The development of efficient nonprecious bifunctional electrocatalysts for water electrolysis is crucial to enhance the sluggish kinetics of the oxygen evolution reaction(OER)and hydrogen evolution reaction(HER).A sel...The development of efficient nonprecious bifunctional electrocatalysts for water electrolysis is crucial to enhance the sluggish kinetics of the oxygen evolution reaction(OER)and hydrogen evolution reaction(HER).A self-supporting,multiscale porous NiFeZn/NiZn-Ni catalyst with a triple interface heterojunction on nickel foam(NF)(NiFeZn/NiZn-Ni/NF)was in-situ fabricated using an electroplating-annealing-etching strategy.The unique multiinterface engineering and three-dimensional porous scaffold significantly modify the mass transport and electron interaction,resulting in superior bifunctional electrocatalytic performance for water splitting.The NiFeZn/NiZn-Ni/NF catalyst demonstrates low overpotentials of 187 m V for HER and 320 mV for OER at a current density of 600 mA/cm^(2),along with high durability over 150 h in alkaline solution.Furthermore,an electrolytic cell assembled with NiFeZn/NiZn-Ni/NF as both the cathode and anode achieves the current densities of 600 and 1000 m A/cm^(2) at cell voltages of 1.796 and 1.901 V,respectively,maintaining the high stability at 50 mA/cm^(2) for over 100 h.These findings highlight the potential of NiFeZn/NiZn-Ni/NF as a cost-effective and highly efficient bifunctional electrocatalyst for overall water splitting.展开更多
In order to improve the comprehensive properties of the Cu-11.9Al-2.5Mn shape memory alloy(SMA),multilayer graphene(MLG)carried by Cu_(51)Zr_(14)inoculant particles was incorporated and dispersed into this alloy throu...In order to improve the comprehensive properties of the Cu-11.9Al-2.5Mn shape memory alloy(SMA),multilayer graphene(MLG)carried by Cu_(51)Zr_(14)inoculant particles was incorporated and dispersed into this alloy through preparing the preform of the cold-pressed MLG-Cu_(51)Zr_(14)composite powders.In the resultant novel MLG/Cu-Al-Mn composites,MLG in fragmented or flocculent form has a good bonding with the Cu-Al-Mn matrix.MLG can prevent the coarsening of grains of the Cu-Al-Mn SMA and cause thermal mismatch dislocations near the MLG/Cu-Al-Mn interfaces.The damping and mechanical properties of the MLG/Cu-Al-Mn composites are significantly improved.When the content of MLG reaches 0.2 wt.%,the highest room temperature damping of 0.0558,tensile strength of 801.5 MPa,elongation of 10.8%,and hardness of HV 308 can be obtained.On the basis of in-depth observation of microstructures,combined with the theory of internal friction and strengthening and toughening theories of metals,the relevant mechanisms are discussed.展开更多
Carbon/carbon composites modified by NiAl alloy were prepared using vacuum reactive melt infiltration methods with NiAl and titanium mixed powders as raw materials. The microstructures were investigated by scanning el...Carbon/carbon composites modified by NiAl alloy were prepared using vacuum reactive melt infiltration methods with NiAl and titanium mixed powders as raw materials. The microstructures were investigated by scanning electron microscopy. The fracture behavior, infiltration and oxidation mechanism were further discussed. The results indicated that NiAl alloy exhibited good wettability on the C/C preform because a TiC reaction layer formed at the interface. Multi-layer(PyC/TiC/NiAl+TiC) coating evenly and compactly distributed on the surface of the carbon fiber in tubular form. The penetration depth of molten NiAl alloys depended on the reaction between the PyC and titanium. The impact fracture was inclined to along the interface between the NiAl permeability layer and C/C matrix. Al_2TiO_5 and TiO_2 formed on the surface, while the interior multi-layer tubular structure partially remained after oxidation at 1773 K for 30 min.展开更多
