In order to better understand the prevailing mechanism of CO2 storage in coal and estimate CO2 sequestration capacity of a coal seam and enhanced coalbed methane recovery （ECBM） with CO2 injection into coal, we inve...In order to better understand the prevailing mechanism of CO2 storage in coal and estimate CO2 sequestration capacity of a coal seam and enhanced coalbed methane recovery （ECBM） with CO2 injection into coal, we investigated the preferential adsorption of CH4 and CO2 on coals. Adsorption of pure CO2, CH4 and their binary mixtures on high-rank coals from Qinshui Basin in China were employed to study the preferential adsorption behaviour. Multiple regression equations were presented to predict CH4 equi- librium concentration from equilibrium pressure and its initial-composition in feed gas. The results show that preferential adsorption of CO2 on coals over the entire pressure range under competitive sorption conditions was observed, however, preferential adsorption of CH4 over CO2 on low-volatile bituminous coal from higher CH4-compostion in source gas was found at up to 1O MPa pressure. Preferential adsorp- tion of CO2 increases with increase of CH4 concentration in source gas, and decreases with increasing pressure. Although there was no systematic investigation of the effect of coal rank on preferential adsorp- tion, there are obvious differences in preferential adsorption of gas between low-volatile bituminous coal and anthracite. The obtained preferential adsorption gives rise to the assumption that CO2 sequestration in coal beds with subsequent CO2-ECBM might be an ootion in Qinshui Basins, China.展开更多
We investigate the subsurface heat exchange process in EGS （enhanced geothermal systems） with a previously developed novel model. This model treats the porous heat reservoir as an equivalent porous medium of a singl...We investigate the subsurface heat exchange process in EGS （enhanced geothermal systems） with a previously developed novel model. This model treats the porous heat reservoir as an equivalent porous medium of a single porosity. However, it considers local thermal non-equilibrium between solid rock matrix and fluid flowing in the factures and employs two energy conservation equations to describe heat transfer in the rock matrix and in the fractures, respectively, enabling the modeling and analyses of convective heat exchange in the heat reservoir. Another salient feature of this model is its capability of simulating the complete subsurface heat exchange process in EGS. The EGS subsurface geometry of interest physically consists of multiple domains： open channels for injection and production wells, the artificial heat reservoir, and the rocks enclosing the heat reservoir, while computationally we treat it as a single-domain of multiple sub-regions associated with different sets of characteristic properties （porosity and permeability, etc.）. This circumvents typical difficulties about matching boundary conditions between sub-domains in traditional multi-domain approaches and facilitates numerical implementation and simulation of the complete subsurface heat exchange process. This model is used to perform a comprehensive parametric study with respect to an imaginary doublet EGS. Effects of several parameters, including the permeability of heat reservoir, heat exchange coefficient in the heat reservoir, the specific area of fractures in the heat reservoir, and thermal compensation from surrounding rocks, on the heat extraction efficiency and EGS lifetime are analyzed.展开更多
Theoretical and numerical analysis on the fluid flow and heat transfer inside a LNG evaporator is conducted in this work. Methane is used instead of LNG as the operating fluid. This is because; methane constitutes ove...Theoretical and numerical analysis on the fluid flow and heat transfer inside a LNG evaporator is conducted in this work. Methane is used instead of LNG as the operating fluid. This is because; methane constitutes over 80% of natural gas. The analytical calculations are performed using simple mass and energy balance equations. The analytical calculations are made to assess the pressure and temperature variations in the steam tube. Multiphase numerical simulations are performed by solving the governing equations(basic flow equations of continuity, momentum and energy equations) in a portion of the evaporator domain consisting of a single steam pipe. The flow equations are solved along with equations of species transport. Multiphase modeling is incorporated using VOF method. Liquid methane is the primary phase. It vaporizes into the secondary phase gaseous methane. Steam is another secondary phase which flows through the heating coils. Turbulence is modeled by a two equation turbulence model. Both the theoretical and numerical predictions are seen to match well with each other. Further parametric studies are planned based on the current research.展开更多
