Microstructure refinement of a dual phase titanium alloy, Ti-3AI-4.5V-5Mo, by severe room temperature compression was investigated. Nanocrystalline grains were observed in the sample with 75% reduction, in which the g...Microstructure refinement of a dual phase titanium alloy, Ti-3AI-4.5V-5Mo, by severe room temperature compression was investigated. Nanocrystalline grains were observed in the sample with 75% reduction, in which the grain sizes of a phase and β phase were approximately 50 and 100 nm. Conversely, the average thicknesses of a phase and β phase in as-received microstructure were measured to be 0.7 and 0.5 μm, respectively. TEM and XRD methods were used to analyze the microstructure and texture changes after severe deformation. Microstructure refinement was deduced to the complex interaction among slip dislocations in the a phase, the complex interaction among slip dislocations and martensites in the β phases. In addition, the interaction between the a phase and the β phase also contributed to the microstructure refinement.展开更多
Au/3DOM(three-dimensionally ordered macroporous) Al2O3 and Au/CeO2/3DOM Al2O3 were prepared using a reduction-deposition method and characterized using scanning electron microscopy,N2 adsorption-desorption,X-ray dif...Au/3DOM(three-dimensionally ordered macroporous) Al2O3 and Au/CeO2/3DOM Al2O3 were prepared using a reduction-deposition method and characterized using scanning electron microscopy,N2 adsorption-desorption,X-ray diffraction,transmission electron microscopy,ultraviolet-visible spectroscopy,temperature-programmed hydrogen reduction,and X-ray photoelectron spectroscopy.Au nanoparticles of similar sizes were well dispersed and supported on the inner walls of uniform macropores.The norminal Au loading is 2%.Al-Ce-O solid solution in CeO2/3DOM Al2O3 catalysts can be formed due to the incorporation of Al^3+ ions into the ceria lattice,which causes the creation of extrinsic oxygen vacancies.The extrinsic oxygen vacancies improved the oxygen-transport properties.The strong metal-support interactions between Au and CeO2 increased the amount of active oxygen on the Au nanoparticle surfaces,and this promoted soot oxidation.The activities of the Au-based catalysts were higher than those of the supports(Al2O3 or CeO2/3DOM Al2O3) at low temperature.Au/CeO2/3DOM Al2O3 had the highest catalytic activity for soot combustion,with T(10),T(50),and T(90) values of 273,364,and 412℃,respectively.展开更多
This review discussed the use of nano ZSM‐5 in naphtha catalytic cracking. The impact of nano ZSM‐5 on product selectivity, reaction conversion and catalyst lifetime were compared with micro‐sized ZSM‐5. The appli...This review discussed the use of nano ZSM‐5 in naphtha catalytic cracking. The impact of nano ZSM‐5 on product selectivity, reaction conversion and catalyst lifetime were compared with micro‐sized ZSM‐5. The application of nano ZSM‐5 not only increased the catalyst lifetime, but also gave more stability for light olefins selectivity. The effects of the reaction parameters of temperature and feedstock on the performance of nano ZSM‐5 were investigated, and showed that high temperature and linear alkanes as feedstock improved light olefin selectivity and conversion.展开更多
A computational model combining large .eddy simulation with quadrature moment method was em-ployed to study nanoparticle evolution in a confined impinging jet. The investigated particle size is limited in the transien...A computational model combining large .eddy simulation with quadrature moment method was em-ployed to study nanoparticle evolution in a confined impinging jet. The investigated particle size is limited in the transient regime, and the particle collision kernel was obtained by using the theory of flux matching. The simulation was validated by comparing it with the experimental results. The numerical results show coherent structure acts to dominate particle number intensity, size and polydispersity distributions, and it also induce particle-laden iet to be diluted by .the ambient.The evolution of particle dynarnics in.the impinging jet flow are strongly related to the Rey-nolds number and nozzle-to-plate distance, and their relationships were analyzed.展开更多
