The concentrations, accumulation and sources of 15 polycyclic aromatic hydrocarbons (PAHs) had been studied or evaluated in the surface layer sediments of Taizhou Bay, China. It showed that the concentrations of PAH...The concentrations, accumulation and sources of 15 polycyclic aromatic hydrocarbons (PAHs) had been studied or evaluated in the surface layer sediments of Taizhou Bay, China. It showed that the concentrations of PAHs ranged from 85.4 to 167.6 ng/g (averaged 138.62 ng/g), and the highest level was found in Jiao Jiang Dock. Percentages of 2-, 3-, 4-, 5- and 6-cyclic aromatic hydrocarbons were 7.8 %, 42.1%, 33.3 %, 9.6 % and 7.2 % respectively. The accumulation indices of PAHs ranged from 532.7 to 1068.9 (averaged 807.5), and the index of Phenanthrene was the highest (122.7), while that of Benzo (a) Pyrene was the lowest (2.7) among them. In Taizhou Bay, PAHs in surface layer sediments came mainly from coal burning, partly from direct pollution of petroleum hydrocarbons.展开更多
This study investigates the distribution of black carbon (BC) and its correlation with total polycyclic aromatic hydrocarbons (EPAH) in the surface sediments of China's marginal seas. BC content ranges from 〈0.1...This study investigates the distribution of black carbon (BC) and its correlation with total polycyclic aromatic hydrocarbons (EPAH) in the surface sediments of China's marginal seas. BC content ranges from 〈0.10 to 2.45 mg/g dw (grams dry weight) in the sediments studied, and varied among the different coastal regions. The Bohai Bay sediments had the highest BC contents (average 2.18 mg/g dw), which comprises a significant fraction (27%-41%) of the total organic carbon (TOC) preserved in the sediments. In comparison, BC in the surface sediments of the North Yellow Sea, Jiaozhou Bay, East China Sea and the South China Sea is less abundant and accounted for an average of 6%, 8%, 14% and 5%, respectively, of the sedimentary organic carbon pool. The concentration of EPAH in the surface sediments ranges from 41 to 3 667 ng/g dw and showed large spatial variations among the sampling sites of different costal regions. The Bohai Bay has the highest ZPAH values, ranging from 79 to 3 667 ng/g dw. This reflects the high anthropogenically contaminated nature of the sediments in the bay. BC is positively correlated to TOC but a strong correlation is not found between BC and ZPAH in the surface sediments studied, suggesting that BC and PAHs preserved in the sediments are derived from different sources and controlled by different biogeochemical processes. Our study suggests that the abundance of BC preserved in the sediments could represent a significant sink pool of carbon cycling in China's marginal seas.展开更多
In this paper, poly(amide-6-β-ethylene oxide) (PEBA1657) copolymer was used to prepare multilayer polyetherimide (PEI)/polydimethylsiloxane (PDMS)/PEBA1657/PDMS composite membranes by dip-coating method. Permeation b...In this paper, poly(amide-6-β-ethylene oxide) (PEBA1657) copolymer was used to prepare multilayer polyetherimide (PEI)/polydimethylsiloxane (PDMS)/PEBA1657/PDMS composite membranes by dip-coating method. Permeation behaviors of ethylene, ethane, propylene, propane, n-butane, methane and nitrogen through the multilayer composite membranes were investigated over a range of operating temperature and pressure. The permeances of light hydrocarbons through PEI/PDMS/PEBA1657/PDMS composite membranes increase with their increasing condensability, and the olefins are more permeable than their corresponding paraffins. For light hydrocarbons, the gas permeances increase significantly as temperature increasing. When the transmembrane pressure difference increases, the gas permeance increases moderately due to plasticization effect, while their apparent activation energies for permeation decrease.展开更多
A type of new loop algebra GM is constructed by making use of the concept of cycled numbers. As its application, an isospectral problem is designed and a new multi-component integrable hierarchy with multi-potential f...A type of new loop algebra GM is constructed by making use of the concept of cycled numbers. As its application, an isospectral problem is designed and a new multi-component integrable hierarchy with multi-potential functions is worked out, which can be reduced to the famous KN hierarchy.展开更多
Coal seam pyrolysis occurs during coal seam fires and during underground coal gasification. This is an important source of polycyclic aromatic hydrocarbon (PAH) emission in China. Pyrolysis in a coal seam was simula...Coal seam pyrolysis occurs during coal seam fires and during underground coal gasification. This is an important source of polycyclic aromatic hydrocarbon (PAH) emission in China. Pyrolysis in a coal seam was simulated in a tubular furnace. The 16 US Environmental Protection Agency priority controlled PAHs were analyzed by HPLC. The effects of temperature, heating rate, pyrolysis atmosphere, and coal size were investigated. The results indicate that the 3-ring PAHs AcP and AcPy are the main species in the pyrolysis gas. The 2-ring NaP and the 4-ring Pyr are also of concern. Increasing temperature caused the total PAH yield to go through a minimum. The lowest value was obtained at the temperature of 600℃. Higher heating rates promote PAH formation, especially formation of the lower molecular weight PAHs. The typical heating rate in a coal seam, 5 ℃/min, results in intermediate yields of PAHs. The total PAHs yield in an atmosphere of N2 is about 1.81 times that seen without added N2, which indicates that an air flow through the coal seam accelerates the formation of PAHs. An increase in coal particle size reduces the total PAHs emission but promotes the formation of 5- and f-ring PAHs.展开更多