Interfacial bonding in as deposited and annealed Co/C soft X ray multilayer structures is investigated by X ray photo electron spectroscopy (XPS).It is found that there is interdiffusion between cobalt and carbon ...Interfacial bonding in as deposited and annealed Co/C soft X ray multilayer structures is investigated by X ray photo electron spectroscopy (XPS).It is found that there is interdiffusion between cobalt and carbon in the as deposited Co/C multilayers,and this is confirmed by structure characterization using low angle X ray diffraction (LAXD).The calculation of the chemical shifts in Co C system based on Miedemas macroscopic atom model suggests that it is impossible to detect the chemical shift experimentally in the Co C compound,which is consistent with the XPS results.The presence of metallic carbide bonding is evidenced through the nature of the carbon bonding in survey taken at Co C and C Co interfaces of annealed samples.Our results also indicate that XPS is a direct method to probe the chemical bonding at the interfaces.展开更多
The selection of the truncation level (TL) and the control of boundary effect (BE) are critical in regional geomagnetic field models that are based on data fitting. We combine Taylor and Legendre polynomials to mo...The selection of the truncation level (TL) and the control of boundary effect (BE) are critical in regional geomagnetic field models that are based on data fitting. We combine Taylor and Legendre polynomials to model geomagnetic data over China's Mainland for years 1960, 1970, 1990, and 2000. To tackle the TL and BE problems, we first determine the range of TL by calculating the root-mean-square error (RMSE) of the models. Next, we determine the optimum TL using the Akaike information criterion (AIC) and the normalized root- mean-square error (NRMSE). We use the regional anomaly addition (RAA) and the uniform addition (UA) method to add supplementary point outside the national boundary, and find that the intensities of extreme points gradually decrease and stabilize. The UA method better controls BEs over China, whereas the RAA method does a better job at smaller scales. In summary, we rely on a three-step method to determine the optimum TL and propose criteria to determine the optimum number of supplementary points.展开更多
The topic on the subspaces for the polynomially or exponentially bounded weak mild solutions of the following abstract Cauchy problem d^2/(dr^2)u(t,x)=Au(t,x);u(0,x)=x,d/(dt)u(0,x)=0,x∈X is studied, wher...The topic on the subspaces for the polynomially or exponentially bounded weak mild solutions of the following abstract Cauchy problem d^2/(dr^2)u(t,x)=Au(t,x);u(0,x)=x,d/(dt)u(0,x)=0,x∈X is studied, where A is a closed operator on Banach space X. The case that the problem is ill-posed is treated, and two subspaces Y(A, k) and H(A, ω) are introduced. Y(A, k) is the set of all x in X for which the second order abstract differential equation has a weak mild solution v( t, x) such that ess sup{(1+t)^-k|d/(dt)〈v(t,x),x^*〉|:t≥0,x^*∈X^*,|x^*‖≤1}〈+∞. H(A, ω) is the set of all x in X for which the second order abstract differential equation has a weak mild solution v(t,x)such that ess sup{e^-ωl|d/(dt)〈v(t,x),x^*)|:t≥0,x^*∈X^*,‖x^*‖≤1}〈+∞. The following conclusions are proved that Y(A, k) and H(A, ω) are Banach spaces, and both are continuously embedded in X; the restriction operator A | Y(A,k) generates a once-integrated cosine operator family { C(t) }t≥0 such that limh→0+^-1/h‖C(t+h)-C(t)‖Y(A,k)≤M(1+t)^k,arbitary t≥0; the restriction operator A |H(A,ω) generates a once- integrated cosine operator family {C(t)}t≥0 such that limh→0+^-1/h‖C(t+h)-C(t)‖H(A,ω)≤≤Me^ωt,arbitary t≥0.展开更多
The growth interfaces of CdMnTe(CMT) crystals grown by traveling heater method(THM) were studied. Two types of polycrystalline CMT feed ingots synthesized in a traditional rocking furnace and vertical Bridgman(VB...The growth interfaces of CdMnTe(CMT) crystals grown by traveling heater method(THM) were studied. Two types of polycrystalline CMT feed ingots synthesized in a traditional rocking furnace and vertical Bridgman(VB) furnace were adopted in THM growth, and the effects of the polycrystalline feed on the growth interface were revealed. The morphology of the growth interface of CMT crystal(CMT2) grown from the feed by vertical Bridgman was smoother with lower curvature compared with that of CMT crystal(CMT1) from the feed by rocking furnace. The radial Mn composition and Te inclusion distribution of the CMT wafers were analyzed and correlated to the growth interface. The Mn segregation along the radial direction and Te inclusion density of CMT2 were lower than those of CMT1. The VB method synthesized polycrystalline feed could improve the growth interface morphology, which is beneficial for decreasing the Te inclusions and Mn segregation in CMT wafers.展开更多
