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多源-多离子耦合作用下水泥胶砂硫酸盐腐蚀机理
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作者 赵高文 王卓 +3 位作者 胡亦奇 徐志军 郭梦真 李镜培 《同济大学学报(自然科学版)》 EI CAS CSCD 北大核心 2024年第8期1286-1296,共11页
硫酸盐渍土地区现浇结构广泛存在多源-多离子耦合腐蚀,利用砂浆内掺Mg^(2+)、Cl^(-)以及SO_(4)^(2-)并置于不同的腐蚀环境中,在腐蚀期间分别测定试样的孔隙分布、质量、尺寸以及不同深度硫酸盐浓度的变化,同时测定了抗折、抗压强度的演... 硫酸盐渍土地区现浇结构广泛存在多源-多离子耦合腐蚀,利用砂浆内掺Mg^(2+)、Cl^(-)以及SO_(4)^(2-)并置于不同的腐蚀环境中,在腐蚀期间分别测定试样的孔隙分布、质量、尺寸以及不同深度硫酸盐浓度的变化,同时测定了抗折、抗压强度的演变规律。采用扫描电镜-能谱分析(SEM-EDS)、X射线衍射(XRD)及热重分析(TG-DTG)等方法观测试样微观结构及矿物成分变化。试验结果表明,内源腐蚀增加了试样的有害孔含量,加速了腐蚀进程;内源腐蚀对试样抗折强度的发展具有明显的不利影响,较无内源腐蚀试样抗折强度降低了50%~67%;内源Mg^(2+)严重影响了硫酸盐环境中试样抗折强度的发展,试样的抗折强度仅为无腐蚀组的4.4%;试样表层的Mg^(2+)缓解了有害孔隙含量增加趋势,对内部结构具有一定的保护作用。 展开更多
关键词 现浇结构 硫酸盐腐蚀 多离子腐蚀 内源腐蚀 劣化机理
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Corrosion risk assessment of chloride-contaminated concrete structures using embeddable multi-cell sensor system 被引量:2
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作者 卢爽 巴恒静 《Journal of Central South University》 SCIE EI CAS 2011年第1期230-237,共8页
Monitoring the service condition of concrete structures requires the quantitative assessment of properties and corrosion rate of structural steels surrounded by concrete.A multi-cell sensor system that included a refe... Monitoring the service condition of concrete structures requires the quantitative assessment of properties and corrosion rate of structural steels surrounded by concrete.A multi-cell sensor system that included a reference electrode,a chloride content sensor,a macrocell current unit and an electrical resistance measurement unit was developed.This system provided the following important electrochemical data in the cover-zone concrete on site:open circuit potential,macrocell current from anodes to cathode,chloride profile,concrete resistance and corrosion rate of built-in anodes.The experimental results show that the macrocell current increases when the chloride content in concrete is higher.Thus,monitoring the chloride content is a good method for monitoring the corrosion state.The chloride ion content and cover depth are the key factors that affect the electrical resistance of concrete.Without considering the temperature and time,a simplified model of the instantaneous corrosion rate of steel rebar in a concrete structure based on the measured chloride contents and concrete resistance was proposed.The test results further prove the reliability of this simplified predicting model. 展开更多
关键词 concrete structures corrosion rate RESISTANCE chloride content macrocell current multi-cell sensor
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