瓦斯抽采钻孔密封用天固封孔材料及工艺应用研究

针对国投新集刘庄煤矿瓦斯抽采钻孔密封效果较差、瓦斯抽采浓度较低及抽采浓度衰减较快等问题,使用天固封孔材料并结合“两堵一注”带压封孔工艺取代聚氨酯吹浆封孔工艺,改善刘庄煤矿瓦斯抽采效果,并将2种封孔工艺进行对比。结果表明:采用天固封孔材料结合“两堵一注”带压封孔工艺因其具有良好的“流固耦合效应”,钻场合抽24 h后的钻孔瓦斯平均浓度为40.51%,明显高于聚氨酯吹浆封孔工艺的钻孔瓦斯平均浓度16.14%,充分证明了改进后的封孔工艺优于聚氨酯吹浆封孔工艺。

天固封孔材料在淮南谢家集一矿的应用效果

介绍了天固封孔材料在淮南谢家集一矿的应用情况,并将其与传统水泥砂浆材料进行对比,从钻孔抽采瓦斯浓度、浓度分布以及浓度衰减程度等方面分析了天固材料的封孔性能,结果表明,采用天固封孔材料封孔的钻场钻孔抽采瓦斯平均浓度为85.1%,而用水泥砂浆封孔的钻场钻孔抽采瓦斯平均浓度为45.6%,并且使用天固封孔材料的钻孔封孔效果更加稳定、浓度衰减程度更小。

花绒寄甲防治旱柳光肩星天牛研究

以天敌昆虫花绒寄甲为研究对象,在北京市内房山区和大兴区道路两旁受危害的旱柳释放花绒寄甲卵,40多天后对防治效果进行调查。结果表明:当年释放卵卡对天牛幼虫致死率最高达到79.17%;取回受害枝做树木解析,调查受害木虫口减少量最高为100%。当年释放花绒寄甲卵对光肩星天牛幼虫控制效果明显,且逐年累计释放花绒寄甲能够有效地控制天牛幼虫的发生。

花绒寄甲防治甘肃省二白杨光肩星天牛试验研究

甘肃省嘉峪关地区受光肩星天牛危害严重,以花绒寄甲成虫和卵卡为研究对象,设置释放卵卡、成虫、卵卡和成虫3种不同的防治方案,对二白杨光肩星天牛进行生物防治,2个月后对防治效果进行调查。结果表明:该地区混合释放花绒寄甲成虫和卵卡对光肩星天牛的防治效果最好,防治效果可以达到53.24%,远远高于对照组和释放成虫组、卵卡组。树木解析结果证明了混合释放花绒寄甲卵卡和成虫的防治效果最好,天牛幼虫的减少率平均可达40%以上。

ENLARGING SAR PATCH-MAPPING AREA BY ANTENNA BEAM SCAN

The approach for enlargement of SAR patch mapping area by antenna beam scan is investigated, which serves for moderate fine-resolution mapping of medium-sized terrain patches. The scanning angular velocity and the scanning angular scope are determined respectively. The angular velocity of the scanning antenna is controlled to scan over just one azimuth 3 dB beam width in the time interval during which the radar platform moves over one synthetic aperture length determined from the desired cross-range resolution, radar wavelength, nominal slant range, and squint angle. The scanning angular scope is mainly determined by the azimuth width of the terrain patch, nominal slant range, squint angle, platform velocity, and azimuth beam width. Finally, the related experimental results of an airborne SAR are presented. The linear range-Doppler algorithm is employed in image formation after motion compensation is conducted to remove the effect of transnational motion of the radar platform relative to the map center.

