园林废弃物经微生物发酵制得的有机覆盖物木奇具有多孔和吸附特性,考察其对水中苯酚的吸附能力,研究苯酚去除率与温度、p H、木奇添加量和振荡时间之间的关系。结果表明,100 m L 50 mg/L的苯酚模拟水样,在木奇用量为1 g左右,p H值为3,...园林废弃物经微生物发酵制得的有机覆盖物木奇具有多孔和吸附特性,考察其对水中苯酚的吸附能力,研究苯酚去除率与温度、p H、木奇添加量和振荡时间之间的关系。结果表明,100 m L 50 mg/L的苯酚模拟水样,在木奇用量为1 g左右,p H值为3,吸附温度20℃,振荡时间为60 min,对苯酚的去除率可达到65. 9%。Freundlich吸附等温式更适合描述木奇对苯酚的吸附过程,偏向于复杂的多重吸附。木奇对苯酚吸附的n值为3. 571,说明木奇的吸附能力比较强,园林铺装木奇对雨水中污染物的吸滞具有积极的作用。展开更多
The viscosity-time curve of a single-component polyurethane(PU)was examined to determine the mixing and compacting temperatures of its mixture and investigate the curing and mechanical properties of single-component P...The viscosity-time curve of a single-component polyurethane(PU)was examined to determine the mixing and compacting temperatures of its mixture and investigate the curing and mechanical properties of single-component PU porous elastic mixture(PPEM).The curing properties of the single-component PU and PPEM were studied with Fourier transform infrared spectroscopy(FTIR)and Marshall test.The mechanical properties of PPEM were explored via the following tests:rutting test,3-point bending test,soaked Marshall stability test,freeze-thaw splitting test,and Cantabro test.The effects of a water bath on the stability of aggregate-PU/asphalt mortar-aggregate systems were evaluated through a pull-out test and a shear test.The results show that the recommended mixing temperatures of toluene diisocyanate and methylene diphenyl diisocyanate range from 75 to 80℃and from 64 to 68℃,respectively.Room temperature(25℃)can be adopted as the compacting temperature of PPEM.PPEM can be fully cured in 4 d.Nevertheless,the water sprinkle method can obviously shorten the full curing time of PPEM.PPEM exhibites good resistance to rutting,brittle cracking,and raveling.The adhesive and shear strength of aggregate-PU/asphalt mortar-aggregate systems are negatively related to water bath duration.展开更多
Porous medium has an obvious effect on the formation of carbon dioxide hydrate. In order to study the characteristics of CO2 hydrate formation in porous medium below the freezing point, the experiment of CO2 hydrate f...Porous medium has an obvious effect on the formation of carbon dioxide hydrate. In order to study the characteristics of CO2 hydrate formation in porous medium below the freezing point, the experiment of CO2 hydrate formation was conducted in a high-pressure 1.8-L cell in the presence of porous media with a particle size of 380 μm, 500 μm and 700 μm, respectively. The test results showed that the porous medium had an important influence on the process of CO2 hydrate formation below the freezing point. Compared with porous media with a particle size of 500 μm and 700 μm, respectively, the average hydrate formation rate and gas storage capacity of carbon dioxide hydrate in the porous medium with a particle size of 380 μm attained 0.016 14 mol/h and 65.094 L/L, respectively. The results also indicated that, within a certain range of particle sizes, the smaller the particle size of porous medium was, the larger the average hydrate formation rate and the gas storage capacity of CO2 hydrate during the process of hydrate formation would be.展开更多
The flow behavior in porous media with threshold pressure gradient(TPG) is more complex than Darcy flow and the equations of motion, and outer boundary and inner boundary with TPG are also different from Darcy flow fo...The flow behavior in porous media with threshold pressure gradient(TPG) is more complex than Darcy flow and the equations of motion, and outer boundary and inner boundary with TPG are also different from Darcy flow for unsteady flow of a producing well in a reservoir. An analytic method to solve this kind of problem is in a need of reestablishment. The classical method of Green's function and Newman product principle in a new way are used to solve the unsteady state flow problems of various shapes of well and reservoir while considering the TPG. Four Green's functions of point, line, band and circle while considering the TPG are achieved. Then, two well models of vertical well and horizontal well are built and simultaneously the function to calculate the moving boundary of each well model is provided. The results show that when considering TPG the pressure field is much different, which has a sudden pressure change, with a moving boundary in it. And the moving boundary of each well model increases with time but slows down rapidly, especially when the TGP is large.展开更多
