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具有相同分子基团的多组分气体现场在线光谱分析
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作者 汤晓君 李玉军 +2 位作者 朱凌建 丁晖 刘君华 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2011年第11期3031-3035,共5页
针对目前傅里叶变换红外光谱分析还不能独立应用于气体成分多、部分成分具有同种分子基团、气体浓度变化范围大的复杂多组分混合气体的在线分析问题,文章以甲烷、乙烷、丙烷、异丁烷和正丁烷五种轻烷烃气体的混合气体的光谱分析为例,提... 针对目前傅里叶变换红外光谱分析还不能独立应用于气体成分多、部分成分具有同种分子基团、气体浓度变化范围大的复杂多组分混合气体的在线分析问题,文章以甲烷、乙烷、丙烷、异丁烷和正丁烷五种轻烷烃气体的混合气体的光谱分析为例,提出采用充分考虑气体温度、压力及干扰气的影响,采用特征提取、光谱畸变识别与修正、神经网络的鲁棒建模与分层建模的方法来实现具有相同分子基团的混合气体光谱分析。最后给出了五种轻烷烃气体的光谱与气相色谱的在线分析结果。分析结果对比曲线表明,两种仪器分析结果曲线几乎完全重合,这说明该文提出的光谱分析方法可以独立应用于具有相同分子基团的多组分气体混合气体现场在线分析,解决了科学研究和工程应用中气体组分复杂、气体浓度变化范围大的复杂多组分混合气现场分析难题。 展开更多
关键词 多组分混合气 光谱在线分析 特征提取 光谱畸变识别与修正 神经网络
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Explosive limits of mixed gases containing CH_4,CO and C_2H_4 in the goaf area 被引量:8
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作者 DENG Jun LUO Zhenmin +1 位作者 WU Xiaochun HU Yaoyuan 《Mining Science and Technology》 EI CAS 2010年第4期557-561,共5页
The explosive gases CO and C2H4, released mainly flammable gases during the process of coal self-ignition, are of the most important ingredients of the multi-component gases in goal areas, along with CH4. We have dete... The explosive gases CO and C2H4, released mainly flammable gases during the process of coal self-ignition, are of the most important ingredients of the multi-component gases in goal areas, along with CH4. We have determined some of the parame- ters of explosive properties of the one-component gases CH4, CO and C2H4 using an explosive trial device of polybasic explosive gas mixtures and emphasized particularly the effect on the limits of explosive concentration of the binary explosive mixed gases CH4+CO, CH4+C2H4, as a function of the amount of CO, C2H4 and inert flame resisting gases (N2, CO2). The experimental results show that the effect of inert gases on the explosive limits of mixed gases, given the property of explosive gas, is obvious: the inert gases (N2, CO2) possess some inhibitory effects on the explosion of the multi-component explosive gas mixtures. The results will provide some experimental support to suppress the occurrence of the gas explosions in goaf areas and provide some directions for designing explosion-proof electric equipment and fire arresters. 展开更多
关键词 gob indication gas of self-ignition GAS concentration explosive limits
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