Diagnosis and treatment of spontaneous colonic perforation:Analysis of 10 cases

AIM: To investigate the etiology, diagnosis and treatment of spontaneous perforation of the colon. METHODS: The clinical data of 10 cases of spontaneous perforation of the colon, observed at Fuding hospital from January 2004 to December 2007, were analyzed retrospectively. RESULTS: The mean age at onset was 65 years (range from 45 to 73). Seven patients had a history of chronic constipation. All patients complained of sudden lower abdominal pain. The perforation occurred after coloclysis and administration of senna leaves in two patients. Nine patients had signs of peritoneal irritation. Seven cases underwent abdominal paracentesis, which was diagnostic in six. Only one case was definitely diagnosed prior to surgery. One patient underwent neoplasty of the colon, another a partial resection of colon, six a neoplasty of the colon plus sigmoid colostomy, and two underwent Hartmann surgery. All perforation sites were opposite to the mesenteric edge. The perforation sites were located on descending colon in one case, sigmoid colon in three cases, and rectosigmoid colon in six cases. In five patients, surgical pathological examination was consistent with the microscopical changes of colonic perforation caused by feces. Three patients died after surgery. CONCLUSION: Spontaneous perforation of the colon most commonly occurs among the elderly with chronic constipation. Abdominal paracentesis is helpful for the diagnosis. The perforation site is located opposite to the mesenteric edge. Sigmoid colon and rectosigmoid colon are the most frequent locations. Neoplasty of the colon and sigmoid colostomy are the most frequenttreatment. The prognosis is bad and the mortality rate after surgery is high.

True triaxial hydraulic fracturing test and numerical simulation of limestone

Hydraulic fracturing,as a key technology of deep energy exploitation,accelerates the rapid development of the modern petroleum industry.To study the mechanisms of hydraulic fracture propagation and rock failure mode of the vertical well hydraulic fracturing,the true triaxial hydraulic fracturing test and numerical simulation are carried out,and the influence of the principal stress difference,water injection displacement,perforation angle and natural fracture on fracture propagation is analyzed.The results show that the fracture propagation mode of limestone is mainly divided into two types:the single vertical fracture and the transverse-longitudinal crossed complex fracture.Under high displacement,the fracturing pressure is larger,and the secondary fracture is more likely to occur,while variable displacement loading is more likely to induce fracture network.Meanwhile,the amplitude of acoustic emission(AE)waveform of limestone during fracturing is between 0.01 and 0.02 mV,and the main frequency is maintained in the range of 230−300 kHz.When perforation angleθ=45°,it is easy to produce the T-type fracture that connects with the natural fracture,while X-type cracks are generated whenθ=30°.The results can be used as a reference for further study on the mechanism of limestone hydraulic fracturing.

Mutual coupling suppression of aperture coupled microstrip antenna array

A mutual coupling suppression method is proposed for microstrip antenna array by cutting four small semi-circle annular apertures on the metal plate. The structure of antenna array is composed of 2 × 2 four elements. The antenna consists of double layer dielectric, and it realizes circular polarization characteristics by cutting rectangular slot on circular patch in the direction of 45°, by using aperture coupling feeding and reverse feeding principle. There is 90＊ phase difference between adjacent antenna elements. Thus, it cuts off the coupling current field between the elements, suppresses the surface wave and reduces the mutual coupling by cutting four semi-circle annular apertures symmetrically on the metal plate. The simulation results show that after cutting four semi-circle annular apertures, the antenna array coupling coefficients decrease significantly, and the side and back lobe levels are suppressed effectively with the gain of antenna improved. So the proposed method is effective to suppress microstrip antenna array mutual coupling.

Cutting parameter optimization for one-step shaft excavation technique based on parallel cutting method

The outcome of the cutting blasting in a one-step shaft excavation is heavily related to the cutting parameters used for parallel cutting method. In this study, the relationships between the cutting parameters（such as the hole spacing L and the empty hole diameter D） and damage zones were investigated by numerical simulation. A damage state index γ was introduced and used to characterize the crushing and crack damage zones through a user-defined subroutine. Two indices, i.e., η1 and η2 that can reflect the cutting performance, were also introduced. The simulation results indicate that an optimal value of L can be obtained so that the η1 and η2 can reach their optimal states for the best cutting performance. A larger D results in better cutting performance when the L value maintains its best. In addition, the influences of the loading rate and the in-situ stress on the cutting performance were investigated. It is found that an explosive with a high loading rate is suit for cutting blasting. The propagation direction and the length of the tensile cracks are affected by the direction and the magnitude of the maximum principal stress.

