Gas phase polymerization of butadiene by neodymium catalyst was modeled. The effects of mass and heat transfer resistances in the external boundary layer and within particles, sorption of butadiene in polybutadiene,an...Gas phase polymerization of butadiene by neodymium catalyst was modeled. The effects of mass and heat transfer resistances in the external boundary layer and within particles, sorption of butadiene in polybutadiene,and deactivation of active sites on polymer particle growth and morphology were studied. Simulation results show that the effects of intraparticle mass and heat transfer resistances on the growth rate of polymer particles are insignificant, and that there is no significant effect of mass transfer resistance on the morphology of polymer particles.The simulation results were compared with the experimental results.展开更多
The non-tidal variation gained from continuous gravity observations in stations usually reflects the regional continuous gravity changes. In this paper we focus on studying the non-tidal variation of Baijiatuan statio...The non-tidal variation gained from continuous gravity observations in stations usually reflects the regional continuous gravity changes. In this paper we focus on studying the non-tidal variation of Baijiatuan station,Beijing where there are two different gravimeters( namely,L&R-804 and PET-031). Based on the original raw tidal records of two gravimeters from 2008 to 2011,we first remove various interference from raw data by the standard procedure software-Tsoft; then we model the solid earth tides, ocean tidal loading and pole tide through related parameters; after that we adopt a new segmented polynomial fitting method based on Tsoft to fit the complex drift of spring gravimeter; and finally we calculate the atmospheric loading effects by a linear regression model. After a series of processing we gain the non-tidal variation of the two gravimeters at Baijiatuan site,Beijing. Furthermore,to analyze the non-tidal variation preliminarily,we study the main component of related tidal data by power spectral density. Comparing the non-tidal variation of two different gravimeters,we find seasonal fluctuations in non-tidal results, which are in accordance with the water storage change. Therefore,we take into account the relevance of gravity changes and water storage based on the gravity data of GRACE and water data of the CMAP model from 2003 to 2011 at different sites in the Chinese mainland( Beijing, Chengdu, Shenyang and Shiquanhe), and make a preliminary analysis on the relationship between gravity changes and water storage.展开更多
With the goal of model fitting species abundance distribution patterns of the tree,shrub and herb layers of the natural Toona ciliata community in Xingdoushan Nature Reserve,Enshi Autonomous Prefecture,Hubei Province,...With the goal of model fitting species abundance distribution patterns of the tree,shrub and herb layers of the natural Toona ciliata community in Xingdoushan Nature Reserve,Enshi Autonomous Prefecture,Hubei Province,we used the data collected from the field survey and employed different ecological niche models.The models tested were the broken stick model(BSM),the overlapping niche model(ONM)and the niche preemption model(NPM),as well as three statistic models,the log-series distribution model(LSD),the log-normal distribution model(LND)and the Weibull distribution model(WDM).To determine the fitted model most suitable to each layer,the fitting effects were judged by criteria of the lowest value of Akaike Information Criterion(AIC),Chi-square and the K-S values with no significant difference(P>0.05)between the theoretical predictions and observed species abundance distribution values.The result showed:(1)The fitting suitability and goodness of fit of the tree,shrub and herb layers by using the three ecological niche models were ranked as:NPM>BSM>ONM.Of the three statistical models,by accepting the fitting results of the three layers,WDM was the best fitting model,followed by LND.By rejecting the fitting tests of the herb layer,LSD had the worst fitting effect.The goodness of the statistical models was ranked as:WDM>LND>LSD.In general,the statistical models had better fitting results than the ecological models.(2)T.ciliata was the dominant species of the tree layer.The species richness and diversity of the herb layer were much higher than those of either the tree layer or the shrub layer.The species richness and diversity of the shrub layer were slightly higher than those of the tree layer.The community evenness accorded to the following order:herb>shrub>tree.Considering the fitting results of the different layers,different ecological niche models or statistical models with optimal goodness of fit and ecological significance can be given priority to in studying the species abundance distribution patterns of T.ciliata communities.展开更多
In order to investigate propagation regularity of hydraulic fractures in the mode of multi-well pads, numerical modeling of simultaneous hydraulic fracturing of multiple wells was conducted. The mathematical model was...In order to investigate propagation regularity of hydraulic fractures in the mode of multi-well pads, numerical modeling of simultaneous hydraulic fracturing of multiple wells was conducted. The mathematical model was established coupling rock deformation with fluid flow in the fractures and wellbores. And then the model was solved by displacement discontinuity method coupling with implicit level set method. The implicit method was based on fracture tip asymptotical solution and used to determine fracture growth length. Simulation results showed that when multiple wells were fractured simultaneously, adjacent fractures might propagate towards each other, showing an effect of attraction other than repulsion. Fracture spacing and well spacing had significant influence on the propagation path and geometry of multiple fractures. Furthermore, when multiple wells were fractured simultaneously, stress reversal regions had a large area, and stress reversal regions were distributed not only in the area between fractures but also on the outside of them. The area of stress reversal regions was related to fracture spacing and well spacing. Results indicated that multi-well fracturing induced larger area of stress reversal regions than one-well fracturing, which was beneficial to generating complex fracture network in unconventional reservoirs.展开更多
基金Supported by the National Natural Science Foundation of China (No. 29876035).