基金supported by the National Natural Science Foundation of China(Nos.51174127 and 21176145)the Natural Science Foundation of Shandong Province(No.ZR2011DM005)the Open Research Fund Program of Key Laboratory of Mine Disaster Prevention and Control(Shandong University of Science and Technology)(No.MDPC0806)
文摘In order to better understand the prevailing mechanism of CO2 storage in coal and estimate CO2 sequestration capacity of a coal seam and enhanced coalbed methane recovery （ECBM） with CO2 injection into coal, we investigated the preferential adsorption of CH4 and CO2 on coals. Adsorption of pure CO2, CH4 and their binary mixtures on high-rank coals from Qinshui Basin in China were employed to study the preferential adsorption behaviour. Multiple regression equations were presented to predict CH4 equi- librium concentration from equilibrium pressure and its initial-composition in feed gas. The results show that preferential adsorption of CO2 on coals over the entire pressure range under competitive sorption conditions was observed, however, preferential adsorption of CH4 over CO2 on low-volatile bituminous coal from higher CH4-compostion in source gas was found at up to 1O MPa pressure. Preferential adsorp- tion of CO2 increases with increase of CH4 concentration in source gas, and decreases with increasing pressure. Although there was no systematic investigation of the effect of coal rank on preferential adsorp- tion, there are obvious differences in preferential adsorption of gas between low-volatile bituminous coal and anthracite. The obtained preferential adsorption gives rise to the assumption that CO2 sequestration in coal beds with subsequent CO2-ECBM might be an ootion in Qinshui Basins, China.
文摘We investigate the subsurface heat exchange process in EGS （enhanced geothermal systems） with a previously developed novel model. This model treats the porous heat reservoir as an equivalent porous medium of a single porosity. However, it considers local thermal non-equilibrium between solid rock matrix and fluid flowing in the factures and employs two energy conservation equations to describe heat transfer in the rock matrix and in the fractures, respectively, enabling the modeling and analyses of convective heat exchange in the heat reservoir. Another salient feature of this model is its capability of simulating the complete subsurface heat exchange process in EGS. The EGS subsurface geometry of interest physically consists of multiple domains： open channels for injection and production wells, the artificial heat reservoir, and the rocks enclosing the heat reservoir, while computationally we treat it as a single-domain of multiple sub-regions associated with different sets of characteristic properties （porosity and permeability, etc.）. This circumvents typical difficulties about matching boundary conditions between sub-domains in traditional multi-domain approaches and facilitates numerical implementation and simulation of the complete subsurface heat exchange process. This model is used to perform a comprehensive parametric study with respect to an imaginary doublet EGS. Effects of several parameters, including the permeability of heat reservoir, heat exchange coefficient in the heat reservoir, the specific area of fractures in the heat reservoir, and thermal compensation from surrounding rocks, on the heat extraction efficiency and EGS lifetime are analyzed.
基金supported by a grant from 2016 Research Funds of Andong National University
文摘Theoretical and numerical analysis on the fluid flow and heat transfer inside a LNG evaporator is conducted in this work. Methane is used instead of LNG as the operating fluid. This is because; methane constitutes over 80% of natural gas. The analytical calculations are performed using simple mass and energy balance equations. The analytical calculations are made to assess the pressure and temperature variations in the steam tube. Multiphase numerical simulations are performed by solving the governing equations(basic flow equations of continuity, momentum and energy equations) in a portion of the evaporator domain consisting of a single steam pipe. The flow equations are solved along with equations of species transport. Multiphase modeling is incorporated using VOF method. Liquid methane is the primary phase. It vaporizes into the secondary phase gaseous methane. Steam is another secondary phase which flows through the heating coils. Turbulence is modeled by a two equation turbulence model. Both the theoretical and numerical predictions are seen to match well with each other. Further parametric studies are planned based on the current research.