Variations in retention efficiency of bivalves to different concentrations and organic content of suspended particles

Retention efficiencies (RE) of scallop (Chlamys farreri),oyster (Crassostrea gigas) and mussel (Mytilus edulis) in a flow-through system were measured to understand the short-term response to various particle and organic matter concentrations.By comparing the RE of C.farreri with that of C.gigas and M.edulis,we gained further knowledge on the feeding physiological characteristics of C.farreri and ascertained the possible cause of high summer mortalities of this species.The experimental feeding conditions included natural differences in the abundance and composition of suspended seston,as well as conditions in which seston abundance and composition were manipulated by adding natural silt or cultured microalgae.The results show that in natural sea water,the minimum particle size for maximal retention in M.edulis,C.gigas and C.farreri was approximately 4,6,and 8 μm,respectively;the RE of 2-μm (equivalent spherical diameter) particles was 17%,19%,and 8%,respectively;and the relative standardized RE was 58%,49%,and 18%,respectively.In C.gigas and M.edulis,the minimal particle size for maximal retention did not change with food quality (organic content).C.farreri was more sensitive to fluctuations in particle concentration and organic content.With particle concentration increase,the minimal particle size for maximal retention in scallop shifted to large particles and the RE for 2-μm particle decreased from 8% in natural seawater to 1.6%-6% in silt-enriched groups.With organic content increase,the minimal particle size for maximal retention shifted from 8 to 5 μm in natural seawater.Variation in RE of C.farreri with food conditions and the relationship between lower RE and smaller particle size may hamper C.farreri from food taking due to the decrease in the size distribution of phytoplankton in Sungo Bay.

Experimental research on hydrophilic characteristics of natural soft rock at high stress state

In order to study features of rock–water interaction, a self-developed experimental system called Intelligent Testing System for Water Absorption in Deep Soft Rocks(ITSWADSR) was utilized to analyze the hydrophilic behaviors of natural soft rock at high stress state. Combining X-ray diffraction and mercury injection test, main influencing factors on hydrophilic characteristics were studied. According to the results, it could be concluded as the following:(1) the effective porosity, and the content of illite, illite/smectite formation(S = 5%) and kaolinite have positive correlation with the water absorption capacity of rock; meanwhile, the initial moisture content, fractal dimension of effective pores, illite/smectite formation(S = 30%) and chlorite present negative correlation;(2) among the positive factors, the ascending order is kaolinite, illite/smectite formation(S = 5%) and illite;(3) the descending order among the negative factors are chlorite, illite/smectite formation(S = 30%) and fractal dimension of the effective pores;(4) influence of effective porosity on the pressurized water absorbing capacity of rock is minimal, while it is maximal in the process of no pressurized water absorption.

Influence of A-type Zeolite on Methane Hydrate Formation

The porous medium has an important effect on hydrate formation.In this paper,the formation process and the gas storage capacity of the methane hydrate were investigated with A-type zeolite and Sodium Dodecyl Sulfate (SDS) existing in the system.The results show that A-type zeolite can influence methane hydrate formation.At the temperature of 273.5 K and pressure of 8.3 MPa,the distilled water with A-type zeolite can form methane hydrate with gaseous methane in 12 hours.The formation process of the system with A-type zeolite was quite steady and the amount of A-type zeolite can influence the gas storage capacity significantly.The adding of A-type zeolite with 0.067 g·(g water)-1 into 2×10-3 g·g-1 SDS-water solution can increase the gas storage capacity,and the maximum increase rate was 31%.Simultaneously the promotion effect on hydrate formation of 3A-type zeolite is much more obvious than that of 5A-type zeolite when the water adding amounts are 0.033 g·g-1 and 0.067 g·g-1 at the experimental conditions.