The heterogeneous multilayer interface of VN/Ag coatings and transition multilayer interface of VN/Ag coatings were prepared on Inconel 781 and Si(100),and the microstructures,mechanical and tribological properties we...The heterogeneous multilayer interface of VN/Ag coatings and transition multilayer interface of VN/Ag coatings were prepared on Inconel 781 and Si(100),and the microstructures,mechanical and tribological properties were investigated from 25 to 700℃.The results showed that the surface roughness and average grain size of VN/Ag coatings with transition multilayer interface are obviously larger than those of VN/Ag coatings with heterogeneous multilayer interface.The coatings with transition multilayer interface have higher adhesion force and hardness than the coatings with heterogeneous multilayer interface,and both coatings can effectively restrict the initiation and propagation of microcracks.Both coatings have excellent self-adaptive lubricating properties with a decrease of friction coefficient as the temperature increases,but their wear rates reveal a drastic increase.The phase composition of the worn area of both coatings was investigated,which indicates that a smooth Ag,Magnéli phase(V2O5)and bimetallic oxides(Ag3VO4 and AgVO3)can be responsible to the excellent lubricity of both coatings.To sum up,the coatings with transition multilayer interface have excellent adaptive lubricating properties and can properly control the diffusion rate and release rate of the lubricating phase,indicating that they have great potential in solving the problem of friction and wear of mechanical parts.展开更多
In this study,an ultra‐fast and simple solvent‐free microwave method was successfully demonstrated using a series of ultra‐small(~2.5 nm)surfactant‐free Ru_(2)P@Ru/CNT heterostructures for the first time.The struc...In this study,an ultra‐fast and simple solvent‐free microwave method was successfully demonstrated using a series of ultra‐small(~2.5 nm)surfactant‐free Ru_(2)P@Ru/CNT heterostructures for the first time.The structure has a high‐density Ru component and Ru_(2)P component interface,which accelerates the hydrogen evolution reaction(HER).The prepared Ru_(2)P@Ru/CNT demonstrated excellent catalytic effects for the HER in alkaline media and real seawater.The experimental results indicate that ratio‐optimized Ru_(2)P@Ru/CNT(Ru_(2)P:Ru=66:34)requires only 23 and 29 mV to reach 10 mA cm^(-2)in 1.0 mol/L KOH and real seawater,respectively.These values are 10 and 24 mV lower than those of commercial Pt/C in 1.0 mol/L KOH(33 mV)and real seawater(53 mV),respectively,making it among the best non‐Pt HER reported in the literature.Additionally,the TOF of Ru_(2)P@Ru/CNT in alkaline freshwater and seawater were 13.1 and 8.5 s^(-1),respectively.These exceed the corresponding values for Pt/C,indicating that the catalyst has excellent intrinsic activity.The high current activity of Ru_(2)P@Ru/CNT in 1.0 mol/L KOH was explored,and only 77 and 104 mV were required to reach 500 and 1000 mA cm^(-2),respectively.After 100 h of durability testing,the catalyst retained excellent catalytic and structural stability in low current density,high current density,and seawater.展开更多
In the present paper, we examine the performance of an efficient type of wave-absorbing porous marine structure under the attack of regular oblique waves by using a Multi-Domain Boundary Element Method(MDBEM). The str...In the present paper, we examine the performance of an efficient type of wave-absorbing porous marine structure under the attack of regular oblique waves by using a Multi-Domain Boundary Element Method(MDBEM). The structure consists of two perforated vertical thin barriers creating what can be called a wave absorbing chamber system. The barriers are surface piercing, thereby eliminating wave overtopping. The problem of the interaction of obliquely incident linear waves upon a pair of perforated barriers is first formulated in the context of linear diffraction theory. The resulting boundary integral equation, which is matched with far-field solutions presented in terms of analytical series with unknown coefficients, as well as the appropriate boundary conditions at the free surface, seabed, and barriers, is then solved numerically using MDBEM. Dissipation of the wave energy due to the presence of the perforated barriers is represented by a simple yet effective relation in terms of the porosity parameter appropriate for thin perforated walls. The results are presented in terms of reflection and transmission coefficients. The effects of the incident wave angles, relative water depths, porosities, depths of the walls, and other major parameters of interest are explored.展开更多
