基于分形理论及毛细管模型,本文研究了非牛顿幂律流体在各向同性多孔介质中径向流动问题,推导了幂律流体径向有效渗透率的分形解析表达式.研究结果表明,幂律流体径向有效无量纲渗透率模型和Chang and Yortsos’s模型吻合很好;同时还得...基于分形理论及毛细管模型,本文研究了非牛顿幂律流体在各向同性多孔介质中径向流动问题,推导了幂律流体径向有效渗透率的分形解析表达式.研究结果表明,幂律流体径向有效无量纲渗透率模型和Chang and Yortsos’s模型吻合很好;同时还得出幂律流体径向有效渗透率随孔隙率、幂指数的增加而增加,随迂曲度分形维数的增加而减少.展开更多
Magnetic resonance imaging (MRI) was used to probe the structure and flow velocity within the interparticle space of a packed bed of agar beads under water-saturated condition. The images of the velocity field at th...Magnetic resonance imaging (MRI) was used to probe the structure and flow velocity within the interparticle space of a packed bed of agar beads under water-saturated condition. The images of the velocity field at three different flow rates were obtained. To determine the pore-parameter of the porous media, the internal structure of the bed was also obtained using image processing technique. The results show that the porosity of the sample is 31.28% and the fitting curve for the distribution of pore equivalent diameter follows Gaussian distribution. The velocity profiles do shift as the flow rate varies and the solution flow through the void space is not a homogeneous flow in any pores. The velocity distributions within the pore are roughly parabolic with the local maximum being near the center. About half of the velocity components are in the class of 0-1 cm/s. The frequency of lower velocity components is lower at higher flow rate, but to higher velocity components, it is just the opposite.展开更多
Open-celled porous NiAl intermetallics with adjustable pore characteristics and mechanical properties were successfully prepared by using spherical carbamide as space-holders via combustion synthesis.Examinations of m...Open-celled porous NiAl intermetallics with adjustable pore characteristics and mechanical properties were successfully prepared by using spherical carbamide as space-holders via combustion synthesis.Examinations of macroscopic and microscopic morphologies as well as the quasi-static compressive test for the resultant materials were carried out.Depending on the volume fraction and particle size of the carbamide,the porosity and pore size of the porous NiAl intermetallics can be controlled freely in a range of 57.57%-84.58% and 0.4-2.0 mm,respectively.Furthermore,quasi-static compressive tests indicate that the mechanical behavior of the present porous materials is in good agreement with the Gibson-Ashby model.展开更多
Porous sound-absorbing materials were prepared from steel slag using waste expanded polystyrene(EPS) particles as pore former.The influences of the experimental conditions such as fly ash content,sintering temperatu...Porous sound-absorbing materials were prepared from steel slag using waste expanded polystyrene(EPS) particles as pore former.The influences of the experimental conditions such as fly ash content,sintering temperature,sintering time,and pore former addition on the performance of the porous sound-absorbing materials were investigated.The results show that the porosity of the specimens can reach above 50.0%;the compressive strength and average sound-adsorption coefficient of the sintered specimens are above 3.0 MPa and 0.47,respectively.The optimum preparation conditions for the steel slag porous sound-absorbing materials are as follows:mass fraction of fly ash 50%,waste EPS particles 3.6 g,sintering temperature 1100℃,and sintering time 7.5h,which are determined by considering the properties of the sound-absorbing materials,energy consumption and cost.展开更多
Lotus-type porous silicon with elongated pores was fabricated by unidirectional solidification under pressurized hydrogen. Porosity, pore diameter, and pore length can be adjusted by changing solidification speed and ...Lotus-type porous silicon with elongated pores was fabricated by unidirectional solidification under pressurized hydrogen. Porosity, pore diameter, and pore length can be adjusted by changing solidification speed and hydrogen pressure. The porosity of the ingot is nearly constant under different solidification speeds, but decreases with the increase of hydrogen pressure. The overall porosities of ingots fabricated at different hydrogen pressures were evaluated through a theoretical model. Findings are in good agreement with experimental values. The average pore diameter and pore length increase simultaneously while the average pore aspect ratio changes slightly with the decreases of solidification speed and hydrogen pressure. The average pore length is raised from 7 to 24 mm and the pore aspect ratio is raised from 8 to 20 respectively with the average pore diameter promoted by about 0.3 mm through improving the superheat degree of the melt from 200 to 300 K.展开更多
