This paper investigated the electrodeposition of sulfur on polycrystalline platinum from sulfide polluted brine. Anodic polarization, potentiostatic and electrochemical impedance spectroscopy （EIS） techniques were p...This paper investigated the electrodeposition of sulfur on polycrystalline platinum from sulfide polluted brine. Anodic polarization, potentiostatic and electrochemical impedance spectroscopy （EIS） techniques were performed. The slope of Warburg straight line in Nyquiest plot of the EIS spectra performed at 0.0 V indicates diffusion control mechanism of the electrodeposition process. At 0.5 V the Rp （determined from EIS measurements） increased rapidly with time indicating more sulfur deposition and more passivation of platinum surface. Samples subjected to potentiostatic experiments at 0.4, 0.9 and 1.0 V were investigated under Scanning Electron Microscope （SEM）. SEM images reveal the deposition of sulfur on the sample surfaces. The degree of sulfur deposit coverage and its morphology depend on both the potential and time of deposition.展开更多
Porous and dense TiNi alloys were successfully fabricated by powder metallurgy(P/M) method, and to further improve their surface biocompatibility, surface modification techniques including grind using silicon-carbide(...Porous and dense TiNi alloys were successfully fabricated by powder metallurgy(P/M) method, and to further improve their surface biocompatibility, surface modification techniques including grind using silicon-carbide(SiC) paper, acid etching and alkali treatment were employed to produce either irregularly rough surface or micro-porous surface roughness. X-ray diffractometry(XRD), scanning electron microscopy(SEM) and energy dispersive X-ray spectroscopy(EDX) attached to SEM were used to characterize surface structure and the Ca-P coatings. Effects of the above surface treatments on the surface morphology, apatite forming ability were systematically investigated. Results indicate that all the above surface treatments increase the apatite forming ability of TiNi alloys in varying degrees when soaked in simulated body fluid(SBF). More apatite coatings formed on TiNi samples sintered at 1050℃ and 1100℃ due to their high porosity and pure TiNi phase that is beneficial to heterogeneous nucleation. Furthermore, more uniform apatite was fabricated on the sample sintered from the mixture of Ni and Ti powders.展开更多
文摘This paper investigated the electrodeposition of sulfur on polycrystalline platinum from sulfide polluted brine. Anodic polarization, potentiostatic and electrochemical impedance spectroscopy （EIS） techniques were performed. The slope of Warburg straight line in Nyquiest plot of the EIS spectra performed at 0.0 V indicates diffusion control mechanism of the electrodeposition process. At 0.5 V the Rp （determined from EIS measurements） increased rapidly with time indicating more sulfur deposition and more passivation of platinum surface. Samples subjected to potentiostatic experiments at 0.4, 0.9 and 1.0 V were investigated under Scanning Electron Microscope （SEM）. SEM images reveal the deposition of sulfur on the sample surfaces. The degree of sulfur deposit coverage and its morphology depend on both the potential and time of deposition.
基金Project(51274247) supported by the National Natural Science Foundation of ChinaProject(2014zzts177) support by the Fundamental Research Funds for the Central Universities,China
文摘Porous and dense TiNi alloys were successfully fabricated by powder metallurgy(P/M) method, and to further improve their surface biocompatibility, surface modification techniques including grind using silicon-carbide(SiC) paper, acid etching and alkali treatment were employed to produce either irregularly rough surface or micro-porous surface roughness. X-ray diffractometry(XRD), scanning electron microscopy(SEM) and energy dispersive X-ray spectroscopy(EDX) attached to SEM were used to characterize surface structure and the Ca-P coatings. Effects of the above surface treatments on the surface morphology, apatite forming ability were systematically investigated. Results indicate that all the above surface treatments increase the apatite forming ability of TiNi alloys in varying degrees when soaked in simulated body fluid(SBF). More apatite coatings formed on TiNi samples sintered at 1050℃ and 1100℃ due to their high porosity and pure TiNi phase that is beneficial to heterogeneous nucleation. Furthermore, more uniform apatite was fabricated on the sample sintered from the mixture of Ni and Ti powders.