Growth of an anthropogenic load on an environment in the second halfofXXth centuries has led to an exacerbation of many ecological problems. Today ecological risk scales cover territories of large regions. In this res...Growth of an anthropogenic load on an environment in the second halfofXXth centuries has led to an exacerbation of many ecological problems. Today ecological risk scales cover territories of large regions. In this respect the territory of Azerbaijan is not exception, within which Baku is noted by very adverse ecological conditions. Complex natural conditions (presence of strong winds, high air temperature and solar radiation) complicate the city ecological situation even greater. In modem conditions a construction boom relates to the factors aggravating the ecological situation of Baku. Last 10 years the city is rapidly built on by multistoried buildings which deform it, hinder visual contacts to the environment and obstruct the natural aeration of Baku amphitheater. The modem multistoried buildings erected ignoring town-planning norms do not correspond with regional climatic conditions, essentially modify the territory wind regime, hamper in surrounding buildings insolation, neglect a territory temperature-humidity conditions. As a result, it is necessary to use energy overly for their adaptation to Baku conditions and creation comfortable microclimate in them that leads to the city environmental pollution. The planning decisions and construction materials applied in these buildings are also alien to Baku climatic conditions. For qualitative transformation of Baku environment and improvement of ecological characteristics of the residential areas the author has carried out the estimation of the city territory on a complex of climatic factors (aeration, insolation and thermal-humidity regimes). For these purposes the multidimensional statistical method is used. As a result the investigated territory of Baku is divided into 5 typological areas on climatic conditions. The brief characteristic and the general recommendations on transformation are worked out by the author for each of these typological units. Results of the research can be a basis for revealing of methods and principles of town-planning and architectural-planning organization of Baku residential areas.展开更多
Separation issue is one of the most important problems about cloud computing security. Tenants should be separated from each other based on cloud infrastructure and different users from one tenant should be separated ...Separation issue is one of the most important problems about cloud computing security. Tenants should be separated from each other based on cloud infrastructure and different users from one tenant should be separated from each other with the constraint of security policies. Learning from the notion of trusted cloud computing and trustworthiness in cloud, in this paper, a multi-level authorization separation model is formally described, and a series of rules are proposed to summarize the separation property of this model. The correctness of the rules is proved. Furthermore, based on this model, a tenant separation mechanism is deployed in a real world mixed-critical information system. Performance benchmarks have shown the availability and efficiency of this mechanism.展开更多
文摘The concentrations, accumulation and sources of 15 polycyclic aromatic hydrocarbons (PAHs) had been studied or evaluated in the surface layer sediments of Taizhou Bay, China. It showed that the concentrations of PAHs ranged from 85.4 to 167.6 ng/g (averaged 138.62 ng/g), and the highest level was found in Jiao Jiang Dock. Percentages of 2-, 3-, 4-, 5- and 6-cyclic aromatic hydrocarbons were 7.8 %, 42.1%, 33.3 %, 9.6 % and 7.2 % respectively. The accumulation indices of PAHs ranged from 532.7 to 1068.9 (averaged 807.5), and the index of Phenanthrene was the highest (122.7), while that of Benzo (a) Pyrene was the lowest (2.7) among them. In Taizhou Bay, PAHs in surface layer sediments came mainly from coal burning, partly from direct pollution of petroleum hydrocarbons.
基金Supported by the National Natural Science Foundation of China (No. 40476038 and 40576039)
文摘This study investigates the distribution of black carbon (BC) and its correlation with total polycyclic aromatic hydrocarbons (EPAH) in the surface sediments of China's marginal seas. BC content ranges from 〈0.10 to 2.45 mg/g dw (grams dry weight) in the sediments studied, and varied among the different coastal regions. The Bohai Bay sediments had the highest BC contents (average 2.18 mg/g dw), which comprises a significant fraction (27%-41%) of the total organic carbon (TOC) preserved in the sediments. In comparison, BC in the surface sediments of the North Yellow Sea, Jiaozhou Bay, East China Sea and the South China Sea is less abundant and accounted for an average of 6%, 8%, 14% and 5%, respectively, of the sedimentary organic carbon pool. The concentration of EPAH in the surface sediments ranges from 41 to 3 667 ng/g dw and showed large spatial variations among the sampling sites of different costal regions. The Bohai Bay has the highest ZPAH values, ranging from 79 to 3 667 ng/g dw. This reflects the high anthropogenically contaminated nature of the sediments in the bay. BC is positively correlated to TOC but a strong correlation is not found between BC and ZPAH in the surface sediments studied, suggesting that BC and PAHs preserved in the sediments are derived from different sources and controlled by different biogeochemical processes. Our study suggests that the abundance of BC preserved in the sediments could represent a significant sink pool of carbon cycling in China's marginal seas.