The rate equations with multipoint boundary conditions are solved by numerical method accurately.A novel method based on genetic algorithm is proposed to optimize distributed pump powers in kilowatt YDDC fiber laser i...The rate equations with multipoint boundary conditions are solved by numerical method accurately.A novel method based on genetic algorithm is proposed to optimize distributed pump powers in kilowatt YDDC fiber laser in this paper.The calculated results show that lower operation temperature and better uniformity can be achieved through an optimized pump arrangement.展开更多
Soil type maps at the scale of I Z 1 000 000 are used extensively to provide soil spatial distribution information for soil erosion assessment and watershed management models in China. However, the soil property maps ...Soil type maps at the scale of I Z 1 000 000 are used extensively to provide soil spatial distribution information for soil erosion assessment and watershed management models in China. However, the soil property maps produced through conventional direct linking method usually suffer low accuracy as well as the lack of spatial details within a soil type polygon. This paper presents an effective method to produce detailed soil property map based on representative samples which were extracted from each polygon on the 1 : 1 000 000 soil type map. The representative sample of each polygon is defined as the location that can represent the largest area within the polygon. The representativeness of a candidate sample is determined by calculating the soil-forming environment condition similarities between the sample and other locations. Once the representative sample of each polygon has been chosen, the property values of the existing typical samples are assigned to the corresponding representative samples with the same soil type. Finally, based on these representative samples, the detailed soil property map could be produced by using existing digital soil mapping methods. The case study in XuanCheng City, Anhui Province of China, demonstrated the proposed method could produce soil property map at a higher level of spatial details and accuracy: 1) The soil organic matter (SOM) map produced based on the representative samples can not only depict the detailed spatial distribution of SOM within a soil type polygon but also largely reduce the abrupt change of soil property at the boundaries of two adjacent polygons. 2) The Root Mean Squared Error (RMSE) of the SOM map based on the representative samples is 1.61, and it is 1.37 for the SOM map produced by using conventional direct linking method. Therefore, the proposed method is an effective approach to produce spatial detailed soil property map with higher accuracy for environment simulation models.展开更多
This paper presents an overview of the recent progress of potential theory method in the analysis of mixed boundary value problems mainly stemming from three-dimensional crack or contact problems of multi-field couple...This paper presents an overview of the recent progress of potential theory method in the analysis of mixed boundary value problems mainly stemming from three-dimensional crack or contact problems of multi-field coupled media. This method was used to derive a series of exact three dimensional solutions which should be of great theoretical significance because most of them usually cannot be derived by other methods such as the transform method and the trial-and-error method. Further, many solutions are obtained in terms of elementary functions that enable us to treat more complicated problems easily. It is pointed out here that the method is usually only applicable to media characterizing transverse isotropy, from which, however, the results for the isotropic case can be readily obtained.展开更多
