Huaibei is an energy city. Coal as the primary energy consumption brings a large number of regional pollution in Huaibei area. Differential optical absorption spectroscopy （DOAS） as optical remote sensing technology...Huaibei is an energy city. Coal as the primary energy consumption brings a large number of regional pollution in Huaibei area. Differential optical absorption spectroscopy （DOAS） as optical remote sensing technology has been applied to monitor regional average concen- trations and inventory of nitrogen dioxide, sulfur dioxide and ozone. DOAS system was set up and applied to monitor the main air pollutants in Huaibei area. Monitoring data were obtained from 7 to 28 August, 2011. Monitoring results show measurements in controlling pollution are effective, and emissions of pollutants are up to the national standard in Huaibei area. Prediction model was also created to track changing trend of pollutions. These will provide raw data support for effective evaluation of environmental quality in Huaibei area.展开更多
In this paper, we use pre-column 2 times low-temperature cryo-trap enrichment--gas chromatography（GC） /nitrogen and phosphorus detector（NPD）to detect and analyze phosphine in Arctic pole area for the first time. T...In this paper, we use pre-column 2 times low-temperature cryo-trap enrichment--gas chromatography（GC） /nitrogen and phosphorus detector（NPD）to detect and analyze phosphine in Arctic pole area for the first time. The results show phosphine exists in all of the samples in Arctic pole biosphere and phosphine concentration in Arctic atmosphere is between 18.54- 132.18 ng/m^3, almost the same as that in Antarctic atmosphere; phosphine concentration in Dalian bay sea surface sediments is between 116. 8- 554.3 ng/kg, almost the same as that reported in Jiao-zhou bay. Our research of phosphine will shed new light on the mechanisms showing how the phosphorus supplement influences the biogeochemical cycle and global warming.展开更多
An in-situ GC-ECD system was used to measure halocarbons at Shangdianzi （SDZ） GAW regional station. In this paper, we reported observational results of atmospheric CFC- 11 （CCI3F） mixing ratios from April 2007 to ...An in-situ GC-ECD system was used to measure halocarbons at Shangdianzi （SDZ） GAW regional station. In this paper, we reported observational results of atmospheric CFC- 11 （CCI3F） mixing ratios from April 2007 to March 2008. The CFC- 11 time series showed large variability. Approximately 62% observed values were filtered as non-background data. The median, 10% and 90% percentiles of CFC-11 background mixing ratios were 245.4 ppt （10-12 mol/mol）, 244.6 ppt and 246.1 ppt, respectively; whereas those of non-background CFC- 11 mixing ratios were 254.7, 246.6 and 272.1 ppt, respectively. Significant differences in background and non-background CFC-11 mixing ratios were observed between summer and autumn, mainly because of the CFC-11 stored in loam being prone to atmospheric release in hot seasons. Comparison of tile SDZ data with the five AGAGE stations suggested agreement with mid-high latitude Northern Hemisphere stations MHD, THD and RPB. The SDZ data were higher than that of Southern Hemisphere stations CGO and SMO. Higher CFC-11 mixing ratios measured in different seasons were always associated with winds from the W-WSW-SW sector, indicating that the airflow coming from this wind sector has a positive contribution to CFC- 11 concentrations. The CFC-11 mixing ratios were higher in autumn and summer than in spring and winter, in which its mixing ratios were very close to the atmospheric background level. This was happened especially when airflow originated from the NNE-NE-ENE-E sector, indicating the air masses coming from these wind directions was relatively clean.展开更多
文摘Huaibei is an energy city. Coal as the primary energy consumption brings a large number of regional pollution in Huaibei area. Differential optical absorption spectroscopy （DOAS） as optical remote sensing technology has been applied to monitor regional average concen- trations and inventory of nitrogen dioxide, sulfur dioxide and ozone. DOAS system was set up and applied to monitor the main air pollutants in Huaibei area. Monitoring data were obtained from 7 to 28 August, 2011. Monitoring results show measurements in controlling pollution are effective, and emissions of pollutants are up to the national standard in Huaibei area. Prediction model was also created to track changing trend of pollutions. These will provide raw data support for effective evaluation of environmental quality in Huaibei area.
基金Supported by the National High Technology Research and Development Programme of China ( No. 2008AA09Z114)the Polar Science Research Foundation ( No. 20070214)the Opening Foundation ( No. PCRRF08016) of State Key Laboratory of Pollution Control and Resource Reuse Nanjing University and the National Ocean science Foundation (No. 2008614)
文摘In this paper, we use pre-column 2 times low-temperature cryo-trap enrichment--gas chromatography（GC） /nitrogen and phosphorus detector（NPD）to detect and analyze phosphine in Arctic pole area for the first time. The results show phosphine exists in all of the samples in Arctic pole biosphere and phosphine concentration in Arctic atmosphere is between 18.54- 132.18 ng/m^3, almost the same as that in Antarctic atmosphere; phosphine concentration in Dalian bay sea surface sediments is between 116. 8- 554.3 ng/kg, almost the same as that reported in Jiao-zhou bay. Our research of phosphine will shed new light on the mechanisms showing how the phosphorus supplement influences the biogeochemical cycle and global warming.
基金supported by Non-profit Research Project to Serve the Public Interest (Grant No. GYHY200806026)International S&T Cooperation Program of MOST (Grant No. 2007DFA20650)Research Fund for Returned Overseas Chinese Scholars of the State Education Ministry (Grant No. [2009]1108)
文摘An in-situ GC-ECD system was used to measure halocarbons at Shangdianzi （SDZ） GAW regional station. In this paper, we reported observational results of atmospheric CFC- 11 （CCI3F） mixing ratios from April 2007 to March 2008. The CFC- 11 time series showed large variability. Approximately 62% observed values were filtered as non-background data. The median, 10% and 90% percentiles of CFC-11 background mixing ratios were 245.4 ppt （10-12 mol/mol）, 244.6 ppt and 246.1 ppt, respectively; whereas those of non-background CFC- 11 mixing ratios were 254.7, 246.6 and 272.1 ppt, respectively. Significant differences in background and non-background CFC-11 mixing ratios were observed between summer and autumn, mainly because of the CFC-11 stored in loam being prone to atmospheric release in hot seasons. Comparison of tile SDZ data with the five AGAGE stations suggested agreement with mid-high latitude Northern Hemisphere stations MHD, THD and RPB. The SDZ data were higher than that of Southern Hemisphere stations CGO and SMO. Higher CFC-11 mixing ratios measured in different seasons were always associated with winds from the W-WSW-SW sector, indicating that the airflow coming from this wind sector has a positive contribution to CFC- 11 concentrations. The CFC-11 mixing ratios were higher in autumn and summer than in spring and winter, in which its mixing ratios were very close to the atmospheric background level. This was happened especially when airflow originated from the NNE-NE-ENE-E sector, indicating the air masses coming from these wind directions was relatively clean.
