本课题制备了一种F掺杂铜氧化物负载活性炭新型复合催化剂,并以此构建三维电极电Fenton体系。为探究此三维电极电Fenton体系对邻硝基苯酚(2-NP)降解的最佳条件,本实验对比了活性炭(GAC)、F掺杂铜氧化物负载活性炭复合催化剂(F/CuOx-GAC...本课题制备了一种F掺杂铜氧化物负载活性炭新型复合催化剂,并以此构建三维电极电Fenton体系。为探究此三维电极电Fenton体系对邻硝基苯酚(2-NP)降解的最佳条件,本实验对比了活性炭(GAC)、F掺杂铜氧化物负载活性炭复合催化剂(F/CuOx-GAC)、未掺杂F的铜氧化物负载活性炭复合催化剂(CuOx-GAC)对2-NP降解情况。并以降解效果最优的催化剂为基础,分别对反应时间、pH值、极板间距、电流密度、电极投加量、电解质浓度、曝气速率这些因素进行了单因素实验。结果表明,最佳实验条件为2 g催化剂、pH = 4、电极间距为3 cm、电流密度为20 mA/cm2、电解质浓度为30 mM、曝气速率为1.25 L/min,在该条件下反应3 h后体系2-NP去除率为98.12%。其中,在一定范围内电流密度与2-NP的去除率成正比,催化剂的量、电极间距在合适时,电流效率和传质效能达到平衡最高点。此外,还通过不同体系对比、催化剂表征、自由基猝灭,初步探明了所构建的三维电极电Fenton体系对2-NP的降解机制,并进一步验证其高效性。In this paper, a novel composite catalyst of F-doped copper oxide supported activated carbon was prepared, and a three-dimensional electrode electro-Fenton system was constructed. In order to explore the optimal conditions for the degradation of o-nitrophenol (2-NP) by this three dimensional electrode electro-Fenton system, this experiment compared the degradation of 2-NP by activated carbon (GAC), F-doped copper oxide supported activated carbon composite catalyst (F/CuOx-GAC), and undoped copper oxide supported activated carbon composite catalyst (CuOx-GAC). Based on the catalyst with the best degradation effect, the single-factor experiments were carried out on the factors of reaction time, pH value, plate spacing, current density, electrode dosage, electrolyte concentration, and aeration rate. The results showed that the optimal experimental conditions were 2 g catalyst, pH = 4, electrode spacing of 3 cm, current density of 20 mA/cm2, electrolyte concentration of 30 mM, and aeration rate of 1.25 L/min. Under these conditions, the removal rate of 2-NP in the system was 98.12% after 3 h of reaction. In a certain range, the current density is proportional to the removal rate of 2-NP, and the current efficiency and mass transfer efficiency reach the highest point of balance when the amount of catalyst and electrode spacing are appropriate. In addition, through the comparison of different systems, catalyst characterization, and radical quenching, the degradation mechanism of 2-NP by the constructed three-dimensional electrode electro-Fenton system was preliminarily proved, and its efficiency was further verified.展开更多
以焦化废水处理过程产生的泡沫分离液为研究对象,对其进行Fenton催化氧化处理实验,考察H2O2用量、Fe2+浓度、pH和反应时间4个因素对处理效果的影响,并结合GC/MS方法比较处理前后泡沫分离液中有机物的种类及其生物降解性的变化。结果表明...以焦化废水处理过程产生的泡沫分离液为研究对象,对其进行Fenton催化氧化处理实验,考察H2O2用量、Fe2+浓度、pH和反应时间4个因素对处理效果的影响,并结合GC/MS方法比较处理前后泡沫分离液中有机物的种类及其生物降解性的变化。结果表明,采用[H2O2]=100 mmol/L、[Fe2+]=100 mg/L、pH=3、反应时间为30 m in的Fenton催化氧化反应条件,可以使分离液的COD去除率达到68%以上;经Fenton处理后,分离液的B/C值由0.12提高至0.38,生物降解性明显改善;通过GC/MS的分析,基本明确分离液中含有的有机物主要为酚、胺、腈、酯类有机物及喹啉、吡啶等杂环化合物,大多数属于难降解且生物毒性较强的有机物。针对这些复杂组分共存的泡沫分离液,利用Fenton试剂较强的氧化能力能够将其含有的有毒/难降解有机物转化为低毒或无毒的小分子有机物,为其后续的生物处理创造良好的条件。展开更多