Failure analysis of railway draw-hook coupler was carried out.The nondestructive testing method was undertaken on some failed couplers in service to designate critical areas of a coupler.Draw-Hook coupler is used to c...Failure analysis of railway draw-hook coupler was carried out.The nondestructive testing method was undertaken on some failed couplers in service to designate critical areas of a coupler.Draw-Hook coupler is used to connect with the same hook coupler or automatic coupler.The influence of each connection types on the coupler strength in this study was discussed.A numerical stress analysis using FEM was performed,and many approaches including critical plane approach were carried out on fatigue life prediction of coupler under different conditions.The results of the proposed fatigue criterion and fatigue life predictions,as well as static numerical analysis,are validated with experimental results.展开更多
We find that the squeezed two-mode number state is just a two-variable Hermite polynomial excitation of thetwo-mode squeezed vacuum state (THPES).We find that the Wigner function of THPES and its marginal distribution...We find that the squeezed two-mode number state is just a two-variable Hermite polynomial excitation of thetwo-mode squeezed vacuum state (THPES).We find that the Wigner function of THPES and its marginal distributionsare just related to two-variable Hermite polynomials (or Laguerre polynomials) and that the tomogram of THPES canbe expressed by one-mode Hermite polynomial.展开更多
基金financially supported from the National Natural Science Foundation of China(No.52201254)the Natural Science Foundation of Shandong Province,China(Nos.ZR2023ME155,ZR2020MB090,ZR2020QE012,ZR2020MB027)+1 种基金the Project of“20 Items of University”of Jinan,China(No.202228046)the Taishan Scholar Project of Shandong Province,China(No.tsqn202306226)。
文摘The development of efficient nonprecious bifunctional electrocatalysts for water electrolysis is crucial to enhance the sluggish kinetics of the oxygen evolution reaction(OER)and hydrogen evolution reaction(HER).A self-supporting,multiscale porous NiFeZn/NiZn-Ni catalyst with a triple interface heterojunction on nickel foam(NF)(NiFeZn/NiZn-Ni/NF)was in-situ fabricated using an electroplating-annealing-etching strategy.The unique multiinterface engineering and three-dimensional porous scaffold significantly modify the mass transport and electron interaction,resulting in superior bifunctional electrocatalytic performance for water splitting.The NiFeZn/NiZn-Ni/NF catalyst demonstrates low overpotentials of 187 m V for HER and 320 mV for OER at a current density of 600 mA/cm^(2),along with high durability over 150 h in alkaline solution.Furthermore,an electrolytic cell assembled with NiFeZn/NiZn-Ni/NF as both the cathode and anode achieves the current densities of 600 and 1000 m A/cm^(2) at cell voltages of 1.796 and 1.901 V,respectively,maintaining the high stability at 50 mA/cm^(2) for over 100 h.These findings highlight the potential of NiFeZn/NiZn-Ni/NF as a cost-effective and highly efficient bifunctional electrocatalyst for overall water splitting.
基金supported by the Natural Science Foundation of Hebei Province,China(No.E2021202017)the National Natural Science Foundation of China(No.52061038)+3 种基金the Foundation Strengthening Program,China(No.2019-JCJQ-ZD-142-00)the Hebei Province Graduate Innovation Funding Project,China(No.CXZZBS2022032)the Jiangsu Provincial Policy Guidance Program(Special Project for the Introduction of Foreign Talents)Talent Introduction Program,China(No.BX2021024)the Science Plan Foundation of Tianjin Municipal Education Commission,China(No.2021KJ026)。
文摘In order to improve the comprehensive properties of the Cu-11.9Al-2.5Mn shape memory alloy(SMA),multilayer graphene(MLG)carried by Cu_(51)Zr_(14)inoculant particles was incorporated and dispersed into this alloy through preparing the preform of the cold-pressed MLG-Cu_(51)Zr_(14)composite powders.In the resultant novel MLG/Cu-Al-Mn composites,MLG in fragmented or flocculent form has a good bonding with the Cu-Al-Mn matrix.MLG can prevent the coarsening of grains of the Cu-Al-Mn SMA and cause thermal mismatch dislocations near the MLG/Cu-Al-Mn interfaces.The damping and mechanical properties of the MLG/Cu-Al-Mn composites are significantly improved.When the content of MLG reaches 0.2 wt.%,the highest room temperature damping of 0.0558,tensile strength of 801.5 MPa,elongation of 10.8%,and hardness of HV 308 can be obtained.On the basis of in-depth observation of microstructures,combined with the theory of internal friction and strengthening and toughening theories of metals,the relevant mechanisms are discussed.