基金Supported by Key Projects in the National Science & Technology Pillar Program (2011BAC08B00)
文摘In this paper, poly(amide-6-β-ethylene oxide) (PEBA1657) copolymer was used to prepare multilayer polyetherimide (PEI)/polydimethylsiloxane (PDMS)/PEBA1657/PDMS composite membranes by dip-coating method. Permeation behaviors of ethylene, ethane, propylene, propane, n-butane, methane and nitrogen through the multilayer composite membranes were investigated over a range of operating temperature and pressure. The permeances of light hydrocarbons through PEI/PDMS/PEBA1657/PDMS composite membranes increase with their increasing condensability, and the olefins are more permeable than their corresponding paraffins. For light hydrocarbons, the gas permeances increase significantly as temperature increasing. When the transmembrane pressure difference increases, the gas permeance increases moderately due to plasticization effect, while their apparent activation energies for permeation decrease.
基金The project supported by National Natural Science Foundation of China under.Grant No. 10371070
文摘A type of new loop algebra GM is constructed by making use of the concept of cycled numbers. As its application, an isospectral problem is designed and a new multi-component integrable hierarchy with multi-potential functions is worked out, which can be reduced to the famous KN hierarchy.
基金provided by the National Natural Science Foundation of China (No. 50876112)the Fundamental Research Funds for the Central Universities (No. 2009QH13)the International Scientific and Technological Cooperation Project(No. 2010DFR60610)
文摘Coal seam pyrolysis occurs during coal seam fires and during underground coal gasification. This is an important source of polycyclic aromatic hydrocarbon (PAH) emission in China. Pyrolysis in a coal seam was simulated in a tubular furnace. The 16 US Environmental Protection Agency priority controlled PAHs were analyzed by HPLC. The effects of temperature, heating rate, pyrolysis atmosphere, and coal size were investigated. The results indicate that the 3-ring PAHs AcP and AcPy are the main species in the pyrolysis gas. The 2-ring NaP and the 4-ring Pyr are also of concern. Increasing temperature caused the total PAH yield to go through a minimum. The lowest value was obtained at the temperature of 600℃. Higher heating rates promote PAH formation, especially formation of the lower molecular weight PAHs. The typical heating rate in a coal seam, 5 ℃/min, results in intermediate yields of PAHs. The total PAHs yield in an atmosphere of N2 is about 1.81 times that seen without added N2, which indicates that an air flow through the coal seam accelerates the formation of PAHs. An increase in coal particle size reduces the total PAHs emission but promotes the formation of 5- and f-ring PAHs.
文摘Growth of an anthropogenic load on an environment in the second halfofXXth centuries has led to an exacerbation of many ecological problems. Today ecological risk scales cover territories of large regions. In this respect the territory of Azerbaijan is not exception, within which Baku is noted by very adverse ecological conditions. Complex natural conditions (presence of strong winds, high air temperature and solar radiation) complicate the city ecological situation even greater. In modem conditions a construction boom relates to the factors aggravating the ecological situation of Baku. Last 10 years the city is rapidly built on by multistoried buildings which deform it, hinder visual contacts to the environment and obstruct the natural aeration of Baku amphitheater. The modem multistoried buildings erected ignoring town-planning norms do not correspond with regional climatic conditions, essentially modify the territory wind regime, hamper in surrounding buildings insolation, neglect a territory temperature-humidity conditions. As a result, it is necessary to use energy overly for their adaptation to Baku conditions and creation comfortable microclimate in them that leads to the city environmental pollution. The planning decisions and construction materials applied in these buildings are also alien to Baku climatic conditions. For qualitative transformation of Baku environment and improvement of ecological characteristics of the residential areas the author has carried out the estimation of the city territory on a complex of climatic factors (aeration, insolation and thermal-humidity regimes). For these purposes the multidimensional statistical method is used. As a result the investigated territory of Baku is divided into 5 typological areas on climatic conditions. The brief characteristic and the general recommendations on transformation are worked out by the author for each of these typological units. Results of the research can be a basis for revealing of methods and principles of town-planning and architectural-planning organization of Baku residential areas.
基金supported by the Fundamental Research funds for the central Universities of China (No. K15JB00190)the Ph.D. Programs Foundation of Ministry of Education of China (No. 20120009120010)the Program for Innovative Research Team in University of Ministry of Education of China (IRT201206)
文摘Separation issue is one of the most important problems about cloud computing security. Tenants should be separated from each other based on cloud infrastructure and different users from one tenant should be separated from each other with the constraint of security policies. Learning from the notion of trusted cloud computing and trustworthiness in cloud, in this paper, a multi-level authorization separation model is formally described, and a series of rules are proposed to summarize the separation property of this model. The correctness of the rules is proved. Furthermore, based on this model, a tenant separation mechanism is deployed in a real world mixed-critical information system. Performance benchmarks have shown the availability and efficiency of this mechanism.