如何采用无酸工艺合成高性能超级电容器(SCs)用多孔炭纳米片电极材料是一个大的挑战。本文报道了一种简便且无酸的由煤焦油沥青(CTP)构建N/S共掺杂相互连接的多孔炭纳米片(NS-IPCNs)的新方法。制备的NS-IPCN_(800)具有相互连接的三维结...如何采用无酸工艺合成高性能超级电容器(SCs)用多孔炭纳米片电极材料是一个大的挑战。本文报道了一种简便且无酸的由煤焦油沥青(CTP)构建N/S共掺杂相互连接的多孔炭纳米片(NS-IPCNs)的新方法。制备的NS-IPCN_(800)具有相互连接的三维结构,这些三维结构由含有大量分级孔的二维炭纳米片组成。其中,丰富的微孔增加了离子吸附所需的活性位点,而短的中孔为离子传输提供了通道。此外,相互连接的三维结构为电子的快速传递提供了通道;掺杂的杂原子为NS-IPCNs电极提供了额外的赝电容。受益于这些优点,NS-IPCN_(800)电极在6 mol L^(−1) KOH电解液中,在0.05 A g^(−1)电流密度下的比电容达302 F g^(−1)。另外,NS-IPCN_(800)电容器在功率密度为25.98 W kg^(−1)下其能量密度达9.71 Wh kg^(−1)。更重要的是,NS-IPCN_(800)电容器在10000次循环充放电后电容保持率为94.2%,表现出优异的循环稳定性。这项工作为由CTP构建高性能储能装置用NS-IPCNs开辟了一种危害较小的策略。展开更多
A new multi-mesh contact algorithm for three-dimensional material point method is presented. The contact algorithm faithfully recovers the opposite acting forces between colliding bodies. Collision procedures between ...A new multi-mesh contact algorithm for three-dimensional material point method is presented. The contact algorithm faithfully recovers the opposite acting forces between colliding bodies. Collision procedures between regular bodies and/or rigid bodies are treated within the same framework. Multi-value of momentum and mass are defined on every node to describe the contact/sliding/separation procedure. Both normal and tangential velocities of each particle at the contact surface are calculated in respective individual mesh. A Coulomb friction is applied to describe the sliding or slipping between the contacting bodies. The efficiency of the contact algorithm is linearly related to the number of the contacting bodies because the overlapped nodes are labeled by sweeping the material particles of all bodies when the nodal momentum and mass are formed at every time step. Numerical simulation shows that our contact algorithm possesses high accuracy and low numerical energy dissipation, which is very important for solving collision problems.展开更多
Al was evaporated on the surface of PS which was prepared by electrochemical anodization in HF solution to form a metal/PS/Si/Al junction.The photoconductivity spectrum and other features were measured which present t...Al was evaporated on the surface of PS which was prepared by electrochemical anodization in HF solution to form a metal/PS/Si/Al junction.The photoconductivity spectrum and other features were measured which present that PS has a stronger visible photoconductivity effect,specially in orange-yellow region.An analysis and discussion were made on it accordingly.展开更多
In maxillofacial surgery, there is a significant need for the design and fabrication of porous scaffolds with customizable bionic structures and mechanical properties suitable for bone tissue engineering. In this pape...In maxillofacial surgery, there is a significant need for the design and fabrication of porous scaffolds with customizable bionic structures and mechanical properties suitable for bone tissue engineering. In this paper, we characterize the porous Ti6Al4V implant, which is one of the most promising and attractive biomedical applications due to the similarity of its modulus to human bones. We describe the mechanical properties of this implant, which we suggest is capable of providing important biological functions for bone tissue regeneration. We characterize a novel bionic design and fabrication process for porous implants. A design concept of “reducing dimensions and designing layer by layer” was used to construct layered slice and rod-connected mesh structure (LSRCMS) implants. Porous LSRCMS implants with different parameters and porosities were fabricated by selective laser melting (SLM). Printed samples were evaluated by microstructure characterization, specific mechanical properties were analyzed by mechanical tests, and finite element analysis was used to digitally calculate the stress characteristics of the LSRCMS under loading forces. Our results show that the samples fabricated by SLM had good structure printing quality with reasonable pore sizes. The porosity, pore size, and strut thickness of manufactured samples ranged from (60.95± 0.27)% to (81.23±0.32)%,(480±28) to (685±31)μm, and (263±28) to (265±28)μm, respectively. The compression results show that the Young’s modulus and the yield strength ranged from (2.23±0.03) to (6.36±0.06) GPa and (21.36±0.42) to (122.85±3.85) MPa, respectively. We also show that the Young’s modulus and yield strength of the LSRCMS samples can be predicted by the Gibson-Ashby model. Further, we prove the structural stability of our novel design by finite element analysis. Our results illustrate that our novel SLM-fabricated porous Ti6Al4V scaffolds based on an LSRCMS are a promising material for bone implants, and are potentially applicable to the field of bone defect repair.展开更多