Sorption behavior of coal for implication in coal bed methane an overview

CBM has been recognized as a significant natural gas resource for a long time. Recently, CO_2 sequestration in coalbeds for ECBM has been attracting growing attention because of greater concerns about the effects of greenhouse gases and the emerging commercial significance of CBM. Reservoir-simulation technology,as a useful tool of reservoir development, has the capability to provide us with an economic means to solve complex reservoir-engineering problems with efficiency. The pore structure of coal is highly heterogeneous, and the heterogeneity of the pores depends on the coal type and rank.

Resistivity in Formation and Decomposition of Natural Gas Hydrate in Porous Medium

A new one-dimensional system for resistivity measurement for natural gas hydrate(NGH)exploitation is designed,which is used to study the formation and decomposition processes of NGH.The experimental results verify the feasibility of the measurement method,especially in monitoring the nucleation and growth of the NGH. Isovolumetric formation experiment of NGH is performed at 2°C and 7.8 MPa.Before the NGH formation,the initial resistivity is measured to be 4-7Ω·m,which declines to the minimum value of 2-3Ω·m when NGH begins to nucleate after the pressure is reduced to 3.3 MPa.As the NGH grows,the resistivity increases to a great extent,and finally it keeps at 11-13Ω·m,indicating the completion of the formation process.The NGH decomposition experiment is then performed.When the outlet pressure decreases,NGH begins to decompose,accordingly,the resistivity declines gradually,and is at 5-9Ω·m when the decomposition process ends,which is slightly higher than the resistivity value before the formation of NGH.The occurrence and distribution uniformity of NGH are determined by the distribution and magnitude of the resistivity measured on an one-dimensional sand-packed model.This study tackles the accurate estimation for the distribution of NGH in porous medium,and provides an experimental basis for further study on NGH exploitation in the future.

Porosity on External Surface of H-Clinoptilolite Sorption of CCI4 and n-C6H14

CCl4 （carbon tetrachloride） and n-C6H14 （n-hexane） sorption studies have been carried out on natural and dealuminated clinoptilolite-type zeolites. External surface area of the materials has been assessed using the αs-plots method. The high resolution αs-plots show that the isotherms are divided into four parts corresponding to adsorption in ultramicropores, intersections, supermicropores and external surface area, respectively. The mineralogies of natural zeolites are determined by X-ray analysis. N： low-pressure hysteresis loops, displayed by some substrata, are related to the micropore structure and to the ion-exchange treatment at which the natural precursors were subjected. The adsorption behavior of these substrata was examined in the range of relative pressures between 10^-5-1. Natural samples were used as reference materials to carry out the sorption analyses of the dealuminated samples. The effect of narrow micropore constrictions on the adsorption behavior of clinoptilolites was explored. The occurrence of a low-pressure hysteresis loop on the sorption isotherm of a modified sample is associated to the strong adsorption of the adsorbate molecules at the entrance of the necked-shape micropores, which interfere with the diffusion of the adsorbate molecules inside the porous structure.

船山注重五经说

先生箸述宏博。而独注重五经者。以是为孔子所删定也。汉氏所出多编。未经孔孟称述者。皆伪谬也。故后世称七经七纬。九经十二经十三经。先生未当肄业及之。盖尊守孔子而已。易书诗春秋。夫子手订成编。惟以礼为执。礼乐者。所以日率七十子。践履时习。而不可须斯离者也。自晨昏奉养。函丈趋承。临涖瞻视。常变交际。辞氣威仪之则。皆载之曲礼内则玉藻诸篇。其郊社禘当冠昏食丧之义。则有大传郊特牲礼连礼器乐记诸篇。皆夫子所示之执礼也。中庸大学祭丧冠昏诸义。则曾子子思。

Synthesis of Gas Transport through Nano Composite Ceramic Membrane for Esterification and Volatile Organic Compound Separations

The transport behaviour of carrier gases with inorganic catalytic ceramic membrane used for ethyl lactate production and VOC （volatile organic compound） recovery in the gauge pressure range of 0.10-1.00 bar and temperature range of 333 K was investigated. The gases include Ar （argon）, N2 （nitrogen） and CO2 （carbon dioxide）. The gas kinetic diameter with respect to permenace was found to occur in the order of At 〉 CO2 〉 N2, which was not in agreement with molecular sieving mechanism of transport after the first dip-coating of the support. However, gas flow rate was found to increase with gauge pressure in the order of Ar 〉 CO2 〉 N2, indicating Knudsen mechanism of transport. The porous ceramic support showed a higher flux indicating Knudsen transport. The surface image of the dip-coated porous ceramic membrane was characterised using SEM （scanning electron microscopy） to determine the surface morphology of the porous support at 333 K.