This study examines oblique wave motion over multiple submerged porous bars in front of a vertical wall. Based on linear potential theory, an analytical solution for the present problem is developed using matched eige...This study examines oblique wave motion over multiple submerged porous bars in front of a vertical wall. Based on linear potential theory, an analytical solution for the present problem is developed using matched eigenfunction expansions. A complex dispersion relation is adopted to describe the wave elevation and energy dissipation over submerged porous bars. In the analytical solution, no limitations on the bar number, bar size, and spacing between adjacent bars are set. The convergence of the analytical solution is satisfactory, and the correctness of the analytical solution is confirmed by an independently developed multi-domain BEM （boundary element method） solution. Numerical examples are presented to examine the reflection and transmission coefficients of porous bars, CR and Cv, respectively, for engineering applications. The calculation results show that when the sum of widths for all the porous bars is fixed, increasing the bar number can significantly improve the sheltering function of the bars. Increasing the bar height can cause more wave energy dissipation and lower CR and Cr. The spacing between adjacent bars and the spacing between the last bar and the vertical wall are the key parameters affecting CR and Ct. The proposed analytical method may be used to analyze the hydrodynamic performance of submerged porous bars in preliminary engineering designs.展开更多
Low-concentration methane(LCM) has been one of the biggest difficulties in using coal mine methane.And previous studies found that premixed combustion in porous media is an effective method of low calorific gas utiliz...Low-concentration methane(LCM) has been one of the biggest difficulties in using coal mine methane.And previous studies found that premixed combustion in porous media is an effective method of low calorific gas utilization. This paper studied the combustion of LCM in a divergent porous medium burner(DPMB) by using computational fluid dynamics(CFD), and investigated the effect of gas initial temperature on combustion characteristic, the distribution of temperature and pollutant at different equivalence ratios in detail. Besides, the comparison of divergent and cylindrical burners was also performed in this paper. The results show that: the peak temperature in DPMB increases as the increasing of equivalence ratio, which is also suitable for the outlet NO discharge; the linear correlation is also discovered between peak temperature and equivalence ratios; NO emission at the initial temperature of 525 K is 5.64 times,larger than NO emission at the initial temperature of 300 K. Thus, it is preferable to balance the effect of thermal efficiency and environment simultaneously when determining the optimal initial temperature range. The working parameter limits of divergent burner are wider than that of cylindrical one which contributes to reducing the influence of LCM concentration and volume fluctuation on combustion.展开更多
In this work, indium nitride(InN) films were successfully grown on porous silicon(PS) using metal oxide chemical vapor deposition(MOCVD) method. Room temperature photoluminescence(PL) and field emission scanning elect...In this work, indium nitride(InN) films were successfully grown on porous silicon(PS) using metal oxide chemical vapor deposition(MOCVD) method. Room temperature photoluminescence(PL) and field emission scanning electron microscopy(FESEM) analyses are performed to investigate the optical, structural and morphological properties of the InN/PS nanocomposites. FESEM images show that the pore size of InN/PS nanocomposites is usually less than 4 μm in diameter, and the overall thickness is approximately 40 μm. The InN nanoparticles penetrate uniformly into PS layer and adhere to them very well. Nitrogen(N) and indium(In) can be detected by energy dispersive spectrometer(EDS). An important gradual decrease of the PL intensity for PS occurs with the increase of oxidation time, and the PL intensity of PS is quenched after 24 h oxidization. However, there is a strong PL intensity of InN/PS nanocomposites at 430 nm(2.88 eV), which means that PS substrate can influence the structural and optical properties of the InN, and the grown InN on PS substrate has good optical quality.展开更多