文摘Gas phase polymerization of butadiene by neodymium catalyst was modeled. The effects of mass and heat transfer resistances in the external boundary layer and within particles, sorption of butadiene in polybutadiene,and deactivation of active sites on polymer particle growth and morphology were studied. Simulation results show that the effects of intraparticle mass and heat transfer resistances on the growth rate of polymer particles are insignificant, and that there is no significant effect of mass transfer resistance on the morphology of polymer particles.The simulation results were compared with the experimental results.
基金sponsored by the Basic Scientific Research of Institute of Geophysics,CEA(DQJB12B20,DQJB12C03,DQJB12B14)
文摘The non-tidal variation gained from continuous gravity observations in stations usually reflects the regional continuous gravity changes. In this paper we focus on studying the non-tidal variation of Baijiatuan station,Beijing where there are two different gravimeters( namely,L&R-804 and PET-031). Based on the original raw tidal records of two gravimeters from 2008 to 2011,we first remove various interference from raw data by the standard procedure software-Tsoft; then we model the solid earth tides, ocean tidal loading and pole tide through related parameters; after that we adopt a new segmented polynomial fitting method based on Tsoft to fit the complex drift of spring gravimeter; and finally we calculate the atmospheric loading effects by a linear regression model. After a series of processing we gain the non-tidal variation of the two gravimeters at Baijiatuan site,Beijing. Furthermore,to analyze the non-tidal variation preliminarily,we study the main component of related tidal data by power spectral density. Comparing the non-tidal variation of two different gravimeters,we find seasonal fluctuations in non-tidal results, which are in accordance with the water storage change. Therefore,we take into account the relevance of gravity changes and water storage based on the gravity data of GRACE and water data of the CMAP model from 2003 to 2011 at different sites in the Chinese mainland( Beijing, Chengdu, Shenyang and Shiquanhe), and make a preliminary analysis on the relationship between gravity changes and water storage.
基金Public Welfare Research Project of Department of Science and Technology in Hubei Province(40 2012DBA40001)Scientific Research Project of Department of Education in Hubei Province(B20160555)
文摘With the goal of model fitting species abundance distribution patterns of the tree,shrub and herb layers of the natural Toona ciliata community in Xingdoushan Nature Reserve,Enshi Autonomous Prefecture,Hubei Province,we used the data collected from the field survey and employed different ecological niche models.The models tested were the broken stick model(BSM),the overlapping niche model(ONM)and the niche preemption model(NPM),as well as three statistic models,the log-series distribution model(LSD),the log-normal distribution model(LND)and the Weibull distribution model(WDM).To determine the fitted model most suitable to each layer,the fitting effects were judged by criteria of the lowest value of Akaike Information Criterion(AIC),Chi-square and the K-S values with no significant difference(P>0.05)between the theoretical predictions and observed species abundance distribution values.The result showed:(1)The fitting suitability and goodness of fit of the tree,shrub and herb layers by using the three ecological niche models were ranked as:NPM>BSM>ONM.Of the three statistical models,by accepting the fitting results of the three layers,WDM was the best fitting model,followed by LND.By rejecting the fitting tests of the herb layer,LSD had the worst fitting effect.The goodness of the statistical models was ranked as:WDM>LND>LSD.In general,the statistical models had better fitting results than the ecological models.(2)T.ciliata was the dominant species of the tree layer.The species richness and diversity of the herb layer were much higher than those of either the tree layer or the shrub layer.The species richness and diversity of the shrub layer were slightly higher than those of the tree layer.The community evenness accorded to the following order:herb>shrub>tree.Considering the fitting results of the different layers,different ecological niche models or statistical models with optimal goodness of fit and ecological significance can be given priority to in studying the species abundance distribution patterns of T.ciliata communities.
基金supported by the National Natural Science Foundation of China(Grant Nos.51234007&51490654)the National Science Foundation for Young Scientists of China(Grant No.51404291)+1 种基金Fundamental Research Funds for Central Universities(Grant Nos.14CX05024A&14CX02045A)Shandong Provincial Natural Science Foundation(Grant No.ZR2014EEQ010)
文摘In order to investigate propagation regularity of hydraulic fractures in the mode of multi-well pads, numerical modeling of simultaneous hydraulic fracturing of multiple wells was conducted. The mathematical model was established coupling rock deformation with fluid flow in the fractures and wellbores. And then the model was solved by displacement discontinuity method coupling with implicit level set method. The implicit method was based on fracture tip asymptotical solution and used to determine fracture growth length. Simulation results showed that when multiple wells were fractured simultaneously, adjacent fractures might propagate towards each other, showing an effect of attraction other than repulsion. Fracture spacing and well spacing had significant influence on the propagation path and geometry of multiple fractures. Furthermore, when multiple wells were fractured simultaneously, stress reversal regions had a large area, and stress reversal regions were distributed not only in the area between fractures but also on the outside of them. The area of stress reversal regions was related to fracture spacing and well spacing. Results indicated that multi-well fracturing induced larger area of stress reversal regions than one-well fracturing, which was beneficial to generating complex fracture network in unconventional reservoirs.