基金Project(2011CB605804) supported by the National Basic Research Development Program of ChinaProject(2015JJ3167) supported by the Natural Science Foundation of Hunan Province,ChinaProject(2013M531810) supported by the Postdoctoral Science Foundation of China
文摘Carbon/carbon composites modified by NiAl alloy were prepared using vacuum reactive melt infiltration methods with NiAl and titanium mixed powders as raw materials. The microstructures were investigated by scanning electron microscopy. The fracture behavior, infiltration and oxidation mechanism were further discussed. The results indicated that NiAl alloy exhibited good wettability on the C/C preform because a TiC reaction layer formed at the interface. Multi-layer(PyC/TiC/NiAl+TiC) coating evenly and compactly distributed on the surface of the carbon fiber in tubular form. The penetration depth of molten NiAl alloys depended on the reaction between the PyC and titanium. The impact fracture was inclined to along the interface between the NiAl permeability layer and C/C matrix. Al_2TiO_5 and TiO_2 formed on the surface, while the interior multi-layer tubular structure partially remained after oxidation at 1773 K for 30 min.
文摘Interfacial bonding in as deposited and annealed Co/C soft X ray multilayer structures is investigated by X ray photo electron spectroscopy (XPS).It is found that there is interdiffusion between cobalt and carbon in the as deposited Co/C multilayers,and this is confirmed by structure characterization using low angle X ray diffraction (LAXD).The calculation of the chemical shifts in Co C system based on Miedemas macroscopic atom model suggests that it is impossible to detect the chemical shift experimentally in the Co C compound,which is consistent with the XPS results.The presence of metallic carbide bonding is evidenced through the nature of the carbon bonding in survey taken at Co C and C Co interfaces of annealed samples.Our results also indicate that XPS is a direct method to probe the chemical bonding at the interfaces.
基金supported by the National Natural Science Foundation of China(Grant Nos.41404053 and 41174165)Special Project for Meteo-Scientific Research in the Public Interest(Grant No.GYHY201306073)Natural Science Foundation of Higher Education Institutions of Jiangsu Province,China(Grant No.14KJB170012)
文摘The selection of the truncation level (TL) and the control of boundary effect (BE) are critical in regional geomagnetic field models that are based on data fitting. We combine Taylor and Legendre polynomials to model geomagnetic data over China's Mainland for years 1960, 1970, 1990, and 2000. To tackle the TL and BE problems, we first determine the range of TL by calculating the root-mean-square error (RMSE) of the models. Next, we determine the optimum TL using the Akaike information criterion (AIC) and the normalized root- mean-square error (NRMSE). We use the regional anomaly addition (RAA) and the uniform addition (UA) method to add supplementary point outside the national boundary, and find that the intensities of extreme points gradually decrease and stabilize. The UA method better controls BEs over China, whereas the RAA method does a better job at smaller scales. In summary, we rely on a three-step method to determine the optimum TL and propose criteria to determine the optimum number of supplementary points.
基金The Natural Science Foundation of Department ofEducation of Jiangsu Province (No06KJD110087)
文摘The topic on the subspaces for the polynomially or exponentially bounded weak mild solutions of the following abstract Cauchy problem d^2/(dr^2)u(t,x)=Au(t,x);u(0,x)=x,d/(dt)u(0,x)=0,x∈X is studied, where A is a closed operator on Banach space X. The case that the problem is ill-posed is treated, and two subspaces Y(A, k) and H(A, ω) are introduced. Y(A, k) is the set of all x in X for which the second order abstract differential equation has a weak mild solution v( t, x) such that ess sup{(1+t)^-k|d/(dt)〈v(t,x),x^*〉|:t≥0,x^*∈X^*,|x^*‖≤1}〈+∞. H(A, ω) is the set of all x in X for which the second order abstract differential equation has a weak mild solution v(t,x)such that ess sup{e^-ωl|d/(dt)〈v(t,x),x^*)|:t≥0,x^*∈X^*,‖x^*‖≤1}〈+∞. The following conclusions are proved that Y(A, k) and H(A, ω) are Banach spaces, and both are continuously embedded in X; the restriction operator A | Y(A,k) generates a once-integrated cosine operator family { C(t) }t≥0 such that limh→0+^-1/h‖C(t+h)-C(t)‖Y(A,k)≤M(1+t)^k,arbitary t≥0; the restriction operator A |H(A,ω) generates a once- integrated cosine operator family {C(t)}t≥0 such that limh→0+^-1/h‖C(t+h)-C(t)‖H(A,ω)≤≤Me^ωt,arbitary t≥0.
