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交联海藻酸钠固定化的腐殖酸多孔性薄膜对铀(Ⅵ)的吸附性能及机理 被引量:16
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作者 谢水波 段毅 +2 位作者 刘迎九 王劲松 刘金香 《化工学报》 EI CAS CSCD 北大核心 2013年第7期2488-2496,共9页
采用戊二醛交联海藻酸钠固定化的腐殖酸,制备得到多孔性薄膜(GA-HA/SA),用于去除含铀废水中的铀(Ⅵ)。通过静态吸附实验,研究了pH值、初始浓度、接触时间、温度对GA-HA/SA吸附U(Ⅵ)效果的影响,进行了吸附过程的热力学与动力学分析;通过... 采用戊二醛交联海藻酸钠固定化的腐殖酸,制备得到多孔性薄膜(GA-HA/SA),用于去除含铀废水中的铀(Ⅵ)。通过静态吸附实验,研究了pH值、初始浓度、接触时间、温度对GA-HA/SA吸附U(Ⅵ)效果的影响,进行了吸附过程的热力学与动力学分析;通过红外光谱(FTIR)、扫描电镜(SEM)、X射线能谱(EDS)探讨了相关吸附机理。实验结果表明,pH值为6时吸附效果最好,吸附在60min基本达到平衡。吸附过程符合Langmuir和Dubinin-Radushkevich(D-R)等温模型;25℃时,最大吸附容量为312.5mg·g-1。吸附动力学过程符合准二级速率方程(R2>0.99),吸附速率的控速步骤为颗粒内扩散。GA-HA/SA对U(Ⅵ)的吸附是自发的吸热反应。SEM-EDS、FTIR和D-R模型分析结果表明,与U(Ⅵ)相互作用的基团主要是羧基,且GA-HA/SA吸附U(Ⅵ)的机理表现为离子交换。 展开更多
关键词 多孔性薄膜 铀(Ⅵ) 热力学 动力学 速率控制 吸附机理
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TiO_2多孔性薄膜光催化降解低浓度甲醛 被引量:12
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作者 杨庆 郭奋 +2 位作者 邢颖 咸才军 郭保文 《环境科学》 EI CAS CSCD 北大核心 2005年第4期35-39,共5页
采用不锈钢丝网负载TiO2多孔性薄膜光催化剂,在间歇式循环光催化反应系统中研究了气相中低浓度甲醛的光催化降解,考察了催化剂载体、催化剂镀膜次数、甲醛初始浓度和光源等因素的影响,并对光催化剂的稳定性进行了研究.结果表明,甲醛降... 采用不锈钢丝网负载TiO2多孔性薄膜光催化剂,在间歇式循环光催化反应系统中研究了气相中低浓度甲醛的光催化降解,考察了催化剂载体、催化剂镀膜次数、甲醛初始浓度和光源等因素的影响,并对光催化剂的稳定性进行了研究.结果表明,甲醛降解率随着丝网目数的增加而增大;丝网使用数量的增多会提高甲醛降解率,但其影响随着丝网数量的增多而逐渐减弱;催化剂镀膜次数从1次增加到6次时,光催化剂的活性先上升后下降;当甲醛初始浓度在1·34~10·72mg/m3范围内增加时,甲醛的浓度变化值相应明显增大,但甲醛降解率先升高继而下降;光源采用杀菌灯时甲醛降解率比黑光灯时约高出19·0%,增大光强度使甲醛降解率提高了20·5%;光催化剂连续使用4次后,仍保持较高的催化活性. 展开更多
关键词 TiO2多孔性薄膜 光催化降解 甲醛 挥发性有机物 空气净化
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TiO_2多孔性薄膜的制备及其环境净化性能研究 被引量:2
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作者 杨庆 郭奋 +1 位作者 邢颖 咸才军 《北京化工大学学报(自然科学版)》 CAS CSCD 北大核心 2005年第5期19-23,共5页
采用溶胶-凝胶工艺,以聚乙二醇(PEG)为造孔剂,不锈钢丝网为金属基底,制备了TiO2多孔性薄膜。通过IR,SEM,BET,Raman光谱等测试方法对TiO2多孔性薄膜进行了表征。实验结果表明,通过控制制备条件得到的TiO2薄膜具有锐钛矿晶型和多孔性结构... 采用溶胶-凝胶工艺,以聚乙二醇(PEG)为造孔剂,不锈钢丝网为金属基底,制备了TiO2多孔性薄膜。通过IR,SEM,BET,Raman光谱等测试方法对TiO2多孔性薄膜进行了表征。实验结果表明,通过控制制备条件得到的TiO2薄膜具有锐钛矿晶型和多孔性结构。TiO2多孔性薄膜的光催化性能与煅烧温度和镀膜次数密切相关。450℃热处理、镀膜4次的TiO2多孔性薄膜具有较高的活性和稳定性,其对气相甲醛的降解率比普通TiO2薄膜高28.8%,在TiO2多孔性薄膜连续使用4次后,甲醛的降解率仍维持在80%以上。 展开更多
关键词 TiO2多孔性薄膜 金属基底 溶胶-凝胶工艺 气相光催化
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Mathematical Modeling of Onset of Convection in a Porous Layer with Viscosity Variation
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作者 Fariborz Rashidi Ali Bahrami Chemical Engineering Department, Amirkabir University of Technology, 424 Hafez Ave., Tehran, IRAN 《Journal of Thermal Science》 SCIE EI CAS CSCD 2000年第2期141-145,共5页