Porous Fe3O4 sub-micro particles with sphere-like, cube-like and walnut-like morphologies were obtained by a two-step process, and the electromagnetic properties of the Fe3O4 particle/wax composites were investigated....Porous Fe3O4 sub-micro particles with sphere-like, cube-like and walnut-like morphologies were obtained by a two-step process, and the electromagnetic properties of the Fe3O4 particle/wax composites were investigated. The reflect loss was less than -20 dB for all of the composites in different frequency ranges. The cube-like and walnut-like Fe3O4 composites exhibit improved complex permittivity and permeability and dual-frequency and wide bandwidth absorption characteristics, which is mainly attributed to the larger shape anisotropy. Such a high absorption property indicates that these porous Fe3O4 particles with various morphologies are very promising for electromagnetic wave absorptive materials.展开更多
基金The Fundamental Research Funds for the Central Research Institute (No. 2020-9054)。
文摘The viscosity-time curve of a single-component polyurethane(PU)was examined to determine the mixing and compacting temperatures of its mixture and investigate the curing and mechanical properties of single-component PU porous elastic mixture(PPEM).The curing properties of the single-component PU and PPEM were studied with Fourier transform infrared spectroscopy(FTIR)and Marshall test.The mechanical properties of PPEM were explored via the following tests:rutting test,3-point bending test,soaked Marshall stability test,freeze-thaw splitting test,and Cantabro test.The effects of a water bath on the stability of aggregate-PU/asphalt mortar-aggregate systems were evaluated through a pull-out test and a shear test.The results show that the recommended mixing temperatures of toluene diisocyanate and methylene diphenyl diisocyanate range from 75 to 80℃and from 64 to 68℃,respectively.Room temperature(25℃)can be adopted as the compacting temperature of PPEM.PPEM can be fully cured in 4 d.Nevertheless,the water sprinkle method can obviously shorten the full curing time of PPEM.PPEM exhibites good resistance to rutting,brittle cracking,and raveling.The adhesive and shear strength of aggregate-PU/asphalt mortar-aggregate systems are negatively related to water bath duration.
基金financially supported by the Natural Science Foundation of China (No. 51266005)the Science and Technology Research Key Project of the Ministry of Education (No. 1106ZBB007)+1 种基金the Hongliu Outstanding Talent Program of LUT (No. Q201101)the Open Fund of Natural Gas Hydrate Key Laboratory, Chinese Academy of Sciences (No. y007s3)
文摘Porous medium has an obvious effect on the formation of carbon dioxide hydrate. In order to study the characteristics of CO2 hydrate formation in porous medium below the freezing point, the experiment of CO2 hydrate formation was conducted in a high-pressure 1.8-L cell in the presence of porous media with a particle size of 380 μm, 500 μm and 700 μm, respectively. The test results showed that the porous medium had an important influence on the process of CO2 hydrate formation below the freezing point. Compared with porous media with a particle size of 500 μm and 700 μm, respectively, the average hydrate formation rate and gas storage capacity of carbon dioxide hydrate in the porous medium with a particle size of 380 μm attained 0.016 14 mol/h and 65.094 L/L, respectively. The results also indicated that, within a certain range of particle sizes, the smaller the particle size of porous medium was, the larger the average hydrate formation rate and the gas storage capacity of CO2 hydrate during the process of hydrate formation would be.
基金Project(51304220) supported by the National Natural Science Foundation of ChinaProject(3144033) supported by the Beijing Natural Science Foundation,ChinaProject(20130007120014) supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China
文摘The flow behavior in porous media with threshold pressure gradient(TPG) is more complex than Darcy flow and the equations of motion, and outer boundary and inner boundary with TPG are also different from Darcy flow for unsteady flow of a producing well in a reservoir. An analytic method to solve this kind of problem is in a need of reestablishment. The classical method of Green's function and Newman product principle in a new way are used to solve the unsteady state flow problems of various shapes of well and reservoir while considering the TPG. Four Green's functions of point, line, band and circle while considering the TPG are achieved. Then, two well models of vertical well and horizontal well are built and simultaneously the function to calculate the moving boundary of each well model is provided. The results show that when considering TPG the pressure field is much different, which has a sudden pressure change, with a moving boundary in it. And the moving boundary of each well model increases with time but slows down rapidly, especially when the TGP is large.
基金supported by the National Natural Science Foundation of China(Nos.51490675,51322903 and 51279224.)
