Slow collisions of highly charged ions with neutral atoms and molecules are of great importance in basic atomic collision physics, Recently, we built a new research facility for atomic physics at the Institute of Mode...Slow collisions of highly charged ions with neutral atoms and molecules are of great importance in basic atomic collision physics, Recently, we built a new research facility for atomic physics at the Institute of Modern Physics. We report here the multiple electron transfer processes in collisions of Ar^9+ with Na gas target at energy of 180 keV.展开更多
Due to its high energy density,lithium-sulfur(Li-S)battery is considered as the most promising candidate for the energy storage systems,but its practical application is hindered by the dissolution of lithium polysulfi...Due to its high energy density,lithium-sulfur(Li-S)battery is considered as the most promising candidate for the energy storage systems,but its practical application is hindered by the dissolution of lithium polysulfides in the electrolyte.In this work,N-bromophthalimide(C8H4NO2Br,NBP),an aromatic molecule with carbophilic,sulfiphilic,lithiophilic,and solvophilic nature,is introduced into active graphene(AG)to fabricate the sulfur composite cathode.The carbophilic NBP is anchored readily on the AG surface viaπ−πstacking interaction.During discharging,the dissolved lithium polysulfide anion(LiS−n)is grafted into the sulfiphilic NBP spontaneously via SN2 substitution reaction to form C8H4NO2SnLi,which brings the dissolved LiS−n back to the AG surface in the composite cathode.Moreover,the lithiophilic and solvophilic nature of NBP improve the wettability of the porous composite cathode,and the electrolyte molecule is easily penetrated into the micro-mesopores of AG to facilitate the diffusion of the electrolyte.Thus,NBP,as a multi-functional compound in Li-S battery,can immobilize LiS−n and enhance the diffusion of the electrolyte.The above features of NBP endow the sulfur composite cathode with improved electrochemical performance in the cycling stability.展开更多
文摘Slow collisions of highly charged ions with neutral atoms and molecules are of great importance in basic atomic collision physics, Recently, we built a new research facility for atomic physics at the Institute of Modern Physics. We report here the multiple electron transfer processes in collisions of Ar^9+ with Na gas target at energy of 180 keV.
基金financially supported by the National Natural Science Foundation of China (21573112, 21935006, 21421001 and 21373118)
文摘Due to its high energy density,lithium-sulfur(Li-S)battery is considered as the most promising candidate for the energy storage systems,but its practical application is hindered by the dissolution of lithium polysulfides in the electrolyte.In this work,N-bromophthalimide(C8H4NO2Br,NBP),an aromatic molecule with carbophilic,sulfiphilic,lithiophilic,and solvophilic nature,is introduced into active graphene(AG)to fabricate the sulfur composite cathode.The carbophilic NBP is anchored readily on the AG surface viaπ−πstacking interaction.During discharging,the dissolved lithium polysulfide anion(LiS−n)is grafted into the sulfiphilic NBP spontaneously via SN2 substitution reaction to form C8H4NO2SnLi,which brings the dissolved LiS−n back to the AG surface in the composite cathode.Moreover,the lithiophilic and solvophilic nature of NBP improve the wettability of the porous composite cathode,and the electrolyte molecule is easily penetrated into the micro-mesopores of AG to facilitate the diffusion of the electrolyte.Thus,NBP,as a multi-functional compound in Li-S battery,can immobilize LiS−n and enhance the diffusion of the electrolyte.The above features of NBP endow the sulfur composite cathode with improved electrochemical performance in the cycling stability.