文摘本课题制备了一种F掺杂铜氧化物负载活性炭新型复合催化剂,并以此构建三维电极电Fenton体系。为探究此三维电极电Fenton体系对邻硝基苯酚(2-NP)降解的最佳条件,本实验对比了活性炭(GAC)、F掺杂铜氧化物负载活性炭复合催化剂(F/CuOx-GAC)、未掺杂F的铜氧化物负载活性炭复合催化剂(CuOx-GAC)对2-NP降解情况。并以降解效果最优的催化剂为基础,分别对反应时间、pH值、极板间距、电流密度、电极投加量、电解质浓度、曝气速率这些因素进行了单因素实验。结果表明,最佳实验条件为2 g催化剂、pH = 4、电极间距为3 cm、电流密度为20 mA/cm2、电解质浓度为30 mM、曝气速率为1.25 L/min,在该条件下反应3 h后体系2-NP去除率为98.12%。其中,在一定范围内电流密度与2-NP的去除率成正比,催化剂的量、电极间距在合适时,电流效率和传质效能达到平衡最高点。此外,还通过不同体系对比、催化剂表征、自由基猝灭,初步探明了所构建的三维电极电Fenton体系对2-NP的降解机制,并进一步验证其高效性。In this paper, a novel composite catalyst of F-doped copper oxide supported activated carbon was prepared, and a three-dimensional electrode electro-Fenton system was constructed. In order to explore the optimal conditions for the degradation of o-nitrophenol (2-NP) by this three dimensional electrode electro-Fenton system, this experiment compared the degradation of 2-NP by activated carbon (GAC), F-doped copper oxide supported activated carbon composite catalyst (F/CuOx-GAC), and undoped copper oxide supported activated carbon composite catalyst (CuOx-GAC). Based on the catalyst with the best degradation effect, the single-factor experiments were carried out on the factors of reaction time, pH value, plate spacing, current density, electrode dosage, electrolyte concentration, and aeration rate. The results showed that the optimal experimental conditions were 2 g catalyst, pH = 4, electrode spacing of 3 cm, current density of 20 mA/cm2, electrolyte concentration of 30 mM, and aeration rate of 1.25 L/min. Under these conditions, the removal rate of 2-NP in the system was 98.12% after 3 h of reaction. In a certain range, the current density is proportional to the removal rate of 2-NP, and the current efficiency and mass transfer efficiency reach the highest point of balance when the amount of catalyst and electrode spacing are appropriate. In addition, through the comparison of different systems, catalyst characterization, and radical quenching, the degradation mechanism of 2-NP by the constructed three-dimensional electrode electro-Fenton system was preliminarily proved, and its efficiency was further verified.
文摘以焦化废水处理过程产生的泡沫分离液为研究对象,对其进行Fenton催化氧化处理实验,考察H2O2用量、Fe2+浓度、pH和反应时间4个因素对处理效果的影响,并结合GC/MS方法比较处理前后泡沫分离液中有机物的种类及其生物降解性的变化。结果表明,采用[H2O2]=100 mmol/L、[Fe2+]=100 mg/L、pH=3、反应时间为30 m in的Fenton催化氧化反应条件,可以使分离液的COD去除率达到68%以上;经Fenton处理后,分离液的B/C值由0.12提高至0.38,生物降解性明显改善;通过GC/MS的分析,基本明确分离液中含有的有机物主要为酚、胺、腈、酯类有机物及喹啉、吡啶等杂环化合物,大多数属于难降解且生物毒性较强的有机物。针对这些复杂组分共存的泡沫分离液,利用Fenton试剂较强的氧化能力能够将其含有的有毒/难降解有机物转化为低毒或无毒的小分子有机物,为其后续的生物处理创造良好的条件。