By employing sintering additives of Li2CO3 and Y2O3,porous Si3N4 ceramics are prepared after experiencing the processes of sintering and post-vacuum heat treatment at 1680 and 1550°C,respectively.The experimental...By employing sintering additives of Li2CO3 and Y2O3,porous Si3N4 ceramics are prepared after experiencing the processes of sintering and post-vacuum heat treatment at 1680 and 1550°C,respectively.The experimental results demonstrate the completed phase transformation fromαtoβ-Si3N4 in Si3N4 ceramic samples with a amount of 1.60 wt%Li2CO3(0.65 wt%Li2O)and 0.33 wt%Y2O3 additives.The as-synthesized porous Si3N4 ceramics exhibit high flexural strength((126.7±2.7)MPa)and high open porosity of 50.4%at elevated temperature(1200°C).These results are attributed to the significant role of added Li2CO3 as sintering additive,where the volatilization of intergranular glassy phase occurs during sintering process.Therefore,porous Si3N4 ceramics with desired mechanical property prepared by altering the addition of sintering additives demonstrate their great potential as a promising candidate for high temperature applications.展开更多
Bi26MO10O69 nanopowder was prepared by hydrothermal method and used as a surface modification material for oxygen separation membrane to enhance oxygen permeability. Thermal decomposition behavior and phase variation ...Bi26MO10O69 nanopowder was prepared by hydrothermal method and used as a surface modification material for oxygen separation membrane to enhance oxygen permeability. Thermal decomposition behavior and phase variation of the precursor were investigated by thermal analyzer (TG-DSC) and high-temperature X-ray diffraction (HT-XRD). Bi26MO10O69 porous layer was coated on the air side of BaCo0.7Fe0.2Nb0.1O3-δ (BCFN) oxygen permeable membrane by dipping method. In the partial oxidation experiment of coke oven gas (COG), the Bi26Mo10O69-coated BCFN membrane exhibits higher oxygen permeability and CH4 conversion than the uncoated BCFN membrane. When the thickness of BCFN membrane was 1 mm and the COG and air fluxes were 120 and 100 mL/min, the oxygen permeation flux reached 16.48 mL/(min.cm^2) at 875℃, which was 16.96% higher than the uncoated BCFN membrane. Therefore, Bi26MoloO69 porous layer on the air side will be promising modification coating on the oxygen permeability of BCFN membrane.展开更多
The effects of surface-modified porous titanium implants with different porosities and pore sizes on osseointegration were investigated in vivo.Three porous titanium implants(A30,A40 and A50 containing volume fraction...The effects of surface-modified porous titanium implants with different porosities and pore sizes on osseointegration were investigated in vivo.Three porous titanium implants(A30,A40 and A50 containing volume fractions of space-holder NaCl being 30%,40%and 50%,respectively)were manufactured by metal injection moulding(MIM).The surface-modified implants were implanted into muscles and femurs of hybrid male dogs.Interface osteogenic activity and histological bone ingrowth of porous titanium implants were evaluated at 28,56 and 84 d.The results showed that when additive space-holder amount of NaCl increased from 30%to 50%(volume fraction),the general porosity and mass fraction of macropores of porous titanium rose from 42.4%to 62.0%and from 8.3%to 69.3%,respectively.Histologic sections and fluorescent labeling showed that the A50 implant demonstrated a significantly higher osteogenic capacity at 28 d than other implants.Bone ingrowth into the A30 implant was lower than that into other implants at 84 d.Therefore,the pore structure of A50 implant was suitable for new bone tissue to grow into porous implant.展开更多
Copper porous materials have been manufactured by the method of powder metallurgy.Electrolytic copper powders and atomized copper powders are used as matrix material.Methylcellulose and paraffin are used as porogen.Th...Copper porous materials have been manufactured by the method of powder metallurgy.Electrolytic copper powders and atomized copper powders are used as matrix material.Methylcellulose and paraffin are used as porogen.The influence of porogen type and copper powder morphology on the property of copper porous materials is investigated as well.The results show that copper porous materials with paraffin as porogen have lower porosity and permeability compared with materials using methylcellulose as porogen,due to the different pore-forming mechanisms.The pore forming mechanism of methylcellulose is thermal decomposition,while the pore forming mechanism of paraffin is melting–evaporation.The morphology of copper powders affects the contact state between adjacent powders,which further influence the sintering shrinkage.The porous materials using arborescent copper powders as matrix have lower porosity,smaller pore size and lower permeability,compared with materials with atomized copper powders as matrix.展开更多