基金Projects(11375112,51472155,11275122)supported by the National Natural Science Foundation of China
文摘The growth interfaces of CdMnTe(CMT) crystals grown by traveling heater method(THM) were studied. Two types of polycrystalline CMT feed ingots synthesized in a traditional rocking furnace and vertical Bridgman(VB) furnace were adopted in THM growth, and the effects of the polycrystalline feed on the growth interface were revealed. The morphology of the growth interface of CMT crystal(CMT2) grown from the feed by vertical Bridgman was smoother with lower curvature compared with that of CMT crystal(CMT1) from the feed by rocking furnace. The radial Mn composition and Te inclusion distribution of the CMT wafers were analyzed and correlated to the growth interface. The Mn segregation along the radial direction and Te inclusion density of CMT2 were lower than those of CMT1. The VB method synthesized polycrystalline feed could improve the growth interface morphology, which is beneficial for decreasing the Te inclusions and Mn segregation in CMT wafers.
基金Project(51505100)supported by the National Natural Science Foundation of China
文摘The heterogeneous multilayer interface of VN/Ag coatings and transition multilayer interface of VN/Ag coatings were prepared on Inconel 781 and Si(100),and the microstructures,mechanical and tribological properties were investigated from 25 to 700℃.The results showed that the surface roughness and average grain size of VN/Ag coatings with transition multilayer interface are obviously larger than those of VN/Ag coatings with heterogeneous multilayer interface.The coatings with transition multilayer interface have higher adhesion force and hardness than the coatings with heterogeneous multilayer interface,and both coatings can effectively restrict the initiation and propagation of microcracks.Both coatings have excellent self-adaptive lubricating properties with a decrease of friction coefficient as the temperature increases,but their wear rates reveal a drastic increase.The phase composition of the worn area of both coatings was investigated,which indicates that a smooth Ag,Magnéli phase(V2O5)and bimetallic oxides(Ag3VO4 and AgVO3)can be responsible to the excellent lubricity of both coatings.To sum up,the coatings with transition multilayer interface have excellent adaptive lubricating properties and can properly control the diffusion rate and release rate of the lubricating phase,indicating that they have great potential in solving the problem of friction and wear of mechanical parts.
文摘In this study,an ultra‐fast and simple solvent‐free microwave method was successfully demonstrated using a series of ultra‐small(~2.5 nm)surfactant‐free Ru_(2)P@Ru/CNT heterostructures for the first time.The structure has a high‐density Ru component and Ru_(2)P component interface,which accelerates the hydrogen evolution reaction(HER).The prepared Ru_(2)P@Ru/CNT demonstrated excellent catalytic effects for the HER in alkaline media and real seawater.The experimental results indicate that ratio‐optimized Ru_(2)P@Ru/CNT(Ru_(2)P:Ru=66:34)requires only 23 and 29 mV to reach 10 mA cm^(-2)in 1.0 mol/L KOH and real seawater,respectively.These values are 10 and 24 mV lower than those of commercial Pt/C in 1.0 mol/L KOH(33 mV)and real seawater(53 mV),respectively,making it among the best non‐Pt HER reported in the literature.Additionally,the TOF of Ru_(2)P@Ru/CNT in alkaline freshwater and seawater were 13.1 and 8.5 s^(-1),respectively.These exceed the corresponding values for Pt/C,indicating that the catalyst has excellent intrinsic activity.The high current activity of Ru_(2)P@Ru/CNT in 1.0 mol/L KOH was explored,and only 77 and 104 mV were required to reach 500 and 1000 mA cm^(-2),respectively.After 100 h of durability testing,the catalyst retained excellent catalytic and structural stability in low current density,high current density,and seawater.
文摘In the present paper, we examine the performance of an efficient type of wave-absorbing porous marine structure under the attack of regular oblique waves by using a Multi-Domain Boundary Element Method(MDBEM). The structure consists of two perforated vertical thin barriers creating what can be called a wave absorbing chamber system. The barriers are surface piercing, thereby eliminating wave overtopping. The problem of the interaction of obliquely incident linear waves upon a pair of perforated barriers is first formulated in the context of linear diffraction theory. The resulting boundary integral equation, which is matched with far-field solutions presented in terms of analytical series with unknown coefficients, as well as the appropriate boundary conditions at the free surface, seabed, and barriers, is then solved numerically using MDBEM. Dissipation of the wave energy due to the presence of the perforated barriers is represented by a simple yet effective relation in terms of the porosity parameter appropriate for thin perforated walls. The results are presented in terms of reflection and transmission coefficients. The effects of the incident wave angles, relative water depths, porosities, depths of the walls, and other major parameters of interest are explored.