文摘This study examines oblique wave motion over multiple submerged porous bars in front of a vertical wall. Based on linear potential theory, an analytical solution for the present problem is developed using matched eigenfunction expansions. A complex dispersion relation is adopted to describe the wave elevation and energy dissipation over submerged porous bars. In the analytical solution, no limitations on the bar number, bar size, and spacing between adjacent bars are set. The convergence of the analytical solution is satisfactory, and the correctness of the analytical solution is confirmed by an independently developed multi-domain BEM （boundary element method） solution. Numerical examples are presented to examine the reflection and transmission coefficients of porous bars, CR and Cv, respectively, for engineering applications. The calculation results show that when the sum of widths for all the porous bars is fixed, increasing the bar number can significantly improve the sheltering function of the bars. Increasing the bar height can cause more wave energy dissipation and lower CR and Cr. The spacing between adjacent bars and the spacing between the last bar and the vertical wall are the key parameters affecting CR and Ct. The proposed analytical method may be used to analyze the hydrodynamic performance of submerged porous bars in preliminary engineering designs.
基金the supports by the National Basic Research Program of China (No. 2011CB201205)the National Natural Science Foundation of China (No. 51204169)+1 种基金the Research Fund for the Doctoral Program of Higher Education of China (No. 20110095120017)the Fund of China Postdoctoral Science Foundation of China (No. 20110491482)
文摘Low-concentration methane(LCM) has been one of the biggest difficulties in using coal mine methane.And previous studies found that premixed combustion in porous media is an effective method of low calorific gas utilization. This paper studied the combustion of LCM in a divergent porous medium burner(DPMB) by using computational fluid dynamics(CFD), and investigated the effect of gas initial temperature on combustion characteristic, the distribution of temperature and pollutant at different equivalence ratios in detail. Besides, the comparison of divergent and cylindrical burners was also performed in this paper. The results show that: the peak temperature in DPMB increases as the increasing of equivalence ratio, which is also suitable for the outlet NO discharge; the linear correlation is also discovered between peak temperature and equivalence ratios; NO emission at the initial temperature of 525 K is 5.64 times,larger than NO emission at the initial temperature of 300 K. Thus, it is preferable to balance the effect of thermal efficiency and environment simultaneously when determining the optimal initial temperature range. The working parameter limits of divergent burner are wider than that of cylindrical one which contributes to reducing the influence of LCM concentration and volume fluctuation on combustion.
基金supported by the Xinjiang Science and Technology Project(No.2015211C275)
文摘In this work, indium nitride(InN) films were successfully grown on porous silicon(PS) using metal oxide chemical vapor deposition(MOCVD) method. Room temperature photoluminescence(PL) and field emission scanning electron microscopy(FESEM) analyses are performed to investigate the optical, structural and morphological properties of the InN/PS nanocomposites. FESEM images show that the pore size of InN/PS nanocomposites is usually less than 4 μm in diameter, and the overall thickness is approximately 40 μm. The InN nanoparticles penetrate uniformly into PS layer and adhere to them very well. Nitrogen(N) and indium(In) can be detected by energy dispersive spectrometer(EDS). An important gradual decrease of the PL intensity for PS occurs with the increase of oxidation time, and the PL intensity of PS is quenched after 24 h oxidization. However, there is a strong PL intensity of InN/PS nanocomposites at 430 nm(2.88 eV), which means that PS substrate can influence the structural and optical properties of the InN, and the grown InN on PS substrate has good optical quality.
基金supported by the National Natural Science Foundation of China (Grant Nos. 51072038, 50772025 and 21001035)NECT, Outstanding Youth Foundation of Heilongjiang Province (Grant No. JC201008)+4 种基金the Natural Science Foundation of Heilongjiang Province, China (Grant No. F200828)the Ministry of Science and Technology of China (Grant No. 2008DFR20420)the Fundamental Research Funds for the Central Universities (Grant Nos. HEUCFT1010, HEUCF101016, HEUCF20111124 and HEUCF101016)the National Basic Research Program of China (Grant No. 2007CB310500)Harbin Key Sci-Tech Project (Grant No. 2010AA4BG004)
文摘Porous Fe3O4 sub-micro particles with sphere-like, cube-like and walnut-like morphologies were obtained by a two-step process, and the electromagnetic properties of the Fe3O4 particle/wax composites were investigated. The reflect loss was less than -20 dB for all of the composites in different frequency ranges. The cube-like and walnut-like Fe3O4 composites exhibit improved complex permittivity and permeability and dual-frequency and wide bandwidth absorption characteristics, which is mainly attributed to the larger shape anisotropy. Such a high absorption property indicates that these porous Fe3O4 particles with various morphologies are very promising for electromagnetic wave absorptive materials.