Lotus-type porous Mg–xMn(x=0,1,2 and 3 wt.%)alloys were fabricated by metal/gas eutectic unidirectional solidification(the Gasar process).The effects of Mn addition and the fabrication process on the porosity,pore di...Lotus-type porous Mg–xMn(x=0,1,2 and 3 wt.%)alloys were fabricated by metal/gas eutectic unidirectional solidification(the Gasar process).The effects of Mn addition and the fabrication process on the porosity,pore diameter and microstructure of the porous Mg-Mn alloy were investigated.Mn addition improved the Mn precipitates and increased the porosity and pore diameter.With increasing hydrogen pressure from 0.1 to 0.6 MPa,the overall porosity of the Mg-2wt.%Mn ingot decreased from 55.3%to 38.4%,and the average pore diameter also decreased from 2465 to 312μm.Based on a theoretical model of the change in the porosity with the hydrogen pressure,the calculated results were in good agreement with the experimental results.It is shown that this technique is a promising method to fabricate Gasar Mg–Mn alloys with uniform and controllable pore structure.展开更多
In this paper, we discussed the relationship of filter effictency and pressure drop with the porosity, fiber diameter and filter thickness by Oeodict. We found that filter efficiency will increase when filter porosity...In this paper, we discussed the relationship of filter effictency and pressure drop with the porosity, fiber diameter and filter thickness by Oeodict. We found that filter efficiency will increase when filter porosity and fiber diameter decreasing or filter thickness increasing. And the pressure drop has a linear relationship with filter thickness and non-linear relationship with filter porosity and fiber diameter. We also compared the simulation results with the real test results by TSI 3160. Although there are some differences, I think Ocodict can be used to predict filter effictency and pressure drop.展开更多
Al was evaporated on the surface of PS which was prepared by electrochemical anodization in HF solution to form a metal/PS/Si/Al junction.The photoconductivity spectrum and other features were measured which present t...Al was evaporated on the surface of PS which was prepared by electrochemical anodization in HF solution to form a metal/PS/Si/Al junction.The photoconductivity spectrum and other features were measured which present that PS has a stronger visible photoconductivity effect,specially in orange-yellow region.An analysis and discussion were made on it accordingly.展开更多
A new type of lead-based porous anode in zinc electrowinning was prepared by negative pressure infiltration. The anodic polarization potential and corrosion rate were studied and compared with those of traditional fia...A new type of lead-based porous anode in zinc electrowinning was prepared by negative pressure infiltration. The anodic polarization potential and corrosion rate were studied and compared with those of traditional fiat anodes (Pb-0.8%Ag) used in industry. The anode corrosion rate was determined by anode actual current density and microstructure. The results show that the anodic oxygen evolution potential decreases first and then increases with the decrease of pore diameter. The anodic potential decreases to the lowest value of 1.729 V at the pore diameter of 1.25-1.60 mm. The porous anode can decrease its actual current density and thus decrease the anodic corrosion rate. When the pore diameter is 1.60-2.00 mm, the anodic relative corrosion rate reaches the lowest value of 52.1%.展开更多
Air leakage may significantly affect the effectiveness of mine ventilation by in- creasing the cost of ventilation and arousing problems for ventilation management.Fur- thermore,air leakage may accelerate the process ...Air leakage may significantly affect the effectiveness of mine ventilation by in- creasing the cost of ventilation and arousing problems for ventilation management.Fur- thermore,air leakage may accelerate the process of coal spontaneous combustion and cause gas explosion,thus greatly threatens the safety of coal production.The estimation of air leakage,therefore,have great practical significance.For any ventilation system of coal mines,there is a defined pattern of pressure gradient which drived the mine air to flow in the network,drives possible air leakage to go shortcut as well.Air leakage may occur through ventilation structures such as ventilation doors and fractures of the surroun- dig coal and rock of airways.A concept and the relevent calculation method of the pres- sure gradient matrix was put forward to assist the analysis of potential air leakage routes. A simplified example was used to introduce the application principle of'pressure gradient matrix in identifying all the potential air leaking routes,which offers a deeper understand- ing over the ventilation system and the prevention of coal spontaneous combustion.展开更多
文摘基于分形理论及毛细管模型,本文研究了非牛顿幂律流体在各向同性多孔介质中径向流动问题,推导了幂律流体径向有效渗透率的分形解析表达式.研究结果表明,幂律流体径向有效无量纲渗透率模型和Chang and Yortsos’s模型吻合很好;同时还得出幂律流体径向有效渗透率随孔隙率、幂指数的增加而增加,随迂曲度分形维数的增加而减少.
