥臻 刘文秀 王卿梅 《生态毒理学报》 CAS CSCD 北大核心 2016年第2期111-123,共13页
本文综述了目前巢湖生态系统中微量有机污染物研究的主要进展。巢湖微量有机污染物研究起步较晚,但发展较快。目前已研究的微量有机污染物包括有机氯农药、多氯联苯、多环芳烃、多溴联苯醚、邻苯二甲酸酯、全氟烷基酸类物质、四溴双酚A... 本文综述了目前巢湖生态系统中微量有机污染物研究的主要进展。巢湖微量有机污染物研究起步较晚,但发展较快。目前已研究的微量有机污染物包括有机氯农药、多氯联苯、多环芳烃、多溴联苯醚、邻苯二甲酸酯、全氟烷基酸类物质、四溴双酚A、抗生素和有机磷农药。研究内容主要包括水、大气、降尘、沉积物、悬浮物、水生生物等多介质分布、来源解析、跨界面迁移、归趋模拟与风险评估等方面。期望本文的综述,可以为巢湖微量有机污染物风险管理和水质改善提供重要决策支撑,对于在其他湖泊开展此类研究有所裨益。 展开更多
关键词 巢湖 微量有机污染物 多介质分布 来源解析 跨界面迁移 归趋模拟 风险评估
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Characterizations of PSD Fractal of Porous Medium 被引量:3
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作者 黄国强 徐世民 李鑫钢 《Transactions of Tianjin University》 EI CAS 2003年第3期170-173,共4页
A volume-based method for measuring particle-size distribution (PSD) fractal dimensions of porous mediums was developed by employing laser size-analyzing technology. Compared with conventional approaches of using hydr... A volume-based method for measuring particle-size distribution (PSD) fractal dimensions of porous mediums was developed by employing laser size-analyzing technology. Compared with conventional approaches of using hydrometer or screen to determine PSD, this method can avoid calculation errors and measure smaller size-scale porous medium. In this paper the experimental porous mediums were brown soil, kaolin and sand soil. A micro-order of magnitude (10 -5 m) in particle-size interval could be shown in PSD results of brown soil and kaolin. The experiments indicated that brown soil had a nearly mono-fractal PSD character, while kaolin and sand soil showed multi-fractal PSD characters. By the adsorption isotherm experiments, the PSD fractal dimensions of the sand soil were also found to keep a linearly increasing relation with the linear adsorptive parameters of the soils in different intervals to adsorb benzene from aqueous solution. 展开更多
关键词 FRACTAL porous medium particle-size distribution ADSORPTION
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Resistivity in Formation and Decomposition of Natural Gas Hydrate in Porous Medium 被引量:14
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作者 李淑霞 夏晞冉 +2 位作者 玄建 刘亚平 李清平 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2010年第1期39-42,共4页
A new one-dimensional system for resistivity measurement for natural gas hydrate(NGH)exploitation is designed,which is used to study the formation and decomposition processes of NGH.The experimental results verify the... A new one-dimensional system for resistivity measurement for natural gas hydrate(NGH)exploitation is designed,which is used to study the formation and decomposition processes of NGH.The experimental results verify the feasibility of the measurement method,especially in monitoring the nucleation and growth of the NGH. Isovolumetric formation experiment of NGH is performed at 2°C and 7.8 MPa.Before the NGH formation,the initial resistivity is measured to be 4-7Ω·m,which declines to the minimum value of 2-3Ω·m when NGH begins to nucleate after the pressure is reduced to 3.3 MPa.As the NGH grows,the resistivity increases to a great extent,and finally it keeps at 11-13Ω·m,indicating the completion of the formation process.The NGH decomposition experiment is then performed.When the outlet pressure decreases,NGH begins to decompose,accordingly,the resistivity declines gradually,and is at 5-9Ω·m when the decomposition process ends,which is slightly higher than the resistivity value before the formation of NGH.The occurrence and distribution uniformity of NGH are determined by the distribution and magnitude of the resistivity measured on an one-dimensional sand-packed model.This study tackles the accurate estimation for the distribution of NGH in porous medium,and provides an experimental basis for further study on NGH exploitation in the future. 展开更多
关键词 RESISTIVITY natural gas hydrate FORMATION decomposition by depressurization
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Numerical Simulation for Thermal Distribution of Air-conditioner Outdoor Units 被引量:4
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作者 Li-Ge Tong Zhen Zhang +3 位作者 Li Wang Shao-Wu Yin Jiangfeng Yu Chun Liu 《Journal of Thermal Science》 SCIE EI CAS CSCD 2012年第3期269-275,共7页
Air-conditioners used in high-rise residential or office buildings often have outdoor units installed on the side-walls or roofs in the confined space of the buildings.The heat released from the outdoor units causes t... Air-conditioners used in high-rise residential or office buildings often have outdoor units installed on the side-walls or roofs in the confined space of the buildings.The heat released from the outdoor units causes the tem-perature rise in the confined installation space and leads to uncomfortable thermal environment and deteriorative performance of air-conditioners.The factors affecting the performance of air-conditioners are the heat released from the outdoor units,the solar radiation and the ventilation of the confined installation space,which are inves-tigated in this study and simulated by FLUENT using the porous model and discrete ordinates (DO) radiation model.It is proved that the porous model is more reliable than the solid model.The optimal installation distance from the supporting wall is obtained.The average temperature of the exit without wind is 1.18% higher than that with wind.The results show that the heat released from the outdoor units and the ventilation of the confined in-stallation space are the main factors affecting the thermal environment in the confined installation space.The in-fluence of the solar radiation is negligible. 展开更多
关键词 high-rise building air conditioner heat rejection porous model solar radiation
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