文摘The rate equations with multipoint boundary conditions are solved by numerical method accurately.A novel method based on genetic algorithm is proposed to optimize distributed pump powers in kilowatt YDDC fiber laser in this paper.The calculated results show that lower operation temperature and better uniformity can be achieved through an optimized pump arrangement.
基金Under the auspices of Program of International Science & Technology Cooperation,Ministry of Science and Technology of China(No.2010DFB24140)National Natural Science Foundation of China(No.41023010,41001298)National High Technology Research and Development Program of China(No.2011AA120305)
文摘Soil type maps at the scale of I Z 1 000 000 are used extensively to provide soil spatial distribution information for soil erosion assessment and watershed management models in China. However, the soil property maps produced through conventional direct linking method usually suffer low accuracy as well as the lack of spatial details within a soil type polygon. This paper presents an effective method to produce detailed soil property map based on representative samples which were extracted from each polygon on the 1 : 1 000 000 soil type map. The representative sample of each polygon is defined as the location that can represent the largest area within the polygon. The representativeness of a candidate sample is determined by calculating the soil-forming environment condition similarities between the sample and other locations. Once the representative sample of each polygon has been chosen, the property values of the existing typical samples are assigned to the corresponding representative samples with the same soil type. Finally, based on these representative samples, the detailed soil property map could be produced by using existing digital soil mapping methods. The case study in XuanCheng City, Anhui Province of China, demonstrated the proposed method could produce soil property map at a higher level of spatial details and accuracy: 1) The soil organic matter (SOM) map produced based on the representative samples can not only depict the detailed spatial distribution of SOM within a soil type polygon but also largely reduce the abrupt change of soil property at the boundaries of two adjacent polygons. 2) The Root Mean Squared Error (RMSE) of the SOM map based on the representative samples is 1.61, and it is 1.37 for the SOM map produced by using conventional direct linking method. Therefore, the proposed method is an effective approach to produce spatial detailed soil property map with higher accuracy for environment simulation models.
基金Project (No. 10372088) supported by the National Natural Science Foundation of China
文摘This paper presents an overview of the recent progress of potential theory method in the analysis of mixed boundary value problems mainly stemming from three-dimensional crack or contact problems of multi-field coupled media. This method was used to derive a series of exact three dimensional solutions which should be of great theoretical significance because most of them usually cannot be derived by other methods such as the transform method and the trial-and-error method. Further, many solutions are obtained in terms of elementary functions that enable us to treat more complicated problems easily. It is pointed out here that the method is usually only applicable to media characterizing transverse isotropy, from which, however, the results for the isotropic case can be readily obtained.
文摘Failure analysis of railway draw-hook coupler was carried out.The nondestructive testing method was undertaken on some failed couplers in service to designate critical areas of a coupler.Draw-Hook coupler is used to connect with the same hook coupler or automatic coupler.The influence of each connection types on the coupler strength in this study was discussed.A numerical stress analysis using FEM was performed,and many approaches including critical plane approach were carried out on fatigue life prediction of coupler under different conditions.The results of the proposed fatigue criterion and fatigue life predictions,as well as static numerical analysis,are validated with experimental results.
基金National Natural Science Foundation of China under Grant Nos.10775097,10874174 and 10647133the Natural Science Foundation of Jiangxi Province under Grant Nos.2007GQS1906 and 2007GZS1871the Research Foundation of the Education Department of Jiangxi Province under Grant No.[2007]22
文摘We find that the squeezed two-mode number state is just a two-variable Hermite polynomial excitation of thetwo-mode squeezed vacuum state (THPES).We find that the Wigner function of THPES and its marginal distributionsare just related to two-variable Hermite polynomials (or Laguerre polynomials) and that the tomogram of THPES canbe expressed by one-mode Hermite polynomial.