基金Project(51374035)supported by the National Natural Science Foundation of ChinaProject(2012BAB08B02)supported by the National Science&Technology Pillar Program During the Twelfth Five-year Plan PeriodProject(NCET-13-0669)supported by the New Century Excellent Talents in University of Ministry of Education of China
文摘Magnetic resonance imaging (MRI) was used to probe the structure and flow velocity within the interparticle space of a packed bed of agar beads under water-saturated condition. The images of the velocity field at three different flow rates were obtained. To determine the pore-parameter of the porous media, the internal structure of the bed was also obtained using image processing technique. The results show that the porosity of the sample is 31.28% and the fitting curve for the distribution of pore equivalent diameter follows Gaussian distribution. The velocity profiles do shift as the flow rate varies and the solution flow through the void space is not a homogeneous flow in any pores. The velocity distributions within the pore are roughly parabolic with the local maximum being near the center. About half of the velocity components are in the class of 0-1 cm/s. The frequency of lower velocity components is lower at higher flow rate, but to higher velocity components, it is just the opposite.
基金Project (51072104) supported by the National Natural Science Foundation of ChinaProject (BS2010CL038) supported by the Research Award Fund for Outstanding Young and Middle-aged Scientists of Shandong Province,China
文摘Open-celled porous NiAl intermetallics with adjustable pore characteristics and mechanical properties were successfully prepared by using spherical carbamide as space-holders via combustion synthesis.Examinations of macroscopic and microscopic morphologies as well as the quasi-static compressive test for the resultant materials were carried out.Depending on the volume fraction and particle size of the carbamide,the porosity and pore size of the porous NiAl intermetallics can be controlled freely in a range of 57.57%-84.58% and 0.4-2.0 mm,respectively.Furthermore,quasi-static compressive tests indicate that the mechanical behavior of the present porous materials is in good agreement with the Gibson-Ashby model.
基金Project(2011AA06A105)supported by the National High-tech Research and Development Program of China
文摘Porous sound-absorbing materials were prepared from steel slag using waste expanded polystyrene(EPS) particles as pore former.The influences of the experimental conditions such as fly ash content,sintering temperature,sintering time,and pore former addition on the performance of the porous sound-absorbing materials were investigated.The results show that the porosity of the specimens can reach above 50.0%;the compressive strength and average sound-adsorption coefficient of the sintered specimens are above 3.0 MPa and 0.47,respectively.The optimum preparation conditions for the steel slag porous sound-absorbing materials are as follows:mass fraction of fly ash 50%,waste EPS particles 3.6 g,sintering temperature 1100℃,and sintering time 7.5h,which are determined by considering the properties of the sound-absorbing materials,energy consumption and cost.
基金Project(51271096)supported by the National Natural Science Foundation of ChinaProject(NCET-12-0310)supported by the Program for New Century Excellent Talents in University,China
文摘Lotus-type porous silicon with elongated pores was fabricated by unidirectional solidification under pressurized hydrogen. Porosity, pore diameter, and pore length can be adjusted by changing solidification speed and hydrogen pressure. The porosity of the ingot is nearly constant under different solidification speeds, but decreases with the increase of hydrogen pressure. The overall porosities of ingots fabricated at different hydrogen pressures were evaluated through a theoretical model. Findings are in good agreement with experimental values. The average pore diameter and pore length increase simultaneously while the average pore aspect ratio changes slightly with the decreases of solidification speed and hydrogen pressure. The average pore length is raised from 7 to 24 mm and the pore aspect ratio is raised from 8 to 20 respectively with the average pore diameter promoted by about 0.3 mm through improving the superheat degree of the melt from 200 to 300 K.
