The European Space Agency will launch the first salinity satellite for remotely sensing the global soil moisture and ocean salinity (SMOS) at a sun-synchronous orbit in 2009. One of the payloads on the satellite is a ...The European Space Agency will launch the first salinity satellite for remotely sensing the global soil moisture and ocean salinity (SMOS) at a sun-synchronous orbit in 2009. One of the payloads on the satellite is a synthetic aperture microwave radiometer (MIRAS), which is an innovative instrument designed as a two-dimensional (2D) interferometer for acquiring brightness temperature (TB) at L-band (1.4 GHz). MIRAS allows measuring TB at a series of incidences for full polarizations. As the satellite travels, a given location within the 2D field of view is observed from different incidence angles. The authors develop a new scheme to retrieve the sea-surface salinity (SSS) from SMOS's TB at multi-incidence angles in a pixel, utilizing the properties of emissivity changing with incidence angles. All measurements of a given Stokes parameter in a pixel are first fitted to incidence angles in three order polynomial, and then the smoothed data are used for retrieving the SSS. The procedure will remove the random noise in TB greatly. Furthermore, the new method shows that the error in retrieved SSS is very sensitive to the system biases in the calibrated TB of the sensor, but the error in the retrieval is also a system bias, which can be corrected by post-launch validation. Therefore, this method may also serve as a means to evaluate the calibration precision in TB.展开更多
Sum frequency generation(SFG) vibrational spectroscopy has been proven an excellent tool to measure the molecular structures, symmetries and orientations at surfaces/interfaces because of its strong polarization depen...Sum frequency generation(SFG) vibrational spectroscopy has been proven an excellent tool to measure the molecular structures, symmetries and orientations at surfaces/interfaces because of its strong polarization dependence. However, a precise quantitative analysis of SFG spectral intensity and molecular orientation at interfaces must be carefully performed. In this work, we summarized the parameters and factors that are often ignored and illustrated them by evaluating studies of CO adsorption on the(111) facet of platinum(Pt) and palladium(Pd) single crystals at the gas(ultra-high vacuum, UHV)/solid interfaces and methanol(water) adsorption at the air/liquid(solid/liquid) interfaces in the presence of sodium iodide(chloride) salts. To intuitively estimate the influence of incidence angles and refractive indices on the SFG intensity, solely a defined factor of|Fyyz| was discussed, which can be individually separated from the macroscopic second-order non-linear susceptibility χ yyz^(2) term and represents the SSP intensity. Moreover, effects of refractive indices and the molecular hyperpolarizability ratio(R) were discussed in the orientational analysis of interfacial CO and methanol molecules. When IPPP/ISSP was identical, molecules with a larger R had smaller tilting angles(q) on Pt(assuming q < 51°), and CO molecules on Pd would tilt much closer to the surface than they did on Pt. A total internal reflection(TIR) geometry enhanced the SFG intensity, but it also amplified the influence of refractive index on SFG intensity at the solid(silica)/liquid interface. The refractive index and R-value had similar influence on the methanol orientation in the presence of sodium iodide salts at air/liquid and solid/liquid interfaces. This work should provide a guideline for analyzing the orientation of molecules with different R, which are adsorbed on catalysts or located at liquid interfaces involving changes of refractive indices.展开更多
文摘The European Space Agency will launch the first salinity satellite for remotely sensing the global soil moisture and ocean salinity (SMOS) at a sun-synchronous orbit in 2009. One of the payloads on the satellite is a synthetic aperture microwave radiometer (MIRAS), which is an innovative instrument designed as a two-dimensional (2D) interferometer for acquiring brightness temperature (TB) at L-band (1.4 GHz). MIRAS allows measuring TB at a series of incidences for full polarizations. As the satellite travels, a given location within the 2D field of view is observed from different incidence angles. The authors develop a new scheme to retrieve the sea-surface salinity (SSS) from SMOS's TB at multi-incidence angles in a pixel, utilizing the properties of emissivity changing with incidence angles. All measurements of a given Stokes parameter in a pixel are first fitted to incidence angles in three order polynomial, and then the smoothed data are used for retrieving the SSS. The procedure will remove the random noise in TB greatly. Furthermore, the new method shows that the error in retrieved SSS is very sensitive to the system biases in the calibrated TB of the sensor, but the error in the retrieval is also a system bias, which can be corrected by post-launch validation. Therefore, this method may also serve as a means to evaluate the calibration precision in TB.
基金in part supported by the Austrian Science Fund FWF through projects Com Cat(I 1041-N28)and DK+Solids4Fun(W1243)by TU Wien via the Innovative Project “SFG Spectroscopy”
文摘Sum frequency generation(SFG) vibrational spectroscopy has been proven an excellent tool to measure the molecular structures, symmetries and orientations at surfaces/interfaces because of its strong polarization dependence. However, a precise quantitative analysis of SFG spectral intensity and molecular orientation at interfaces must be carefully performed. In this work, we summarized the parameters and factors that are often ignored and illustrated them by evaluating studies of CO adsorption on the(111) facet of platinum(Pt) and palladium(Pd) single crystals at the gas(ultra-high vacuum, UHV)/solid interfaces and methanol(water) adsorption at the air/liquid(solid/liquid) interfaces in the presence of sodium iodide(chloride) salts. To intuitively estimate the influence of incidence angles and refractive indices on the SFG intensity, solely a defined factor of|Fyyz| was discussed, which can be individually separated from the macroscopic second-order non-linear susceptibility χ yyz^(2) term and represents the SSP intensity. Moreover, effects of refractive indices and the molecular hyperpolarizability ratio(R) were discussed in the orientational analysis of interfacial CO and methanol molecules. When IPPP/ISSP was identical, molecules with a larger R had smaller tilting angles(q) on Pt(assuming q < 51°), and CO molecules on Pd would tilt much closer to the surface than they did on Pt. A total internal reflection(TIR) geometry enhanced the SFG intensity, but it also amplified the influence of refractive index on SFG intensity at the solid(silica)/liquid interface. The refractive index and R-value had similar influence on the methanol orientation in the presence of sodium iodide salts at air/liquid and solid/liquid interfaces. This work should provide a guideline for analyzing the orientation of molecules with different R, which are adsorbed on catalysts or located at liquid interfaces involving changes of refractive indices.