Instability theory is applied to diffusion-convection phenomenon in porous media, where the area in direction of transfer is large and viscosity of the oil varies due to gas dissolution. An important application of th... Instability theory is applied to diffusion-convection phenomenon in porous media, where the area in direction of transfer is large and viscosity of the oil varies due to gas dissolution. An important application of this theory arises where diffusion-convection is employed as an EOR technique in oil reservoirs. As a bed of gas is formed below a colunm of oil, gas starts to diffuse into the oil. Therefore, the oil becomes lighter and an inverse gradient of density is developed as more gas diffuses in. Although this inverse density gradient is potentially unstable, convection will not initiate until the gradient extends to a certain value. The condition at which convection begins is known as "the onset of convectin" and is well specified by the dimensionless Rayleigh number. In this study, an instability analysis is made for convection-diffusion in large porous media. Unlike Other studies where viscosity is assumed constant in this work viscosity is postulated to be a function of gas concentration. It is shown that the mathematical model developed reduces to previous models if the viscosity vacations are ignored. 展开更多
关键词 instability theory flat porous media Rayleigh number onset of convection viscosity variations.
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Structure and photoluminescence properties of InN films grown on porous silicon by MOCVD 被引量:1
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作者 王军 张红燕 《Optoelectronics Letters》 EI 2017年第3期214-216,共3页
In this work, indium nitride(InN) films were successfully grown on porous silicon(PS) using metal oxide chemical vapor deposition(MOCVD) method. Room temperature photoluminescence(PL) and field emission scanning elect... In this work, indium nitride(InN) films were successfully grown on porous silicon(PS) using metal oxide chemical vapor deposition(MOCVD) method. Room temperature photoluminescence(PL) and field emission scanning electron microscopy(FESEM) analyses are performed to investigate the optical, structural and morphological properties of the InN/PS nanocomposites. FESEM images show that the pore size of InN/PS nanocomposites is usually less than 4 μm in diameter, and the overall thickness is approximately 40 μm. The InN nanoparticles penetrate uniformly into PS layer and adhere to them very well. Nitrogen(N) and indium(In) can be detected by energy dispersive spectrometer(EDS). An important gradual decrease of the PL intensity for PS occurs with the increase of oxidation time, and the PL intensity of PS is quenched after 24 h oxidization. However, there is a strong PL intensity of InN/PS nanocomposites at 430 nm(2.88 eV), which means that PS substrate can influence the structural and optical properties of the InN, and the grown InN on PS substrate has good optical quality. 展开更多
关键词 MOCVD FESEM indium adhere nitride spectrometer dispersive uniformly Room porous
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