Separation of injectable salidroside by column chromatography of macroporous resins for treating myocardial ischemia

The objective of the present study is to develop a method for large-scale separating and purifying salidroside from rhodiola kirilowii roots and for preparing injectable medicinal ingredient.Crude extract of salidroside was prepared by water-ethanol system,and purified by column chromatography of macroporous resins.Static adsorption and desorption studies were performed on six kinds of macroporous resins,and SP825 resin was chosen,followed by optimizing process parameters.The optimum sample volume,feed concentration,ratio of diameter to height,and feeding flow rate were 1.5 bed volumes(BV),15 mg/mL,1:10 and 1 BV/h,respectively.Dynamic desorption was performed consecutively with 8 BV of distilled water,3 BV of 5% ethanol and 8 BV of 10% ethanol at a flow rate of 2 BV/h.After three cycles in separating 3.5 tons of rhodiola kirilowii roots,salidroside purity was increased from 3.4% in the crude extract to 93.6% in purified salidroside product.This study provides a novel method to separate salidroside for injectable use.

Factors influencing the porosity of gas hydrate bearing sediments

Porosity is a key parameter in calculating the velocity of gas hydrate bearing sediments and quantifying the amount of gas hydrate. The variation of porosity is affected by many factors. The influences of different factors on porosity are distinct. The purpose of this paper is to analyze the main factors that affect the overall and local change of porosity in marine sediments where gas hydrate was sampled. Porosity logs were collected from ODP Leg 164, Blake Ridge, ODP Leg 204, Hydrate Ridge, and IODP expedition 311, Cascadia Margin. Based on the characteristic of porosity variation in depth, porosity was divided into three components: low frequency component, middle frequency component, and high frequency component. The factors influencing each component were discussed. From the analysis, we observed that the porosity of unconsolidated sediment was very high, and the decreasing trend of low frequency component versus depth was affected by compaction. In addition, the initial porosity and slope of low frequency component variation were affected by the content of fine grain and geothermal gradient respectively. The middle component could reflect the variation of lithology, which was affected by the content variation of different sized grains and gas hydrate. The high frequency component was affected by the frequent change of grain size. The existence of volcanic ash-rich sand caused a high value to the high frequency component. The results are applicable to porosity evaluation in gas hydrate bearing sediments.

XFEM modeling of hydraulic fracture in porous rocks with natural fractures

Hydraulic fracture （HF） in porous rocks is a complex multi-physics coupling process which involves fluid flow, diffusion and solid deformation. In this paper, the extended finite element method （XFEM） coupling with Biot theory is developed to study the HF in permeable rocks with natural fractures （NFs）. In the recent XFEM based computational HF models, the fluid flow in fractures and interstitials of the porous media are mostly solved separately, which brings difficulties in dealing with complex fracture morphology. In our new model the fluid flow is solved in a unified framework by considering the fractures as a kind of special porous media and introducing Poiseuille-type flow inside them instead of Darcy-type flow. The most advantage is that it is very convenient to deal with fluid flow inside the complex frac^xre network, which is important in shale gas extraction. The weak formulation for the new coupled model is derived based on virtual work principle, which includes the XFEM formulation for multiple fractures and fractures intersection in porous media and finite element formulation for the unified fluid flow. Then the plane strain Kristianovic-Geertsma-de Klerk （KGD） model and the fluid flow inside the fracture network are simulated to validate the accuracy and applicability of this method. The numerical results show that large injection rate, low rock permeability and isotropic in-situ stresses tend to lead to a more uniform and productive fracture network.