基金Project(202045007)supported by the Start-up Funds for Outstanding Talents in Central South University,China。
文摘By employing sintering additives of Li2CO3 and Y2O3,porous Si3N4 ceramics are prepared after experiencing the processes of sintering and post-vacuum heat treatment at 1680 and 1550°C,respectively.The experimental results demonstrate the completed phase transformation fromαtoβ-Si3N4 in Si3N4 ceramic samples with a amount of 1.60 wt%Li2CO3(0.65 wt%Li2O)and 0.33 wt%Y2O3 additives.The as-synthesized porous Si3N4 ceramics exhibit high flexural strength((126.7±2.7)MPa)and high open porosity of 50.4%at elevated temperature(1200°C).These results are attributed to the significant role of added Li2CO3 as sintering additive,where the volatilization of intergranular glassy phase occurs during sintering process.Therefore,porous Si3N4 ceramics with desired mechanical property prepared by altering the addition of sintering additives demonstrate their great potential as a promising candidate for high temperature applications.
基金Projects(51272154,51472156)supported by the National Natural Science Foundation of ChinaProjects(sdcx2012033,sdcx2012062)supported by the Innovation Fund of Shanghai University,China+1 种基金Project(14ZR1416400)supported by Special Research Foundation for Training and Selecting Outstanding Young Teachers of Universities in Shanghai,Chinasupported by Shanghai Science and Technology Committee,China
文摘Bi26MO10O69 nanopowder was prepared by hydrothermal method and used as a surface modification material for oxygen separation membrane to enhance oxygen permeability. Thermal decomposition behavior and phase variation of the precursor were investigated by thermal analyzer (TG-DSC) and high-temperature X-ray diffraction (HT-XRD). Bi26MO10O69 porous layer was coated on the air side of BaCo0.7Fe0.2Nb0.1O3-δ (BCFN) oxygen permeable membrane by dipping method. In the partial oxidation experiment of coke oven gas (COG), the Bi26Mo10O69-coated BCFN membrane exhibits higher oxygen permeability and CH4 conversion than the uncoated BCFN membrane. When the thickness of BCFN membrane was 1 mm and the COG and air fluxes were 120 and 100 mL/min, the oxygen permeation flux reached 16.48 mL/(min.cm^2) at 875℃, which was 16.96% higher than the uncoated BCFN membrane. Therefore, Bi26MoloO69 porous layer on the air side will be promising modification coating on the oxygen permeability of BCFN membrane.
基金Project(81571021) supported by the National Natural Science Foundation of ChinaProjects(2015WK3012,2018SK2017) supported by the Hunan Provincial Science and Technology Department Project,ChinaProject(20160301) supported by New Talent Project of the Third Xiangya Hospital of Central South University,China
文摘The effects of surface-modified porous titanium implants with different porosities and pore sizes on osseointegration were investigated in vivo.Three porous titanium implants(A30,A40 and A50 containing volume fractions of space-holder NaCl being 30%,40%and 50%,respectively)were manufactured by metal injection moulding(MIM).The surface-modified implants were implanted into muscles and femurs of hybrid male dogs.Interface osteogenic activity and histological bone ingrowth of porous titanium implants were evaluated at 28,56 and 84 d.The results showed that when additive space-holder amount of NaCl increased from 30%to 50%(volume fraction),the general porosity and mass fraction of macropores of porous titanium rose from 42.4%to 62.0%and from 8.3%to 69.3%,respectively.Histologic sections and fluorescent labeling showed that the A50 implant demonstrated a significantly higher osteogenic capacity at 28 d than other implants.Bone ingrowth into the A30 implant was lower than that into other implants at 84 d.Therefore,the pore structure of A50 implant was suitable for new bone tissue to grow into porous implant.