文摘如何采用无酸工艺合成高性能超级电容器(SCs)用多孔炭纳米片电极材料是一个大的挑战。本文报道了一种简便且无酸的由煤焦油沥青(CTP)构建N/S共掺杂相互连接的多孔炭纳米片(NS-IPCNs)的新方法。制备的NS-IPCN_(800)具有相互连接的三维结构,这些三维结构由含有大量分级孔的二维炭纳米片组成。其中,丰富的微孔增加了离子吸附所需的活性位点,而短的中孔为离子传输提供了通道。此外,相互连接的三维结构为电子的快速传递提供了通道;掺杂的杂原子为NS-IPCNs电极提供了额外的赝电容。受益于这些优点,NS-IPCN_(800)电极在6 mol L^(−1) KOH电解液中,在0.05 A g^(−1)电流密度下的比电容达302 F g^(−1)。另外,NS-IPCN_(800)电容器在功率密度为25.98 W kg^(−1)下其能量密度达9.71 Wh kg^(−1)。更重要的是,NS-IPCN_(800)电容器在10000次循环充放电后电容保持率为94.2%,表现出优异的循环稳定性。这项工作为由CTP构建高性能储能装置用NS-IPCNs开辟了一种危害较小的策略。
基金The project supported by the Science Foundation of Laboratory of Computational Physics,Science Foundation of China Academy of Engineering Physics,and National Natural Science Foundation of China under Grant Nos.10702010,10775018,10472052,and 10604010
文摘A new multi-mesh contact algorithm for three-dimensional material point method is presented. The contact algorithm faithfully recovers the opposite acting forces between colliding bodies. Collision procedures between regular bodies and/or rigid bodies are treated within the same framework. Multi-value of momentum and mass are defined on every node to describe the contact/sliding/separation procedure. Both normal and tangential velocities of each particle at the contact surface are calculated in respective individual mesh. A Coulomb friction is applied to describe the sliding or slipping between the contacting bodies. The efficiency of the contact algorithm is linearly related to the number of the contacting bodies because the overlapped nodes are labeled by sweeping the material particles of all bodies when the nodal momentum and mass are formed at every time step. Numerical simulation shows that our contact algorithm possesses high accuracy and low numerical energy dissipation, which is very important for solving collision problems.
文摘Al was evaporated on the surface of PS which was prepared by electrochemical anodization in HF solution to form a metal/PS/Si/Al junction.The photoconductivity spectrum and other features were measured which present that PS has a stronger visible photoconductivity effect,specially in orange-yellow region.An analysis and discussion were made on it accordingly.
基金Project supported by the National Natural Science Foundation of China(No.51775506)the Zhejiang Provincial Natural Science Foundation of China(No.LY18E050022)+2 种基金the Public Welfare Technology Application Research Project of Zhejiang Province(Nos.LGG19E050022 and 2017C33115)the Zhejiang Provincial Science&Technology Project for Medicine&Health(No.2018KY878)the Open Foundation of Zhejiang Provincial Top Key Discipline of Mechanical Engineering of Hangzhou Dianzi University,China
文摘In maxillofacial surgery, there is a significant need for the design and fabrication of porous scaffolds with customizable bionic structures and mechanical properties suitable for bone tissue engineering. In this paper, we characterize the porous Ti6Al4V implant, which is one of the most promising and attractive biomedical applications due to the similarity of its modulus to human bones. We describe the mechanical properties of this implant, which we suggest is capable of providing important biological functions for bone tissue regeneration. We characterize a novel bionic design and fabrication process for porous implants. A design concept of “reducing dimensions and designing layer by layer” was used to construct layered slice and rod-connected mesh structure (LSRCMS) implants. Porous LSRCMS implants with different parameters and porosities were fabricated by selective laser melting (SLM). Printed samples were evaluated by microstructure characterization, specific mechanical properties were analyzed by mechanical tests, and finite element analysis was used to digitally calculate the stress characteristics of the LSRCMS under loading forces. Our results show that the samples fabricated by SLM had good structure printing quality with reasonable pore sizes. The porosity, pore size, and strut thickness of manufactured samples ranged from (60.95± 0.27)% to (81.23±0.32)%,(480±28) to (685±31)μm, and (263±28) to (265±28)μm, respectively. The compression results show that the Young’s modulus and the yield strength ranged from (2.23±0.03) to (6.36±0.06) GPa and (21.36±0.42) to (122.85±3.85) MPa, respectively. We also show that the Young’s modulus and yield strength of the LSRCMS samples can be predicted by the Gibson-Ashby model. Further, we prove the structural stability of our novel design by finite element analysis. Our results illustrate that our novel SLM-fabricated porous Ti6Al4V scaffolds based on an LSRCMS are a promising material for bone implants, and are potentially applicable to the field of bone defect repair.
