In order to better understand the prevailing mechanism of CO2 storage in coal and estimate CO2 sequestration capacity of a coal seam and enhanced coalbed methane recovery （ECBM） with CO2 injection into coal, we inve...In order to better understand the prevailing mechanism of CO2 storage in coal and estimate CO2 sequestration capacity of a coal seam and enhanced coalbed methane recovery （ECBM） with CO2 injection into coal, we investigated the preferential adsorption of CH4 and CO2 on coals. Adsorption of pure CO2, CH4 and their binary mixtures on high-rank coals from Qinshui Basin in China were employed to study the preferential adsorption behaviour. Multiple regression equations were presented to predict CH4 equi- librium concentration from equilibrium pressure and its initial-composition in feed gas. The results show that preferential adsorption of CO2 on coals over the entire pressure range under competitive sorption conditions was observed, however, preferential adsorption of CH4 over CO2 on low-volatile bituminous coal from higher CH4-compostion in source gas was found at up to 1O MPa pressure. Preferential adsorp- tion of CO2 increases with increase of CH4 concentration in source gas, and decreases with increasing pressure. Although there was no systematic investigation of the effect of coal rank on preferential adsorp- tion, there are obvious differences in preferential adsorption of gas between low-volatile bituminous coal and anthracite. The obtained preferential adsorption gives rise to the assumption that CO2 sequestration in coal beds with subsequent CO2-ECBM might be an ootion in Qinshui Basins, China.展开更多
It has been suggested that microcracks do play a key role in the triggering of the bone remodeling process.In order to evaluate the influence of microcracks on the poroelastic behaviors of an osteon,a finite element m...It has been suggested that microcracks do play a key role in the triggering of the bone remodeling process.In order to evaluate the influence of microcracks on the poroelastic behaviors of an osteon,a finite element model is established and investigated by using the Comsol Multiphysics software.The findings show that the presence of a microcrack in the osteon wall strongly modifies(enlarges)its local fluid pressure and velocity.Especially,the pressure and velocity amplitudes produced in the microcracked region are larger than those of the non-cracked region.Thus,this study can also be used for proposing a likely mechanism that bone can sense the changes of surrounding mechanical environments.展开更多
基金supported by the National Natural Science Foundation of China(Nos.51174127 and 21176145)the Natural Science Foundation of Shandong Province(No.ZR2011DM005)the Open Research Fund Program of Key Laboratory of Mine Disaster Prevention and Control(Shandong University of Science and Technology)(No.MDPC0806)
文摘In order to better understand the prevailing mechanism of CO2 storage in coal and estimate CO2 sequestration capacity of a coal seam and enhanced coalbed methane recovery （ECBM） with CO2 injection into coal, we investigated the preferential adsorption of CH4 and CO2 on coals. Adsorption of pure CO2, CH4 and their binary mixtures on high-rank coals from Qinshui Basin in China were employed to study the preferential adsorption behaviour. Multiple regression equations were presented to predict CH4 equi- librium concentration from equilibrium pressure and its initial-composition in feed gas. The results show that preferential adsorption of CO2 on coals over the entire pressure range under competitive sorption conditions was observed, however, preferential adsorption of CH4 over CO2 on low-volatile bituminous coal from higher CH4-compostion in source gas was found at up to 1O MPa pressure. Preferential adsorp- tion of CO2 increases with increase of CH4 concentration in source gas, and decreases with increasing pressure. Although there was no systematic investigation of the effect of coal rank on preferential adsorp- tion, there are obvious differences in preferential adsorption of gas between low-volatile bituminous coal and anthracite. The obtained preferential adsorption gives rise to the assumption that CO2 sequestration in coal beds with subsequent CO2-ECBM might be an ootion in Qinshui Basins, China.
基金supported by the program for the OIT of Higher Learning Institutions of Shanxi,the National Natural Science Foundation of China(Grant Nos.11302143 and 11472185)the Natural Science Foundation of Shanxi(Grant No.2014021013)
文摘It has been suggested that microcracks do play a key role in the triggering of the bone remodeling process.In order to evaluate the influence of microcracks on the poroelastic behaviors of an osteon,a finite element model is established and investigated by using the Comsol Multiphysics software.The findings show that the presence of a microcrack in the osteon wall strongly modifies(enlarges)its local fluid pressure and velocity.Especially,the pressure and velocity amplitudes produced in the microcracked region are larger than those of the non-cracked region.Thus,this study can also be used for proposing a likely mechanism that bone can sense the changes of surrounding mechanical environments.