AIM:To investigate colorectal uptake of solid lipid nanoparticles(SLNs) in mice receiving different doses of 1,2-dimethylhydrazine(DMH) using magnetic resonance(MR) and laser-scanning confocal fluorescence microscope(...AIM:To investigate colorectal uptake of solid lipid nanoparticles(SLNs) in mice receiving different doses of 1,2-dimethylhydrazine(DMH) using magnetic resonance(MR) and laser-scanning confocal fluorescence microscope(LSCFM) imaging.METHODS:Eight mice were sacrificed in a pilot study to establish the experimental protocol and to visualize colorectal uptake of SLNs in normal mice.Gadopentetate dimeglumine and fluorescein isothiocyanate(FITC)-loaded SLN(Gd-FITC-SLN) enemas were performed on mice receiving DMH for 10 wk(group 1,n = 9) or 16 wk(group 2,n = 7) and FITC-SLN enema wasperformed on 4 DMH-treated mice(group 3).Pre-and post-enema MR examinations were made to visualize the air-inflated distal colorectum.Histological and LSCFM examinations were performed to verify colorectal malignancy and to track the distribution of SLNs.RESULTS:Homogeneous enhancement and dense fluorescence(FITC) deposition in colorectal wall were observed in normal mice and 1 DMH-treated mouse(group 1) on fluid attenuated inversion recovery(FLAIR) and LSCFM images,respectively.Heterogeneous mural enhancement was found in 6 mice(4 in group 1;2 in group 2).No visible mural enhancement was observed in the other mice.LSCFM imaging revealed linear fluorescence deposition along the colorectal mucosa in all groups.Nine intraluminal masses and one prolapsed mass were detected by MR imaging with different enhancement modes and pathologies.Interstitial FITC deposition was identified where obvious enhancement was observed in FLAIR images.Bladder imaging agent accumulations were observed in 11 of 16 DMH-treated mice of groups 1 and 2.CONCLUSION:There are significant differences in colorectal uptake and distribution of SLNs between normal and DMH-treated mice,which may provide a new mechanism of contrast for MR colonography.展开更多
Nano-sized silica-alumina particles were in-situ synthesized in supersolubilizing reverse micellae.Both the most probable pore diameters and the particle sizes were distributed in nano-scale SiO2-Al2O3 particulates.Th...Nano-sized silica-alumina particles were in-situ synthesized in supersolubilizing reverse micellae.Both the most probable pore diameters and the particle sizes were distributed in nano-scale SiO2-Al2O3 particulates.The influence of SiO2/Al2O3 mass ratio and the surfactant content on the particle size and morphology,pore structure,and acidity was characterized by the low temperature nitrogen adsorption/desorption (BET),SEM,TEM and NH3-TPD methods.The test results indicated that the most probable pore diameter of SiO2-Al2O3 nanoparticles was around 10 nm,the specific surface area was about 223-286 m2 /g,the pore volumes were about 0.48-0.63 cm 3 /g,and the particle sizes of porous SiO2-Al2O3 calcined at 550 ℃ were distributed always in the range between 10 nm to 50 nm.The calcined SiO2-Al2O3 nano-powders showed their acidity being stronger than the porous γ-Al2O3 support.展开更多
文摘Microstructure refinement of a dual phase titanium alloy, Ti-3AI-4.5V-5Mo, by severe room temperature compression was investigated. Nanocrystalline grains were observed in the sample with 75% reduction, in which the grain sizes of a phase and β phase were approximately 50 and 100 nm. Conversely, the average thicknesses of a phase and β phase in as-received microstructure were measured to be 0.7 and 0.5 μm, respectively. TEM and XRD methods were used to analyze the microstructure and texture changes after severe deformation. Microstructure refinement was deduced to the complex interaction among slip dislocations in the a phase, the complex interaction among slip dislocations and martensites in the β phases. In addition, the interaction between the a phase and the β phase also contributed to the microstructure refinement.
基金supported by the National Natural Science Foundation of China (21477146,21303263)the National High Technology Research and Development Program of China (863 Program,2015AA034603)+2 种基金Beijing Nova Program (Z141109001814072)the Specialized Research Fund for the Doctoral Program of Higher Education of China (20130007120011)the Science Foundation of China University of Petroleum-Beijing (YJRC-2013-13,2462013BJRC003)~~
文摘Au/3DOM(three-dimensionally ordered macroporous) Al2O3 and Au/CeO2/3DOM Al2O3 were prepared using a reduction-deposition method and characterized using scanning electron microscopy,N2 adsorption-desorption,X-ray diffraction,transmission electron microscopy,ultraviolet-visible spectroscopy,temperature-programmed hydrogen reduction,and X-ray photoelectron spectroscopy.Au nanoparticles of similar sizes were well dispersed and supported on the inner walls of uniform macropores.The norminal Au loading is 2%.Al-Ce-O solid solution in CeO2/3DOM Al2O3 catalysts can be formed due to the incorporation of Al^3+ ions into the ceria lattice,which causes the creation of extrinsic oxygen vacancies.The extrinsic oxygen vacancies improved the oxygen-transport properties.The strong metal-support interactions between Au and CeO2 increased the amount of active oxygen on the Au nanoparticle surfaces,and this promoted soot oxidation.The activities of the Au-based catalysts were higher than those of the supports(Al2O3 or CeO2/3DOM Al2O3) at low temperature.Au/CeO2/3DOM Al2O3 had the highest catalytic activity for soot combustion,with T(10),T(50),and T(90) values of 273,364,and 412℃,respectively.