基金Project(2015DFR50580)supported by International S&T Cooperation Program of ChinaProject(51505503)supported by the National Natural Science Foundation of China
文摘Copper porous materials have been manufactured by the method of powder metallurgy.Electrolytic copper powders and atomized copper powders are used as matrix material.Methylcellulose and paraffin are used as porogen.The influence of porogen type and copper powder morphology on the property of copper porous materials is investigated as well.The results show that copper porous materials with paraffin as porogen have lower porosity and permeability compared with materials using methylcellulose as porogen,due to the different pore-forming mechanisms.The pore forming mechanism of methylcellulose is thermal decomposition,while the pore forming mechanism of paraffin is melting–evaporation.The morphology of copper powders affects the contact state between adjacent powders,which further influence the sintering shrinkage.The porous materials using arborescent copper powders as matrix have lower porosity,smaller pore size and lower permeability,compared with materials with atomized copper powders as matrix.
基金Project(51771101)supported by the National Natural Science Foundation of China。
文摘Lotus-type porous Mg–xMn(x=0,1,2 and 3 wt.%)alloys were fabricated by metal/gas eutectic unidirectional solidification(the Gasar process).The effects of Mn addition and the fabrication process on the porosity,pore diameter and microstructure of the porous Mg-Mn alloy were investigated.Mn addition improved the Mn precipitates and increased the porosity and pore diameter.With increasing hydrogen pressure from 0.1 to 0.6 MPa,the overall porosity of the Mg-2wt.%Mn ingot decreased from 55.3%to 38.4%,and the average pore diameter also decreased from 2465 to 312μm.Based on a theoretical model of the change in the porosity with the hydrogen pressure,the calculated results were in good agreement with the experimental results.It is shown that this technique is a promising method to fabricate Gasar Mg–Mn alloys with uniform and controllable pore structure.
基金Supported by SRC/ERC Programof MOST/KOSEF (R11 -2005 -065) ,Soongsil University
文摘In this paper, we discussed the relationship of filter effictency and pressure drop with the porosity, fiber diameter and filter thickness by Oeodict. We found that filter efficiency will increase when filter porosity and fiber diameter decreasing or filter thickness increasing. And the pressure drop has a linear relationship with filter thickness and non-linear relationship with filter porosity and fiber diameter. We also compared the simulation results with the real test results by TSI 3160. Although there are some differences, I think Ocodict can be used to predict filter effictency and pressure drop.
文摘Al was evaporated on the surface of PS which was prepared by electrochemical anodization in HF solution to form a metal/PS/Si/Al junction.The photoconductivity spectrum and other features were measured which present that PS has a stronger visible photoconductivity effect,specially in orange-yellow region.An analysis and discussion were made on it accordingly.
基金Project(2007SK2009) supported by the Science and Technology Research Project of Hunan Province, China
文摘A new type of lead-based porous anode in zinc electrowinning was prepared by negative pressure infiltration. The anodic polarization potential and corrosion rate were studied and compared with those of traditional fiat anodes (Pb-0.8%Ag) used in industry. The anode corrosion rate was determined by anode actual current density and microstructure. The results show that the anodic oxygen evolution potential decreases first and then increases with the decrease of pore diameter. The anodic potential decreases to the lowest value of 1.729 V at the pore diameter of 1.25-1.60 mm. The porous anode can decrease its actual current density and thus decrease the anodic corrosion rate. When the pore diameter is 1.60-2.00 mm, the anodic relative corrosion rate reaches the lowest value of 52.1%.
基金the National Natural Science Foundation of China(50174045)the Natural Science Foundation of Shaanxi Province China(2006E205)
文摘Air leakage may significantly affect the effectiveness of mine ventilation by in- creasing the cost of ventilation and arousing problems for ventilation management.Fur- thermore,air leakage may accelerate the process of coal spontaneous combustion and cause gas explosion,thus greatly threatens the safety of coal production.The estimation of air leakage,therefore,have great practical significance.For any ventilation system of coal mines,there is a defined pattern of pressure gradient which drived the mine air to flow in the network,drives possible air leakage to go shortcut as well.Air leakage may occur through ventilation structures such as ventilation doors and fractures of the surroun- dig coal and rock of airways.A concept and the relevent calculation method of the pres- sure gradient matrix was put forward to assist the analysis of potential air leakage routes. A simplified example was used to introduce the application principle of'pressure gradient matrix in identifying all the potential air leaking routes,which offers a deeper understand- ing over the ventilation system and the prevention of coal spontaneous combustion.