文摘This review discussed the use of nano ZSM‐5 in naphtha catalytic cracking. The impact of nano ZSM‐5 on product selectivity, reaction conversion and catalyst lifetime were compared with micro‐sized ZSM‐5. The application of nano ZSM‐5 not only increased the catalyst lifetime, but also gave more stability for light olefins selectivity. The effects of the reaction parameters of temperature and feedstock on the performance of nano ZSM‐5 were investigated, and showed that high temperature and linear alkanes as feedstock improved light olefin selectivity and conversion.
基金Supported by the Ministry of Science and Technology of China (No.2005CCA06900).
文摘A computational model combining large .eddy simulation with quadrature moment method was em-ployed to study nanoparticle evolution in a confined impinging jet. The investigated particle size is limited in the transient regime, and the particle collision kernel was obtained by using the theory of flux matching. The simulation was validated by comparing it with the experimental results. The numerical results show coherent structure acts to dominate particle number intensity, size and polydispersity distributions, and it also induce particle-laden iet to be diluted by .the ambient.The evolution of particle dynarnics in.the impinging jet flow are strongly related to the Rey-nolds number and nozzle-to-plate distance, and their relationships were analyzed.
基金Supported by National Natural Science Foundation of China,No.30670610
文摘AIM:To investigate colorectal uptake of solid lipid nanoparticles(SLNs) in mice receiving different doses of 1,2-dimethylhydrazine(DMH) using magnetic resonance(MR) and laser-scanning confocal fluorescence microscope(LSCFM) imaging.METHODS:Eight mice were sacrificed in a pilot study to establish the experimental protocol and to visualize colorectal uptake of SLNs in normal mice.Gadopentetate dimeglumine and fluorescein isothiocyanate(FITC)-loaded SLN(Gd-FITC-SLN) enemas were performed on mice receiving DMH for 10 wk(group 1,n = 9) or 16 wk(group 2,n = 7) and FITC-SLN enema wasperformed on 4 DMH-treated mice(group 3).Pre-and post-enema MR examinations were made to visualize the air-inflated distal colorectum.Histological and LSCFM examinations were performed to verify colorectal malignancy and to track the distribution of SLNs.RESULTS:Homogeneous enhancement and dense fluorescence(FITC) deposition in colorectal wall were observed in normal mice and 1 DMH-treated mouse(group 1) on fluid attenuated inversion recovery(FLAIR) and LSCFM images,respectively.Heterogeneous mural enhancement was found in 6 mice(4 in group 1;2 in group 2).No visible mural enhancement was observed in the other mice.LSCFM imaging revealed linear fluorescence deposition along the colorectal mucosa in all groups.Nine intraluminal masses and one prolapsed mass were detected by MR imaging with different enhancement modes and pathologies.Interstitial FITC deposition was identified where obvious enhancement was observed in FLAIR images.Bladder imaging agent accumulations were observed in 11 of 16 DMH-treated mice of groups 1 and 2.CONCLUSION:There are significant differences in colorectal uptake and distribution of SLNs between normal and DMH-treated mice,which may provide a new mechanism of contrast for MR colonography.
基金the financial support of Liaoning Province National Science Fund (No.20072009)
文摘Nano-sized silica-alumina particles were in-situ synthesized in supersolubilizing reverse micellae.Both the most probable pore diameters and the particle sizes were distributed in nano-scale SiO2-Al2O3 particulates.The influence of SiO2/Al2O3 mass ratio and the surfactant content on the particle size and morphology,pore structure,and acidity was characterized by the low temperature nitrogen adsorption/desorption (BET),SEM,TEM and NH3-TPD methods.The test results indicated that the most probable pore diameter of SiO2-Al2O3 nanoparticles was around 10 nm,the specific surface area was about 223-286 m2 /g,the pore volumes were about 0.48-0.63 cm 3 /g,and the particle sizes of porous SiO2-Al2O3 calcined at 550 ℃ were distributed always in the range between 10 nm to 50 nm.The calcined SiO2-Al2O3 nano-powders showed their acidity being stronger than the porous γ-Al2O3 support.